38 1001 Cohen, Ronald University of California, Berkeley TD-LIF: Thermal Dissociation - Laser Induced Fluorescence of nitrogen dioxide from thermal dissociated nitric acid TC4 1 1 2007 07 31 2011 09 07 0 start_UTC, s {number of seconds from 000000 UTC} 4 1 1 1 1 999999 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv {Nitric acid = 580 C channel - 330 C channel, pptv} HNO3sigma 0 20 PI_CONTACT_INFO: Address: Chemistry Department, University of California, Berkeley, CA 94720; cohen@cchem.berkeley.edu; 510-642-2357 PLATFORM: NASA DC-8 LOCATION: DC8_AIRCRAFT ASSOCIATED_DATA: N/A INSTRUMENT_INFO: NO2 laser induced fluorescence following thermal dissociation of nitrooxy compounds DATA_INFO: All data in pptv. Measurement cycle is 20 seconds on, 5 seconds off at approximately 1 Hz. UNCERTAINTY: estimate of NO2 calibration bottle accuracy is +/-5 percent ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; N/A; N/A; DM_CONTACT_INFO: Paul Wooldridge, UC Berkeley, pjwool@berkeley.edu PROJECT_INFO: TC4; 13 July - 13 August 2007 STIPULATIONS_ON_USE: Use of these data requires PRIOR OK from the PI OTHER_COMMENTS: N/A REVISION: R2 R2: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R1: Corrected for quenching of NO2 fluoresence by H2O using DLH data, further chemical corrections pending. start_UTC stop_UTC mid_UTC HNO3 HNO3sigma 44756 44765 44760 97 432 44866 44876 44871 1340 984 44976 44986 44981 704 638 45086 45096 45091 1013 440 45196 45206 45201 717 439 45306 45316 45311 770 436 45417 45426 45421 1339 1000 45527 45536 45532 982 551 45637 45647 45642 502 415 45747 45757 45752 282 93 45857 45867 45862 272 151 45967 45977 45972 183 132 46077 46087 46082 302 122 46188 46197 46192 210 134 46297 46307 46302 246 87 46407 46417 46412 113 103 46627 46637 46632 227 159 46737 46747 46742 56 197 46848 46857 46852 103 128 46958 46967 46963 141 184 47068 47077 47072 87 228 47178 47187 47182 108 135 47288 47298 47293 75 175 47398 47408 47403 128 178 47508 47518 47513 32 226 47618 47628 47623 26 202 47728 47738 47733 51 194 47989 47999 47994 47 202 48099 48109 48104 98 178 48210 48219 48214 -6 194 48320 48330 48325 37 209 48430 48440 48435 66 187 48540 48550 48545 -17 196 48650 48660 48655 72 189 48760 48770 48765 74 226 48870 48880 48875 29 165 48981 48990 48986 137 250 49090 49100 49095 -9 155 49200 49210 49205 -24 229 49310 49320 49315 0 250 49420 49430 49425 16 89 49531 49540 49535 71 174 49641 49651 49646 92 170 49751 49761 49756 -14 157 49861 49871 49866 -8 157 49972 49981 49976 36 182 50192 50202 50197 102 157 50302 50312 50307 55 209 50413 50422 50417 -22 202 50523 50533 50528 50 184 50633 50643 50638 103 249 50744 50753 50749 -51 177 50854 50864 50859 33 195 50964 50974 50969 -65 146 51074 51083 51079 66 211 51184 51194 51189 -28 245 51294 51304 51299 10 171 51404 51413 51409 64 182 51514 51524 51519 -34 217 51624 51634 51629 50 260 51734 51744 51739 -79 127 51844 51854 51849 12 211 51954 51964 51959 -34 66 52064 52074 52069 28 150 52174 52184 52179 -46 195 52284 52294 52289 13 157 52394 52404 52399 -1 198 52504 52514 52509 -92 159 52615 52624 52619 -111 112 52725 52734 52729 -4 153 52835 52845 52840 -29 166 52945 52955 52950 -26 246 53055 53065 53060 -17 192 53427 53436 53431 20 164 53536 53546 53541 62 153 53756 53766 53761 37 149 53866 53876 53871 -33 223 53976 53986 53981 -82 166 54086 54096 54091 41 252 54196 54206 54201 0 124 54306 54316 54311 156 181 54416 54426 54421 -38 150 54526 54536 54531 75 191 54636 54646 54641 72 190 54746 54756 54751 -20 222 54856 54866 54861 -70 114 54966 54976 54971 -163 84 55076 55086 55081 7 149 55186 55196 55191 3 151 55296 55306 55301 100 156 55406 55416 55411 74 179 55516 55526 55521 154 178 55626 55636 55631 157 151 55736 55746 55741 89 117 55846 55856 55851 141 149 55956 55966 55961 1 121 56066 56076 56071 104 122 56176 56186 56181 14 192 56548 56558 56553 43 175 56658 56667 56663 200 175 56768 56778 56773 70 163 56878 56888 56883 -108 174 56988 56998 56993 169 226 57098 57108 57103 -21 263 57319 57328 57323 45 242 57429 57439 57434 28 153 57539 57548 57544 32 161 57649 57659 57654 27 145 57759 57769 57764 57 145 57869 57879 57874 83 0 57979 57989 57984 -94 204 58089 58099 58094 103 185 58199 58209 58204 31 219 58310 58319 58315 18 212 58420 58430 58425 142 198 58530 58540 58535 33 181 58640 58650 58645 -71 209 58750 58760 58755 29 120 58860 58870 58865 116 191 58971 58980 58975 64 207 59081 59090 59086 119 139 59191 59201 59196 55 167 59301 59311 59306 31 170 59411 59421 59416 52 153 59522 59531 59527 26 189 59631 59641 59636 24 166 59741 59751 59746 18 153 59851 59861 59856 145 119 59962 59971 59966 100 187 60072 60082 60077 73 199 60182 60191 60187 124 201 60292 60302 60297 86 159 60402 60412 60407 123 219 60512 60522 60517 24 202 60622 60632 60627 78 183 60842 60852 60847 88 209 60952 60962 60957 106 177 61062 61072 61067 56 169 61172 61182 61177 116 132 61282 61292 61287 143 157 61393 61403 61398 7 247 61503 61513 61508 167 166 61613 61623 61618 78 186 61723 61733 61728 120 186 61833 61843 61838 115 179 61943 61953 61948 36 149 62053 62063 62058 27 129 62163 62173 62168 144 204 62425 62434 62429 28 136 62535 62544 62539 89 200 62644 62654 62649 13 212 62754 62764 62759 29 173 62864 62874 62869 98 158 62974 62984 62979 104 146 63084 63094 63089 58 201 63304 63313 63308 88 216 63414 63423 63418 54 208 63523 63533 63528 17 136 63633 63643 63638 63 150 63743 63753 63748 -80 103 63853 63863 63858 17 252 63963 63972 63967 91 202 64072 64082 64077 47 140 64182 64192 64187 174 192 64363 64373 64368 36 197 64473 64483 64478 43 270 64583 64593 64588 54 257 64955 64965 64960 -68 208 65065 65075 65070 0 174 65176 65185 65180 -2 150 65286 65296 65291 141 105 65396 65406 65401 39 123 65506 65516 65511 71 198 65616 65626 65621 57 130 65726 65736 65731 265 158 65837 65847 65842 195 134 65947 65957 65952 266 124 66057 66067 66062 217 116 66167 66177 66172 334 82 66278 66287 66283 290 125 66388 66397 66392 217 128 66498 66508 66503 216 70 66608 66618 66613 266 134 66718 66728 66723 295 121 66828 66838 66833 232 85 66939 66948 66943 179 105 67049 67058 67054 163 120 67159 67169 67164 236 109 67269 67279 67274 109 84 67379 67389 67384 122 73 67489 67499 67494 125 79 67599 67609 67604 131 96 67709 67719 67714 135 76 67970 67980 67975 177 77 68080 68090 68085 197 105 68191 68200 68195 211 153 68301 68311 68306 184 144 68411 68421 68416 188 113 68521 68531 68526 151 118 68631 68641 68636 153 123 68741 68751 68746 190 82 68851 68861 68856 111 77 68961 68971 68966 154 61 69072 69082 69077 146 100 69182 69192 69187 104 78 69292 69302 69297 58 85 69402 69412 69407 21 103 69513 69523 69518 32 76 69733 69743 69738 150 154 69843 69853 69848 95 166 69953 69963 69958 -23 136 70063 70073 70068 81 200 70174 70184 70179 29 200 70284 70294 70289 19 196 70394 70404 70399 -30 243 70766 70776 70771 48 151 70876 70886 70881 11 127 70987 70996 70991 71 148 71097 71106 71102 112 232 71207 71216 71212 39 187 71317 71327 71322 79 179 71427 71437 71432 9 211 71537 71547 71542 94 119 71647 71657 71652 76 115 71757 71767 71762 70 128 71868 71877 71872 178 159 71977 71987 71982 161 78 72087 72097 72092 216 102 72198 72208 72203 156 96 72308 72318 72313 175 126 72418 72427 72422 152 152 72528 72538 72533 173 231 72638 72648 72643 470 181 72748 72758 72753 225 227 72859 72868 72863 181 146