NASA - National Aeronautics and Space Administration

TOGA measures volatile organic compounds (VOCs). TOGA was deployed with an Agilent quadrupole mass spectrometer from 2006 through 2018. Since 2019, the TOGA has been equipped with a TOFWERK high-resolution time-of-flight (HR-TOF) mass spectrometer detector (TOGA-TOF). Specific data will be obtained for radical precursors, tracers of anthropogenic and biogenic activities, tracers of urban and biomass combustion emissions, tracers of ocean emissions, products of oxidative processing, precursors to aerosol formation, and compounds important for aerosol modification and transformation. TOGA measures a wide range of VOCs with high sensitivity (low to sub-ppt), frequency (2 minutes or better), accuracy (20% or better), and precision (<3%). Over 100 species are routinely measured throughout the troposphere and lower stratosphere from the surface to 16 km or higher. See table for list of VOCs that have been quantified using TOGA and TOGA-TOF. The TOGA-TOF is contained in a dual extended HIAPER rack, weighs approximately 225 kg and consumes ~1 kW of power. The major components of the instrument are the inlet, cryogenic preconcentrator, gas chromatograph, time-of-flight mass spectrometer detector, zero air/calibration system, and the control/data acquisition system. All processes and data acquisition are computer controlled.

Principle: The CU aircraft version of the Aerodyne High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) detects non-refractory submicron aerosol composition by impaction on a vaporizer at 600°C, followed by electron ionization and time-of-flight mass spectral analysis. Size-resolved composition can be quantified by measuring the arrival times of the aerosol at the vaporizer.

Aircraft Operation: (1 min cycles, can be adjusted to meet mission goals):
46 s total concentration measurements (1 s resolution, can be increased to up to 10 Hz upon request)
5 s speciated size distribution measurements (with improved S/N detection due to ePToF acquisition)
9 s Background + Overhead
Higher accuracy due to flight day calibrations using built-in system
Custom pressure controlled inlet with confirmed performance up to 45 kft

Real Time Data Products: 
PM1 Aerosol Mass Concentrations:
Organic aerosol (OA) , SO4, NO3, NH4, Chloride 
OA Chemical Markers: f44 (Secondary OA), f57 (hydrocarbon-like OA), f60 (biomass burning OA), f82 (isoprene epoxide-SOA), other fx upon request

More Advanced Products:
- PM1 Seasalt, ClO4, total I, total Br, MSA concentrations
- O/C, H/C, OA/OC, OSc
- Particle organic nitrates (pRONO2)
- Ammonium Balance, estimated pH
- OA components by positive matrix factorization (PMF)
- Particle eddy covariance fluxes of all species
- Speciated Aerosol size distributions

Detection Limits (1s, ng sm-3), (1 min, ng sm-3) from start of the flight (due to custom cryopump):
Sulfate: 40, 15
Nitrate: 15, 6
Ammonium: 3, 1
Chloride: 30, 12
OA: 200, 80
For detailed OA analysis, longer averaging (3-30 s, depending on OA concentration) is needed. A 1 min product is hence provided as well.

The Unmanned Aircraft Systems (UAS) Chromatograph for Atmospheric Trace Species (UCATS) was designed and built for autonomous operation on remotely piloted aircraft, but has also been used on manned aircraft. It uses chromatography to separate atmospheric trace gases along narrow heated columns, followed by precise and accurate detection with electron capture detectors. There are currently three chromatography channels on UCATS, which measure nitrous oxide (N2O) and sulfur hexafluoride (SF6); CFC-11, CFC-12, CFC-113, and halon 1211; and chloroform (CHCl3) and carbon tetrachloride. On an earlier version of UCATS, with only two channels, we also measured methane, hydrogen, and carbon monoxide, along with N2O and SF6. In addition, there is a small ozone instrument and a tunable diode laser instrument for water vapor. Gas is pumped into the instruments from an inlet outside the aircraft, measured, and vented. UCATS has flown on the Altair UAS, the GV during HIPPO, the NASA Global Hawk UAS during the Global Hawk Pacific (GloPac) and ATTREX missions, where a record was set for the longest duration research flight (more than 28 hours), the DC-8 for ATom, and the ER-2 for DCOTSS. UCATS is relatively lightweight and compact, making it ideal for smaller platforms, but it is easily adaptable to a mid-size platform like the GV or Global Hawk. The data are used to measure sources and sinks of trace gases involved in climate and air quality, as well as transport through the atmosphere.

UCATS is three different instruments in one enclosure:

1. 3-channel (formerly 2-channel, up until 2020) gas chromatograph (GC)
2. Dual-beam ozone photometer (OZ)
3. Tunable diode laser (TDL) spectrometer for water vapor (WV)

As part of the measurement team on the NASA DC-8 we operate two related installations: a mist chamber/ion chromatograph (MC/IC) sampling/analysis system providing near real time results for selected species, and a bulk aerosol system that collects particulates onto filters for subsequent analysis. We use ion chromatography on aqueous extracts of the bulk aerosol samples collected on Teflon filters to quantify soluble ions (Cl^-, Br^-, NO3^-, SO4^2-, C2O4^2-, Na⁺, NH4⁺, K⁺, Ca⁺, and Mg⁺). Filters are exposed on all level flight legs. Below 3 km exposure times are 5 minutes or less, increasing at higher altitudes to a maximum sample time of 15 minutes. Aerosols participate in heterogeneous chemistry, impact radiative transfer, and can be detected from space. Our measurements help to validate and extend retrievals of aerosol distributions and properties by MODIS, MISR and CALIPSO. In addition, several of the particle-associated ions are tracers of sources of gas and aerosol pollutants (e.g., SO4^2- from industrial emissions of SO2, enhancements of C2O4^2-, K⁺, and NH4⁺ indicate encounters with biomass burning plumes, Na⁺, and Cl^- are tracers of seasalt, Mg²⁺ and Ca²⁺ are tracers of dust). Our system has two inlets, allowing collection of paired samples simultaneously.

The CIMS instrument consists of a low pressure ion molecule reactor (IMR) coupled to a quadrupole mass filter by an actively pumped collisional dissociation chamber (CDC) and an octopole ion guide. The vacuum system is a 100 mm outer diameter stainless steel chamber evacuated with two small turbo pumps (70 l s^-1). The mass filter is a set of 9.5 mm diameter quadrupole rods housed in the main vacuum chamber. The CDC is a short 80 mm diameter chamber that houses an octopole ion guide and is evacuated with a hybrid molecular drag pump. The IMR is evacuated with a scroll pump (300 l min^-1) that also serves as the backing pump for the mass spectrometer.

Click here for the Collaborative Ground and Airborne Observations description page.

The SP2 is a laser-induced incandescence instrument primarily used for measuring the refractory BC  (rBC) mass content of individual accumulation-mode aerosol particles. It is able to provide this data product independently of the total particle morphology and mixing state, and thus delivers detailed information not only about BC loadings, but also size distributions, even in exceptionally clean air. The instrument can also provide the optical size of individual particles containing rBC, and identify the presence of materials associated with the BC fraction (i.e. identify the rBC’s mixing state). Since its introduction in 2003, the SP2 has been substantially improved, and now can be considered a highly competent instrument for assessing BC loadings and mixing state in situ.  NOAA deploys multiple SP2s with different designs: the first was built for the WB-57F research aircraft. Two others are rack-mounted units customized at NOAA; one of the rack mounted units can be humidified, and has been deployed with a paired dry rack-mounted SP2 as the "Humidified-Dual SP2" (HD-SP2). The rack mounted units are suitable for in-cabin operations.

The UC-Irvine research group collected whole air samples aboard the NASA DC-8 aircraft during the summer 2019 NASA Fire Influence on Regional to Global Environments Experiment - Air Quality (FIREX-AQ) field mission. More than 70 trace gases were identified and quantified at our Irvine laboratory, including C2-C10 NMHCs, C1-C2 halocarbons, C1-C5 alkyl nitrates, and selected sulfur compounds using our established technique of airborne whole air sampling followed by laboratory analysis using gas chromatography (GC) with flame ionization detection (FID), electron capture detection (ECD), and mass spectrometric detection (MSD). Our experimental procedures build on those that have been successfully employed for numerous prior NASA field missions, for example PEM Tropics A and B, TRACE-P, INTEX-A and B, ARCTAS, DC-3, SEAC4RS, ATom, KORUS-AQ, FIREX-AQ, and SARP.

The NOAA PALMS instrument measures single-particle aerosol composition using UV laser ablation to generate ions that are analyzed with a time-of-flight mass spectrometer.  The PALMS size range is approximately 150 to >3000 nm and encompasses most of the accumulation and coarse mode aerosol volume. Individual aerosol particles are classified into compositional classes.  The size-dependent composition data is combined with aerosol counting instruments from Aerosol Microphysical Properties (AMP), the Langley Aerosol Research Group Experiment (LARGE), and other groups to generate quantitative, composition-resolved aerosol concentrations.  Background tropospheric concentrations of climate-relevant aerosol including mineral dust, sea salt, and biomass burning particles are the primary foci for the ATom campaigns.  PALMS also provides a variety of compositional tracers to identify aerosol sources, probe mixing state, track particle aging, and investigate convective transport and cloud processing.

*_Standard data products_**: *

Particle type number fractions: sulfate/organic/nitrate mixtures, biomass burning, EC, sea salt, mineral dust, meteoric, alkali salts, heavy fuel combustion, and other. Sampling times range from 1-5 mins.

*_Advanced data products_**:*

Number, surface area, volume, and mass concentrations of the above particle types. Total sulfate and organic mass concentrations. Relative and absolute abundance of various chemical markers and aerosol sub-components: methanesulfonic acid, sulfate acidity, organic oxidation level, iodine, bromine, organosulfates, pyridine, and other species.

PANTHER uses Gas Chromatography with Electron Capture Detection and (GC-ECD) and Gas Chromatography with Mass Selective Detection (GC-MSD) to measure numerous trace gases, including methyl halides, HCFCs, peroxyacetyl nitrate, nitrous oxide, SF6, CFC-12, CFC-11, Halon-1211, methyl chloroform, carbon tetrachloride.

3 ECDs with packed columns (OV-101, Porapak-Q, molecular sieve).

1 ECD with a TE (thermal electric) cooled RTX-200 capillary column.

2-channel MSD (mass selective detector). The MSD analyzes two independent samples air concentrated onto TE cooled Haysep traps, which are then heated to desorb the analytes and separate using through two temperature programmed RTX-624 capillary columns.

With the exception of PAN, all channels of chromatography are normalized to a stable in-flight calibration gas references to NOAA scales. The PAN data are normalized to an in-flight PAN source of ≈ 100 ppt with ±5 % reproducibility. This source is generated by efficient photolytic conversion of NO in the presence of acetone. Detector non-linearity is taken out by lab calibrations for all molecules.

The Meteorological Measurement System (MMS) is a state-of-the-art instrument for measuring accurate, high resolution in situ airborne state parameters (pressure, temperature, turbulence index, and the 3-dimensional wind vector). These key measurements enable our understanding of atmospheric dynamics, chemistry and microphysical processes. The MMS is used to investigate atmospheric mesoscale (gravity and mountain lee waves) and microscale (turbulence) phenomena. An accurate characterization of the turbulence phenomenon is important for the understanding of dynamic processes in the atmosphere, such as the behavior of buoyant plumes within cirrus clouds, diffusions of chemical species within wake vortices generated by jet aircraft, and microphysical processes in breaking gravity waves. Accurate temperature and pressure data are needed to evaluate chemical reaction rates as well as to determine accurate mixing ratios. Accurate wind field data establish a detailed relationship with the various constituents and the measured wind also verifies numerical models used to evaluate air mass origin. Since the MMS provides quality information on atmospheric state variables, MMS data have been extensively used by many investigators to process and interpret the in situ experiments aboard the same aircraft.