46 1001 ;header lines file format index HEIDT/VEDDER NCAR/NASA MIXING RATIOS FROM WHOLE AIR SAMPLER AASE II 1 1 ;vol total vol 1991 11 02 1993 07 18 ;flight date date of submission to archive 0 ;non uniform time increment UT SECONDS CONTINUOUS FROM T/O DATE ;UT is independent variable 16 ;number of primary variables 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ;scale factors 99.99 99.99 999.99 999 999.9 9.99 999.9 999.9 999.9 999.9 999.9 999.9 99.9 999.9 999.9 99999 ALT (km) P.ALT ;MMS data pressure altitude LAT (deg N) N.LAT ;MMS data LONG (deg W) ;MMS data THETA (deg K) P.T. ;MMS data CO2 (ppmv) ;overall error ~ 1% CH4 (ppmv) ;overall error ~ 50 ppbv N2O (ppbv) ;overall error ~ 5% CCl2F2 (pptv) F12 ;overall error ~ 6% CCl3F (pptv) F11 ;overall error ~ 7% CHClF2 (pptv) F22 ;overall error ~ 5% CH3Cl(pptv) ;overall error ~8% C2Cl3F3 (pptv) F113 ;overall error ~ 4% CHCl3(pptv) ;overall error ~ 3% CH3CCl3 (pptv) ;overall error ~ 3% CCl4 (pptv) ;overall error ~ 5% Flag column ;see comment section for key 4 ;number of special comment lines (specific to this flight) Flight 92-021 Sample # 4 valve did not seal Only 17 samples taken Samples #13-17 (the last five samples) appear to be from an urban plume. 12 ;number of normal comment lines (occur each flight) UT IS TIME CANISTER IS HALF FULL; 0.0 - Concentration Below Detection Limit; None of the AASE II ER-2 flights contain CO values due to apparent contamination. Based on the relationships between CH3CCl3 "(and CCl4) and CFC 11 and between CH3CCl3 (and CCl4) and CH4, we estimate approximately10% of all " "samples showed apparent loss of CH3CCl3 in cans, and approximately 14% of all samples showed apparent" loss of CCl4 in cans. Most of the samples showing apparent loss of CH3CCl3 were from Oct-Dec flights. Over half of the samples showing apparent loss of CCl4 were during dives and descents. Specific samples we feel contain the most suspect CH3CCl3 and CCl4 values are flagged in the last column of the data set. "A value of 10000 indicates suspect CCl4, 20000 indicates suspect CH3CCl3, and 30000 indicates both are " suspect. A value of 1000 indicates a flag was not placed on the sample. Please note we have flagged only those samples we consider most suspect. "N2O, CFC 11, and CFC 12 were recalculated based on revised calibration curves." UTIME P.ALT N.LAT LONG P.T. CO2 CH4 N2O F12 F11 F22 CH3Cl F113 CHCl3 CH3CCl3 CCl4 flag 69792 20.13 43.71 74.56 505 349.3 1.31 999.9 317.9 115.1 61.7 210.6 26.2 0.0 9.5 9.5 1000 69992 20.21 43.83 74.04 506 347.7 1.30 999.9 313.0 114.9 63.1 189.2 31.4 0.0 9.7 22.1 1000 70204 20.32 43.95 73.48 507 343.3 1.42 999.9 367.0 152.2 75.9 253.2 39.8 0.0 12.7 30.5 1000 70566 19.24 44.26 72.60 483 353.8 1.43 999.9 369.6 167.0 73.3 272.2 42.7 0.0 16.2 29.3 1000 70791 18.05 44.54 72.11 456 356.0 1.50 999.9 407.8 197.0 78.6 313.8 49.0 0.0 28.1 34.1 1000 71017 16.87 44.81 71.62 427 354.4 1.61 999.9 444.5 238.7 82.6 383.2 58.7 0.6 53.2 39.2 20000 71242 16.15 45.01 71.11 411 350.3 1.64 999.9 477.2 273.5 93.3 447.0 65.7 1.4 78.3 87.5 1000 71468 15.13 45.00 70.53 391 342.1 1.67 999.9 490.4 288.1 96.0 465.0 67.6 2.2 91.4 90.7 1000 71693 13.94 44.93 69.94 375 353.8 1.69 999.9 501.9 297.7 94.1 489.8 70.1 3.1 106.0 88.7 1000 71918 10.60 44.89 69.43 330 358.1 1.78 999.9 544.5 314.9 104.1 516.2 77.6 7.9 141.3 104.2 1000 72143 5.25 44.81 68.94 313 351.7 1.79 999.9 553.1 321.9 107.3 535.4 77.5 9.8 148.3 104.5 1000 72369 1.02 44.71 68.59 999 365.1 1.87 999.9 583.2 359.0 155.8 518.2 91.6 18.9 256.8 104.7 1000 72595 0.89 44.70 68.37 999 361.5 1.85 999.9 588.4 358.6 173.8 558.6 93.2 21.2 266.3 114.2 1000 72821 0.96 44.81 68.41 999 358.6 1.83 999.9 574.7 334.7 146.1 502.6 86.7 21.0 224.4 105.1 1000 73046 0.48 44.80 68.70 999 359.4 1.84 999.9 565.8 332.5 133.4 560.9 85.2 21.9 193.4 112.8 1000 73274 0.05 44.80 68.70 999 357.4 1.83 999.9 556.9 323.7 127.4 513.6 85.5 22.9 189.1 112.3 1000