30 1001 Viggiano, A 781-377-4208, Ballenthin, J -3755, Hunton, D -4057, Miller, T -5031 Air Force Research Laboratory, AFRL/VSBP, 29 Randolph Rd, Hanscom AFB, MA 01731 Trace Gas Concentrations from Chemical Ionization Mass Spectrometer (CIMS) SONEX Campaign, Bangor - Shannon, October, 1997 1 1 1997 10 15 1998 7 31 0 Elapsed Time in UT Seconds from 0 hours on day of flight 2 1 1 9999 9999 HNO3 concentration (pptv) SO2 concentration (pptv) 3 Comments for this flight: Calibration source: CIMS data normalized to UNH HNO3 Comparison to UNH HNO3: Relative trends agree well 11 Comments for entire CIMS Final Data Set: Time dependence of permeation tube emission rate has been included 5% correction of tube center flow to average flow rate has been included Deconvolution of adjacent ion peaks has been done using least squares peak fitting Instrumental background count rate ("dark" counts) has been subtracted No additional background subtraction (e.g. to correct wall outgassing) for HNO3 or SO2 has been done. Data are ten second averages - time listed is end of integration period One-second data can be provided as requested for specific times Calibrations have been replaced with missing data codes; altitude transitions are included SO2 sensitivity based on HNO3 permeation tube calibrations and k(HNO3) / k(SO2) = 1.7 UT(sec) HNO3 SO2 49140 212 272 49150 176 435 49160 200 367 49170 240 326 49180 200 299 49190 252 340 49200 168 319 49210 168 353 49220 200 312 49230 180 244 49240 212 346 49250 180 340 49260 120 258 49270 172 258 49280 156 285 49290 160 380 49300 172 224 49310 140 210 49320 124 258 49330 124 258 49340 124 258 49350 124 9999 49360 124 9999 49370 124 9999 49380 124 9999 49390 124 9999 49400 9999 9999 49410 9999 9999 49420 9999 9999 49430 9999 9999 49440 9999 9999 49450 9999 9999 49460 9999 9999 49470 9999 278 49480 28 142 49490 64 278 49500 52 136 49510 52 190 49520 36 129 49530 84 129 49540 28 258 49550 72 197 49560 9999 183 49570 9999 149 49580 9999 204 49590 9999 156 49600 9999 170 49610 9999 272 49620 9999 156 49630 9999 142 49640 9999 156 49650 9999 183 49660 9999 176 49670 9999 156 49680 9999 170 49690 9999 231 49700 9999 170 49710 9999 163 49720 9999 231 49730 9999 170 49740 9999 197 49750 9999 108 49760 9999 136 49770 9999 142 49780 9999 115 49790 9999 129 49800 9999 136 49810 9999 156 49820 9999 190 49830 9999 156 49840 9999 95 49850 9999 190 49860 9999 210 49870 9999 285 49880 9999 204 49890 9999 278 49900 9999 238 49910 9999 183 49920 9999 136 49930 9999 9999 50230 156 129 50240 104 136 50250 9999 9999 50740 120 312 50750 112 360 50760 104 272 50770 84 210 50780 116 102 50790 80 217 50800 88 170 50810 100 163 50820 100 129 50830 88 238 50840 108 197 50850 104 272 50860 72 102 50870 124 217 50880 92 197 50890 96 156 50900 108 265 50910 116 204 50920 84 149 50930 72 142 50940 84 217 50950 108 95 50960 124 190 50970 116 122 50980 88 224 50990 132 170 51000 92 231 51010 96 204 51020 100 108 51030 92 251 51040 92 142 51050 116 231 51060 104 88 51070 64 20 51080 64 149 51090 92 190 51100 108 136 51110 68 108 51120 76 136 51130 112 149 51140 140 149 51150 156 258 51160 96 272 51170 128 204 51180 76 278 51190 136 176 51200 136 224 51210 84 176 51220 88 142 51230 68 238 51240 108 258 51250 120 20 51260 84 217 51270 128 20 51280 84 95 51290 132 306 51300 108 176 51310 92 129 51320 80 217 51330 104 122 51340 92 210 51350 92 204 51360 108 217 51370 68 204 51380 96 183 51390 120 190 51400 112 81 51410 120 244 51420 88 149 51430 88 136 51440 9999 9999 56060 9999 40 56070 9999 40 56080 9999 40 56090 9999 30 56100 9999 30 56110 9999 71 56120 9999 10 56130 9999 20 56140 9999 20 56150 9999 71 56160 9999 0 56170 9999 20 56180 9999 40 56190 9999 20 56200 9999 51 56210 9999 30 56220 9999 51 56230 9999 30 56240 9999 40 56250 9999 40 56260 9999 10 56270 9999 30 56280 9999 30 56290 9999 40 56300 9999 30 56310 1128 61 56320 1200 0 56330 1008 112 56340 1164 91 56350 1212 71 56360 1206 30 56370 1302 40 56380 1026 0 56390 1098 40 56400 1254 61 56410 1008 30 56420 1110 71 56430 1092 51 56440 1104 61 56450 1110 30 56460 1032 51 56470 1284 40 56480 1242 71 56490 1272 20 56500 1158 40 56510 1080 40 56520 1224 51 56530 1170 61 56540 1008 40 56550 1062 81 56560 1140 91 56570 1128 61 56580 1122 20 56590 1110 71 56600 1116 40 56610 1032 71 56620 1122 30 56630 1170 30 56640 1020 30 56650 1134 71 56660 1080 51 56670 960 61 56680 1164 30 56690 948 81 56700 1032 51 56710 1146 102 56720 1062 61 56730 1164 81 56740 1092 20 56750 1056 20 56760 906 0 56770 995 51 56780 954 91 56790 1098 81 56800 995 61 56810 960 81 56820 894 51 56830 852 91 56840 1008 112 56850 774 51 56860 870 61 56870 930 30 56880 822 102 56890 888 30 56900 858 40 56910 798 81 56920 780 20 56930 750 91 56940 672 51 56950 726 91 56960 756 71 56970 642 40 56980 798 112 56990 726 91 57000 750 51 57010 768 102 57020 684 112 57030 840 132 57040 804 81 57050 612 61 57060 654 51 57070 774 30 57080 732 81 57090 576 81 57100 774 102 57110 624 91 57120 708 30 57130 564 122 57140 786 71 57150 660 122 57160 540 122 57170 582 61 57180 594 40 57190 528 40 57200 618 61 57210 810 40 57220 780 81 57230 870 81 57240 9999 61 57250 9999 81 57260 9999 9999 58140 399 9999 58150 617 9999 58160 845 9999 58170 872 9999 58180 607 9999 58190 754 9999 58200 962 9999 58210 698 9999 58220 1045 9999 58230 1053 9999 58240 1107 9999 58250 945 9999 58260 1007 9999 58270 945 9999 58280 1127 9999 58290 1153 9999 58300 1172 9999 58310 1272 9999 58320 1365 9999 58330 1280 9999 58340 1144 9999 58350 899 9999 58360 1081 9999 58370 1016 9999 58380 1426 9999 58390 1189 9999 58400 1062 9999 58410 1209 9999 58420 1181 9999 58430 825 9999 58440 962 9999 58450 999 9999 58460 854 9999 58470 825 9999 58480 954 9999 58490 1098 9999 58500 907 9999 58510 962 9999 58520 1016 9999 58530 825 9999 58540 971 9999 58550 1280 9999 58560 1153 9999 58570 1081 9999 58580 1227 9999 58590 1345 9999 58600 1218 9999 58610 1254 9999 58620 1062 9999 58630 1327 9999 58640 899 9999 58650 1036 9999 58660 1045 9999 58670 962 9999 58680 1036 9999 58690 1027 9999 58700 971 9999 58710 9999 9999 59680 9999 51 59690 9999 61 59700 9999 20 59710 9999 102 59720 9999 71 59730 9999 81 59740 9999 102 59750 9999 61 59760 9999 102 59770 9999 51 59780 9999 40 59790 9999 71 59800 9999 81 59810 9999 112 59820 9999 40 59830 9999 153 59840 9999 91 59850 9999 30 59860 9999 71 59870 9999 30 59880 9999 81 59890 9999 112 59900 9999 9999 60610 54 61 60620 42 102 60630 66 112 60640 66 91 60650 78 122 60660 72 91 60670 90 153 60680 48 132 60690 60 71 60700 113 122 60710 138 91 60720 120 183 60730 90 142 60740 102 173 60750 66 142 60760 96 102 60770 138 122 60780 126 61 60790 108 112 60800 60 204 60810 66 163 60820 132 183 60830 102 132 60840 144 153 60850 113 102 60860 120 183 60870 102 153 60880 90 163 60890 113 214 60900 96 193 60910 120 173 60920 84 193 60930 72 153 60940 138 142 60950 66 112 60960 84 173 60970 66 122 60980 102 132 60990 54 122 61000 48 102 61010 102 122 61020 78 153 61030 78 71 61040 66 91 61050 96 102 61060 54 91 61070 54 132 61080 60 91 61090 66 61 61100 84 153 61110 66 51 61120 90 61 61130 66 142 61140 9999 71 61150 9999 91 61160 9999 132 61170 9999 91 61180 9999 91 61190 9999 112 61200 9999 51 61210 9999 153 61220 9999 81 61230 9999 51 61240 9999 40 61250 9999 102 61260 9999 71 61270 9999 112 61280 9999 51 61290 9999 81 61300 9999 30 61310 9999 112 61320 9999 102 61330 9999 173 61340 9999 132 61350 9999 61 61360 9999 112 61370 9999 91 61380 9999 102 61390 9999 112 61400 9999 102 61410 9999 71 61420 9999 91 61430 9999 132 61440 9999 81 61450 9999 81 61460 9999 61 61470 9999 91 61480 9999 112 61490 9999 153 61500 9999 153 61510 9999 81 61520 9999 132 61530 9999 142 61540 9999 81 61550 9999 71 61560 9999 20 61570 9999 81 61580 9999 122 61590 9999 91 61600 9999 51 61610 9999 71 61620 9999 61 61630 9999 132 61640 9999 132 61650 9999 122 61660 9999 112 61670 9999 0 61680 9999 102 61690 9999 61 61700 9999 51 61710 9999 81 61720 9999 40 61730 9999 91 61740 9999 132 61750 9999 102 61760 9999 61 61770 9999 51 61780 9999 61 61790 9999 81 61800 9999 112 61810 9999 102 61820 9999 142 61830 9999 91 61840 9999 10 61850 9999 81 61860 9999 81 61870 9999 142 61880 9999 173 61890 9999 112 61900 9999 91 61910 9999 122 61920 9999 153 61930 9999 71 61940 9999 102 61950 9999 142 61960 9999 71 61970 9999 142 61980 9999 91 61990 198 81 62000 174 71 62010 120 51 62020 102 112 62030 96 91 62040 162 102 62050 150 91 62060 162 91 62070 78 61 62080 120 132 62090 108 142 62100 113 91 62110 132 112 62120 108 122 62130 126 132 62140 113 122 62150 156 61 62160 150 204 62170 210 71 62180 138 132 62190 186 102 62200 198 122 62210 204 153 62220 138 61 62230 180 91 62240 156 112 62250 150 112 62260 132 112 62270 162 122 62280 120 81 62290 120 122 62300 186 142 62310 150 132 62320 113 132 62330 174 255 62340 138 163 62350 198 224 62360 144 153 62370 126 153 62380 162 214 62390 150 214 62400 138 204 62410 120 112 62420 204 132 62430 150 193 62440 132 234 62450 156 193 62460 126 204 62470 216 255 62480 150 285 62490 96 204 62500 186 255 62510 162 255 62520 138 224 62530 138 132 62540 192 204 62550 138 153 62560 138 173 62570 132 204 62580 132 204 62590 144 275 62600 144 204 62610 120 306 62620 162 316 62630 192 275 62640 138 224 62650 210 275 62660 198 306 62670 168 244 62680 120 183 62690 192 428 62700 204 316 62710 132 224 62720 192 214 62730 168 224 62740 126 255 62750 222 357 62760 186 183 62770 144 306 62780 168 255 62790 192 214 62800 198 295 62810 168 316 62820 174 224 62830 150 142 62840 126 316 62850 156 265 62860 228 326 62870 162 367 62880 222 306 62890 126 357 62900 132 183 62910 138 234 62920 186 346 62930 168 306 62940 186 387 62950 162 316 62960 198 255 62970 198 244 62980 168 193 62990 180 326 63000 162 397 63010 239 255 63020 174 214 63030 180 173 63040 174 193 63050 162 295 63060 102 306 63070 126 285 63080 162 316 63090 132 306 63100 186 357 63110 180 428 63120 132 306 63130 144 357 63140 180 244 63150 150 316 63160 186 295 63170 180 367 63180 108 244 63190 174 265 63200 156 204 63210 120 397 63220 174 285 63230 246 479 63240 246 316 63250 246 306 63260 246 285 63270 246 397 63280 246 357 63290 246 265 63300 9999 9999