86 1001 Rowland, F.S. UCI DC-8 Grab_Samples_GC AASE II 1 1 1992 03 14 1993 07 13 0 Sample start time in UT seconds 35 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 Stop_Time;_GMT_(seconds) Sample_Midpoint;_GMT_(seconds) CFC_115;_(pptv) CF3BR;_(pptv) CFC-22;_(pptv) CH3CL;_(pptv) CFC-114;_(pptv) CBRCLF2;_(pptv) CH3BR;_(pptv) CFC-11;_(pptv) CFC-113;_(pptv) CHCL3;_(pptv) CH3CCL3;_(pptv) CCL4;_(pptv) C2HCL3;_(pptv) C2CL4;_(pptv) ETHANE;_(pptv) ETHENE;_(pptv) PROPANE;_(pptv) PROPENE;_(pptv) i_BUTANE;_(pptv) n_BUTANE;_(pptv) ETHYNE;_(pptv) t_2_BUTENE;_(pptv) 1_BUTENE;_(pptv) i_PENTANE;_(pptv) n_PENTANE;_(pptv) 1_3_BUTADIENE;_(pptv) PROPYNE;_(pptv) 1_PENTENE;_(pptv) 2_BUTYNE;_(pptv) 1_BUTYNE;_(pptv) BENZENE;_(pptv) TOLUENE;_(pptv) CFC-12;_(pptv) 0 35 (# of comment lines below) Measurement below the detection limit are indicated by 0. The detection limits in pptv are: CFC_115 = 0.1; Accuracy +/- 25%; Measurment precision (M1-9) 25% (M10-19) 2% CF3BR = 0.1; Accuracy +/- 25%; Measurment precision (M1-9) 10% (M10-19) 2% CFC-22 = 1; Accuracy +/- 10%; Measurment precision (M1-9) 15% (M10-19) 2% CH3CL = 10; Accuracy +/- 5%; Measurment precision (M1-9) 10% (M10-19) 3% CFC-114 = 0.1; Accuracy +/- 25%; Measurment precision (M1-9) 10% (M10-19) 2% CBRCLF2 = 0.01; Accuracy +/- 25%; Measurment precision (M1-9) 10% (M10-19) 2% CH3BR = 0.5; Accuracy +/- 25%; Measurment precision (M1-9) 10% (M10-19) 2% CFC-11 = 1; Accuracy +/- 5%; Measurment precision (M1-9) 5% (M10-19) 2% CFC-113 = 1; Accuracy +/- 5%; Measurment precision (M1-9) 10% (M10-19) 2% CHCL3 = 0.5; Accuracy +/- 25%; Measurment precision (M1-9) 10% (M10-19) 2% CH3CCL3 = 1; Accuracy +/- 10%; Measurment precision (M1-9) 10% (M10-19) 2% CCL4 = 1; Accuracy +/- 10%; Measurment precision (M1-9) 10% (M10-19) 2% C2HCL3 = 0.1; Accuracy +/- 25%; Measurment precision (M1-9) 10% (M10-19) 2% C2CL4 = 0.01; Accuracy +/- 10%; Measurment precision (M1-9) 10% (M10-19) 2% ETHANE = 2; Accuracy +/- 10%; Measurment precision (all) 3% ETHENE = 2; Accuracy +/- 25%; Measurment precision (all) 3% PROPANE = 2; Accuracy +/- 10%; Measurment precision (all) 3% PROPENE = 2; Accuracy +/- 25%; Measurment precision (all) 5% i_BUTANE = 2; Accuracy +/- 10%; Measurment precision (all) 5% n_BUTANE = 2; Accuracy +/- 10%; Measurment precision (all) 5% ETHYNE = 2; Accuracy +/- 10%; Measurment precision (all) 3% t_2_BUTENE = 2; Accuracy +/- 25%; Measurment precision (all) 5% 1_BUTENE = 2; Accuracy +/- 25%; Measurment precision (all) 5% i_PENTANE = 2; Accuracy +/- 10%; Measurment precision (all) 5% n_PENTANE = 2; Accuracy +/- 10%; Measurment precision (all) 5% 1_3_BUTADIENE = 2; Accuracy +/- 10%; Measurment precision (all) 5% PROPYNE = 2; Accuracy +/- 10%; Measurment precision (all) 5% 1_PENTENE = 2; Accuracy +/- 25%; Measurment precision (all) 5% 2_BUTYNE = 2; Accuracy +/- 10%; Measurment precision (all) 5% 1_BUTYNE = 2; Accuracy +/- 10%; Measurment precision (all) 5% BENZENE = 2; Accuracy +/- 15%; Measurment precision (all) 5% TOLUENE = 2; Accuracy +/- 15%; Measurment precision (all) 5% CFC_12 = 1; Accuracy +/- 5%; Measurment precision (M1-9) 5% (M10-19) 2% 50110 50165 50137 2.58 2.86 95.1 554 9.61 1.46 6.75 235.4 71.2 3.27 120.7 93.4 0.43 1.424 162.4 99999 4.6 99999 0 2.4 14.7 0 0 0 0 0 0 0 0 0 3 0 456.1 52390 52445 52417 2.27 2.85 97.2 565.5 9.74 1.56 7.13 230.8 72.7 3.47 124.5 96.6 0.46 1.954 206.1 99999 9.9 99999 0 0 21.2 0 0 0 0 0 0 0 0 0 3.8 0 466.8 54665 54730 54697 3.05 2.66 94.1 547.8 9.45 1.44 6.71 230.1 71.5 2.76 116.3 92.8 0.35 1.275 125.2 99999 2.8 99999 0 0 8.3 0 0 0 0 0 0 0 0 0 5 0 456.1 56660 56725 56692 2.66 2.77 95 551 9.52 1.44 6.66 231.2 70.7 2.91 119.3 92.7 0.44 0.825 121.3 99999 2.2 99999 0 0 7.8 0 0 0 0 0 0 0 0 0 0 0 455.2 58600 58665 58632 2.32 2.88 100.6 570.4 9.84 1.56 7.04 228.7 73.6 3.34 122.5 96.3 0.45 1.57 157.1 99999 3.7 99999 0 0 15 0 0 0 0 0 0 0 0 0 4.8 0 452.2 61900 61980 61940 2.05 2.75 95.1 549.9 9.55 1.43 6.58 224.5 71.1 2.06 115.4 92.7 0.3 0.872 135.8 99999 3.9 99999 0 0 9.2 0 0 0 0 0 0 0 0 0 2.1 0 453.9 64155 64230 64192 1.72 2.85 98.6 567.2 9.91 1.5 6.68 220.5 72.4 2.89 121.9 93.6 0.4 1.071 121.3 99999 2.3 99999 0 0 9.9 0 0 0 0 0 0 0 0 0 3.8 0 432.5 64620 64680 64650 99999 2.8 96.6 566.8 9.7 1.54 7.03 231.8 73.2 2.94 121.6 96.5 0.37 1.81 176.5 14.7 5.5 2.4 0 0 18.4 0 0 0 0 0 0 0 0 0 5.3 0 465.7 64700 64755 64727 99999 3.02 100.9 587 9.96 1.65 7.44 255.3 75.2 3.9 130.8 100.2 0.66 3.411 328.9 99999 24.8 99999 0 0 52.7 0 0 0 0 0 0 0 0 0 5.6 0 473.1 64795 64850 64822 2.23 3.12 102 601.9 10.11 1.79 7.98 270.3 77.9 5.44 138.7 101.9 0.97 9.572 774.8 99999 139.8 99999 15.2 28.5 156.1 0 0 6.9 4.5 0 0 0 0 0 23.8 0 484.3 64890 64930 64910 2.54 3.25 108.8 623.1 10.29 1.94 8.38 262.1 81.6 7.48 151.1 106.5 2.7 22.533 1750 34.5 526.3 5.3 78.5 164.3 396.6 0 0 53.9 30.3 0 0 0 0 0 66.4 3.5 499.3 64975 65015 64995 2.85 3.35 111.3 620.8 10.31 1.98 9.05 263.6 80.8 8.24 157.7 108.1 3.69 27.135 2012.3 37.6 675.8 5.8 102.4 231.7 445.1 0 0 73.5 44.9 0 2.7 0 0 0 82 12.7 494 65065 65100 65082 3.1 3.45 119.3 626.4 10.42 2.01 9.4 257.6 81.1 9.14 164.3 108.3 5.03 33.994 2448.8 99999 964.3 99999 161.8 388.4 547.8 0 0 136.3 71.8 0 2.5 0 0 0 97.2 27.7 498.5 65155 65200 65177 2.43 3.33 110.9 620.1 10.3 1.98 8.98 266.4 82.1 7.96 153.9 107.8 3.12 24.855 1899.9 25.2 543.6 3.7 72.5 152.4 408.2 0 0 41.1 27.6 0 0 0 0 0 70.3 5 497.7 65233 65265 65249 99999 3.4 110.9 626.1 10.33 1.98 8.48 264.4 81.2 7.94 154.1 108.2 3.06 23.489 1660.4 17.9 443.3 4.2 62 121.3 380.7 0 0 29 21.3 0 0 0 0 0 64.4 5.3 495.9 65340 65370 65355 2.52 3.45 115.3 630.4 10.68 2.05 8.78 262.1 82.4 8.77 161.4 108.8 9.77 37.981 1791.2 99999 513.1 99999 99.8 186.4 535.1 0 0 77.1 39.6 0 3.6 0 0 0 98.7 37 496.5 65790 65820 65805 99999 3.42 113.1 613 10.28 2.05 8.6 267.4 82.7 8.88 157.1 107.5 7.49 30.036 1916.6 55.8 599.1 3 106.7 208 503 0 0 71.5 41.3 0 3.2 0 0 0 92.4 24.4 495.8 65875 65908 65891 99999 3.46 116.4 629.1 10.42 2.08 8.58 263.7 82.6 9.3 163.7 108.8 11.98 33.744 2048.9 82.6 689.4 4.3 143.2 279.5 590.6 0 0 99.8 60.6 0 4.5 0 0 0 115 45.1 495.2 65976 66003 65989 99999 3.47 114 617.2 10.38 2.07 8.53 264.6 82 8.63 164.8 109.4 12.37 33.847 2128.9 97.7 745.7 5 159.4 308.5 600.5 0 0 110.6 65.5 0 5.6 0 0 0 113.1 46.4 498.3 66063 66084 66073 2.77 3.47 116.4 620.1 10.65 2.15 8.64 266.1 84.4 9.63 163.3 108.9 12.91 34.915 2178.5 147.6 765.1 5.7 187.5 350.5 656.6 0 0 139.2 74.5 0 6.7 0 0 0 134.8 68.2 498.3 66150 66170 66160 99999 3.68 116.7 629.7 10.72 2.24 8.7 274.4 84.1 10.42 168 109.6 15.33 41.503 2316 235.5 880.2 5.3 239.1 449.3 813.3 0 0 195.7 102.3 0 11.2 0 0 0 171 111.9 499.4 66247 66262 66254 3.04 3.82 123.5 628 11.01 2.26 8.82 270.6 86.2 12.03 182.6 110.9 23.03 61.159 2763.7 514.6 1208 12 359.2 665.6 1175.5 0 0 340.7 182.1 0 22.1 0 0 0 248.4 207.6 503.3 66325 66345 66335 3.07 3.71 124.9 632.7 10.88 2.25 8.82 274.5 87 11.44 174.8 110.1 20.09 53.661 2652.4 432.4 1157.3 12.6 333.1 615 1083.6 0 0 305.4 165.5 0 18.6 0 0 0 230.5 185.3 501 66415 66435 66425 2.86 3.66 121.6 629.3 10.76 2.22 8.84 289.8 85.8 11.56 171.5 111.3 18.49 56.442 2782.1 464.6 1127.7 7 298.5 559.8 1301.1 0 0 281.4 173.2 0 22 0 0 0 292.3 155.7 501.9 66900 66916 66908 99999 3.88 120.7 630 10.44 2.24 8.82 281 85.7 12.19 176.4 110.9 20.17 58.314 2862.6 454.6 1196.7 9.3 326.9 617.5 1314.6 0 0 299.2 176.1 0 22.8 0 0 0 285.1 174.6 505.4 66996 67018 67007 2.89 3.71 123.5 627.9 10.53 2.26 8.8 286.7 86.6 11.47 171.5 110.1 18.55 51.332 2593.4 370.6 1074.2 10.1 300.9 565.9 1056.9 0 0 271.5 147.1 0 16.4 0 0 0 230.4 160.3 501.6 67040 67060 67050 99999 3.66 119.1 631.3 10.42 2.26 8.79 271.6 85.7 11.04 178 108.5 17.77 46.438 2425.5 294.9 949.3 8.2 275.7 510.3 925.2 0 0 235.3 122.8 0 12.8 0 0 0 217.9 119.4 500.5 67085 67115 67100 2.91 3.75 117.6 635.4 10.79 2.2 8.73 277.3 87.2 9.21 173.2 111.9 13.36 42.609 2062.7 138.1 689.8 4.9 156.1 300.6 676.4 0 0 132.9 78.3 0 8.1 0 0 0 143.9 71.4 510.6 67133 67160 67146 2.7 3.72 123.4 629 10.64 2.18 9 280.2 85.3 10.81 174.5 109.1 15.64 47.376 2337 290.9 941.9 8.4 243.5 449.5 848.9 0 0 217.3 115.8 0 11.8 0 0 0 168.4 130.7 499.9 67178 67195 67186 99999 3.7 119.3 625.8 10.42 2.19 8.71 265 85.6 10.21 175 107.4 6 42.122 2217 196.7 824.4 11.8 209.8 387.8 724.7 0 0 171.5 92.3 0 8.9 0 0 0 151.2 3.1 497.8 67234 67255 67244 99999 3.8 118.5 617.7 10.47 2.31 8.69 266 83.8 10.6 170.6 107.9 17.53 45.4 2343.1 304 941 5.6 270.8 503.7 898 0 0 242.4 133.5 0 15.7 0 0 0 216.4 135.3 497.9 67274 67299 67286 3.03 3.35 116.7 619.9 10.32 2.05 8.72 272.8 83.1 8.77 159.7 108.1 7.74 29.358 1904.9 68.1 593.3 5.9 112.9 211.8 508.1 0 0 76.5 45 0 2.4 0 0 0 97.5 32.3 496.5 67318 67342 67330 2.71 3.54 109.2 612.7 10.33 2.07 8.6 269.1 83.2 8.87 160.8 108.4 6.71 28.431 1824.4 49 565.1 5.8 100.8 192.7 474.3 0 0 62.3 40.4 0 2.1 0 0 0 85.1 21.7 497.4 67365 67395 67380 2.23 3.56 113.3 626.2 10.53 2.12 8.59 252 83.1 8.49 162 108.9 6.91 28.328 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 490.5 67413 67440 67426 2.98 3.37 113.9 616.2 10.2 1.98 8.59 257.8 81.9 8.27 158.5 105.9 5.5 26.305 1637.3 30.9 419.5 2.7 62.5 119.9 411.7 0 0 38.6 23.4 0 2.6 0 0 0 72.6 14.5 492.3 67460 67490 67475 2.83 3.49 109.3 622.1 10.34 2.03 8.49 268.6 82.6 8.11 156 108.1 3.47 24.345 1671.4 20 463 4.6 61.9 123.7 411.3 0 0 35 25.1 0 0 0 0 0 69.1 8.9 492.4 67495 67522 67508 99999 3.44 113 626.7 10.39 2.01 8.45 267.2 83 7.93 156 108.5 2.81 23.518 1705.5 16.5 463.1 4.7 64.2 123.1 399.1 0 0 32.3 25.1 0 0 0 0 0 71.3 4.9 496.6 67539 67570 67554 2.85 3.32 114 621.2 10.19 1.96 8.91 258.6 81 7.84 157.1 107.8 3.03 23.132 1813 18.9 505 2.7 64.8 138.4 405.8 0 0 37.7 25.8 0 3 0 0 0 64.4 6.5 491.2 67984 68015 67999 2.9 3.47 110.1 620.1 10.35 2.03 8.42 265.5 82.4 7.92 155.3 108.1 2.92 22.494 1550.5 12.6 390.8 4.3 52.3 100.6 359 0 0 26.4 18.2 0 0 0 0 0 62 4.9 494.6 68030 68055 68042 3.17 3.44 113 624.3 10.37 1.98 8.32 262.3 81.7 7.55 155 107.7 2.6 21.3 1471.6 10.9 370 4.1 49.2 94.6 335.5 0 0 23.8 18.2 0 0 0 0 0 57.9 3.5 493.2 68064 68094 68079 99999 3.32 111.5 622.5 10.23 1.95 8.27 260.6 81.1 7.08 155.8 107.1 2.59 20.833 1498 13.4 356.4 5.9 46.5 92.1 333.3 0 0 21.6 15.6 0 0 0 0 0 54.2 3.9 492 68100 68130 68115 2.34 3.45 107.4 623.3 10.39 2.01 8.22 263.5 82.4 7.48 153.1 108.2 2.52 20.051 1397 9.3 315 4.8 39.7 75.4 305.3 0 0 17.9 13.6 0 0 0 0 0 63.9 9.5 497.8 68140 68175 68157 3.07 3.36 111.5 625.9 10.28 1.95 8.31 267.2 81.8 7.39 152.6 107.5 2.18 20.391 1489 12 353.6 3.1 43 83.7 316.5 0 0 19.2 14.2 0 2.1 0 0 0 53.8 2.1 496.2 68190 68220 68205 99999 3.37 110.9 620.8 10.26 1.96 8.42 251 81.2 7.62 156.9 107.1 2.5 21.254 1560.6 10.7 375.5 7.4 45.9 85.9 338.7 0 0 21 14.9 0 0 0 0 0 61.7 5 492 68280 68315 68297 2.16 3.39 110.7 631.5 10.32 1.98 8.47 273.8 82.2 7.37 154.2 107.7 2.61 22.18 1525.7 11.3 376 5 46 92.6 334.6 0 0 22.7 17.9 0 0 0 0 0 107.3 4.5 495.4 68335 68370 68352 2.73 3.42 111 605.1 10.07 1.91 8.14 271.6 80.8 7.92 151.2 105.3 3.66 24.869 1709 20.9 491.4 2.7 69.6 138.3 409.8 0 0 38.8 26.4 0 0 0 0 0 62.3 0 497.3 68380 68415 68397 2.67 3.36 108.6 629.4 10.23 1.89 8.19 259.2 80.9 6.69 147.2 105.3 1.59 17.327 1266.3 20.4 333.8 9.4 45.2 90.7 295.9 0 0 21.2 15.3 0 0 0 0 0 35 0 482.9 68420 68460 68440 99999 3.08 104.2 619.1 10.05 1.77 7.72 246.3 78.4 5.45 139.4 102.9 0.79 9.648 772.7 99999 132 99999 15.5 26.2 161.1 0 0 4.2 3 0 0 0 0 0 18.6 0 484.2 68470 68515 68492 2.61 3.13 99.1 593.7 9.8 1.67 7.42 249.7 75.8 4.38 131.6 100.2 0.75 5.955 501.4 99999 66.5 99999 5.4 9.6 90.4 0 0 2.6 0 0 0 0 0 0 0 0 471.4 68520 68567 68543 2.17 3.13 102.2 606.7 10.01 1.7 7.55 256.2 77.7 4.04 132.5 101 0.55 4.998 435.6 99999 50.9 99999 3.4 6.1 78.5 0 0 0 2.1 0 0 0 0 0 8.3 0 477.5 68573 68622 68597 99999 2.97 97.6 589.2 9.9 1.65 7.49 244.2 75.9 4.08 130.1 99.2 0.51 3.811 348.6 99999 32.4 99999 0 5.4 59.6 0 0 0 0 0 0 0 0 0 6.1 0 475.2 68872 68920 68896 2.37 3.15 101.7 597.2 9.95 1.66 7.35 250.9 75.6 3.99 131.6 99.6 0.76 5.035 365.4 99999 45.1 99999 4.3 7.4 73.2 0 0 2.5 2 0 0 0 0 0 0 0 476.1 70298 70342 70320 2.32 3 100.8 589.3 9.84 1.61 7.24 254.2 75.2 3.35 126.7 98.5 0.43 2.196 239.8 99999 13.7 99999 0 2.3 28.9 0 0 0 0 0 0 0 0 0 0 0 470.5 71170 71220 71195 99999 2.84 97.5 579.1 9.89 1.57 7.12 242.8 74.3 3.33 124.3 96.9 0.4 1.503 170.8 99999 4.6 99999 0 0 18.8 0 0 0 0 0 0 0 0 0 2 0 469.4 71263 71319 71291 2.37 2.86 93.2 565.5 9.63 1.49 6.8 234.7 72.7 2.87 118.8 93.9 0.37 1.05 131.5 99999 3.8 99999 0 0 12.2 0 0 0 0 0 0 0 0 0 3.1 0 456.4 71335 71395 71365 2.82 2.87 93.3 561.3 9.59 1.46 6.63 222.5 71.3 2.93 118.4 92.8 0.41 0.918 128.2 99999 3.1 99999 0 0 10.4 0 0 0 0 0 0 0 0 0 6.5 0 459.7 71419 71487 71453 2.87 2.76 94.2 550.4 9.56 1.45 6.54 229.2 71.6 2.4 118.1 92.4 0.38 1.147 125.8 99999 2.9 99999 0 0 9.1 0 0 0 0 0 0 0 0 0 5 0 455.3 71505 71579 71542 3.15 2.7 91.7 552.7 9.49 1.43 6.48 225.8 71.2 2.7 116.9 91.2 0.44 1.16 137.6 99999 3.6 99999 0 0 12.4 0 0 0 0 0 0 0 0 0 5.2 0 454.9 71586 71670 71628 2.27 2.76 93.2 555.1 9.67 1.41 6.46 230.5 70.9 2.76 117.3 90.7 0.41 0.824 111.1 99999 4 99999 0 0 7.9 0 0 2.2 0 0 0 0 0 0 4.1 0 450.9 72570 72658 72614 2.39 2.75 98.3 568.9 9.59 1.5 6.61 233.9 72.9 2.39 120.3 94.5 0.38 0.984 155.3 99999 3.5 99999 0 0 12.2 0 0 0 0 0 0 0 0 0 2.1 0 461.6 73540 73630 73585 3.13 2.8 94.5 565.3 9.6 1.5 6.69 229.3 72.7 2.74 118.9 93.7 0.46 1.062 171.7 99999 4 99999 0 0 9.4 0 0 0 0 0 0 0 0 0 3.2 0 461.7 74500 74585 74542 2.65 2.54 91.7 530.5 9.34 1.26 5.98 208.3 67.3 2.32 109.3 84.1 0.41 0.451 73.6 99999 3.6 99999 0 0 6 0 0 2.6 0 0 0 0 0 0 2.7 0 437.8 75480 75565 75522 2.48 2.59 87.7 522 9.2 1.25 5.85 210.3 67.7 2.11 106.1 84.8 0.26 0.604 76.6 99999 3.5 99999 0 0 6.2 0 0 0 0 0 0 0 0 0 3.2 0 436.9 76435 76520 76477 2.34 2.46 88.4 515.8 9.1 1.22 5.75 200.8 66.8 2.26 105.2 82.9 0.3 0.472 71.3 99999 2.4 99999 0 0 5.6 0 0 0 0 0 0 0 0 0 0 0 432.9 76970 77055 77012 2.09 2.78 91.1 530.8 9.22 1.29 5.99 216.3 68.3 2.48 108.1 85 0.31 0.499 83.6 99999 0 99999 0 0 7 0 0 0 0 0 0 0 0 0 3 0 439.3 78270 78355 78312 2.85 2.54 88.2 531.3 9.29 1.31 6.07 213.8 69 2.34 109.7 86.5 0.36 0.837 95.4 99999 0 99999 0 0 5.2 0 0 0 0 0 0 0 0 0 5.9 0 442.2 79605 79690 79647 2.25 2.6 89.7 517.4 9.1 1.25 5.78 203.1 66.8 2.02 105 83.5 0.27 0.498 80.2 99999 0 99999 0 0 6.4 0 0 12.6 0 0 0 0 0 0 0 0 437.2 80613 80682 80647 3.17 2.49 91.6 536.6 9.42 1.3 5.89 220.3 68.4 2.49 109.9 85.6 0.34 0.529 82.1 99999 2.7 99999 0 0 5.4 0 0 0 0 0 0 0 0 0 4.6 0 445