84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2018, 04, 24, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 55931,55948,410.53,1869.62,100.09,331.01,9.67,546.22,-999.99,-999.99,102.06,245.8,507.23,609.94,22.16,3.34,7.21,229.23,24.69,0.531,70.55,51.25,10.02,1.941,80.18,0.803,1.048,0.33,11.84,513.4,0.365,7.05,0.416,0.999,0.13,0.22,1.44,0.94,0.35,0.471,0,0.004,0.104,10,48.05,0.61,2.17,4.09,0.159,-0.006,0.291,0.13 59566,59584,409.48,1872.08,90.33,331.02,9.53,543.82,-999.99,-999.99,101.16,244.52,506.94,629.84,22.1,3.35,7.38,228.98,24.55,0.06,70.35,43.9,8.33,1.905,80.16,0.671,0.741,0.12,4.83,473.8,0.34,6.41,0.413,0.983,0.15,0.17,1.42,0.69,0.54,0.461,0.003,-0.001,0.096,7.2,36.15,0.26,1.21,2.38,0.136,0.023,0.237,0.09 68168,68187,409.49,1853.27,78.92,330.47,9.59,539.61,-999.99,-999.99,100.45,243.06,507.62,585.59,22.06,3.36,6.88,229.71,24.52,0.058,70.64,39.94,8.64,1.904,80.31,0.992,0.822,0.72,6.33,509.5,0.333,6.55,0.41,0.981,0.08,0.16,1.38,0.53,0.33,0.467,0.009,0.002,0.109,7.26,22.2,0.25,0.71,1.04,0.182,-0.017,0.147,0.187 68650,68658,408.9,1841.95,67.88,330.61,9.54,539.54,-999.99,-999.99,99.76,241.97,508.31,566.87,22.03,3.34,6.65,229.58,24.23,0.037,70.65,36.58,7.8,1.914,80.1,0.885,0.712,0.5,3.21,518.8,0.33,6.14,0.413,0.961,0.06,0.14,1.39,0.25,0.32,0.458,0.002,-0.001,0.095,6.1,11.25,0.23,0.22,0.4,0.168,0.007,0.101,0.18 68933,68940,408.79,1857.06,79.76,331.38,9.57,533.81,-999.99,-999.99,99.89,241.32,507.66,584.69,22.02,3.34,6.76,229.61,24.2,0.077,70.62,31.44,7.66,1.879,80.14,0.898,0.693,0.57,5.62,487.1,0.313,6.22,0.406,0.95,0.02,0.17,1.37,0.37,0.38,0.45,0.004,0.001,0.091,4.43,27.69,0.41,1.06,2.05,0.169,0.001,0.086,0.146 69394,69400,409.69,1852.75,86.95,331.1,9.58,536.75,-999.99,-999.99,99.97,241,506.77,594.91,21.86,3.35,6.8,228.92,24.33,0.541,70.5,32.2,8.54,1.905,79.8,1.477,0.789,2.96,10.41,507,0.325,6.37,0.402,0.968,0.4,0.18,1.4,2.04,0.34,0.439,0.031,0.004,0.156,4.6,19.79,1.39,2.79,1.27,0.29,-0.006,0.198,0.451 70259,70268,409.12,1844.84,70.71,330.53,9.54,539.17,-999.99,-999.99,99.99,241.54,506.68,572.68,22,3.36,6.71,229.23,24.3,0.048,70.45,38.17,8.28,1.889,80.28,0.908,0.791,0.53,4.16,518.6,0.334,6.32,0.416,0.975,0.16,0.19,1.39,0.73,0.39,0.45,0.002,0.004,0.103,6.52,10.17,0.48,0.75,0.89,0.186,0.011,0.103,0.169 71296,71322,410.17,1861.78,92.73,329.79,9.52,542.78,-999.99,-999.99,101.63,244.37,508.59,608.79,22.2,3.34,7.08,229.98,24.6,0.079,70.77,41.77,9.19,1.927,80.42,1.07,0.935,0.97,10.73,514.8,0.339,7.01,0.417,0.982,0.22,0.17,1.39,0.46,0.48,0.471,0.006,0.002,0.123,7.13,31.42,0.52,1.39,1.67,0.202,0.003,0.257,0.228 72208,72223,408.94,1843.84,71.67,330.2,9.57,539.28,-999.99,-999.99,99.79,241.47,507.23,574.97,21.99,3.35,6.74,229.34,24.24,0.068,70.54,35.19,7.97,1.917,80.08,0.98,0.705,0.68,4.62,511,0.327,6.14,0.41,0.965,0.14,0.13,1.4,0.44,0.37,0.441,0.008,0.001,0.11,5.79,12,0.25,0.58,1.07,0.183,-0.006,0.089,0.192 73259,73267,411.87,1883.9,117.96,330.71,9.7,540.26,-999.99,-999.99,104.07,249.35,508.09,627.3,22.45,3.38,7.36,230.54,25.33,0.968,70.66,56.38,12.65,1.962,80.13,1.309,1.306,1.79,27.31,530.9,0.394,8.5,0.419,1.046,0.31,0.39,1.43,1.57,0.51,0.494,0.029,0.003,0.131,11.92,32.59,1.4,3.09,1.93,0.25,0.004,0.278,0.305 73916,73925,409.87,1856.56,84.79,331.19,9.54,540,-999.99,-999.99,101.19,243.69,508.66,594.33,22.12,3.39,6.97,230.01,24.67,0.256,70.75,38.36,8.94,1.915,80.4,1.05,0.957,1.01,10.89,516.4,0.336,6.92,0.414,0.989,0.13,0.25,1.4,1.96,0.58,0.461,0.003,0.007,0.118,6.5,22.64,1.76,3.36,1.52,0.188,-0.007,0.253,0.23 74314,74326,409.39,1849.48,79.66,330.8,9.55,539.27,-999.99,-999.99,100.35,242.27,507.11,585.19,22.05,3.37,6.89,229.37,24.51,0.141,70.55,36.19,8.31,1.925,80.08,1.037,0.869,0.98,7.98,515.1,0.327,6.47,0.423,0.977,0.13,0.2,1.38,1.32,0.51,0.456,0.003,0.006,0.115,5.93,19.03,0.96,1.98,1.61,0.191,-0.037,0.126,0.202 75201,75225,410.1,1858.72,88.33,330.93,9.59,539.94,-47.32,-8.575,101.39,244.33,507.96,588.69,22.11,3.35,6.97,229.56,24.56,0.05,70.67,43.45,9.4,1.95,80.07,1.015,0.9,0.67,5.25,521.9,0.356,7.14,0.41,0.981,0.2,0.2,1.42,0.62,0.3,0.477,0.005,0.004,0.116,7.81,24.68,0.34,1.1,1.2,0.188,0.005,0.282,0.198 76452,76461,410.22,1860.52,90.54,331.44,9.63,542.16,-47.347,-8.625,101.72,244.24,508.01,603.92,22.09,3.34,7.05,230.11,24.64,0.223,70.67,41.32,9.15,1.93,80.39,1.012,0.879,1.01,12.5,526.4,0.35,7.02,0.413,0.98,0.11,0.21,1.42,1.45,0.3,0.454,0.001,0.005,0.107,7.26,24.17,0.75,1.79,1.4,0.193,0.001,0.147,0.187 76958,76965,412.28,1918.44,120.21,331.11,9.83,515.81,-47.493,-8.758,108.68,255.98,507.73,579.29,22.93,3.4,7.44,230.54,26.13,1.031,70.56,78.98,18.16,2.048,80.3,1.124,2.429,1.01,29.09,530.1,0.509,12.83,0.415,1.125,0.06,0.59,1.47,3.59,0.44,0.541,0.013,0.004,0.139,20.19,98.11,2.98,9.71,5.05,0.313,-0.004,0.505,0.282 78881,78901,409.94,1864.35,85.6,330.76,9.62,542.07,-47.406,-8.619,100.99,244.99,506.13,600.55,22.16,3.32,7.08,229.06,24.58,0.053,70.5,50.5,9.67,1.883,79.95,0.783,0.911,0.29,6.43,515.2,0.368,6.77,0.409,0.979,0.11,0.23,1.42,0.98,0.41,0.469,0.004,0.003,0.097,10.23,31.3,0.48,1.22,2.17,0.174,0,0.151,0.132 79919,79931,410.54,1862.38,94.39,330.07,9.57,545.71,-47.421,-8.655,101.63,244.71,505.65,598.92,22.07,3.33,7.14,228.88,24.64,0.042,70.51,49.24,9.41,1.89,79.93,0.825,0.994,0.34,11.63,513.1,0.352,6.88,0.414,0.978,0.12,0.22,1.42,0.29,0.37,0.474,-0.001,0.001,0.099,9.84,40.03,0.31,1.25,2.49,0.157,0.024,0.151,0.122 80352,80360,409.33,1843.24,68.53,331.34,9.56,540.75,-47.377,-8.589,100.45,242.8,507.88,559.86,21.99,3.34,6.68,229.89,24.41,0.058,70.53,38.24,7.75,1.884,80.14,0.75,0.739,0.25,2.59,517.5,0.33,6.31,0.41,0.963,0.08,0.17,1.4,1.4,0.31,0.462,0.002,0.004,0.092,6.5,8.95,0.77,1.21,0.23,0.136,0.007,0.224,0.116 80786,80793,412.89,1913.78,116.94,331.06,9.81,520.09,-47.471,-8.812,106.25,253.94,505.95,578.49,22.8,3.35,7.24,229.82,25.81,0.713,70.41,79.21,17.58,2.002,80.09,1.073,2.303,0.77,29.15,527.6,0.493,10.34,0.416,1.119,0.06,0.61,1.45,2.36,0.57,0.534,0.006,0.008,0.145,20.91,104.2,1.92,6.9,6.01,0.253,-0.02,0.509,0.243 81989,82147,410.55,1861.87,92.7,330.17,9.55,544.72,-47.364,-8.671,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 82507,82669,408.76,1870.86,89.93,330.95,9.51,537.06,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 83585,83663,408.64,1856.37,71.6,331.54,9.53,538.96,-47.375,-8.601,100.06,242.16,507.14,594.3,21.99,3.32,7,228.83,24.19,0.059,70.5,34.99,6.72,1.885,79.92,0.59,0.448,0.06,0.79,461.8,0.331,6.19,0.409,0.952,0.12,0.13,1.4,0.73,0.48,0.45,0.005,0.007,0.091,3.82,22.39,0.17,0.72,1.71,0.097,-0.006,0.087,0.042 85922,85936,410.75,1870.81,98.97,331.13,9.62,545.34,-47.399,-8.663,102.09,246.07,506.39,606.59,22.04,3.33,7.16,228.94,24.72,0.045,70.49,52.31,10.01,1.918,80.19,0.812,1.07,0.32,14.22,514.7,0.365,7.15,0.414,0.986,0.25,0.22,1.41,0.79,0.54,0.474,0.002,-0.002,0.101,10.41,46.65,0.63,1.87,3.67,0.164,-0.002,0.297,0.129 86651,86659,413.24,1895.97,131.82,330.7,9.75,554.78,-47.333,-8.768,104.41,253.2,507.77,646.87,22.38,3.38,7.89,230.34,25.78,0.051,70.48,95.48,14.46,1.918,80.57,0.772,1.773,0.31,19.1,539.2,0.426,7.57,0.415,1.005,0.09,0.43,1.46,0.91,0.56,0.542,0,0.002,0.116,27.4,49.44,0.34,2.22,3.26,0.195,0.003,0.304,0.144