84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2018, 05, 17, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 37508,37521,410.93,1866.72,84.07,331.13,9.7,542.18,-47.352,-8.666,102.47,246.95,505.92,594.09,22.2,3.33,7.14,229.47,24.96,0.044,70.48,60.23,10.33,1.889,79.83,0.781,1.131,0.29,7.75,517.9,0.365,7.31,0.403,1.007,0.19,0.25,1.46,3,0.89,0.498,0.001,0.005,0.104,13.15,72.6,1.65,5.39,11.55,0.188,0,0.382,0.151 38698,38707,412.69,1902.89,114.04,330.54,9.83,533.59,-47.418,-8.756,106.13,253.23,503.79,576.63,22.8,3.36,7.27,229.14,25.59,0.038,70.26,80.43,15.75,1.999,79.79,0.859,1.996,0.35,21.16,515,0.459,9.55,0.413,1.1,0.56,0.41,1.48,1.89,0.71,0.538,0,0.002,0.139,21.01,111.44,1.14,6.07,10.49,0.214,-0.012,0.795,0.148 39164,39170,413.18,1917.54,111.31,331.34,9.81,522.08,-47.532,-8.85,110.03,255.66,506.72,564.31,22.98,3.4,7.18,230.27,26,0.777,70.51,77.34,16.57,2.026,79.89,1.117,2.531,1.13,21.72,524.6,0.482,12.27,0.429,1.156,0.24,0.43,1.49,4.89,0.69,0.547,0.029,0.002,0.147,18.7,140.05,1.93,7.21,11.21,0.271,0.015,0.579,0.276 40156,40168,411.96,1884.82,96.35,329.53,9.67,538.56,-47.378,-8.707,104.83,251.3,504.61,605.1,22.44,3.35,7.39,229.66,25.42,0.049,70.66,75.85,13.09,1.898,79.99,0.785,1.579,0.37,13.32,525.2,0.416,8.24,0.416,1.03,0.31,0.43,1.46,5.67,0.96,0.534,-0.004,0.002,0.106,20.79,139.76,2.93,9.84,22.02,0.199,0,0.418,0.152 40629,40643,411.31,1895.96,109.82,331.37,9.64,543.95,-47.45,-8.682,109.24,252.44,504.86,616.46,22.42,3.36,7.48,229.74,25.62,0.107,70.65,66.76,12.19,2,79.96,0.832,1.889,0.48,17.64,517.7,0.401,11.02,0.41,1.045,0.69,0.43,1.47,13.69,1.9,0.519,0.001,0.005,0.191,15.88,336.32,11.58,26.56,65.35,0.226,-0.005,0.383,0.182 41929,41935,412.93,1913.83,107.52,331.43,9.86,524.14,-47.483,-8.793,110.65,255.59,504.98,563.89,22.85,3.4,7.25,229.87,26.04,0.272,70.5,73.86,15.26,2.034,80.1,0.928,2.369,0.68,14.23,520,0.476,12.58,0.422,1.137,0.01,0.42,1.5,4.02,0.61,0.535,0.004,0.007,0.145,17.64,132.11,1.51,6.02,10.81,0.256,-0.01,0.58,0.213 42403,42410,412.3,1910.84,106.38,332.19,9.9,524.99,-47.452,-8.781,109.02,254.18,505.49,562.9,22.88,3.35,7.16,229.87,25.85,1.115,70.51,75.88,15.86,2.004,79.68,1.086,2.235,0.96,17.7,533.4,0.46,11.66,0.416,1.141,0.26,0.47,1.5,5.36,0.91,0.536,0.027,0.006,0.145,17.68,92.67,1.39,5.07,6.67,0.249,-0.004,0.492,0.265 44535,44548,411.26,1886.79,104.17,332.06,9.79,541.46,-47.389,-8.677,106.39,251.35,505.34,596.14,22.39,3.36,7.33,229.14,25.37,0.064,70.39,69.06,12.27,1.941,79.91,0.797,2.013,0.35,20.19,518.8,0.411,9.39,0.407,1.04,0.98,0.39,1.46,9.94,1.81,0.523,0.006,0.005,0.134,16.66,269.46,7.99,19.46,49.09,0.247,0.003,0.503,0.17 45639,45648,412.28,1897.17,106.3,329.44,9.74,535.78,-47.342,-8.745,105.74,253.27,505.73,585.57,22.63,3.35,7.32,228.33,25.58,0.061,70.12,80.91,15.71,1.956,79.67,0.79,1.931,0.33,20.83,531.4,0.444,8.98,0.407,1.078,0.33,0.52,1.45,4.26,1.03,0.528,0.001,0.002,0.127,22.05,133.48,2.15,8.45,15.51,0.24,-0.006,0.829,0.15 46362,46369,413.81,1933.42,121.66,331.28,9.79,514.02,-47.539,-8.885,107.79,254.29,506.33,561.62,23.02,3.4,7.06,230.17,25.96,0.222,70.45,82.16,18.13,2.054,79.53,1.111,2.498,1.18,31.76,511.8,0.511,11.22,0.414,1.157,0.3,0.62,1.51,6.03,1.22,0.536,0.007,0.009,0.142,19.77,167.15,2.96,10.49,13.95,0.28,-0.008,0.622,0.283 46920,46928,412.93,1916.53,114.53,331.74,9.78,521.23,-47.546,-8.809,108.14,254.73,506.59,570.78,22.84,3.38,7.26,230.14,25.96,0.193,70.34,79.49,16.28,1.987,79.98,0.908,2.33,0.54,22.48,519.1,0.478,10.98,0.419,1.126,0.5,0.52,1.51,6.69,1.22,0.547,0.001,0.009,0.134,20.12,162.4,3.49,10.63,18.2,0.239,-0.003,0.728,0.208 48409,48423,412.06,1883.31,99.31,330.59,9.71,545.41,-47.363,-8.741,104.32,252.21,506.79,618.39,22.34,3.36,7.48,229.67,25.49,0.029,70.56,84.78,13.19,1.889,79.95,0.7,1.437,0.17,7.52,498.1,0.411,7.47,0.412,1.012,0.39,0.36,1.47,1.16,0.73,0.538,0.003,0,0.108,22.51,40.54,0.25,2.2,2.92,0.172,-0.011,0.395,0.099 51395,51406,413.22,1911.12,116.71,330.7,9.76,529.77,-47.362,-8.82,107.26,256.67,505.52,578.73,23.04,3.36,7.27,229.82,26.04,0.066,70.1,86.71,17.99,1.967,80.36,0.871,2.335,0.39,19.2,517.4,0.501,10.3,0.415,1.14,0.62,0.56,1.52,1.21,0.55,0.551,0.001,0.006,0.129,25.13,97.94,0.62,3.94,6.1,0.214,0.011,0.888,0.156 52106,52113,414.11,1934.74,120.96,331.34,9.8,513.14,-47.535,-8.906,107.73,254.8,506.97,559.91,23.02,3.4,7.14,230.05,25.75,0.603,70.56,79.41,17.99,2.085,79.88,1.165,2.339,1.58,33.82,515.3,0.499,11.15,0.417,1.166,0.16,0.62,1.51,3.37,0.53,0.546,0.072,0.007,0.139,19.83,156.62,1.52,8.63,11.58,0.289,0,0.625,0.344 56422,56440,411.67,1892.88,98.84,327.66,9.63,529.4,-47.364,-8.747,105.05,251.73,502.28,572.5,22.62,3.34,7.32,226.14,25.41,0.052,69.99,73.68,13.56,2.035,80.03,0.752,1.869,0.13,10.23,457.4,0.442,9.65,0.41,1.166,0.39,0.48,1.47,1.55,0.63,0.518,0.008,0.003,0.12,19.29,117.56,0.93,4.97,9.11,0.166,-0.01,0.499,0.104 57282,57289,414.37,1933.31,121.09,330.87,9.77,512.87,-47.549,-8.946,107.41,254.36,506.16,555.02,22.92,3.41,6.93,229.64,25.94,0.483,70.36,78.93,18.3,2.094,79.75,1.319,2.565,2.51,30.69,513.8,0.513,11.08,0.409,1.156,0.27,0.62,1.47,3.04,0.59,0.525,0.014,0.005,0.145,19.08,156.18,2.36,8.78,12.51,0.325,-0.014,0.624,0.389 57804,57812,414.98,1930.37,117.88,331.86,9.82,516.42,-47.548,-8.924,107.87,254.84,506.42,558.14,23.01,3.41,6.97,229.59,25.81,0.192,70.23,77.97,17.68,2.048,79.53,1.106,2.462,1.05,26.33,512.1,0.497,11.43,0.432,1.151,0.21,0.57,1.49,3.71,1.65,0.53,0.027,0.011,0.136,18.62,163.63,2.35,8.7,13.29,0.271,-0.014,0.613,0.287 59464,59495,405.13,1762.48,38.67,308.57,9.21,542.39,-46.805,-8.491,92.4,230.89,469.84,507.02,21.13,2.79,5.93,200.2,21.61,0.073,62.6,26.63,1.92,1.295,64.84,0.048,0.207,0.05,2.64,363.4,0.269,5.25,0.314,0.69,0.19,0.1,1.29,1.33,1.33,0.414,0.003,0.004,0.021,0.8,6.93,0.23,0.81,1.21,0.011,0.003,0.055,0.015 62805,62837,402.8,1680.81,29.92,289.57,8.85,546.71,-46.329,-8.426,86.63,221.29,439.13,442.78,20.4,2.4,4.38,175.88,18.55,0.157,53.29,14.3,0.62,0.817,49.92,-0.001,0.936,0.03,2.64,303.6,0.236,4.44,0.242,0.459,0.83,0.12,1.16,1.87,1.57,0.376,0.003,0.014,0.009,0.21,11.66,0.3,1.02,1.65,0.007,0.009,0.13,0.006 67905,67912,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99