85 1001 ;header lines file format index ATLAS, ELLIOT University of Miami MIXING RATIOS FROM WHOLE AIR SAMPLER CR-AVE 1 1 ;vol total vol 2006 01 21 2007 06 05 ;DATE RDATE 0 ;DX(1) Elapsed UT seconds from 0 hours on T/O DATE ;UTMID 46 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ;scale factors 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 UTSTART (sec) ;MMS data UTSTOP (sec) ;MMS data CCl3F (pptv) CFC 11 CCl2F2 (pptv) CFC 12 C2ClF5 (pptv) CFC 115 C2Cl2F4 (pptv) CFC 114 C2Cl3F3 (pptv) CFC 113 CHClF2 (pptv) HCFC 22 CH3CCl2F (pptv) HCFC 141b CH3CClF2 (pptv) HCFC 142b CHCl2F (pptv) HCFC 21 C2HCl2F3 (pptv) HCFC 123 C2HClF4 (pptv) HCFC 124 C2H2F4 (pptv) HFC 134a C2H4F2 (pptv) HFC 152a CBrF3 (pptv) Halon 1301 CBrClF2 (pptv) Halon 1211 C2Br2F4 (pptv) Halon 2402 OCS (pptv) Carbonyl sulfide CH3Cl (pptv) Methyl chloride C2H5Cl (pptv) Ethyl chloride CH3Br (pptv) Methyl bromide CH3I (pptv) Methyl iodide CHCl3 (pptv) Chloroform CH2Cl2(pptv) Methylene chloride C2H4Cl2 (pptv) 1,2Dichloroethane CH3CCl3 (pptv) Methyl chloroform CCl4 (pptv) Carbon tetrachloride C2Cl4 (pptv) Perchlorethylene CH3ONO2 (pptv) Methyl nitrate C2H5ONO2 (pptv) Ethyl nitrate C3H7ONO2 (pptv) Isopropyl nitrate C3H7ONO2 (pptv) n-propyl nitrate C4H9ONO2 (pptv) 2-butyl nitrate CH2Br2 (pptv) Methylene bromide CHBr2Cl (pptv) Dibromochloromethane CHBr3 (pptv) Bromoform C2H6 (pptv) Ethane C2H2 (pptv) Ethyne C3H8 (pptv) Propane C4H10 (pptv) i-Butane C4H10 (pptv) n-Butane C6H6 (pptv) Benzene CH4 (ppbv) Methane N2O (ppbv) Nitrous Oxide CO (ppbv) Carbon monoxide 0 ;number of special comment lines (specific to this flight) 22 ;number of normal comment lines (occur each flight) UTSTART IS THE TIME THE CANISTER BEGAN FILLING UTMID IS THE AVERAGE OF THE START AND STOP TIMES UTSTOP IS THE TIME THE CANISTER FINISHED FILLING 0.0 - Concentration Below Detection Limit Negative mixing ratios for benzene are reported in cases when a small, constant blank value is subtracted from all the sample values. In previous missions, CO measurements from WAS appeared high in the lower stratosphere (O3>125 ppb) by 10-25 ppb due to canister artifacts. CRAVE data appear less affected by this artifact and are reported with no correction. Some trace gas data were deleted from the archive due to contamination associated with new canisters first used during the mission, and outliers associated with these canisters have been removed from the data set. Mixing ratios of CFCs 114 and 115 are undergoing recalibration, but data reported here is on the same scale as all prior NASA missions. Expected corrections will be approximately 1.25 for CFC115 and 1.15 for CFC114. Additional bromocarbon species were measured for a subset of the samples during CRAVE and are available on request from the PI. For questions, contact Elliot Atlas, RSMAS, University of Miami, Ph: 305-421-4128, e-mail: eatlas@rsmas.miami.edu UTMID UTSTART UTSTOP CFC_11 CFC_12 CFC_115 CFC_114 CFC_113 HCFC_22 HCFC_141b HCFC_142b HCFC_21 HCFC_123 HCFC_124 HFC_134a HFC_152a Halon_1301 Halon_1211 Halon_2402 OCS CH3Cl EtCl CH3Br CH3I CHCl3 CH2Cl2 1_2_dichloroethane CH3CCl3 CCl4 C2Cl4 MeONO2 EthONO2 i_PropONO2 n_PropONO2 2_ButylONO2 CH2Br2 CHClBr2 CHBr3 Ethane Ethyne Propane Isobutane n_Butane Benzene CH4_ppbv N2O_ppbv CO_ppbv 61052 61045 61059 252 531 6.61 14.3 79.3 168 18.2 16.9 0.2 0.15 0.77 37.2 3.9 2.63 4.13 0.49 467 556 0.31 7.97 0 8.09 15.7 3.46 16.1 95 1.19 7.94 1.59 0.97 0 0 0.95 0.11 0.74 487 72 45 2.4 4.7 6.6 1759 319.1 81 61358 61348 61368 251 537 6.9 14.5 79.1 169 17.9 16.7 0.19 0.26 0.82 37.1 3.4 2.85 4.08 0.45 473 590 0.22 8.34 0 6.59 12.9 1.77 15.4 94 0.61 1.77 0.28 0.17 0 0 0.61 0.04 0.1 492 86 32 1.2 2.9 1.2 1762 318.9 83 61670 61656 61684 251 534 6.5 14.5 79.6 168 17.9 16.7 0.19 0.1 0.79 36.4 3.6 2.52 4.09 0.47 486 563 0.22 8.06 0 6.36 12.3 1.38 14.4 95 0.43 2.3 0.22 0.09 0 0 0.53 0 0.08 382 45 19 0.9 2.4 0.6 1751 318.7 62 61991 61972 62010 252 536 6.73 14.6 79 169 17.8 17.2 0.18 0.22 0.84 35.7 3.7 2.42 4.03 0.42 494 560 0.23 7.9 0 6.16 12.4 1.42 14.1 94 0.36 2.35 0.21 0 0 0 0.51 0.05 0.08 343 37 13 0.5 2 0.7 1748 318.8 60 62321 62299 62342 250 533 6.8 14.6 82.8 167 99999 17.3 0.2 0.13 0.75 36.4 3.7 2.6 4.02 0.46 99999 542 0.17 99999 0.04 5.05 12.7 99999 99999 99999 0.18 99999 99999 99999 99999 99999 99999 99999 99999 340 33 13 0.3 0.7 1.7 1754 319.1 53 62373 62352 62394 251 534 6.8 14.4 79.1 168 17.6 16.4 0.19 0.12 0.81 36.9 3.7 2.55 4.13 0.41 496 545 0.26 8.04 0 5.23 11.9 1.21 13.4 94 0.26 1.48 0.14 0 0 0 0.46 0 0.05 348 31 12 0.7 1.5 0.1 1753 318.6 50 62703 62682 62724 252 537 6.95 14.4 79.4 170 17.7 16.8 0.21 0.15 0.87 36.6 3.3 2.55 4.06 0.45 488 553 0.2 7.86 0.06 5.5 12.1 1.05 13.7 95 0.26 1.59 0.07 0 0 0 0.43 0 0.06 339 29 10 0.6 2.2 4.5 1748 318.7 51 63037 63012 63061 250 535 6.89 14.3 80 167 17.4 16.5 0.18 0.14 0.83 36.8 3.8 2.66 4.07 0.45 481 550 0.23 7.85 0 4.74 11.6 0.81 13.4 95 0.19 1.3 0 0 0 0 0.35 0 0 316 29 10 0.4 1.6 0 1750 317.8 49 63376 63349 63403 245 518 6.2 14 78.5 165 17.2 16.1 0.19 0.12 0.9 34.5 3.3 2.13 3.9 0.44 429 532 0.21 7.55 0.05 4.38 10.7 0.61 13.2 92 0.16 0.93 0 0 0 0 0.29 0 0.03 281 9 6 0.6 1.9 -0.3 1741 316.3 44 63719 63692 63745 235 528 6.85 14.3 78.4 166 17.1 16.2 0.21 0.15 0.79 35.8 4 2.44 3.94 0.43 99999 556 99999 99999 0 4.69 11.3 1.04 13.3 86 0.1 1.39 99999 99999 99999 99999 0.37 0 0 226 18 7 1.5 2.9 0.7 1739 315.2 99999 64056 64033 64078 251 532 6.45 14.4 79.7 171 17.6 16.7 0.23 0.15 0.77 36.8 3.5 2.39 4.1 0.47 484 550 0.17 7.92 0 5.43 12.2 0.95 13.5 94 0.25 1.49 0 0 0 0 0.42 0 0 286 29 13 0.5 1.3 0.2 1752 318.6 56 64391 64366 64415 249 533 6.28 14.5 79.4 169 17.5 16.8 0.2 0.17 0.81 36.2 3.7 2.77 4.06 0.46 491 552 0.24 7.82 0 5.29 11.8 1.24 13.3 94 0.21 1.37 0.1 0 0 0 0.48 0 0 325 29 12 0 1.9 -0.1 1752 318 53 64732 64703 64760 248 533 6.57 14.3 78.2 170 17.4 16.6 0.21 0.09 0.76 36.4 3.6 2.14 4.06 0.46 454 538 0.23 7.75 0 4.73 11 0.78 13 93 0.13 0.89 0 0 0 0 0.34 0 0 269 20 6 0.6 2.1 0.5 1748 317.2 39 64868 64841 64895 250 534 6.75 14.5 79.1 172 17.4 16.2 0.21 0.16 0.8 37 3.7 2.44 4.13 0.44 483 547 0.39 7.88 0 5.13 11.4 1.05 13.1 95 0.18 1.14 0 0 0 0 0.4 0 0 298 23 8 0.6 2.2 0.4 1749 318.4 47 65042 65022 65062 249 534 6.68 14.3 76.1 99999 99999 16 0.16 0.09 0.77 36 3.3 2.63 4.16 99999 99999 99999 0 99999 0 99999 99999 99999 99999 99999 0.13 99999 99999 99999 99999 99999 99999 99999 99999 314 21 13 1 2.3 0.6 1749 319.7 51 65090 65071 65108 252 538 6.89 14.4 79.7 170 17.8 16.2 0.22 0.12 0.75 37.2 3.5 2.46 4.1 0.46 484 556 0.17 8.01 0 5.64 12 1.6 14.7 97 0.39 2.78 0.16 0 0 0 0.61 0 0 346 34 14 0.6 1 0.4 1752 319.1 52 65251 65236 65265 254 542 6.88 14.6 80.7 170 17.8 16.4 0.19 0.13 0.8 36.9 3.4 2.43 4.27 0.49 481 588 0.23 8.31 0 6.69 13.4 2.03 15.5 97 0.59 2.13 0.24 0 0 0 0.61 0 0.03 480 70 34 1.3 3.2 0.5 1765 319.5 72 65404 65392 65415 253 537 6.74 14.5 79.7 174 18.3 16.6 0.21 0.14 0.83 37.5 3.9 2.41 4.25 0.46 478 583 0.39 8.32 0 8.07 18.1 4.46 15.7 97 1.12 2.76 0.47 0.18 0 0 0.81 0.09 0.15 573 102 59 2.9 6.3 3.7 1773 319.8 78 65554 65542 65565 252 536 6.87 14.3 80.1 175 18.4 16.9 0.22 0.12 0.83 38.1 4.8 2.58 4.23 0.48 444 589 0.43 8.45 0.06 8.41 21 5.24 15.7 97 1.29 2.7 0.63 0.37 0 0 0.85 0.1 0.25 619 121 72 4.3 8.9 7.5 1777 319.7 86 65705 65692 65718 246 537 6.79 14.3 79 172 18.1 17 0.21 0.15 0.83 36.6 3.6 2.39 4.14 0.44 99999 99999 99999 8.84 0 7.85 18.4 4.4 14.8 94 0.97 3.51 99999 99999 99999 99999 0.81 0.07 0.21 569 86 63 4.4 10.4 3.1 1772 319.8 99999 65861 65845 65876 258 550 6.96 14.9 80.9 175 18.7 16.9 0.21 0.16 0.88 38.4 3.9 2.64 4.26 0.44 515 575 0.27 8.27 0 7.43 16.3 2.66 15 96 0.77 3.38 0.36 0.15 0 0 0.73 0.06 0.1 486 78 48 2.3 5.2 1.3 1763 319.6 65 66022 66003 66040 258 553 7.24 15 81.9 173 18.3 17.2 0.19 0.12 0.87 38 3.8 2.74 4.35 0.44 483 573 0.19 8.16 0.05 6.47 13.2 1.66 14.5 96 0.54 2.51 0.23 0.19 0 0 0.6 0 0.11 401 53 25 1 2.2 0.4 1755 319.4 61 66189 66168 66209 254 539 6.79 14.3 81.2 168 18.1 16.7 0.2 0.18 0.83 36.9 3.7 2.46 4.08 0.46 497 556 0.25 7.89 0 6.46 12.7 2 15.1 97 0.5 2.97 0.34 0.14 0 0 0.71 0.05 0.08 349 45 17 0.7 1.9 -0.1 1748 319.1 56 66362 66336 66388 253 543 7.03 14.4 78.7 170 17.8 16.8 0.19 0.07 0.81 36.7 3.6 2.59 4.14 0.4 496 552 0.2 7.92 0 5.31 12.2 0.86 12.9 92 0.24 1.45 0 0 0 0 0.39 0 0.05 316 31 11 0.4 0.6 -0.3 1750 318 46 66545 66515 66575 247 536 6.78 14.4 73.1 99999 99999 16.1 0.16 0.15 0.86 36.2 3.1 2.72 4.05 99999 99999 99999 0.09 99999 0 99999 99999 99999 99999 99999 0.07 99999 99999 99999 99999 99999 99999 99999 99999 304 29 8 0.6 0.8 0.4 1749 318.7 45 66616 66584 66648 250 535 6.96 14.3 78.2 166 17.6 16.5 0.19 0.08 0.88 35.9 3.1 2.71 4.02 0.43 478 542 0.2 7.85 0 3.96 9.8 0.39 12.6 91 0.11 0.91 0 0 0 0 0.21 0 0 279 27 7 0.5 1.4 -0.4 1746 317.7 36 66805 66776 66834 250 540 6.76 14.5 78.1 169 17.4 16.5 0.2 0.13 0.99 36.5 3.9 2.8 4.07 0.4 477 553 0.23 7.71 0 4.13 10.2 0.47 12.4 90 0.1 0.92 0 0 0 0 0.24 0 0 298 28 9 0.4 1.4 -0.1 1747 318.6 47 66990 66961 67019 245 525 6.43 14.2 76.8 168 17.1 16 0.18 0.15 0.78 35 3.4 2.5 3.99 0.43 472 539 0.19 7.79 0 4.15 10 0.44 12.2 90 0.11 1.04 0 0 0 0 0.24 0 0 306 22 9 0.8 2.4 -0.1 1749 318.4 44 67175 67146 67204 248 533 6.84 14.3 78.5 168 17.1 16.5 0.17 0.11 0.7 36.1 3.2 2.68 4.13 0.4 466 552 0.18 7.76 0.04 4.63 10.7 0.6 12.4 91 0.11 1.15 0 0 0 0 0.28 0 0 314 32 10 0 1.4 -0.1 1751 318.7 46 67521 67492 67550 244 535 6.9 14.4 77.7 170 17.2 16.4 0.18 0.12 0.8 35.9 3.2 2.63 4.13 0.4 99999 570 99999 99999 99999 4.92 10.9 0.7 12.2 86 0.12 99999 99999 99999 99999 99999 0.34 0 0 324 32 15 1.6 5 0.5 1749 319.5 99999 67869 67839 67899 249 534 6.84 14.4 77.7 170 17.2 15.9 0.2 0.13 0.83 35.3 3.2 2.59 4.1 0.44 442 546 0.19 7.88 0 4.73 10.9 0.64 12.3 91 0.14 1.19 0 0 0 0 0.31 0 0.03 314 27 10 0.6 2.1 0 1749 318.8 46 68223 68186 68259 246 533 6.64 14.3 78.5 168 17.4 16.3 0.2 0.11 0.69 34.9 3.2 2.41 4 0.42 417 540 0.2 7.67 0 4 9.9 0.44 12.8 91 0.09 0.8 0 0 0 0 0.22 0 0 260 20 7 0.5 2.3 0.1 1747 317.4 42 68591 68547 68634 246 532 6.82 14.3 78.5 170 17.2 16 0.18 0.15 0.7 35.4 3.1 2.51 3.93 0.41 463 539 0.17 7.47 0 3.53 9.3 0.3 12.2 90 0.08 0.52 0 0 0 0 0.16 0 0 219 24 8 0.4 1.1 -0.1 99999 99999 99999 68968 68922 69013 245 529 6.71 14.2 77.8 167 17.1 15.6 0.19 0.15 0.75 33.8 2.9 2.37 3.82 0.45 437 535 0.2 7.43 0 3.15 9.1 0.19 11.8 89 0.05 0.52 0 0 0 0 0.11 0 0 196 12 4 0.4 1.2 0 1742 316.1 36 69456 69403 69509 242 529 6.74 14.1 76.6 165 16.9 16.2 0.19 0.13 0.81 34.4 3.2 2.44 3.87 0.38 459 526 0.2 7.32 0 2.17 7.1 0.96 11.3 87 0 0.4 0 0 0 0 0.06 0 0 184 15 3 0.5 1 -0.1 1738 315.1 38 69841 69797 69885 242 529 6.65 14.2 76 168 16.9 16.1 0.17 0.08 0.79 34.3 3.2 2.45 3.87 0.39 464 529 0.19 7.21 0 1.87 6.1 0.93 10.9 88 0 0.26 0 0 0 0 0.06 0 0 176 8 3 0.4 1.7 0.1 1741 315 35 70218 70173 70263 243 533 8.28 14.4 76.9 168 17.1 16.4 0.21 0.08 0.9 34.5 3.6 2.96 3.78 0.4 424 532 0.34 7.45 0.06 2.35 5.7 0.83 10.7 87 99999 0.35 0 0.12 0 0.21 0 0 0 167 15 3 2.3 8.4 0.7 1738 314.7 35 70598 70551 70645 243 533 7.68 14.5 77.9 169 16.9 16.4 0.18 0.12 0.82 35.7 3.5 2.78 3.84 0.4 453 529 0.19 7.19 0 1.82 5.7 0.89 10.6 87 0.05 0.34 0 0 0 0 0.05 0 0 147 10 2 0.4 1.6 1.9 1737 314.2 32 70980 70933 71026 238 531 7.46 14.6 77.5 168 17.1 16.9 0.2 0.1 0.86 33.9 3 2.82 3.67 0.38 99999 535 99999 8.15 99999 1.75 5.7 0.96 10.3 99999 0.05 99999 99999 99999 99999 99999 0.07 0 0 129 16 5 1.5 4.4 0.4 1737 314.2 99999 71360 71314 71405 241 528 7.55 14.4 77.6 168 17.1 16.7 0.17 0.08 0.78 34 3.2 2.83 3.7 0.39 437 523 0.21 6.97 0 1.5 5.3 0.87 10.4 87 0 0.3 0 0 0 0 0 0 0 114 7 2 0.5 2 -0.3 1733 313 33 71738 71693 71783 238 526 6.84 14.2 77.9 165 17.1 16.2 0.17 0.09 0.81 34.8 2.7 2.57 3.64 0.41 438 515 0.15 6.93 0 1.38 4.9 0.83 10.5 88 0 0.23 0 0 0 0 0.07 0 0 108 7 2 0.5 3.1 -0.2 1731 312.9 28 72119 72072 72166 238 525 7.29 14.4 77.3 164 17 16.5 0.19 0.08 0.74 34.5 3 2.66 3.64 0.39 451 515 0.16 6.91 0 1.25 4.8 0.88 10.4 87 0 0.28 0 0 0 0 0.04 0 0 105 6 2 0.6 3 -0.1 1729 312.6 26 72500 72453 72547 236 516 6.86 14.3 76.2 165 16.5 15.9 0.19 0.11 0.8 33.8 3.3 2.09 3.66 0.38 425 510 0.16 7.01 0 1.31 4.7 0.81 10 86 0 0.23 0 0 0 0 0 0 0 101 5 2 0.7 4.5 -0.2 1730 312.4 29 72884 72835 72932 238 529 7.14 14.4 74.5 99999 99999 16.2 0.18 0.06 0.78 34.7 2.8 2.23 3.59 0.36 99999 99999 0.09 99999 0 99999 99999 99999 99999 99999 0 99999 99999 99999 99999 99999 99999 99999 99999 102 5 2 0.4 0.8 0.3 1730 312.8 30 73003 72941 73065 238 521 6.98 14.1 76.3 166 16.9 16.1 0.18 0.1 0.85 34.6 3.1 2.12 3.59 0.36 386 510 0.16 6.89 0 1.27 5.1 0.9 10.3 85 0 0.16 0 0 0 0 0 0 0 99 7 2 0.6 1.7 -0.2 1728 311.8 28 73401 73352 73449 237 521 6.94 14.1 76.4 165 16.8 16 0.18 0.1 0.83 34.2 3.2 2 3.63 0.38 432 510 0.16 6.93 0 1.2 5 0.79 10.3 86 0.05 0.23 0 0 0 0 0 0 0 95 6 2 0.8 2.7 0.1 1728 310.8 31 73787 73737 73836 237 520 6.95 14.4 76.7 163 17 16.5 0.17 0.13 0.84 34.3 3.3 2.24 3.59 0.42 428 506 0.13 6.94 0 1.09 4.8 0.83 10.2 86 0 0.25 0 0 0 0 0 0 0 95 7 2 0.5 0.8 -0.2 1723 310.9 27 74116 74073 74158 237 521 7.05 14.3 76.9 164 16.6 16 0.2 0.1 0.86 34.1 3.3 2.27 3.65 0.4 441 508 0.14 6.95 0 1.17 5 0.87 10.1 86 0 0.31 0 0 0 0 0 0 0 108 8 2 0.6 1.8 0 1727 311.8 27 74341 74316 74365 239 527 6.75 14.3 77.7 169 16.9 16.5 0.18 0.11 0.79 34.9 3.4 2.29 3.8 0.41 523 542 99999 8.21 99999 99999 7.5 99999 11 83 0.07 99999 99999 99999 99999 99999 0.12 0 0 222 21 11 1.2 4.8 1 1742 315.4 99999