38 1001 Cohen, Ronald University of California, Berkeley TD-LIF: Thermal Dissociation - Laser Induced Fluorescence of nitrogen dioxide from thermal dissociated nitric acid TC4 1 1 2007 08 05 2011 09 07 0 start_UTC, s {number of seconds from 000000 UTC} 4 1 1 1 1 999999 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv {Nitric acid = 580 C channel - 330 C channel, pptv} HNO3sigma 0 20 PI_CONTACT_INFO: Address: Chemistry Department, University of California, Berkeley, CA 94720; cohen@cchem.berkeley.edu; 510-642-2357 PLATFORM: NASA DC-8 LOCATION: DC8_AIRCRAFT ASSOCIATED_DATA: N/A INSTRUMENT_INFO: NO2 laser induced fluorescence following thermal dissociation of nitrooxy compounds DATA_INFO: All data in pptv. Measurement cycle is 20 seconds on, 5 seconds off at approximately 1 Hz. UNCERTAINTY: estimate of NO2 calibration bottle accuracy is +/-5 percent ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; N/A; N/A; DM_CONTACT_INFO: Paul Wooldridge, UC Berkeley, pjwool@berkeley.edu PROJECT_INFO: TC4; 13 July - 13 August 2007 STIPULATIONS_ON_USE: Use of these data requires PRIOR OK from the PI OTHER_COMMENTS: N/A REVISION: R2 R2: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R1: Corrected for quenching of NO2 fluoresence by H2O using DLH data, further chemical corrections pending. start_UTC stop_UTC mid_UTC HNO3 HNO3sigma 44657 44666 44661 26 145 44767 44777 44772 184 103 44877 44887 44882 108 82 44987 44997 44992 108 101 45097 45107 45102 61 139 45207 45217 45212 44 114 45317 45327 45322 140 128 45428 45437 45432 18 88 45538 45547 45542 174 110 45647 45657 45652 64 113 45757 45767 45762 55 109 46019 46028 46023 139 75 46129 46139 46134 60 118 46239 46249 46244 117 116 46349 46359 46354 141 161 46459 46469 46464 95 134 46679 46689 46684 384 224 46789 46799 46794 398 186 46899 46909 46904 141 170 47009 47019 47014 49 213 47119 47129 47124 -67 180 47229 47239 47234 142 150 47339 47349 47344 56 184 47449 47459 47454 123 157 47559 47569 47564 58 131 47669 47679 47674 62 144 47780 47790 47785 15 138 47890 47900 47895 6 137 48000 48009 48005 59 147 48110 48120 48115 98 142 48220 48230 48225 -68 130 48330 48340 48335 104 97 48440 48450 48445 80 139 48550 48560 48555 -11 134 48660 48670 48665 23 161 48770 48780 48775 28 202 48880 48890 48885 57 150 48990 49000 48995 -59 151 49100 49110 49105 -18 165 49211 49220 49215 -4 128 49321 49331 49326 47 129 49431 49441 49436 -47 126 49541 49551 49546 -17 158 49651 49661 49656 34 0 49762 49771 49766 -30 176 49871 49881 49876 39 212 49981 49991 49986 12 122 50202 50212 50207 -71 207 50312 50322 50317 26 144 50422 50432 50427 -134 174 50532 50542 50537 -4 70 50642 50652 50647 -87 155 50752 50762 50757 -44 205 50863 50873 50868 -85 181 50973 50983 50978 -63 210 51083 51093 51088 -8 173 51193 51203 51198 13 169 51303 51312 51308 -24 173 51413 51423 51418 -108 125 51523 51533 51528 -117 171 51633 51643 51638 16 171 51743 51753 51748 -21 146 51853 51863 51858 16 120 51963 51973 51968 -20 158 52073 52083 52078 -26 162 52183 52193 52188 -30 219 52294 52303 52298 -56 175 52404 52413 52409 3 164 52514 52524 52519 12 200 52775 52785 52780 -53 168 52957 52966 52962 -50 145 53138 53147 53143 138 191 53248 53257 53253 -11 154 53358 53368 53363 83 231 53468 53478 53473 32 123 53649 53659 53654 -9 121 53940 53950 53945 45 143 54051 54060 54056 36 153 54161 54171 54166 6 143 54271 54281 54276 30 163 54381 54391 54386 53 174 54491 54501 54496 71 167 54602 54611 54606 -37 166 54712 54722 54717 53 122 54821 54831 54826 29 141 54931 54941 54936 -11 140 55042 55051 55047 71 166 55152 55162 55157 157 256 55262 55272 55267 -135 172 55372 55382 55377 127 172 55482 55492 55487 75 144 55593 55602 55598 104 160 55703 55713 55708 91 137 55813 55823 55818 48 139 55923 55933 55928 -52 105 56033 56043 56038 13 115 56143 56153 56148 74 109 56253 56263 56258 35 119 56363 56373 56368 -10 119 56474 56484 56479 56 106 56584 56594 56589 51 171 56694 56704 56699 94 119 56876 56885 56880 96 172 56985 56995 56990 86 130 57095 57105 57100 8 123 57205 57215 57210 55 138 57315 57325 57320 69 134 57425 57435 57430 -32 94 57535 57545 57540 56 149 57645 57655 57650 57 123 57755 57765 57760 112 110 57866 57876 57871 90 197 57976 57985 57980 -72 110 58086 58095 58091 -52 132 58196 58206 58201 -30 114 58306 58316 58311 7 135 58416 58426 58421 25 131 58526 58536 58531 -47 82 58787 58797 58792 -6 77 58897 58907 58902 33 124 59007 59017 59012 -9 95 59117 59127 59122 58 146 59227 59237 59232 65 108 59337 59347 59342 58 181 59447 59457 59452 123 120 59558 59567 59562 135 165 59668 59677 59672 87 168 59778 59788 59783 -61 111 59888 59898 59893 176 112 60108 60118 60113 98 80 60219 60228 60224 154 147 60329 60339 60334 106 95 60439 60449 60444 52 43 60549 60558 60554 135 79 60659 60669 60664 149 150 60769 60779 60774 252 117 60879 60889 60884 285 139 60989 60999 60994 288 146 61251 61261 61256 227 156 61361 61371 61366 257 117 61471 61481 61476 205 142 61581 61591 61586 282 111 61691 61701 61696 190 130 61802 61811 61806 144 143 61912 61921 61916 205 66 62022 62032 62027 163 141 62132 62142 62137 220 174 62242 62252 62247 119 124 62353 62362 62357 176 151 62463 62473 62468 155 133 62573 62583 62578 137 107 62683 62693 62688 166 148 62793 62803 62798 205 0 62903 62913 62908 60 108 63165 63175 63170 126 116 63275 63285 63280 85 97 63385 63395 63390 180 104 63495 63505 63500 45 116 63605 63615 63610 83 135 63715 63725 63720 78 108 63825 63835 63830 148 126 63935 63945 63940 122 112 64045 64055 64050 81 84 64155 64165 64160 154 112 64265 64275 64270 67 131 64375 64385 64380 107 157 64485 64495 64490 168 113 64595 64605 64600 145 174 64706 64715 64710 60 145 64887 64897 64892 95 40 64997 65007 65002 144 98 65107 65117 65112 108 139 65217 65227 65222 118 51 65327 65337 65332 134 66 65437 65447 65442 199 117 65547 65557 65552 84 123 65657 65667 65662 64 92 65768 65777 65772 23 116 65878 65888 65883 178 107 65988 65998 65993 3 156 66098 66108 66103 104 93 66208 66218 66213 25 122 66318 66328 66323 28 96 66428 66438 66433 99 164 66539 66548 66543 101 128 66649 66659 66654 18 170 66759 66769 66764 149 169 66869 66879 66874 33 184 66979 66989 66984 66 156 67089 67099 67094 -8 172 67199 67209 67204 17 132 67309 67319 67314 108 0 67419 67429 67424 37 129 67681 67691 67686 0 163 67791 67800 67796 52 101 67901 67910 67905 7 194 68011 68021 68016 107 143 68121 68131 68126 118 201 68231 68241 68236 13 134 68341 68351 68346 25 118 68451 68461 68456 93 91 68561 68571 68566 191 110 68671 68681 68676 141 105 68782 68791 68786 75 102 68891 68901 68896 84 103 69002 69012 69007 62 84 69112 69122 69117 50 106 69222 69232 69227 65 129 69332 69342 69337 15 105 69442 69452 69447 220 153 69553 69563 69558 153 201 69663 69672 69668 225 241