98, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2016, 07, 29, 2019, 02, 27 0 Start_UTC, seconds 62 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group SF6_HATS_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by mass spectrometry in HATS group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13C_CH4_PFP, per mil, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13C_CO2_PFP, per mil, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC13_PFP, ppt, chlorotrifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC115_PFP, ppt, chloropentafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC112_PFP, ppt, 1,1,2,2-tetrachloro-1,2-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC124_PFP, ppt, 1-chloro-1,2,2,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC23_PFP, ppt, trifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC32_PFP, ppt, difluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC125_PFP, ppt, pentafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC143a_PFP, ppt, 1,1,1-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) H1301_PFP, ppt, bromotrifluoromethane (halon-1301), dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CF4_PFP, ppt, tetrafluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2F6_PFP, ppt, hexafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) NF3_PFP, ppt, nitrogen trifluoride, dry-air mole fraction, pico mole per mole (as part per trillion) SO2F2_PFP, ppt, sulfuryl fluoride, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) Ethyne_PFP, ppt, C2H4 (or acetylene), dry-air mole fraction, pico mole per mole (as part per trillion) Ethane_PFP, ppt, C2H6, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10, or 2-methyl propane), dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12, or 2-methyl butane), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) Toluene_PFP, ppt, C7H8, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC236fa_PFP, ppt, 1,1,1,3,3,3-hexafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) C2HCl3_PFP, ppt, trichloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) C3F8_PFP, ppt, octafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) CS2_PFP, ppt, carbon disulfide, dry-air mole fraction, pico mole per mole (as part per trillion) 0 22 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-1; 10-Jul-2016 to 26-Aug-2016; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Until made public, only the ATom science team is allowed to use this data, per the ATom data protocol. Notificaiton of S. Montzka or C. Sweeney is also requested. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions REVISION: R5 R1: Preliminary Field Data, compound names modified to include "_PFP" R2: Preliminary Field Data, start and stop times corrected, isotope data included R3: Preliminary Field Data, updated with all other flights R4: revised data, for public release R5: revised data to increase consistency across all ATom deployments, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,SF6_HATS_PFP,H2_PFP,d13C_CH4_PFP,d13C_CO2_PFP,CFC11_PFP,CFC12_PFP,CFC13_PFP,CFC113_PFP,CFC115_PFP,CFC112_PFP,HCFC22_PFP,HCFC142b_PFP,HCFC141b_PFP,HCFC21_PFP,HCFC133a_PFP,HCFC124_PFP,HFC23_PFP,HFC32_PFP,HFC134a_PFP,HFC152a_PFP,HFC125_PFP,HFC143a_PFP,HFC227ea_PFP,HFC365mfc_PFP,H1211_PFP,H1301_PFP,H2402_PFP,CCl4_PFP,CH3CCl3_PFP,CF4_PFP,C2F6_PFP,NF3_PFP,SO2F2_PFP,CH3Cl_PFP,CH3Br_PFP,CH3I_PFP,CH2Br2_PFP,CHBr3_PFP,OCS_PFP,CH2Cl2_PFP,CHCl3_PFP,C2Cl4_PFP,Ethyne_PFP,Ethane_PFP,Propane_PFP,nButane_PFP,iButane_PFP,nPentane_PFP,iPentane_PFP,Benzene_PFP,Toluene_PFP,CH2BrCl_PFP,HFC236fa_PFP,C2HCl3_PFP,C3F8_PFP,CS2_PFP 55050,55080,-999.99,1878.69,86.36,329.45,9.03,9.035,535.04,-47.704,-8.445,230.457,511.673,3.264,72.044,8.566,-999.99,249.217,22.443,25.472,-999.99,0.496,-999.99,-999.99,15.13,100.43,10.013,22.98,20.268,1.26,0.925,3.476,3.311,0.427,81.379,2.849,82.613,4.586,-999.99,2.65,606.755,7.746,0.331,0.794,-999.99,516.775,39.035,8.203,-999.99,-999.99,1359.095,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 56881,56894,-999.99,1857.75,88.12,329.21,9.1,9.079,528,-47.407,-8.468,230.947,512.857,3.345,71.066,8.485,-999.99,247.336,22.356,25.529,-999.99,0.509,-999.99,-999.99,13.309,96.477,8.784,21.692,20.074,1.248,0.911,3.496,3.323,0.401,82.046,2.449,82.847,4.58,-999.99,2.638,574.481,7.718,0.464,0.658,-999.99,531.742,48.92,9.109,-999.99,-999.99,909.807,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 57746,57755,-999.99,1831.18,72.86,329.77,9.02,9.005,530.05,-47.511,-8.491,231.04,512.497,3.347,71.31,8.525,-999.99,240.477,22.051,25.015,-999.99,0.458,-999.99,-999.99,12.186,93.882,7.08,21.157,19.617,1.27,0.916,3.54,3.328,0.411,82.022,2.553,82.738,4.622,-999.99,2.371,574.969,7.346,0.304,0.797,-999.99,518.246,31.835,6.295,-999.99,-999.99,227.574,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 58103,58113,-999.99,1846.99,81.33,329.37,8.98,8.96,535.22,-47.515,-8.452,230.247,512.394,3.258,71.303,8.518,-999.99,240.007,22.03,25.144,-999.99,0.45,-999.99,-999.99,11.517,93.095,7.02,20.991,19.58,1.215,0.894,3.568,3.331,0.42,82.356,2.57,82.263,4.608,-999.99,2.367,603.489,7.385,0.382,0.712,-999.99,506.115,34.94,6.912,-999.99,-999.99,377.988,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 59717,59747,-999.99,1861.16,83.06,329.75,9.04,8.993,529.51,-47.625,-8.434,230.621,511.879,3.303,71.569,8.555,-999.99,245.207,22.273,25.459,-999.99,0.464,-999.99,-999.99,13.739,97.347,8.463,22.14,20.035,1.241,0.936,3.421,3.293,0.418,81.805,2.723,82.597,4.592,-999.99,2.602,629.337,7.706,0.534,0.834,-999.99,513.31,37.156,7.898,-999.99,-999.99,956.445,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 61166,61176,-999.99,1846.48,78.44,329.56,8.98,8.972,528.85,-47.445,-8.42,230.55,512.394,3.307,71.411,8.528,-999.99,239.066,22.169,24.827,-999.99,0.453,-999.99,-999.99,11.482,92.457,6.672,20.759,19.487,1.21,0.9,3.539,3.317,0.429,81.905,2.535,82.572,4.617,-999.99,2.352,624.667,7.356,0.274,0.706,-999.99,497.502,31.799,7.087,-999.99,-999.99,406.801,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 61689,61697,-999.99,1839.51,75.14,329.21,9.03,9.014,527.21,-47.495,-8.408,230.434,512.548,3.34,71.512,8.575,-999.99,241.37,22.138,25.203,-999.99,0.483,-999.99,-999.99,12.106,93.365,7.221,21.045,19.511,1.249,0.917,3.489,3.294,0.417,82.055,2.57,82.863,4.616,-999.99,2.466,555.691,7.197,0.545,0.835,-999.99,520.191,37.664,7.753,-999.99,-999.99,208.284,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 62718,62736,-999.99,1840.83,63.79,329.85,9.01,9.005,530.89,-47.651,-8.415,230.061,512.085,3.261,71.396,8.506,-999.99,238.324,22.092,24.65,-999.99,0.465,-999.99,-999.99,11.66,91.895,6.714,20.723,19.346,1.234,0.858,3.606,3.303,0.418,81.438,2.417,82.638,4.593,-999.99,2.362,598.71,7.301,0.272,0.836,-999.99,514.834,30.919,6.613,-999.99,-999.99,367.976,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 63607,63639,-999.99,1854.43,74.41,329.85,8.98,8.965,530.97,-47.563,-8.45,230.248,512.291,3.273,71.196,8.546,-999.99,240.552,22.04,24.821,-999.99,0.462,-999.99,-999.99,12.42,94.05,7.394,21.127,19.615,1.243,0.882,3.509,3.272,0.399,81.388,2.565,82.547,4.575,-999.99,2.427,630.505,7.462,0.466,0.784,-999.99,505.171,33.553,7.317,-999.99,-999.99,609.712,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 65072,65081,-999.99,1834.38,68.18,329.53,9.03,8.984,527.81,-47.499,-8.47,229.735,511.776,3.316,71.44,8.474,-999.99,236.269,21.867,24.234,-999.99,0.452,-999.99,-999.99,11.284,90.724,6.16,20.355,19.218,1.201,0.856,3.523,3.318,0.426,81.463,2.42,82.53,4.572,-999.99,2.269,585.245,7.066,0.405,0.822,-999.99,503.753,27.584,6.407,-999.99,-999.99,300.095,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 65481,65489,-999.99,1824.6,65.69,329.45,8.93,8.888,526.3,-47.411,-8.454,229.386,512.033,3.315,71.382,8.483,-999.99,233.818,21.737,24.003,-999.99,0.422,-999.99,-999.99,10.801,89.028,5.735,20.001,18.883,1.165,0.827,3.516,3.303,0.43,81.496,2.469,82.363,4.565,-999.99,2.295,574.026,6.895,0.508,0.887,-999.99,503.544,24.98,6.216,-999.99,-999.99,224.155,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 66306,66320,-999.99,1844.17,68.55,329.55,8.93,9.027,528.19,-47.613,-8.394,230.108,512.136,3.309,71.44,8.516,-999.99,237.927,21.893,24.693,-999.99,0.44,-999.99,-999.99,11.508,91.858,6.595,20.732,19.232,1.283,0.875,3.524,3.315,0.433,81.454,2.494,82.688,4.583,-999.99,2.344,611.14,7.258,0.428,0.82,-999.99,503.647,30.254,6.81,-999.99,-999.99,406.556,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 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