97, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2016, 08, 17, 2019, 02, 27 0 Start_UTC, seconds 62 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group SF6_HATS_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by mass spectrometry in HATS group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13C_CH4_PFP, per mil, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13C_CO2_PFP, per mil, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC13_PFP, ppt, chlorotrifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC115_PFP, ppt, chloropentafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC112_PFP, ppt, 1,1,2,2-tetrachloro-1,2-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC124_PFP, ppt, 1-chloro-1,2,2,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC23_PFP, ppt, trifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC32_PFP, ppt, difluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC125_PFP, ppt, pentafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC143a_PFP, ppt, 1,1,1-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) H1301_PFP, ppt, bromotrifluoromethane (halon-1301), dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CF4_PFP, ppt, tetrafluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2F6_PFP, ppt, hexafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) NF3_PFP, ppt, nitrogen trifluoride, dry-air mole fraction, pico mole per mole (as part per trillion) SO2F2_PFP, ppt, sulfuryl fluoride, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) Ethyne_PFP, ppt, C2H4 (or acetylene), dry-air mole fraction, pico mole per mole (as part per trillion) Ethane_PFP, ppt, C2H6, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10, or 2-methyl propane), dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12, or 2-methyl butane), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) Toluene_PFP, ppt, C7H8, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC236fa_PFP, ppt, 1,1,1,3,3,3-hexafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) C2HCl3_PFP, ppt, trichloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) C3F8_PFP, ppt, octafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) CS2_PFP, ppt, carbon disulfide, dry-air mole fraction, pico mole per mole (as part per trillion) 0 21 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-1; 10-Jul-2016 to 26-Aug-2016; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Until made public, only the ATom science team is allowed to use this data, per the ATom data protocol. Notificaiton of S. Montzka or C. Sweeney is also requested. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions REVISION: R4 R1: Preliminary Field Data, all times should be accurate, updated results from R0 R2: Preliminary Field Data, all times should be accurate, updated results from R1 including full isotope results R3: revised data, for public release R4: revised data to increase consistency across all ATom deployments, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,SF6_HATS_PFP,H2_PFP,d13C_CH4_PFP,d13C_CO2_PFP,CFC11_PFP,CFC12_PFP,CFC13_PFP,CFC113_PFP,CFC115_PFP,CFC112_PFP,HCFC22_PFP,HCFC142b_PFP,HCFC141b_PFP,HCFC21_PFP,HCFC133a_PFP,HCFC124_PFP,HFC23_PFP,HFC32_PFP,HFC134a_PFP,HFC152a_PFP,HFC125_PFP,HFC143a_PFP,HFC227ea_PFP,HFC365mfc_PFP,H1211_PFP,H1301_PFP,H2402_PFP,CCl4_PFP,CH3CCl3_PFP,CF4_PFP,C2F6_PFP,NF3_PFP,SO2F2_PFP,CH3Cl_PFP,CH3Br_PFP,CH3I_PFP,CH2Br2_PFP,CHBr3_PFP,OCS_PFP,CH2Cl2_PFP,CHCl3_PFP,C2Cl4_PFP,Ethyne_PFP,Ethane_PFP,Propane_PFP,nButane_PFP,iButane_PFP,nPentane_PFP,iPentane_PFP,Benzene_PFP,Toluene_PFP,CH2BrCl_PFP,HFC236fa_PFP,C2HCl3_PFP,C3F8_PFP,CS2_PFP 30062,30078,-999.99,1858.56,91.83,329.6,8.97,8.954,528.07,-47.428,-8.36,229.057,512.394,3.27,70.972,8.596,-999.99,238.472,22.021,24.303,-999.99,0.437,-999.99,-999.99,11.243,90.884,6.047,20.303,19.131,1.231,0.83,3.468,3.331,0.409,79.998,2.489,82.585,4.586,-999.99,2.244,605.293,7.428,0.046,0.667,-999.99,486.134,33.877,7.256,-999.99,-999.99,471.996,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 31068,31099,-999.99,1850.11,73.81,329.4,8.92,8.931,526.31,-47.368,-8.434,228.568,511.776,3.328,70.188,8.524,-999.99,236.813,21.735,24.104,-999.99,0.456,-999.99,-999.99,11.308,90.18,6.112,20.351,19.084,1.207,0.823,3.44,3.321,0.394,78.587,2.327,82.577,4.529,-999.99,2.237,604.257,7.147,0.035,0.492,-999.99,488.869,29.007,6.008,-999.99,-999.99,468.089,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 32374,32384,-999.99,1833.65,230.12,329.32,8.78,8.857,562.95,-47.275,-8.597,229.313,511.93,3.322,71.216,8.556,-999.99,232.951,21.703,23.704,-999.99,0.428,-999.99,-999.99,10.365,87.567,5.342,19.606,18.692,1.17,0.829,3.479,3.267,0.405,80.173,2.536,82.344,4.546,-999.99,2.219,643.686,7.611,0.174,0.705,-999.99,509.217,24.309,6.355,-999.99,-999.99,939.109,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 33798,33815,-999.99,1862.06,92.47,329.3,8.96,8.978,530.17,-47.229,-8.344,229.592,511.827,3.287,70.979,8.467,-999.99,239.81,22.085,24.434,-999.99,0.467,-999.99,-999.99,11.376,91.783,6.235,20.645,19.419,1.22,0.855,3.528,3.294,0.408,80.541,2.454,82.686,4.551,-999.99,2.244,600.282,7.498,0.111,0.674,-999.99,496.441,37.594,7.508,-999.99,-999.99,505.449,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 34962,34991,-999.99,1876.28,110.91,328.95,9,8.995,531.07,-47.332,-8.235,228.824,511.106,3.296,69.706,8.543,-999.99,242.087,22.03,24.445,-999.99,0.445,-999.99,-999.99,11.544,92.804,6.386,20.712,19.461,1.214,0.819,3.487,3.334,0.4,78.47,2.203,82.952,4.55,-999.99,2.301,614.489,7.739,0.126,0.539,-999.99,486.293,37.625,7.403,-999.99,-999.99,631.444,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 36380,36389,-999.99,1822.15,156.53,328.64,8.79,8.847,548.34,-47.38,-8.528,228.405,511.003,3.293,71.152,8.53,-999.99,231.565,21.709,23.701,-999.99,0.4,-999.99,-999.99,10.232,86.873,5.089,19.501,18.549,1.205,0.81,3.45,3.31,0.418,80.607,2.352,82.535,4.524,-999.99,2.164,620.738,7.235,1.133,0.986,-999.99,512.635,22.815,6.458,-999.99,-999.99,509.844,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 37205,37217,-999.99,1855.54,114.69,329.2,8.96,8.975,536.03,-47.198,-8.409,229.639,511.003,3.335,71.066,8.543,-999.99,239.957,22.078,24.334,-999.99,0.452,-999.99,-999.99,11.696,92.588,6.51,20.834,19.512,1.3,0.864,3.461,3.304,0.443,80.892,2.433,82.794,4.578,-999.99,2.331,593.496,7.647,0.5,0.753,-999.99,498.176,35.699,7.681,-999.99,-999.99,496.414,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 38592,38629,-999.99,1856.65,123.94,329.31,8.9,8.949,536.33,-47.296,-8.258,229.057,510.591,3.354,71.49,8.548,-999.99,238.25,22.035,24.279,-999.99,0.451,-999.99,-999.99,11.364,91.482,6.116,20.502,19.155,1.227,0.899,3.453,3.272,0.424,81.368,2.393,82.794,4.595,-999.99,2.224,612.907,7.733,0.282,0.81,-999.99,480.352,34.619,7.538,-999.99,-999.99,540.61,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 40163,40172,-999.99,1820.29,148.97,328.62,8.82,8.842,545.42,-47.312,-8.489,228.801,510.488,3.284,70.835,8.53,-999.99,230.772,21.588,23.479,-999.99,0.4,-999.99,-999.99,10.408,87.332,5.184,19.526,18.592,1.193,0.827,3.536,3.27,0.408,80.315,2.371,82.586,4.53,-999.99,2.174,617.011,7.218,1.27,0.927,-999.99,507.641,23.193,6.368,-999.99,-999.99,349.907,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 41314,41332,-999.99,1849.93,109.87,329.41,8.97,8.977,531.67,-47.053,-8.345,229.08,510.952,3.327,71.102,8.51,-999.99,239.166,22.083,24.547,-999.99,0.455,-999.99,-999.99,11.513,92.223,6.474,20.893,19.317,1.195,0.873,3.543,3.286,0.424,80.842,2.428,82.894,4.553,-999.99,2.205,584.628,7.448,0.713,0.849,-999.99,503.435,34.567,8.007,-999.99,-999.99,399.719,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 42359,42399,-999.99,1853.27,107.56,328.97,8.98,8.982,531.22,-47.313,-8.351,229.499,510.385,3.325,71.36,8.473,-999.99,238.967,22.159,24.291,-999.99,0.46,-999.99,-999.99,11.631,92.785,6.564,20.845,19.521,1.21,0.933,3.509,3.316,0.422,81.317,2.442,82.927,4.563,-999.99,2.226,581.753,7.441,0.406,0.854,-999.99,501.069,35.308,7.931,-999.99,-999.99,414.614,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 44223,44231,-999.99,1883.48,100.59,328.75,9.11,9.156,514.23,-47.397,-8.216,230.57,512.136,3.356,70.821,8.555,-999.99,246.741,22.705,25.756,-999.99,0.499,-999.99,-999.99,13.709,98.828,8.63,22.689,20.945,1.271,1.055,3.469,3.324,0.438,81.174,2.522,82.977,4.648,-999.99,2.349,541.937,7.512,1.266,1.088,-999.99,499.265,47.268,11.427,-999.99,-999.99,421.695,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 44860,44895,-999.99,1876.51,90.61,329.5,9.1,9.051,529.24,-47.402,-8.332,229.895,511.673,3.311,70.721,8.585,-999.99,248.277,22.439,25.477,-999.99,0.476,-999.99,-999.99,12.475,96.158,7.184,21.472,19.985,1.328,0.913,3.573,3.315,0.427,81.215,2.487,82.901,4.606,-999.99,2.285,580.317,7.792,0.388,0.709,-999.99,511.148,45.608,9.138,-999.99,-999.99,526.936,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 46054,46087,-999.99,1867.44,100.29,329.44,8.96,8.996,531.33,-47.314,-8.142,229.289,512.6,3.361,70.333,8.491,-999.99,243.027,22.276,25.258,-999.99,0.476,-999.99,-999.99,12.123,93.562,6.888,20.978,19.626,1.23,0.921,3.533,3.308,0.408,80.388,2.436,82.56,4.622,-999.99,2.246,600.266,7.868,0.103,0.62,-999.99,486.173,40.353,8.048,-999.99,-999.99,513.018,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 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