68 1001 Shetter, Rick NCAR, Boulder, CO Photolysis frequencies (J-values) by actinic flux spectroradiometry SONEX 1 1 1997 11 12 1998 03 19 0 Elapsed time in UT seconds from 0 hours on the day given in line 7 11 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 999 999 999 999 999 999 999 999 999 999 999 JNO2(1/s) JO3(1/s) JHONO(1/s) JHNO3(1/s) JH2O2(1/s) JCH2O(1/s) JCH3OOH(1/s) JCH3NO3(1/s) JCH3CH2NO3(1/s) JCH3OCH3(1/s) JPAN(1/s) 0 43 The quantities reported in this file are the photolysis frequencies (or pho- tolysis rate coefficients or J-values) of 11 photolysis reactions. The method used for these measurements was scanning actinic flux spectroradiometry. Calibration was based on NIST traceable QTH lamps. A preliminary estimate of the instrumental uncertainty of the spectroradiometer technique is 12%. Mo- lecular data used in the calculations was as follows: NO2 sigma: [JPL-94]-temp. below 232 K treated like 232 K phi: [JPL-94] O3 sigma: [Molina and Molina 1986]: linear regression between 226 K and 263 K resp. between 263 K and 298 K temp. below 230 K treated like 230 K phi: [Talukdar et al. 1998]: between 320 K and 203 K: 0.06+A*exp(-B/T) temp. above 320 K treated like 320 K temp. below 203 K treated like 203 K HONO sigma: [JPL-94] phi: unity HNO3 sigma: [Burkholder et al. 1993] phi: unity H2O2 sigma: [JPL-94] phi: unity CH2O sigma: [Cantrell et al. 1990] parametr. of temp. dep. temp.: below 223 K treated like 223 K phi: Evaluation by Sasha Madronich [priv. comm.] using data from: [Moortgat et al. 1983] and [Horowitz and Calvert 1978] CH3OOH sigma: [JPL-94] phi: unity CH3ONO2 sigma: [Talukdar et al. 1997] phi: unity CH3CH2ONO2 sigma: [Talukdar et al. 1997] phi: unity CH3COCH3 sigma: [Gierczak et al. 1998] phi: [Gierczak et al. 1998] PAN sigma: [Talukdar et al. 1995] phi: unity Temperatures used for temperature dependent cross section and quantum yield data are "Static Air Temperature" from the DADS data files. Pressures used for pressure dependent cross section and quantum yield data are also from the DADS data files. The given lower limits of detection are the 2-sigma values of the dark current. All data points taken are included, i.e. no outlier screening or smoothing has been applied to these data. 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