84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2017, 10, 17, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 37883,37901,404.5,1815.03,65.25,324.22,9.14,537.17,-47.188,-8.463,93.21,234.82,501.04,557.76,21.51,3.382,6.74,222.5,23.21,0.049,68.69,20.8,3.12,1.655,74.38,0.147,-999.99,0.01,0.68,457.8,0.263,5.04,0.38,0.77,0.11,0.09,-999.99,1.5,2.48,0.425,0,0.002,0.043,0.4,15.92,0.24,0.87,2.18,0.022,-0.02,0.104,0.004 40994,41015,404.84,1822.62,79.89,329.85,9.23,534.53,-47.256,-8.452,94.06,235.5,506.56,565.56,21.63,3.496,6.58,227.22,23.75,0.041,70.47,22.07,5.87,2.083,79.08,0.763,-999.99,0.19,2.86,486,0.256,5.17,0.411,0.883,0.19,0.14,-999.99,1.39,2.24,0.422,-0.001,0.001,0.108,2.11,11.66,0.19,0.67,1.4,0.137,0.009,0.075,0.064 41554,41566,404.94,1821.14,83.01,329.94,9.25,534.77,-47.261,-8.461,94.1,235.43,508.74,572,21.83,3.49,6.61,227.92,23.88,0.056,70.48,22.02,6.12,2.095,79.49,0.8,-999.99,0.28,6.72,492.2,0.256,5.12,0.404,0.864,0.06,0.16,-999.99,1.1,2.66,0.427,0.001,0,0.117,2.11,12.11,0.25,0.52,1.18,0.161,0,0.082,0.087 41934,41942,403.13,1845.21,89.12,329.53,9.17,499.09,-47.371,-8.319,93.88,235.28,506.44,648.74,21.45,3.451,7.23,227.38,23.94,0.355,70.59,22.14,7.73,2.122,79.03,0.851,-999.99,0.49,22.19,479.8,0.261,5.24,0.41,0.889,1.93,0.18,1.39,15.59,3.64,0.41,0.004,0.018,0.102,1.92,137.36,15.51,24.58,42.06,0.216,-0.015,0.05,0.134 42289,42295,401.08,1875.5,77.5,329,9.14,510.7,-47.608,-8.275,93.42,235.56,508.57,556.34,21.77,3.428,6.9,228.14,24.16,1.307,70.75,22.59,8.69,2.126,79.46,1.135,-999.99,1.21,17.08,486.6,0.257,4.86,0.413,0.886,1.09,0.18,1.33,16.8,6.5,0.419,0.631,0.006,0.147,2.08,142.01,21.86,35.68,54.21,0.427,-0.005,0.089,0.328 42867,42875,405.19,1825.14,89.57,329.23,9.2,516.95,-47.287,-8.422,94.69,235.17,506.16,580.56,21.74,3.422,7.22,227.26,23.97,0.239,70.79,22.03,7.24,2.105,79.06,0.831,-999.99,0.47,17.15,479.5,0.263,5.06,0.401,0.929,1.27,0.15,-999.99,14.8,2.55,0.424,0.002,0.019,0.098,2.12,136.06,11.56,20.87,29.34,0.178,-0.009,0.111,0.123 44829,44852,405.03,1824.53,83.57,329.38,9.26,535.71,-47.274,-8.449,94.42,235.69,507.34,571.77,21.76,3.517,6.69,227.29,23.78,0.055,70.59,22.92,5.72,2.019,79.17,0.694,-999.99,0.13,2.24,484.7,0.262,4.99,0.411,0.876,0.1,0.14,-999.99,1.24,1.69,0.427,0.002,-0.001,0.099,2.02,16.6,0.3,1.15,2.05,0.13,0,0.055,0.059 45663,45677,405.03,1830.15,81.22,329.51,9.23,530.9,-47.348,-8.412,94.65,236.3,508.85,563.97,21.77,3.49,6.59,228.11,24.03,0.057,70.81,22.85,6.2,2.089,79.7,0.767,-999.99,0.27,6.9,481.3,0.259,5.11,0.413,0.877,0.3,0.19,-999.99,1.15,2.14,0.439,-0.001,0.003,0.095,2.41,17.42,0.42,1.35,1.48,0.16,0,0.125,0.097 46001,46009,404.84,1822.78,78.53,328.81,9.17,535.4,-47.273,-8.448,94.26,235.36,507.46,564.63,21.7,3.442,6.64,227.19,23.93,0.045,70.56,21.99,5.77,2.068,79.27,0.763,-999.99,0.27,5.22,493.1,0.25,5.09,0.41,0.878,0.06,0.19,-999.99,1.41,1.04,0.419,-0.005,0.001,0.098,2.17,7.93,0.16,0.62,0.86,0.156,0.007,0.046,0.086 46429,46436,403.66,1815.51,62.25,328.42,9.14,521.91,-47.233,-8.417,92.3,233.79,507.26,545.4,21.6,3.443,6.27,227.66,-999.99,0.765,70.56,20.52,7.5,2.153,78.99,1.022,-999.99,0.79,6.08,492.6,0.264,5.1,0.405,0.864,0.2,0.18,1.34,6.22,2.35,0.412,0.113,0.028,0.156,2.04,20.35,3.04,6.29,4.13,0.193,-0.005,0.077,0.174 49079,49106,404.79,1837.17,97.24,329.83,9.25,533.64,-47.314,-8.423,95.6,236.97,507.09,577.82,21.75,3.512,6.85,228.55,24.12,0.062,70.67,22.96,6.15,2.012,79.51,0.733,-999.99,0.17,5.2,466.1,0.27,5.2,0.42,0.875,0.07,0.15,-999.99,1.47,2.42,0.425,-0.001,0.005,0.109,2.34,25.98,0.48,1.52,2.88,0.162,0.005,0.129,0.087 50308,50316,404.76,1817.72,79.26,327.9,9.14,532.18,-47.221,-8.434,93.22,234.19,504.74,564.17,21.65,3.474,6.67,226.65,23.95,0.072,70.26,21.36,6.05,2.105,78.58,0.792,-999.99,0.31,6.35,491.6,0.26,5.04,0.417,0.856,0.21,0.19,-999.99,1.17,2.92,0.422,0.003,-0.003,0.111,2.04,13,0.27,0.94,1.74,0.158,-0.014,0.063,0.098 50780,50787,403.96,1815.68,62.09,329.06,9.15,523.56,-47.324,-8.411,91.96,233.16,507.15,543.27,21.54,3.413,6.08,226.87,23.62,0.271,70.61,20.21,7.16,2.119,78.8,1.008,-999.99,0.72,5.51,482.3,0.262,5.17,0.416,0.869,0.09,0.14,1.31,2.26,0.82,0.427,0.002,0.007,0.134,1.9,15.31,1.19,3.14,2.42,0.191,0.009,0.106,0.164 51620,51632,405.44,1820.6,79.98,329.22,9.21,533.98,-47.298,-8.422,93.25,234.34,504.72,564.69,21.59,3.369,6.59,227.37,23.69,0.025,70.55,21.76,5.96,2.035,79.09,0.76,-999.99,0.2,2.59,486,0.258,5.45,0.409,0.881,0.24,0.11,-999.99,1.08,0.72,0.415,-0.001,0.003,0.116,1.98,11.28,0.27,0.67,0.63,0.145,0,0.067,0.085 55278,55313,405.26,1824.72,89.52,328.11,9.23,539.05,-47.249,-8.466,93.81,235.88,505.47,578.75,21.85,3.387,6.83,225.95,23.66,0.042,69.75,23.58,5.14,1.919,76.96,0.476,-999.99,0.04,1.33,461.2,0.259,5.44,0.395,0.837,0.27,0.12,-999.99,1.09,0.94,0.418,0.002,0.003,0.1,1.59,21.12,0.35,0.87,1.51,0.09,0.011,0.092,0.027 56679,56692,404.2,1819.72,67.85,329.55,9.24,531.63,-47.237,-8.411,94.19,235.77,507.17,550.47,21.59,3.397,6.39,228.1,23.82,0.041,70.77,22.05,6.08,2.074,79.74,0.834,-999.99,0.34,3.07,484,0.262,5.61,0.423,0.892,0.05,0.09,-999.99,0.64,0.65,0.414,-0.001,0.002,0.124,2.22,6.58,0.18,0.3,0.64,0.15,-0.007,0.059,0.096 57003,57010,404.46,1817.39,68.29,328.43,9.15,529.43,-47.311,-8.401,93.23,234.28,508.12,551.79,21.58,3.442,6.25,227.56,23.74,0.114,70.59,21.15,6.36,2.08,79.23,0.891,-999.99,0.42,4.81,491,0.271,4.64,0.413,0.875,0.17,0.13,-999.99,0.2,0.66,0.434,-0.001,0.001,0.126,1.96,9.31,0.15,0.3,0.77,0.159,-0.009,0.072,0.114 57390,57397,404.19,1816.16,66.9,328.79,9.22,522.99,-47.269,-8.381,92.29,233.34,507.98,551.73,21.66,3.352,6.31,227.51,23.62,0.592,70.81,20.41,7.12,2.133,78.93,0.925,-999.99,0.54,6.64,483.2,0.26,5.18,0.405,0.882,0.13,0.16,1.29,2.53,0.5,0.407,0.009,0.022,0.151,2,19.85,1.23,3.59,3.45,0.179,0.006,0.103,0.133 59991,60027,404.27,1827.19,62.87,329.76,9.26,532.97,-47.358,-8.421,94.79,237.61,507.64,568.58,21.71,3.53,6.48,228.69,24.05,0.033,70.87,27.82,6.27,1.996,79.62,0.701,-999.99,0.1,0.97,484.2,0.265,4.7,0.411,0.893,0.17,0.17,-999.99,0.86,0.68,0.434,0,0.004,0.107,2.91,18.85,0.19,1.16,1.74,0.149,-0.011,0.075,0.066 60613,60627,405.07,1841.44,83.72,329.48,9.33,534.29,-47.381,-8.448,95.8,238.15,507.49,572.56,21.89,3.474,6.72,228.46,24.05,0.031,70.77,25.05,6.46,2.045,79.7,0.817,-999.99,0.27,7.42,474.1,0.278,5.28,0.414,0.921,0.07,0.25,-999.99,0.55,0.78,0.431,-0.001,0,0.114,2.75,20.05,0.29,0.66,1.35,0.151,-0.039,0.137,0.096 60923,60931,404.79,1828.11,78.5,328.67,9.21,535.23,-47.316,-8.464,94.23,236.02,507.2,567.45,21.81,3.419,6.67,227.52,23.83,0.023,70.36,23.34,5.85,2.033,79.17,0.76,-999.99,0.19,5.08,480.8,0.269,5.28,0.407,0.875,-0.03,0.18,-999.99,0.69,0.75,0.425,-0.004,0.003,0.109,2.44,18.08,0.36,1.18,2.09,0.147,-0.023,0.064,0.083 61311,61318,404.22,1816.7,73.21,328.79,9.22,531.43,-47.314,-8.414,93.3,234.53,507.54,553.42,21.48,3.394,6.37,227.71,23.69,0.436,70.45,20.45,6.11,2.091,79.09,0.822,-999.99,0.36,5.5,486.9,0.258,5.46,0.415,0.875,0.82,0.16,1.28,2.58,1.32,0.421,0.033,0.023,0.112,1.91,10.07,1.65,2.68,1.53,0.157,0.005,0.068,0.107 64977,65137,404.99,1852.82,115.42,330.28,9.26,539.04,-47.38,-8.421,96.32,239.5,506.51,599.23,21.82,3.513,7.17,228.08,24.14,0.06,70.57,27.39,6.81,2.016,79.45,0.711,-999.99,0.14,7.95,448.2,0.28,6.25,0.408,0.916,1.55,0.15,-999.99,1.38,1.09,0.422,0.001,0.005,0.118,3.52,49.01,0.48,1.96,4.26,0.151,0.005,0.145,0.083 68979,68988,410.71,1838.82,191.61,329.58,9.26,559.33,-47.267,-8.646,94.16,235.11,507.33,648.7,21.6,3.445,7.22,227.81,23.8,0.244,70.53,21.55,6.47,2.054,79.12,0.71,-999.99,0.28,48.78,486.1,0.258,5.36,0.399,0.897,0.92,0.46,-999.99,1.93,1.06,0.419,-0.002,0.023,0.106,2.15,50.39,0.74,3.04,3.45,0.159,0.001,0.051,0.083