35 1001 Kondo, Yutaka University of Tokyo NO, NOy/Chemiluminescence SOLVE Expedition 1999-2000 1 1 2000 03 15 2000 10 11 0.0 Elapsed time in UT seconds from 0 hours on day given by 'DATE' 4 1.0 1.0 1.0 1.0 999999.9 999999.9 999999.9 999999.9 NO Mixing Ratio (pptv) NOy Mixing Ratio (pptv) Total NOy Mixing ratio (pptv) NO2 Mixing Ratio (pptv) 1 SOLVE Flight #31 16 *General comments: Total NOy (gas phase NOy + amplified particulate-NOy) was measured using a forward facing inlet which was heated to 100 degrees C. NO2 was measured using NO chemiluminescence detector combined with a photolysis cell. Although the 1 Hz data for NO, NOy, Total NOy and NO2 are reported here, variations within short time periods are mostly due to fluctuations in the measurements. The 1 Hz data are useful for investigating the rapid changes, such as spikes due to aircraft emissions. However, averaging for a time period of more than 10 seconds for other analyses is generally recommended. *Address: Yutaka Kondo Research Center for Advanced Science and Technology, University of Tokyo 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904, Japan phone:+81-3-5452-5145, fax:+81-3-5452-5148 e-mail:kondo@atmos.rcast.u-tokyo.ac.jp UT_sec NO NOy Total_NOy NO2 56959.0 999999.9 999999.9 999999.9 999999.9 56960.0 999999.9 999999.9 999999.9 974.5 56961.0 999999.9 999999.9 999999.9 785.9 56962.0 207.1 1546.1 999999.9 641.7 56963.0 182.9 1408.6 999999.9 631.7 56964.0 166.1 956.1 999999.9 547.6 56965.0 100.5 690.6 999999.9 403.9 56966.0 36.0 1421.4 999999.9 131.1 56967.0 132.0 1592.4 999999.9 260.2 56968.0 192.8 1830.3 999999.9 576.0 56969.0 227.0 2253.7 999999.9 655.7 56970.0 304.3 2449.2 999999.9 843.0 56971.0 356.7 2363.4 999999.9 1073.1 56972.0 338.5 2670.0 999999.9 1063.2 56973.0 393.8 2700.1 999999.9 1127.3 56974.0 420.1 2409.3 999999.9 1302.2 56975.0 371.5 2091.9 999999.9 1241.9 56976.0 287.8 2117.8 999999.9 992.0 56977.0 294.3 1716.1 999999.9 949.4 56978.0 234.5 1035.9 999999.9 786.5 56979.0 105.4 796.3 999999.9 493.4 56980.0 56.3 878.6 999999.9 216.7 56981.0 73.3 917.5 999999.9 136.3 56982.0 84.5 804.5 999999.9 265.3 56983.0 66.0 795.5 999999.9 225.1 56984.0 66.6 727.9 999999.9 176.1 56985.0 55.9 711.2 999999.9 143.5 56986.0 55.4 648.2 999999.9 130.9 56987.0 45.7 614.1 999999.9 102.1 56988.0 33.0 620.9 999999.9 80.4 56989.0 28.4 583.1 999999.9 98.1 56990.0 29.4 594.0 999999.9 67.1 56991.0 34.2 611.1 999999.9 76.8 56992.0 31.8 612.4 999999.9 85.2 56993.0 34.8 667.9 999999.9 86.1 56994.0 46.3 728.8 999999.9 83.4 56995.0 48.7 755.9 999999.9 130.4 56996.0 61.9 618.7 999999.9 175.1 56997.0 41.8 610.3 999999.9 118.0 56998.0 36.6 637.5 999999.9 93.8 56999.0 43.7 610.6 999999.9 102.5 57000.0 38.6 618.8 999999.9 88.2 57001.0 41.8 621.1 999999.9 77.5 57002.0 39.3 639.4 999999.9 92.6 57003.0 41.2 647.1 999999.9 113.9 57004.0 46.4 631.5 999999.9 116.9 57005.0 40.6 610.4 999999.9 111.9 57006.0 40.3 606.0 999999.9 112.4 57007.0 35.2 606.8 999999.9 119.5 57008.0 43.5 658.6 999999.9 76.9 57009.0 44.2 651.1 999999.9 109.5 57010.0 48.6 675.2 999999.9 116.2 57011.0 47.6 652.7 999999.9 129.8 57012.0 49.5 678.1 999999.9 147.6 57013.0 52.0 647.7 999999.9 123.9 57014.0 45.0 654.4 999999.9 151.4 57015.0 46.7 625.1 999999.9 120.3 57016.0 44.0 631.9 999999.9 115.2 57017.0 45.3 623.2 999999.9 127.4 57018.0 45.7 637.5 999999.9 119.6 57019.0 39.3 617.7 999999.9 130.2 57020.0 41.3 616.2 999999.9 114.4 57021.0 40.6 672.8 999999.9 119.2 57022.0 47.6 672.8 999999.9 131.2 57023.0 53.0 686.5 999999.9 151.1 57024.0 53.5 672.8 999999.9 137.3 57025.0 48.5 656.1 999999.9 159.1 57026.0 52.6 706.9 999999.9 123.7 57027.0 55.7 702.9 999999.9 165.6 57028.0 58.1 701.7 999999.9 161.7 57029.0 59.3 708.3 999999.9 175.1 57030.0 54.4 710.3 999999.9 157.3 57031.0 58.6 723.6 999999.9 177.5 57032.0 59.5 733.3 999999.9 158.5 57033.0 54.0 712.1 999999.9 200.8 57034.0 56.5 690.5 999999.9 168.7 57035.0 50.3 734.3 999999.9 165.1 57036.0 58.5 746.1 999999.9 171.0 57037.0 63.4 735.9 999999.9 165.1 57038.0 61.0 722.0 999999.9 167.3 57039.0 61.2 745.1 999999.9 163.7 57040.0 64.9 710.6 999999.9 180.3 57041.0 52.3 639.3 999999.9 199.9 57042.0 46.1 648.8 999999.9 165.5 57043.0 45.2 630.6 999999.9 140.6 57044.0 46.3 694.9 999999.9 122.1 57045.0 51.1 826.2 999999.9 145.2 57046.0 83.2 958.9 999999.9 196.8 57047.0 105.7 966.9 999999.9 294.6 57048.0 107.4 953.0 999999.9 304.3 57049.0 103.6 981.1 999999.9 329.5 57050.0 110.1 994.1 999999.9 294.0 57051.0 104.8 1010.8 999999.9 340.1 57052.0 105.0 1009.1 999999.9 344.9 57053.0 114.4 1022.6 999999.9 340.7 57054.0 111.5 999.3 999999.9 356.0 57055.0 119.5 1007.4 999999.9 384.5 57056.0 118.7 970.5 999999.9 370.2 57057.0 112.9 960.5 999999.9 305.1 57058.0 114.2 1047.8 999999.9 310.6 57059.0 117.7 1079.1 999999.9 348.2 57060.0 126.8 999.0 999999.9 359.7 57061.0 103.1 944.9 999999.9 380.0 57062.0 101.1 1015.2 999999.9 287.1 57063.0 100.0 1015.7 999999.9 351.2 57064.0 119.4 1023.1 999999.9 295.8 57065.0 109.8 957.6 999999.9 339.6 57066.0 102.4 1025.4 999999.9 999999.9 57067.0 111.8 1133.0 999999.9 999999.9 57068.0 134.0 1073.0 999999.9 999999.9 57069.0 127.4 1029.1 999999.9 999999.9 57070.0 118.7 965.8 999999.9 999999.9 57071.0 101.6 962.4 999999.9 999999.9 57072.0 101.8 991.0 999999.9 999999.9 57073.0 110.4 1179.6 999999.9 999999.9 57074.0 135.0 1394.8 999999.9 999999.9 57075.0 177.9 1337.7 999999.9 999999.9 57076.0 171.6 1330.3 999999.9 999999.9 57077.0 166.6 1355.4 999999.9 999999.9 57078.0 173.3 1355.1 999999.9 999999.9 57079.0 178.2 1246.2 999999.9 999999.9 57080.0 154.7 1141.2 999999.9 999999.9 57081.0 131.9 1101.0 999999.9 999999.9 57082.0 117.7 1217.7 999999.9 999999.9 57083.0 139.9 1315.5 999999.9 999999.9 57084.0 168.2 1335.3 999999.9 999999.9 57085.0 165.6 1312.7 999999.9 999999.9 57086.0 168.0 1279.8 999999.9 999999.9 57087.0 157.3 1243.4 999999.9 999999.9 57088.0 144.2 1134.7 999999.9 999999.9 57089.0 130.0 1151.0 999999.9 999999.9 57090.0 134.2 1264.0 999999.9 999999.9 57091.0 162.2 1360.1 999999.9 999999.9 57092.0 171.5 1372.9 999999.9 999999.9 57093.0 174.9 1314.2 999999.9 999999.9 57094.0 167.5 1156.9 999999.9 999999.9 57095.0 131.3 1129.1 999999.9 999999.9 57096.0 131.7 1338.5 999999.9 999999.9 57097.0 152.8 1420.1 999999.9 999999.9 57098.0 184.2 1369.3 999999.9 999999.9 57099.0 173.5 970.9 999999.9 999999.9 57100.0 101.1 1155.7 999999.9 999999.9 57101.0 128.7 962.8 999999.9 999999.9 57102.0 96.8 1281.5 999999.9 999999.9 57103.0 157.4 1038.7 999999.9 999999.9 57104.0 112.3 977.8 999999.9 999999.9 57105.0 98.4 1020.4 999999.9 999999.9 57106.0 101.6 946.8 999999.9 999999.9 57107.0 93.6 787.0 999999.9 999999.9 57108.0 71.2 766.6 999999.9 999999.9 57109.0 58.3 861.1 1439.6 999999.9 57110.0 79.3 867.5 1510.6 999999.9 57111.0 81.9 953.6 1448.1 999999.9 57112.0 93.2 1024.2 1487.7 999999.9 57113.0 108.9 902.3 1488.3 999999.9 57114.0 90.3 855.4 1412.0 999999.9 57115.0 85.1 820.0 1303.1 999999.9 57116.0 72.9 907.1 1293.8 999999.9 57117.0 83.9 983.7 1344.7 999999.9 57118.0 100.1 1016.7 1410.5 999999.9 57119.0 107.2 1002.3 1431.8 999999.9 57120.0 107.1 975.3 1429.8 999999.9 57121.0 107.4 937.0 1352.6 999999.9 57122.0 91.5 866.6 1318.6 999999.9 57123.0 86.3 854.9 1236.8 999999.9 57124.0 81.1 895.0 1233.7 999999.9 57125.0 94.0 947.7 1262.0 999999.9 57126.0 98.7 950.0 1288.3 999999.9 57127.0 101.3 964.8 1313.8 999999.9 57128.0 105.8 957.4 1311.5 999999.9 57129.0 102.3 887.7 1302.3 999999.9 57130.0 93.1 780.1 1211.2 999999.9 57131.0 83.2 696.0 1106.2 999999.9 57132.0 60.5 577.4 981.3 999999.9 57133.0 43.2 556.1 860.3 999999.9 57134.0 40.8 534.3 825.0 999999.9 57135.0 34.7 521.5 784.7 999999.9 57136.0 33.4 484.8 768.8 999999.9 57137.0 26.7 470.4 781.1 999999.9 57138.0 15.4 443.4 718.8 999999.9 57139.0 11.4 421.1 707.2 999999.9 57140.0 13.0 409.9 686.1 999999.9 57141.0 9.4 408.3 662.0 999999.9 57142.0 12.5 413.2 678.1 999999.9 57143.0 9.4 400.3 658.8 999999.9 57144.0 10.4 392.1 657.2 999999.9 57145.0 6.4 396.8 641.0 999999.9 57146.0 6.8 404.0 661.1 999999.9 57147.0 8.2 395.4 642.7 999999.9 57148.0 10.0 401.9 628.6 999999.9 57149.0 9.8 407.4 628.1 999999.9 57150.0 11.2 405.4 636.7 999999.9 57151.0 10.0 400.0 607.8 999999.9 57152.0 8.6 374.6 598.1 999999.9 57153.0 8.4 387.9 628.5 999999.9 57154.0 6.4 381.1 593.2 999999.9 57155.0 7.0 416.3 602.8 999999.9 57156.0 7.8 486.5 620.1 999999.9 57157.0 25.1 791.6 714.2 999999.9 57158.0 92.5 831.9 1038.6 999999.9 57159.0 96.9 484.7 1057.6 999999.9 57160.0 31.7 396.3 687.7 999999.9 57161.0 9.5 391.9 605.3 999999.9 57162.0 8.1 387.9 600.8 999999.9 57163.0 6.5 390.2 605.8 999999.9 57164.0 11.4 390.1 612.7 999999.9 57165.0 11.1 393.2 593.8 999999.9 57166.0 5.8 396.8 581.6 999999.9 57167.0 16.1 394.5 588.5 999999.9 57168.0 8.4 379.4 607.8 999999.9 57169.0 10.7 393.5 599.6 999999.9 57170.0 7.7 380.2 604.2 999999.9 57171.0 10.8 402.8 621.2 999999.9 57172.0 7.8 403.3 601.3 999999.9 57173.0 6.2 407.6 616.0 999999.9 57174.0 11.4 410.9 585.3 999999.9 57175.0 12.2 408.9 577.5 999999.9 57176.0 13.4 434.7 598.2 999999.9 57177.0 15.3 507.3 637.2 999999.9 57178.0 33.7 583.7 733.7 999999.9 57179.0 51.2 620.4 764.3 999999.9 57180.0 52.7 601.2 833.8 999999.9 57181.0 51.3 632.1 788.6 999999.9 57182.0 56.3 644.3 830.3 999999.9 57183.0 51.4 701.9 830.6 999999.9 57184.0 62.0 769.8 883.2 999999.9 57185.0 86.5 758.1 973.8 999999.9 57186.0 76.3 765.9 964.3 999999.9 57243.0 999999.9 999999.9 999999.9 999999.9 57244.0 52.9 523.1 642.0 148.2 57245.0 49.3 530.4 625.6 105.6 57246.0 53.4 528.4 639.8 112.1 57247.0 52.7 525.2 647.7 112.0 57248.0 47.9 506.6 610.2 114.3 57249.0 50.5 495.5 610.6 84.9 57250.0 46.2 477.8 583.4 116.5 57251.0 47.4 508.3 615.7 98.0 57252.0 46.4 493.5 594.7 90.7 57253.0 47.7 516.4 602.6 111.4 57254.0 50.0 514.8 640.7 107.9 57255.0 52.5 522.6 631.6 136.1 57256.0 56.6 529.6 645.0 98.8 57257.0 56.0 538.9 626.4 104.5 57258.0 56.1 520.2 654.4 127.4 57259.0 52.3 545.3 655.5 119.2 57260.0 57.3 538.5 651.6 132.4 57261.0 56.3 551.2 633.5 118.3 57262.0 57.9 541.3 646.8 132.0 57263.0 63.2 547.3 655.9 124.2 57264.0 61.0 537.5 677.7 140.4 57265.0 63.5 536.2 655.2 114.3 57266.0 53.6 531.0 642.0 125.1 57267.0 59.2 523.0 662.0 134.1 57268.0 51.3 479.4 654.7 125.8 57269.0 45.8 473.4 611.2 92.4 57270.0 44.1 411.4 587.5 93.6 57271.0 36.3 381.6 536.8 69.7 57272.0 17.0 346.0 501.7 48.7 57273.0 15.7 346.9 458.0 32.6 57274.0 9.0 340.2 465.1 49.8 57275.0 13.6 314.5 446.8 11.7 57276.0 4.6 325.9 438.5 27.8 57277.0 6.0 296.8 405.7 2.0 57278.0 0.3 296.0 408.2 7.6 57279.0 4.3 291.5 382.2 -4.5 57280.0 7.0 315.2 385.9 1.9 57281.0 4.7 315.5 406.3 6.6 57282.0 12.5 314.8 420.0 15.6 57283.0 17.0 312.6 450.0 8.4 57284.0 7.4 299.4 402.0 29.4 57285.0 2.7 291.3 405.5 15.2 57286.0 3.7 291.1 405.8 12.8 57287.0 6.5 303.1 399.6 18.7 57288.0 2.9 295.2 395.3 7.0 57289.0 8.6 302.5 402.5 0.7 57290.0 5.6 294.0 392.9 18.5 57291.0 2.5 298.9 393.8 -5.2 57292.0 4.0 285.5 380.5 8.4 57293.0 9.4 286.9 392.6 -3.5 57294.0 5.5 280.5 393.5 -6.3 57295.0 4.3 297.6 392.9 -7.3 57296.0 4.2 294.0 382.2 11.7 57297.0 3.6 288.4 385.9 20.4 57298.0 6.1 275.4 375.5 0.3 57299.0 -0.1 271.2 364.1 0.9 57300.0 5.8 286.0 374.2 -14.9 57301.0 6.5 297.0 377.4 -6.2 57302.0 8.5 368.0 375.2 9.5 57303.0 27.4 325.6 456.3 17.7 57304.0 7.1 304.5 433.4 29.1 57305.0 10.1 325.3 415.8 -3.4 57306.0 4.8 316.0 408.4 11.3 57307.0 3.4 333.1 410.5 6.4 57308.0 6.4 335.2 403.0 -5.2 57309.0 6.5 317.3 434.9 8.3 57310.0 7.9 337.0 430.6 -19.3 57311.0 9.1 309.1 429.6 -1.9 57312.0 7.3 310.1 405.2 16.5 57313.0 4.8 316.2 384.3 26.4 57314.0 5.1 318.9 396.0 27.0 57315.0 7.4 302.2 402.5 15.3 57316.0 5.4 301.9 407.6 2.3 57317.0 2.7 305.8 396.0 10.1 57318.0 5.7 300.6 392.0 6.2 57319.0 8.6 313.5 419.5 -12.0 57320.0 7.5 301.2 403.9 10.0 57321.0 8.1 303.3 406.0 18.8 57322.0 4.9 310.8 393.0 28.9 57323.0 8.8 316.1 391.9 -3.2 57324.0 6.3 311.3 395.1 17.5 57325.0 6.5 318.7 394.1 4.1 57326.0 4.6 303.8 401.1 8.3 57327.0 8.8 316.2 408.6 9.6 57328.0 5.1 320.6 399.3 2.7 57329.0 5.6 329.9 398.3 24.8 57330.0 4.7 305.6 391.8 15.1 57331.0 7.9 320.4 413.9 22.1 57332.0 5.6 323.0 410.8 17.6 57333.0 12.0 324.4 418.9 -2.0 57334.0 9.3 333.0 429.7 19.2 57335.0 6.9 329.6 391.2 9.4 57336.0 8.9 318.4 400.6 0.0 57337.0 7.8 341.1 410.3 31.0 57338.0 5.2 348.6 417.0 6.4 57339.0 8.2 344.3 444.9 17.7 57340.0 9.1 344.2 428.6 15.5 57341.0 10.0 345.0 447.9 16.7 57342.0 4.9 349.8 435.1 13.6 57343.0 7.8 349.3 452.3 29.4 57344.0 8.1 358.8 441.9 9.6 57345.0 6.8 366.1 473.9 33.9 57346.0 6.6 362.0 466.3 9.5 57347.0 7.2 365.0 437.0 21.2 57348.0 10.8 352.5 460.1 -4.9 57349.0 6.0 366.8 463.6 34.8 57350.0 9.9 364.0 461.9 9.0 57351.0 7.8 374.7 473.3 37.4 57352.0 8.7 362.1 458.6 16.3 57353.0 9.5 367.1 448.1 8.4 57354.0 10.8 367.6 467.3 2.3 57355.0 6.1 348.5 479.2 17.1 57356.0 9.6 359.6 476.8 12.2 57357.0 6.7 355.7 448.5 26.8 57358.0 7.1 366.5 466.9 44.8 57359.0 12.1 368.5 448.1 -8.6 57360.0 7.1 365.8 468.3 8.0 57361.0 3.4 356.4 480.2 23.1 57362.0 9.4 363.5 472.7 2.1 57363.0 4.8 368.5 483.2 14.2 57364.0 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