56, 1001 HINTSA, ERIC; MOORE, FRED; DUTTON, GEOFF; HALL, BRAD; NANCE, DAVID; ELKINS, JAMES NOAA/ESRL/GMD and University of Colorado, CIRES UCATS Gas Chromatograph ATTREX-3 1, 1 2013, 12, 20, 2015, 08, 27 0 Start_UTC, seconds, ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON FLIGHT DATE TO START OF SAMPLING 11 1.0, 1.0, 1.0, 1.0, 1.0, 1.0, 1.0, 1.0, 1.0, 1.0, 1.0 -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999 Stop_UTC, seconds, elapsed time in GMT on flight date to end of sampling N2O, DRY MOLE FRACTION MIXING RATIO (PPB) N2Oe, ERROR 1-s (PPB) SF6, DRY MOLE FRACTION MIXING RATIO (PPT) SF6e, ERROR 1-s (PPT) CH4, DRY MOLE FRACTION MIXING RATIO (PPB) CH4e, ERROR 1-s (PPB) H2, DRY MOLE FRACTION MIXING RATIO (PPB) H2e, ERROR 1-s (PPB) CO, DRY MOLE FRACTION MIXING RATIO (PPB) COe, ERROR 1-s (PPB) 11 Error estimates are based on in-flight measurement precision of a calibration standard, the precision of laboratory measurements of a suite of calibration standards, and the goodness of fit of a simple curve to calibration data. Timestamps are the times of injection of the air samples into the GC. No timestamp adjustments have been made to account for the transit time of sample air through the aircraft inlet and pump. If you use this data in a publication or report, we would appreciate that you contact the principal investigators (PIs) first and discuss your interests. The PIs can discuss the quality of the data and any potential problems with its analysis. Please contact the PIs for more information. 20 PI_CONTACT_INFO: NOAA/ESRL/GMD, 325 Broadway, Boulder, CO; email: Eric.J.Hintsa@noaa.gov, James.W.Elkins@noaa.gov PLATFORM: Global Hawk LOCATION: Aircraft location in separate file ASSOCIATED_DATA: MMS-FlightPath INSTRUMENT_INFO: UCATS Gas Chromatograph DATA_INFO: Units for N2O, CH4, H2, and CO are ppb; units for SF6 are ppt UNCERTAINTY: Uncertainty is described above, and provided for each measurement ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Geoff Dutton, NOAA, geoff.dutton@noaa.gov PROJECT_INFO: ATTREX-3, December 2013-March 2014 STIPULATIONS_ON_USE: Please contact the PIs OTHER_COMMENTS: N/A REVISION: R2 R0: Preliminary data. No time adjustments have been made. R1: Revised data and calibrations. CO data removed for ozone > ~300 ppb R2: Final data. Calibration standards reanalyzed and updated calibration curves applied. Corrected for drift in H2. Start_UTC, Stop_UTC, N2O, N2Oe, SF6, SF6e, CH4, CH4e, H2, H2e, CO, COe 72528.0, 72531.0, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, 85.1, 2.2 72668.0, 72671.0, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, 88.6, 2.2 72808.0, 72811.0, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, 84.8, 2.2 73088.0, 73091.0, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, 102.2, 2.2 73228.0, 73231.0, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, 86.8, 2.2 73368.0, 73371.0, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, 87.0, 2.2 73648.0, 73651.0, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, 88.5, 2.2 73788.0, 73791.0, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, 88.1, 2.2 73928.0, 73931.0, -99999, -99999, -99999, -99999, -99999, -99999, -99999, -99999, 92.9, 2.2 74138.0, 74141.0, 326.8, 0.9, 8.26, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 74208.0, 74211.0, 325.2, 0.9, 8.18, 0.06, 1853.8, 4.3, 512.0, 2.3, 75.8, 2.2 74278.0, 74281.0, 324.8, 0.9, 8.30, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 74348.0, 74351.0, 324.9, 0.9, 8.23, 0.06, 1840.5, 4.3, 511.0, 2.3, 87.5, 2.2 74418.0, 74421.0, 324.4, 0.9, 8.18, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 74488.0, 74491.0, 326.3, 0.9, 8.28, 0.06, 1849.7, 4.3, 518.0, 2.3, 91.4, 2.2 74558.0, 74561.0, 325.4, 0.9, 8.23, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 74698.0, 74701.0, 325.1, 0.9, 8.26, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 74768.0, 74771.0, 325.0, 0.9, 8.23, 0.06, 1846.5, 4.3, 518.1, 2.3, 85.3, 2.2 74838.0, 74841.0, 325.3, 0.9, 8.15, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 74908.0, 74911.0, 324.8, 0.9, 8.15, 0.06, 1838.0, 4.3, 516.6, 2.3, 65.7, 2.2 74978.0, 74981.0, 324.4, 0.9, 8.14, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 75048.0, 75051.0, 324.4, 0.9, 8.11, 0.06, 1828.5, 4.3, 517.1, 2.3, 64.7, 2.2 75118.0, 75121.0, 322.4, 0.9, 7.99, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 75258.0, 75261.0, 318.2, 0.9, 7.94, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 75328.0, 75331.0, 314.5, 0.9, 7.87, 0.06, 1780.3, 4.3, 525.6, 2.3, 34.6, 2.2 75398.0, 75401.0, 314.0, 0.9, 7.82, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 75468.0, 75471.0, 314.4, 0.9, 7.92, 0.06, 1798.5, 4.3, 528.2, 2.3, 35.5, 2.2 75538.0, 75541.0, 312.8, 0.9, 7.85, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 75608.0, 75611.0, 311.7, 0.9, 7.75, 0.06, 1767.1, 4.3, 529.2, 2.3, 37.9, 2.2 75678.0, 75681.0, 312.1, 0.9, 7.81, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 75818.0, 75821.0, 313.3, 0.9, 7.87, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 75888.0, 75891.0, 305.6, 0.9, 7.75, 0.06, 1752.8, 4.3, 530.9, 2.3, 33.1, 2.2 75958.0, 75961.0, 304.8, 0.9, 7.72, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 76028.0, 76031.0, 302.8, 0.9, 7.71, 0.06, 1715.0, 4.3, 532.2, 2.3, 25.1, 2.2 76098.0, 76101.0, 300.0, 0.9, 7.63, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 76168.0, 76171.0, 300.7, 0.9, 7.72, 0.06, 1706.9, 4.3, 530.4, 2.3, -99999, -99999 76238.0, 76241.0, 294.5, 0.9, 7.55, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 76378.0, 76381.0, 293.4, 0.9, 7.57, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 76448.0, 76451.0, 292.3, 0.9, 7.52, 0.06, 1670.7, 4.3, 528.7, 2.3, -99999, -99999 76518.0, 76521.0, 293.3, 0.9, 7.62, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 76588.0, 76591.0, 283.1, 0.9, 7.47, 0.06, 1620.0, 4.3, 538.7, 2.3, -99999, -99999 76658.0, 76661.0, 280.0, 0.9, 7.36, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 76728.0, 76731.0, 282.4, 0.9, 7.51, 0.06, 1625.4, 4.3, 531.1, 2.3, -99999, -99999 76798.0, 76801.0, 266.6, 0.9, 7.28, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 76938.0, 76941.0, 271.9, 0.9, 7.28, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 77008.0, 77011.0, 268.6, 0.9, 7.20, 0.06, 1569.2, 4.3, 538.4, 2.3, -99999, -99999 77078.0, 77081.0, 270.4, 0.9, 7.27, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 77148.0, 77151.0, 272.1, 0.9, 7.24, 0.06, 1569.7, 4.3, 535.6, 2.3, -99999, -99999 77218.0, 77221.0, 271.3, 0.9, 7.36, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 77288.0, 77291.0, 271.3, 0.9, 7.27, 0.06, 1579.4, 4.3, 539.4, 2.3, -99999, -99999 77358.0, 77361.0, 268.1, 0.9, 7.27, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 77498.0, 77501.0, 265.9, 0.9, 7.31, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 77568.0, 77571.0, 265.6, 0.9, 7.23, 0.06, 1558.4, 4.3, 539.0, 2.3, -99999, -99999 77638.0, 77641.0, 266.1, 0.9, 7.13, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 77708.0, 77711.0, 266.9, 0.9, 7.26, 0.06, 1557.1, 4.3, 535.8, 2.3, -99999, -99999 77778.0, 77781.0, 267.9, 0.9, 7.29, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 77848.0, 77851.0, 268.1, 0.9, 7.28, 0.06, 1561.2, 4.3, 537.7, 2.3, -99999, -99999 77918.0, 77921.0, 266.3, 0.9, 7.23, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 78058.0, 78061.0, 266.7, 0.9, 7.25, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 78128.0, 78131.0, 264.9, 0.9, 7.29, 0.06, 1550.0, 4.3, 537.8, 2.3, -99999, -99999 78198.0, 78201.0, 266.4, 0.9, 7.27, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 78268.0, 78271.0, 266.3, 0.9, 7.12, 0.06, 1564.5, 4.3, 535.2, 2.3, -99999, -99999 78338.0, 78341.0, 267.4, 0.9, 7.25, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 78408.0, 78411.0, 268.4, 0.9, 7.28, 0.06, 1557.5, 4.3, 536.8, 2.3, -99999, -99999 78478.0, 78481.0, 267.3, 0.9, 7.20, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 78618.0, 78621.0, 266.3, 0.9, 7.07, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 78688.0, 78691.0, 267.3, 0.9, 7.25, 0.06, 1558.5, 4.3, 536.6, 2.3, -99999, -99999 78758.0, 78761.0, 266.6, 0.9, 7.18, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 78828.0, 78831.0, 263.4, 0.9, 7.13, 0.06, 1551.3, 4.3, 542.1, 2.3, -99999, -99999 78898.0, 78901.0, 265.5, 0.9, 7.25, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 78968.0, 78971.0, 259.6, 0.9, 7.21, 0.06, 1523.8, 4.3, 537.5, 2.3, -99999, -99999 79038.0, 79041.0, 268.9, 0.9, 7.29, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 79178.0, 79181.0, 262.3, 0.9, 7.15, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 79248.0, 79251.0, 265.5, 0.9, 7.24, 0.06, 1555.5, 4.3, 539.2, 2.3, -99999, -99999 79318.0, 79321.0, 277.0, 0.9, 7.36, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 79388.0, 79391.0, 266.3, 0.9, 7.21, 0.06, 1559.9, 4.3, 539.6, 2.3, -99999, -99999 79458.0, 79461.0, 266.3, 0.9, 7.29, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 79528.0, 79531.0, 267.4, 0.9, 7.27, 0.06, 1567.7, 4.3, 534.4, 2.3, -99999, -99999 79598.0, 79601.0, 262.9, 0.9, 7.20, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 79738.0, 79741.0, 270.2, 0.9, 7.22, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 79808.0, 79811.0, 263.1, 0.9, 7.17, 0.06, 1545.5, 4.3, 535.1, 2.3, -99999, -99999 79878.0, 79881.0, 261.6, 0.9, 7.18, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 79948.0, 79951.0, 270.7, 0.9, 7.30, 0.06, 1588.5, 4.3, 539.3, 2.3, -99999, -99999 80018.0, 80021.0, 268.5, 0.9, 7.33, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 80088.0, 80091.0, 264.4, 0.9, 7.16, 0.06, 1556.8, 4.3, 536.4, 2.3, -99999, -99999 80158.0, 80161.0, 269.0, 0.9, 7.34, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 80298.0, 80301.0, 264.5, 0.9, 7.30, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 80368.0, 80371.0, 260.6, 0.9, 7.26, 0.06, 1540.3, 4.3, 539.3, 2.3, -99999, -99999 80438.0, 80441.0, 260.3, 0.9, 7.18, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 80508.0, 80511.0, 259.2, 0.9, 7.23, 0.06, 1530.3, 4.3, 538.4, 2.3, -99999, -99999 80578.0, 80581.0, 264.6, 0.9, 7.24, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 80648.0, 80651.0, 264.5, 0.9, 7.26, 0.06, 1559.9, 4.3, 538.8, 2.3, -99999, -99999 80718.0, 80721.0, 263.9, 0.9, 7.27, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 80858.0, 80861.0, 273.0, 0.9, 7.37, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 80928.0, 80931.0, 267.1, 0.9, 7.30, 0.06, 1560.7, 4.3, 542.3, 2.3, -99999, -99999 80998.0, 81001.0, 263.0, 0.9, 7.12, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 81068.0, 81071.0, 263.9, 0.9, 7.23, 0.06, 1549.8, 4.3, 542.5, 2.3, -99999, -99999 81138.0, 81141.0, 261.3, 0.9, 7.21, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 81208.0, 81211.0, 263.7, 0.9, 7.38, 0.06, 1549.1, 4.3, 539.7, 2.3, -99999, -99999 81278.0, 81281.0, 262.4, 0.9, 7.23, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 81418.0, 81421.0, 281.6, 0.9, 7.47, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 81488.0, 81491.0, 266.8, 0.9, 7.38, 0.06, 1582.6, 4.3, 534.4, 2.3, -99999, -99999 81558.0, 81561.0, 270.1, 0.9, 7.35, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 81628.0, 81631.0, 263.1, 0.9, 7.27, 0.06, 1547.1, 4.3, 536.6, 2.3, -99999, -99999 81698.0, 81701.0, 259.1, 0.9, 7.25, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 81768.0, 81771.0, 260.4, 0.9, 7.18, 0.06, 1531.5, 4.3, 535.9, 2.3, -99999, -99999 81838.0, 81841.0, 270.5, 0.9, 7.44, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 81978.0, 81981.0, 268.8, 0.9, 7.39, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 82048.0, 82051.0, 273.4, 0.9, 7.37, 0.06, 1593.0, 4.3, 527.7, 2.3, -99999, -99999 82118.0, 82121.0, 280.0, 0.9, 7.37, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 82188.0, 82191.0, 270.9, 0.9, 7.30, 0.06, 1578.2, 4.3, 536.4, 2.3, -99999, -99999 82258.0, 82261.0, 264.9, 0.9, 7.36, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 82328.0, 82331.0, 266.2, 0.9, 7.21, 0.06, 1565.5, 4.3, 531.1, 2.3, -99999, -99999 82398.0, 82401.0, 265.0, 0.9, 7.32, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 82538.0, 82541.0, 264.8, 0.9, 7.21, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 82608.0, 82611.0, 272.9, 0.9, 7.26, 0.06, 1583.6, 4.3, 535.9, 2.3, -99999, -99999 82678.0, 82681.0, 280.7, 0.9, 7.47, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 82748.0, 82751.0, 284.1, 0.9, 7.41, 0.06, 1647.1, 4.3, 531.3, 2.3, -99999, -99999 82818.0, 82821.0, 272.7, 0.9, 7.36, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 82888.0, 82891.0, 265.6, 0.9, 7.26, 0.06, 1557.6, 4.3, 537.4, 2.3, -99999, -99999 82958.0, 82961.0, 270.9, 0.9, 7.26, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 83098.0, 83101.0, 272.8, 0.9, 7.43, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 83168.0, 83171.0, 264.3, 0.9, 7.26, 0.06, 1557.3, 4.3, 533.9, 2.3, -99999, -99999 83238.0, 83241.0, 274.8, 0.9, 7.37, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 83308.0, 83311.0, 279.8, 0.9, 7.46, 0.06, 1625.9, 4.3, 533.0, 2.3, -99999, -99999 83378.0, 83381.0, 282.1, 0.9, 7.45, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 83448.0, 83451.0, 270.6, 0.9, 7.28, 0.06, 1582.5, 4.3, 534.4, 2.3, -99999, -99999 83518.0, 83521.0, 273.9, 0.9, 7.41, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 83658.0, 83661.0, 272.1, 0.9, 7.41, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 83728.0, 83731.0, 277.1, 0.9, 7.38, 0.06, 1608.8, 4.3, 539.6, 2.3, -99999, -99999 83798.0, 83801.0, 277.5, 0.9, 7.40, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 83868.0, 83871.0, 284.9, 0.9, 7.59, 0.06, 1642.9, 4.3, 544.8, 2.3, -99999, -99999 83938.0, 83941.0, 278.3, 0.9, 7.39, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 84008.0, 84011.0, 279.2, 0.9, 7.26, 0.06, 1614.0, 4.3, 535.4, 2.3, -99999, -99999 84078.0, 84081.0, 276.7, 0.9, 7.36, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 84218.0, 84221.0, 277.9, 0.9, 7.35, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 84288.0, 84291.0, 280.2, 0.9, 7.43, 0.06, 1624.8, 4.3, 536.7, 2.3, -99999, -99999 84358.0, 84361.0, 277.8, 0.9, 7.43, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 84428.0, 84431.0, 278.8, 0.9, 7.32, 0.06, 1620.0, 4.3, 537.9, 2.3, -99999, -99999 84498.0, 84501.0, 277.5, 0.9, 7.33, 0.06, -99999, -99999, -99999, -99999, -99999, -99999 84568.0, 84571.0, 279.7, 0.9, 7.42, 0.06, 1626.9, 4.3, 536.6, 2.3, -99999, -99999 84638.0, 84641.0, 284.8, 0.9, 7.49, 0.06, -99999, -99999, -99999, -99999, -99999, -99999