84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2018, 05, 14, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 39699,39716,407.13,1864.7,77.18,331.24,9.55,525.67,-999.99,-999.99,98.41,238.56,503.82,591.62,21.83,3.3,6.97,228.02,23.93,0.029,69.76,29.37,7.4,1.808,78.67,0.652,0.572,0.13,1.46,436.5,0.298,5.76,0.402,0.913,0.56,0.11,1.39,1.18,0.51,0.427,-0.002,0.002,0.087,4.23,21.21,2.12,2.41,3.06,0.132,0.014,0.244,0.075 41131,41138,406.44,1843.83,65.1,330.65,9.45,531.34,-999.99,-999.99,97.77,237.16,504.86,570.21,21.63,3.32,6.87,228.01,23.71,0.036,70.21,24.86,5.92,1.835,79.37,0.596,0.562,0.16,2.23,489.6,0.274,5.45,0.407,0.92,0.19,0.1,1.36,1.5,0.42,0.422,0.001,0.004,0.077,3.24,6.99,1.28,1.09,0.45,0.115,-0.011,0.146,0.074 41599,41606,406.39,1830.49,67.07,329.78,9.46,531.21,-999.99,-999.99,97.97,237.15,505.59,575.57,21.65,3.3,6.72,228.34,23.88,0.703,70.58,24.48,6.7,1.872,79.48,0.657,0.747,0.37,5.88,525.8,0.28,5.28,0.406,0.923,0.25,0.14,1.47,8.24,0.44,0.427,0.064,0.008,0.088,3.12,5.31,2.5,3.09,0.82,0.133,0.016,0.134,0.121 42854,42865,406.27,1849.86,77.28,330.65,9.49,528.91,-999.99,-999.99,97.63,237.55,503.74,588.63,21.57,3.3,7.09,227.63,23.7,0.026,70.01,26.74,6.66,1.856,79.32,0.652,0.605,0.16,2.79,476.8,0.277,5.62,0.401,0.919,0.26,0.18,1.37,2.25,0.51,0.421,0.003,0.001,0.088,3.44,21.91,1.31,1.55,1.06,0.142,0.005,0.08,0.088 43650,43666,407.71,1861.28,93.04,331.26,9.54,533.77,-999.99,-999.99,99.98,240.93,507.14,603.22,21.9,3.35,7.31,229.2,24.19,0.034,70.24,33.7,7.64,1.841,79.63,0.71,0.734,0.17,3.61,460.4,0.311,6.38,0.406,0.96,0.17,0.14,1.4,0.65,0.52,0.45,0.003,0.004,0.091,4.87,25.2,1.03,1.76,2.28,0.148,-0.009,0.202,0.095 45365,45371,407.15,1846.92,83.45,330.17,9.47,533.18,-999.99,-999.99,98.65,239,504.48,589.96,21.7,3.29,7.1,227.8,23.98,0.348,70.33,28.69,7.02,1.834,79.49,0.676,0.874,0.31,7.72,517.4,0.295,5.81,0.408,0.93,0.24,0.17,1.41,9.53,0.49,0.445,0.006,0.012,0.094,3.99,10.61,2.16,3.62,1.04,0.145,-0.012,0.204,0.099 45693,45699,407.06,1844.87,82.87,330.1,9.46,532.79,-999.99,-999.99,98.56,238.71,507,591.76,21.77,3.31,7.12,229.16,23.95,0.615,70.28,28.14,6.99,1.853,79.42,0.682,0.879,0.37,10.64,506.1,0.289,5.72,0.419,0.946,0.18,0.15,1.5,7.67,0.63,0.434,0.029,0.004,0.106,3.92,9.03,2.43,2.72,0.53,0.15,-0.001,0.089,0.109 45743,45750,406.94,1845.96,83.23,330.99,9.48,532.32,-999.99,-999.99,98.74,238.22,507.1,591.93,21.78,3.33,7.18,228.72,23.83,0.601,70.29,28.28,7.16,1.846,79.53,0.686,1.071,0.38,8.81,506,0.289,5.72,0.402,0.941,0.24,0.18,1.38,10.6,0.55,0.434,0.051,0.012,0.089,3.88,9.21,3.24,3.75,0.66,0.155,0.012,0.216,0.125 47834,47851,408.5,1865.75,93.75,330.69,9.64,533.41,-999.99,-999.99,101.49,242.09,502.86,594.05,22.01,3.34,7.24,228.26,24.37,0.147,70.34,38.87,8.72,1.888,79.53,0.824,1.079,0.56,9.97,499.1,0.329,7.01,0.414,0.987,0.35,0.24,1.41,2.74,0.59,0.456,0.004,0.005,0.102,6.73,23.98,1.67,2.01,1.76,0.2,-0.004,0.158,0.172 48998,49005,410.39,1875.37,145.66,330.83,9.65,547.17,-999.99,-999.99,101.88,243.89,505.85,619.06,22.08,3.33,7.6,229.29,24.58,0.399,70.18,42.09,8.88,1.887,79.32,0.813,1.209,0.44,40.68,523.7,0.339,7.34,0.419,0.996,2.35,0.28,1.43,5.23,0.83,0.461,0.003,0.007,0.108,7.45,53.73,3.76,4.16,4.82,0.19,-0.005,0.218,0.155 49435,49442,409.89,1883.37,98.49,331.02,9.68,532.03,-999.99,-999.99,105.21,247.44,504.95,583.83,22.25,3.37,7.25,229.02,24.9,0.805,70.25,52.68,11.3,1.963,79.46,0.981,1.751,0.99,10.92,539.4,0.382,8.97,0.415,1.083,0.23,0.29,1.45,6.92,0.64,0.486,0.057,0.008,0.136,10.78,19.77,3.69,3.14,1.08,0.281,0.005,0.355,0.272 51602,51624,409.61,1872.85,103.47,331.07,9.65,536.96,-999.99,-999.99,101.83,243.66,505.46,606.62,22.16,3.34,7.3,229.17,24.45,0.042,70.58,41.34,9.13,1.877,79.99,0.851,0.991,0.25,3.73,498.8,0.352,7.3,0.415,1.02,0.54,0.22,1.46,2.41,0.86,0.464,0.001,0.006,0.106,6.84,40.19,2.74,2.72,3.68,0.19,-0.001,0.167,0.135 52638,52651,409.55,1869.2,101.49,331.34,9.62,538.09,-47.264,-8.444,101.14,243.26,506.48,603.43,22.13,3.41,7.29,229.09,24.42,0.094,70.55,39.6,8.74,1.886,79.62,0.833,1.062,0.5,14.84,511.5,0.336,7.09,0.414,1.01,0.39,0.19,1.46,1.74,0.54,0.452,0,0.005,0.1,6.95,39.3,0.61,1.78,2.98,0.167,-0.005,0.302,0.15 53512,53519,411.26,1890.31,99.28,332.03,9.73,530.86,-47.362,-8.623,106.25,251.03,507.74,580.54,22.63,3.35,7.33,229.81,25.38,0.559,70.61,60.4,12.84,1.987,80.18,1.088,1.771,1.29,11.95,558.5,0.413,9.35,0.417,1.099,0.05,0.34,1.47,5.2,0.49,0.506,0.013,0.004,0.138,13.8,23.81,0.71,1.82,0.99,0.315,-0.008,0.386,0.306 54058,54065,410.5,1872.82,132.32,330.66,9.61,542.9,-47.295,-8.607,101.5,243.86,506.47,616.18,22.1,3.35,7.59,228.91,24.52,0.273,70.24,41.37,8.8,1.93,79.46,0.764,1.109,0.38,37.44,515.8,0.345,7,0.408,0.991,2.14,0.3,1.42,7.79,0.97,0.459,0.007,0.005,0.101,7.82,58.84,3.02,5.72,8.19,0.185,0.001,0.227,0.126 55942,55964,408.57,1867.21,87.9,330.47,9.53,531.01,-47.367,-8.556,100.52,242.54,506.87,600.53,22.02,3.34,7.25,229.03,24.36,0.033,70.23,36.6,8.41,1.853,79.9,0.758,0.865,0.12,2.34,487.3,0.326,6.73,0.414,1.007,0.15,0.18,1.4,1.84,0.6,0.449,0.005,0.005,0.103,5.78,33.17,0.44,1.88,3.29,0.152,-0.009,0.136,0.076 56664,56676,410.57,1869.26,81.99,331.41,9.67,539.05,-47.355,-8.641,102.35,244.72,504.78,604.07,22.11,3.33,7.08,228.48,24.61,0.033,70.25,44.95,9.05,1.912,79.66,0.844,1.255,0.4,3.89,502.3,0.358,7.54,0.41,1.004,0.04,0.18,1.43,0.63,0.61,0.474,0,0,0.114,8.2,61.72,0.36,2.24,3.77,0.166,-0.032,0.223,0.134 57753,57760,411.99,1893.9,96.85,330.88,9.66,530.09,-47.357,-8.721,107.32,252.8,507.96,573.73,22.69,3.39,7.22,230.3,25.6,0.532,70.86,68.26,14.07,2.001,80.26,1.019,1.943,0.91,10.39,571.5,0.436,9.79,0.417,1.103,0.18,0.36,1.51,5.28,0.62,0.507,0.01,0.016,0.136,16.47,36.72,0.79,2.59,1.73,0.265,-0.008,0.523,0.236 58673,58686,410.4,1867.25,80.52,330.8,9.6,539.88,-47.254,-8.656,101.84,243.59,505.17,598.59,22.1,3.35,7.08,228.39,24.51,0.047,70.15,42.2,8.73,1.95,79.69,0.831,1.28,0.47,3.99,522.9,0.336,7.4,0.41,1.008,-0.03,0.29,1.42,2.17,0.58,0.475,0.005,0.003,0.113,7.63,56.43,0.5,2.04,3.28,0.169,0.01,0.147,0.13 59424,59447,408.89,1867.5,90.09,331.49,9.57,532.76,-47.294,-8.592,101.14,243,506.71,598.93,22.1,3.35,7.2,228.91,24.37,0.042,70.66,38.4,8.77,1.921,80.26,0.791,1.497,0.29,3.72,491.4,0.335,7.07,0.406,1.016,0.35,0.2,1.41,1.67,0.68,0.453,0.006,0.006,0.105,6.72,27.48,0.62,1.78,2.67,0.176,-0.005,0.339,0.126 61186,61194,412.06,1899.29,97.84,329.87,9.75,528.64,-47.382,-8.746,106.89,251.87,504.45,571.14,22.62,3.38,7.2,228.9,25.5,0.737,69.96,68.55,14.64,1.972,79.54,1.009,2.08,1.14,12.17,562.8,0.442,10.07,0.414,1.112,0.13,0.37,1.47,5.87,0.6,0.512,0.014,0.006,0.146,16.67,44.62,1.11,3.23,2.7,0.244,-0.01,0.426,0.243 61801,61810,410.75,1866.15,95.2,330.76,9.56,543.6,-47.217,-8.655,101.99,244.09,506.87,588.61,22.16,3.4,7.2,229.64,24.58,0.079,70.54,39.14,7.91,1.958,80.01,0.689,1.397,0.22,7.55,523.8,0.343,7.17,0.413,0.994,0.16,0.24,1.42,4.46,0.8,0.47,0.008,0.009,0.092,6.64,23.1,0.69,1.43,0.9,0.146,-0.001,0.193,0.095 63467,63488,411.58,1873.89,96.23,331.17,9.65,542.92,-47.345,-8.684,102.56,246.69,506.74,622.32,22.2,3.35,7.31,229.26,24.9,0.046,70.56,52.09,9.97,1.883,79.95,0.872,1.508,0.36,6.16,517.3,0.365,7.6,0.412,1.046,1.13,0.21,1.41,2.14,0.89,0.481,0.009,0.005,0.109,10.05,92.35,1.59,3.6,8.71,0.177,-0.001,0.354,0.136 66830,66837,412.48,1901.17,104.97,331.35,9.76,527.55,-47.337,-8.763,106.88,253.97,505.33,578.81,22.82,3.38,7.23,229.79,25.71,0.044,70.74,73.32,14.81,1.965,80,0.788,2.411,0.27,12.82,545.5,0.46,9.98,0.41,1.088,0.58,0.4,1.5,3.68,0.87,0.524,0.002,0.003,0.119,20.02,168.3,2.28,9.27,19.28,0.186,-0.016,0.545,0.14