40 1001 Cohen, Ronald University of California, Berkeley TD-LIF: Thermal Dissociation - Laser Induced Fluorescence of nitrogen dioxide and PANs TC4 1 1 2007 08 06 2011 09 07 0 start_UTC, s 6 1 1 1 1 1 1 999999 999999 999999 999999 999999 999999 stop_UTC, s mid_UTC, s NO2, pptv {NO2 (unheated channel)} NO2_sigma {variance of fast data over these time periods} PNs, pptv {Total Peroxynitrates = 200 C channel - unheated channel} PNs_sigma 0 20 PI_CONTACT_INFO: Address: Chemistry Department, University of California, Berkeley, CA 94720; cohen@cchem.berkeley.edu; 510-642-2357 PLATFORM: NASA DC-8 LOCATION: DC8_AIRCRAFT ASSOCIATED_DATA: N/A INSTRUMENT_INFO: NO2 laser induced fluorescence following thermal dissociation of nitrooxy compounds DATA_INFO: All data in pptv. Measurement cycle is 20 seconds on, 5 seconds off at approximately 1 Hz. UNCERTAINTY: estimate of NO2 calibration bottle accuracy is +/-5 percent ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; N/A; N/A; DM_CONTACT_INFO: Paul Wooldridge, UC Berkeley, pjwool@berkeley.edu PROJECT_INFO: TC4; 13 July - 13 August 2007 STIPULATIONS_ON_USE: Use of these data requires PRIOR OK from the PI OTHER_COMMENTS: N/A REVISION: R2 R2: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R1: Corrected for quenching of NO2 fluoresence by H2O using DLH data, further chemical corrections pending. start_UTC stop_UTC mid_UTC NO2 NO2_sigma PNs PNs_sigma 39249 39258 39254 13438 839 999999 999999 39277 39286 39281 13257 1053 46404 4092 39290 39300 39295 15143 1067 50329 5225 39304 39313 39309 11566 1153 999999 999999 39331 39341 39336 11426 1929 38440 5823 39345 39355 39350 13277 1452 42424 5666 39359 39368 39364 14196 998 999999 999999 39387 39396 39391 14480 844 999999 999999 39400 39410 39405 14768 1121 999999 999999 39414 39423 39419 17392 1250 999999 999999 39442 39451 39446 19591 1483 999999 999999 39455 39465 39460 29134 5860 999999 999999 39496 39506 39501 -2 2 999999 999999 39510 39520 39515 -1 0 999999 999999 42383 42393 42388 2400 373 999999 999999 42411 42421 42416 454 304 67 229 42425 42435 42430 164 60 -29 86 42439 42448 42443 92 62 999999 999999 42466 42476 42471 87 57 55 129 42480 42490 42485 100 65 64 97 42494 42503 42498 129 67 999999 999999 42521 42530 42526 90 58 -16 83 42535 42545 42540 38 40 -29 75 42549 42558 42553 67 48 999999 999999 42576 42586 42581 76 48 15 92 42590 42600 42595 58 44 30 91 42604 42613 42609 57 48 999999 999999 42631 42641 42636 57 45 32 87 42645 42655 42650 43 34 34 81 42659 42668 42663 93 68 999999 999999 42686 42696 42691 90 43 30 99 42700 42710 42705 76 55 107 89 42714 42723 42719 134 54 999999 999999 42741 42751 42746 83 47 67 104 42755 42765 42760 108 55 46 104 42769 42778 42774 123 71 999999 999999 42796 42806 42801 106 47 63 106 42810 42820 42815 117 47 58 93 42824 42833 42829 85 50 999999 999999 42851 42861 42856 97 43 113 87 42865 42875 42870 67 44 81 104 42879 42888 42884 57 42 999999 999999 42906 42916 42911 70 46 125 93 42920 42930 42925 91 39 90 90 42934 42943 42939 82 38 999999 999999 42961 42971 42966 71 41 88 95 43168 43177 43172 87 55 40 120 43182 43191 43186 82 47 61 74 43195 43205 43200 85 46 999999 999999 43258 43267 43262 93 46 102 120 43464 43473 43468 110 51 93 79 43478 43487 43482 88 41 59 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35 98 44041 44050 44046 62 45 999999 999999 44069 44078 44073 52 41 -4 91 44082 44092 44087 54 42 1 84 44096 44105 44101 46 37 999999 999999 44124 44133 44128 57 36 -13 65 44138 44147 44142 33 45 29 83 44151 44161 44156 70 37 999999 999999 44179 44188 44183 77 44 26 78 44192 44202 44197 118 44 -42 94 44206 44216 44211 98 49 999999 999999 44234 44243 44238 88 46 -13 97 44247 44257 44252 76 43 1 68 44261 44271 44266 86 49 999999 999999 44289 44298 44294 62 56 -9 95 44303 44312 44308 236 52 -44 121 44316 44326 44321 73 54 999999 999999 44344 44353 44349 98 72 -50 120 44358 44368 44363 95 32 -25 75 44372 44381 44376 155 73 999999 999999 44399 44408 44404 234 83 -29 117 44413 44423 44418 288 79 -40 129 44427 44436 44431 253 57 999999 999999 44454 44464 44459 124 51 -42 87 44468 44478 44473 103 42 -20 74 44482 44491 44487 145 44 999999 999999 44509 44519 44514 120 42 -68 84 44564 44574 44569 120 53 -22 93 44578 44588 44583 128 49 -30 82 44592 44601 44597 86 54 999999 999999 44620 44629 44624 107 51 -27 85 44633 44643 44638 90 50 -77 90 44647 44656 44652 118 54 999999 999999 44675 44684 44679 42 47 -52 78 44689 44698 44693 49 48 -9 92 44702 44712 44707 51 46 999999 999999 44730 44739 44734 35 60 15 84 44744 44753 44748 146 57 -27 106 44757 44767 44762 76 56 999999 999999 44785 44794 44790 33 47 13 81 44799 44809 44804 30 32 20 92 44812 44822 44817 15 38 999999 999999 44840 44849 44845 105 42 15 68 44854 44864 44859 59 41 -12 56 44868 44877 44872 50 37 999999 999999 44895 44905 44900 70 39 17 87 44909 44919 44914 15 43 -31 85 44923 44932 44927 46 34 999999 999999 44950 44960 44955 27 40 50 79 44964 44974 44969 41 33 -10 74 44978 44987 44983 35 39 999999 999999 45005 45015 45010 50 50 20 104 45019 45029 45024 105 58 42 84 45033 45042 45037 30 44 999999 999999 45060 45070 45065 16 30 97 85 45074 45084 45079 30 37 40 83 45088 45097 45093 35 35 999999 999999 45115 45125 45120 18 34 98 83 45129 45139 45134 35 39 31 94 45143 45152 45148 45 35 999999 999999 45171 45180 45175 -4 40 131 95 45184 45194 45189 18 35 124 93 45198 45208 45203 42 42 999999 999999 45226 45235 45230 17 43 102 91 45240 45249 45244 37 40 157 93 45253 45263 45258 11 32 999999 999999 45281 45290 45285 14 46 109 93 45295 45304 45300 19 41 74 84 45308 45318 45313 25 34 999999 999999 45336 45345 45341 21 36 73 79 45350 45360 45355 8 35 148 90 45363 45373 45368 17 33 999999 999999 45391 45400 45396 33 47 88 85 45405 45414 45409 -8 35 132 93 45418 45428 45423 36 37 999999 999999 45446 45455 45451 4 41 180 81 45460 45469 45465 30 44 102 108 45473 45483 45478 38 48 999999 999999 45501 45510 45506 35 41 100 133 45515 45525 45520 97 62 52 119 45529 45538 45533 75 56 999999 999999 45556 45565 45561 87 51 41 111 45570 45580 45575 89 52 73 111 45584 45593 45588 71 53 999999 999999 45611 45620 45616 65 52 125 120 45625 45635 45630 71 93 116 183 45639 45648 45643 12 40 999999 999999 45666 45675 45671 56 51 58 152 45680 45689 45685 58 54 152 150 45693 45703 45698 89 54 999999 999999 45721 45730 45726 49 51 115 140 45735 45744 45739 -1 57 192 112 45748 45758 45753 79 62 999999 999999 45776 45785 45780 62 0 -49 0 45789 45799 45794 55 61 69 143 45803 45813 45808 44 62 999999 999999 45831 45840 45836 42 58 94 139 45845 45855 45850 48 49 153 126 45858 45868 45863 65 58 999999 999999 45886 45895 45891 34 62 60 110 45900 45910 45905 21 55 134 97 45914 45923 45918 62 53 999999 999999 45941 45951 45946 51 70 69 105 45955 45965 45960 54 61 65 123 45969 45978 45973 38 65 999999 999999 45996 46006 46001 31 63 125 134 46010 46020 46015 30 53 19 117 46024 46033 46029 48 64 999999 999999 46052 46061 46056 46 62 22 123 46065 46075 46070 50 64 40 135 46079 46089 46084 32 52 999999 999999 46107 46116 46111 35 76 71 153 46120 46130 46125 13 62 49 139 46134 46144 46139 39 63 999999 999999 46162 46171 46167 16 53 108 116 46176 46185 46180 45 58 45 141 46189 46199 46194 36 60 999999 999999 46217 46226 46222 67 74 28 141 46231 46241 46236 57 63 41 153 46245 46254 46249 34 76 999999 999999 46272 46281 46277 68 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46997 46992 15 46 102 112 47001 47010 47006 21 58 999999 999999 47029 47038 47033 32 49 71 112 47042 47052 47047 -29 49 85 106 47056 47066 47061 9 49 999999 999999 47084 47093 47088 34 67 26 137 47097 47107 47102 20 69 -18 109 47111 47120 47116 4 51 999999 999999 47139 47148 47143 -5 46 66 110 47152 47162 47157 10 54 55 123 47166 47176 47171 0 55 999999 999999 47194 47203 47199 25 59 62 118 47208 47218 47213 5 55 76 161 47222 47231 47226 -23 60 999999 999999 47249 47258 47254 31 46 -13 95 47263 47273 47268 -7 47 21 119 47277 47286 47281 4 59 999999 999999 47304 47314 47309 -11 54 96 112 47318 47328 47323 0 63 22 128 47332 47341 47336 7 61 999999 999999 47359 47369 47364 11 60 45 102 47373 47383 47378 -25 44 86 98 47387 47396 47392 10 54 999999 999999 47415 47424 47419 -9 55 45 112 47428 47438 47433 -6 43 80 107 47442 47451 47447 6 53 999999 999999 47470 47479 47474 23 60 10 118 47555 47564 47560 7 43 77 147 47568 47578 47573 1 57 999999 999999 47596 47605 47600 -28 48 77 107 47609 47619 47614 6 49 59 128 47623 47633 47628 27 58 999999 999999 47651 47660 47655 11 55 32 117 47664 47674 47669 6 30 40 125 47678 47688 47683 6 49 999999 999999 47706 47715 47710 -3 63 -6 129 47719 47729 47724 25 54 -13 106 47733 47743 47738 1 48 999999 999999 47761 47770 47765 28 48 6 120 47774 47784 47779 11 54 -20 123 47788 47797 47793 22 61 999999 999999 47816 47825 47820 -7 51 78 109 47829 47839 47834 -5 41 142 126 47843 47853 47848 -4 52 999999 999999 47871 47880 47875 15 57 -3 103 47884 47894 47889 53 58 -22 151 47898 47907 47903 -10 52 999999 999999 47926 47935 47930 -3 66 81 126 47939 47949 47944 -1 60 61 149 47953 47963 47958 34 68 999999 999999 47981 47990 47985 14 53 72 135 47994 48004 47999 58 46 1 130 48008 48018 48013 36 71 999999 999999 48036 48045 48040 36 62 -32 186 48050 48059 48054 5 69 39 118 48063 48073 48068 21 61 999999 999999 48091 48100 48095 -10 55 126 152 48104 48114 48109 32 59 22 116 48118 48127 48123 37 69 999999 999999 48173 48182 48178 29 47 999999 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