84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2018, 04, 27, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 59713,59727,413.49,1906.15,140.76,331.6,9.98,546.41,-47.336,-8.787,106.53,259.02,507.16,652.47,22.53,3.4,8.01,229.82,26.5,0.044,70.73,131.15,18.14,1.944,80.68,0.832,2.662,0.35,25.21,543.3,0.45,8.33,0.402,1.053,0.57,0.67,1.53,2.24,0.6,0.551,-0.001,0.001,0.127,45.36,110.67,2.85,10.42,15.87,0.206,-0.003,0.643,0.152 61761,61768,413.6,1921.28,126.26,330.78,9.76,521.03,-47.457,-8.85,107.03,255.19,507.57,581.94,22.87,3.41,7.16,230.39,25.81,0.309,70.49,81.84,19.04,2.011,80.16,1.028,2.588,0.77,38.15,557.1,0.498,10.67,0.417,1.127,0.39,0.62,1.5,2.45,0.43,0.536,0.006,0,0.141,22.38,172,2.82,11.46,15.35,0.239,-0.005,0.674,0.213 62003,62009,413.12,1924.23,129.91,331.17,9.81,517.47,-47.383,-8.84,107.86,256.01,507.95,581.01,22.93,3.42,7.23,230.28,25.93,0.565,70.53,83.24,19.49,2.026,79.99,1.108,2.737,1.04,41.96,554.6,0.513,11.41,0.42,1.154,0.42,0.62,1.49,3.6,0.54,0.531,0.018,-0.002,0.144,22.52,170.52,4.24,13.17,15.85,0.254,0.009,0.667,0.236 62853,62865,411.67,1894.49,108.08,329.48,9.72,531.79,-47.335,-8.749,104.83,252.65,504.73,592.29,22.53,3.33,7.35,227.77,25.39,0.049,70.08,79.69,15.5,1.95,79.66,0.857,1.939,0.34,12.2,549.6,0.45,9.13,0.403,1.046,0.15,0.48,1.47,1.89,0.46,0.526,0.006,0.001,0.111,22.74,151.97,1.74,8.84,15.68,0.219,0.005,0.54,0.159 63656,63671,409.11,1847.93,82.42,323.48,9.52,539.39,-47.134,-8.658,99.83,244.22,493.8,574.53,21.97,3.15,7.08,219.06,24.3,0.078,68.33,63.9,10.92,1.869,75.77,0.627,0.978,0.1,3.35,488.3,0.362,7.2,0.384,0.942,0.05,0.34,1.4,0.88,0.67,0.503,0.036,-0.001,0.108,14.5,83.46,0.78,4.51,7.29,0.127,-0.011,0.316,0.069 64923,64932,412.14,1911.25,117.74,330.96,9.75,523.73,-47.416,-8.796,107.49,254.9,507.22,582.01,22.78,3.41,7.5,229.82,25.87,0.085,70.57,77.36,16.74,2.009,80.14,0.896,2.427,0.45,25.47,542,0.47,11.93,0.416,1.103,0.47,0.49,1.5,2.26,0.62,0.528,0.001,0,0.119,21.22,162.18,3.72,9.3,17.64,0.226,0.004,0.714,0.182 65413,65419,414.1,1930.49,134.25,331.85,9.78,518.5,-47.471,-8.923,107.52,255.29,506.85,576.97,22.88,3.4,7.18,229.42,25.82,0.519,70.34,84.85,19.45,2.038,79.62,1.163,2.882,1.17,48.21,565.3,0.517,11.08,0.426,1.13,0.57,0.63,1.5,3.53,0.89,0.538,0.069,0.008,0.157,23.36,250.85,4.12,17.78,28.11,0.26,0.011,0.61,0.258 66440,66452,412.45,1909.03,116.93,330.24,9.88,526.99,-47.377,-8.752,106.55,255.05,505.95,594.39,22.93,3.37,7.42,229.55,25.82,0.055,70.44,87.92,18.08,2.014,79.94,0.895,2.68,0.42,26.68,550.2,0.488,9.95,0.423,1.06,0.33,0.63,1.5,4.41,0.77,0.561,0.008,0.003,0.133,27.95,230.12,4.38,16.74,28.47,0.264,-0.006,0.878,0.199 67755,67772,406.98,1812.15,57.41,317.34,9.39,541.1,-47.066,-8.575,96.08,237.93,485.39,541.3,21.59,3,6.83,211.58,23.1,0.106,66.89,41.51,6.84,1.75,72.46,0.442,0.42,0.05,1.55,459.3,0.314,6.22,0.359,0.894,0.13,0.16,1.32,0.88,0.88,0.445,0.047,0.003,0.07,4.86,48.77,0.3,2.16,2.96,0.08,-0.001,0.102,0.037 71453,71460,415.35,1930.79,151.89,331.17,9.82,531.93,-47.395,-8.912,107.63,260.34,505.98,602.21,23.33,3.39,7.43,231.13,26.1,0.146,70.42,103.32,27.06,2.017,80.41,0.892,2.954,0.38,49.77,598.4,0.596,10.63,0.422,1.104,0.5,0.82,1.52,1.41,0.56,0.535,0.002,0.005,0.145,37.71,188.69,1.3,9.86,13.66,0.225,-0.01,1.401,0.171 71866,71874,415.02,1934.86,136.53,330.67,9.77,518.28,-47.494,-8.947,107.58,255,505.39,572.87,22.86,3.38,7.03,229.65,25.93,0.533,70.49,84.73,19.39,2.02,79.57,1.17,2.925,1.09,56.59,580.4,0.492,11.06,0.422,1.151,0.88,0.71,1.5,5.85,0.96,0.532,0.046,0.004,0.146,22.28,306.16,6.39,25.76,36.98,0.262,0.003,0.665,0.286 72946,72957,413.9,1924.12,138.03,331.43,9.95,529.66,-47.28,-8.844,108.15,261.65,505.67,601.57,23.27,3.39,7.65,230.92,26.48,0.126,70.34,109.03,23.22,2.001,80.49,0.966,2.968,0.63,38.56,582.4,0.555,10.68,0.426,1.214,0.31,0.88,1.52,2.97,0.83,0.571,0.004,0.001,0.14,35.58,199.41,3.52,14.36,20.45,0.278,-0.001,0.99,0.211 73792,73812,410.65,1877.57,93.18,329.28,9.63,539,-47.232,-8.71,103.09,247.46,501.79,593.84,22.31,3.31,7.22,226.49,24.81,0.057,69.53,57.04,10.13,1.875,78.27,0.706,1.297,0.16,2.67,472.9,0.379,8.45,0.392,0.973,0.11,0.3,1.41,2.87,0.49,0.484,0.006,0.003,0.118,9.45,131.91,1.57,7.37,16.97,0.165,-0.011,0.314,0.1 75170,75179,414,1923.01,129.62,331.37,9.77,522.19,-47.346,-8.849,106.7,254.12,504.34,582.29,22.85,3.42,7.25,229.63,25.73,0.056,70.39,83.93,18.33,2.066,79.82,1.022,2.94,0.61,44.53,511.9,0.508,10.6,0.409,1.127,0.86,0.6,1.43,6.47,1.13,0.54,0.004,0.003,0.147,23.82,299.34,5.4,21.89,37.03,0.253,0.004,0.616,0.211 75715,75722,415.85,1938.9,135.98,331.78,9.84,514.46,-47.519,-8.969,107.45,255.14,507.71,570.32,22.94,3.38,6.98,230.3,25.97,0.343,70.49,84.24,19.64,2.069,80.09,1.194,3.043,1.19,58.11,525.7,0.512,10.84,0.418,1.146,0.52,0.69,1.49,6.82,1.19,0.545,0.051,0.011,0.137,22.46,323.83,6.26,25.84,38.17,0.29,-0.003,0.571,0.291 76715,76728,416.54,1929.06,180.71,331.87,9.78,520.78,-47.385,-8.966,107.74,252.68,504.89,587.41,22.77,3.4,7.09,230.14,25.68,0.074,70.69,74.79,16.5,2.026,79.95,0.96,2.887,0.49,76.33,490.8,0.475,10.78,0.414,1.123,7.41,0.51,1.43,7.9,1.51,0.515,0.018,0.002,0.143,18.9,326.38,6.39,22.05,39.76,0.212,-0.01,0.398,0.182 78110,78137,402.84,1695.07,31.37,292.58,8.88,545.74,-46.222,-8.419,86.71,222.36,442.56,452.54,20.63,2.41,5.18,180.15,20.03,0.314,59.19,21.94,2.51,1.414,59.12,0.104,0.309,0.01,3.14,345.4,0.239,4.48,0.273,0.684,0.26,0.12,1.17,2.82,2.2,0.39,0.062,0.022,0.026,0.62,44.39,0.35,1.11,2,0.008,-0.012,0.039,-0.005 82858,82891,403.34,1716.97,32.41,298.1,8.95,543.84,-46.362,-8.43,88.31,224.61,451.26,466.19,20.75,2.56,5.17,186.54,20.05,0.193,57.07,22.28,2.26,1.161,54.99,0.104,0.244,0.01,1.97,337.2,0.256,4.7,0.267,0.564,0.25,0.1,1.2,1.86,1.78,0.4,0.017,0.01,0.027,0.59,40.13,0.28,0.72,1.67,0.007,-0.007,0.147,0.011 83888,83902,412.48,1907.88,118.48,329.04,9.78,528.24,-47.293,-8.774,105.35,253.98,502.92,590.31,22.98,3.35,7.36,228.16,25.57,0.062,70,87.31,18.86,1.984,79.2,0.916,2.704,0.33,28.22,495,0.538,9.89,0.399,1.082,0.41,0.66,1.46,6.01,1.14,0.541,0.008,0.003,0.141,25.62,251.3,4.64,17.65,31.42,0.224,-0.02,0.683,0.152 84361,84370,414.33,1927.83,128.34,330.38,9.74,519.47,-47.433,-8.869,107.15,253.93,506,577.46,22.92,3.39,7.16,229.13,25.73,0.093,70.46,80.44,17.4,2.035,79.94,1.025,3.456,0.64,45.6,516.8,0.5,10.81,0.411,1.119,0.83,0.58,1.48,8.29,1.52,0.529,0.036,0.011,0.147,22.16,336.55,6.89,25.39,43.13,0.251,-0.017,0.632,0.212 84799,84806,415.7,1942.96,138.06,331.21,9.87,513.78,-47.634,-8.96,107.47,255.37,506.81,572.1,22.97,3.41,7.27,230.21,25.93,0.108,70.54,84,19.04,2.063,80.09,1.117,3.033,1.31,60.87,519.5,0.509,11.08,0.422,1.136,0.17,0.65,1.43,8.29,1.3,0.536,0.014,0.002,0.148,22.34,348.38,7.32,30.31,45.13,0.272,-0.006,0.654,0.313 88572,88579,417.58,1952.12,136.84,330.96,9.76,506.03,-47.702,-9.086,107.41,254.52,504.19,558.23,23.04,3.42,7.43,229.58,25.83,0.282,70.26,83.03,19.23,2.027,79.78,1.152,2.341,3.53,56.49,513.2,0.523,10.91,0.401,1.133,0,0.65,1.44,18.63,4.73,0.542,0.004,0.001,0.155,21.72,215.08,15.25,28.25,55.73,0.297,0.001,0.543,0.59 89426,89434,415.66,1938.47,137.93,331.78,9.81,514.89,-47.57,-8.916,107.47,254.87,507.27,572.61,23.08,3.37,7,230.07,25.93,0.231,70.56,86.06,19.73,2.072,79.86,1.189,3.161,1.12,55.79,512.2,0.522,10.86,0.415,1.173,0.66,0.65,1.5,9.53,1.3,0.553,0.016,0.005,0.16,23.07,350.72,7.07,27.75,45.11,0.288,-0.026,0.578,0.287 89899,89913,412.3,1909.79,115.23,330.42,9.73,525.48,-47.259,-8.775,105.45,252.83,504.16,585.8,22.67,3.36,7.18,228.76,25.4,0.056,70.08,77.77,15.84,2.001,79.37,0.898,2.503,0.29,18.33,495.2,0.489,9.74,0.407,1.079,0.15,0.52,1.42,5.4,0.75,0.54,0.002,0.003,0.14,20.52,242.72,3.2,15.35,29.07,0.21,-0.005,0.622,0.16