27 1001 Wennberg,P.O., Cohen,R.C., and J.G. Anderson Harvard University, Cambridge, MA 02138, Tel (617) 495-5922 HOx SPADE 1 1 1993 05 12 1994 1 3 0 Elapsed time (sec) from 0 GMT on flight day 2 1 1 999999 999999 OH Volume Mixing Ratio (x 1e15) HO2 Volume Mixing Ratio (x 1e15) 0 11 ***** Final Data - Software version 2.2 ***** OH and HO2 measurements are taken within 10 sec of timestamp Absolute Uncertainties (2-sigma) are approximately +/- 30 percent +/- .01 ppt for OH; +/- 40 percent +/- .01 ppt for HO2 Absolute Uncertainty for the ratio: OH/HO2 is approximately 25 percent Reported HO2 will contain a fractional contribution from RO2. R=CH3,C2H5 HO2 reported = [HO2] + (.4 - .6)[RO2] for pressures less than 150 torr ***** Final Data - Software version 2.2 ***** Time OH HO2 79817 324 2725 79840 439 2873 79863 417 2808 79891 325 2796 79914 447 2818 79937 518 2648 79965 385 2642 79988 406 2723 80011 372 2856 80039 503 2548 80062 547 2770 80085 549 2555 80113 398 2539 80136 478 2899 80159 631 3031 80187 407 3029 80210 588 3346 80233 678 2833 80261 546 3160 80284 638 3343 80307 522 3023 80335 677 2847 80358 604 2551 80381 649 2512 80409 673 2702 80432 692 2765 80455 644 2563 80483 751 2414 80506 753 2312 80529 700 2366 80557 654 2830 80580 711 2585 80603 705 2563 80631 750 2603 80654 734 2871 80677 753 2919 80705 751 3017 80728 835 3050 80751 819 3026 80779 718 3214 80802 833 3070 80825 855 2791 80853 753 3033 80876 787 2855 80899 811 3023 80927 741 2921 80950 752 2898 80973 767 2810 81001 721 2803 81024 693 2911 81047 717 3043 81075 801 2770 81098 750 2828 81121 785 2949 81149 758 3066 81172 854 3375 81195 776 3582 81223 825 3616 81246 817 3585 81269 828 3501 81297 838 3667 81320 842 3652 81343 850 3758 81371 826 3675 81394 756 3691 81417 798 3901 81445 853 3751 81468 833 3908 81491 867 3897 81519 792 4099 81542 883 3809 81565 924 4046 81593 783 4327 81616 988 3958 81639 933 4072 81667 936 4124 81690 821 4190 81713 864 4125 81741 879 4109 81764 922 3999 81787 909 4133 82104 912 3912 82127 879 4109 82150 892 3984 82178 900 4793 82201 896 4355 82224 882 4004 82252 906 4230 82275 855 4528 82298 889 4417 82326 846 3949 82349 836 3996 82372 862 4360 82400 846 4254 82423 768 4338 82446 866 4298 82474 773 4297 82497 864 4077 82520 849 4368 82548 882 4426 82571 794 4560 82594 832 4551 82622 914 4587 82645 949 4311 82668 890 4406 82696 927 4510 82719 905 4587 82742 863 4581 82770 907 4630 82793 998 4419 82816 963 4421 82844 938 4593 82867 973 4331 82890 952 4177 82918 913 4121 82941 933 3803 82964 950 4108 82992 876 3838 83015 949 3775 83038 904 3906 83066 854 3962 83089 884 3863 83112 893 3916 83140 717 4101 83163 849 4382 83186 847 4281 83214 853 4293 83237 931 4197 83260 881 4277 83288 908 4262 83311 862 4222 83334 894 4502 83362 884 4120 83385 806 4171 83408 818 4343 83436 748 4214 83459 788 4268 83482 795 4278 83510 798 4652 83533 836 4396 83556 785 4438 83584 825 4468 83607 814 4327 83630 806 4519 83658 762 4264 83681 833 4197 83704 787 4262 83732 733 4470 83755 865 4043 83778 800 4066 83806 703 4305 83829 798 4061 83852 809 4025 83880 815 4072 83903 822 3907 83926 826 4192 83954 769 4135 83977 781 4033 84000 839 4136 84028 717 4083 84051 756 4136 84074 1372 4235 84391 826 3787 84414 764 3850 84437 766 3718 84465 773 3727 84488 769 3723 84511 810 3537 84539 778 3856 84562 786 3931 84585 721 3813 84613 790 3536 84636 838 3532 84659 810 3467 84687 773 3291 84710 786 3426 84733 772 3634 84761 859 3357 84784 779 3395 84807 826 3741 84835 840 3886 84858 909 3854 84881 876 3979 84909 838 3834 84932 830 3761 84955 824 3842 84983 729 3977 85006 820 3959 85029 864 3657 85057 830 3808 85080 857 3470 85103 752 3520 85131 749 3581 85154 772 3586 85177 705 3925 85205 804 3439 85228 735 3546 85251 787 3408 85279 697 3316 85302 724 3345 85325 678 3525 85353 727 3390 85376 717 3503 85399 720 3478 85427 689 3394 85450 674 3599 85473 751 3461 85501 718 3669 85524 792 3693 85547 680 3494 85575 776 3840 85598 746 3595 85621 750 3538 85649 802 3608 85672 740 3533 85695 803 3643 85723 805 3872 85746 785 3464 85769 790 3609 85797 845 3517 85820 869 3491 85843 795 3867 85871 774 3682 85894 717 3660 85917 723 3990 85945 768 3570 85968 717 3640 85991 742 3415 86019 674 3542 86042 737 3625 86065 754 3328 86093 839 3282 86116 762 3449 86139 712 3453 86167 779 3243 86190 784 3240 86213 698 3461 86241 747 3516 86264 731 3582 86287 720 3497 86315 745 3304 86338 766 3223 86361 708 3401 86678 709 3523 86701 673 3589 86724 729 3490 86752 708 3764 86775 716 3596 86798 709 3255 86826 710 3378 86849 746 3547 86872 735 3453 86900 699 3508 86923 747 3387 86946 723 3343 86974 708 3307 86997 709 3282 87020 677 3336 87048 627 3402 87071 718 3413 87094 674 3454 87122 724 3537 87145 744 3567 87168 712 3341 87196 740 3515 87219 718 3287 87242 665 3128 87270 718 2938 87293 683 3006 87316 690 3214 87344 663 2996 87367 614 3139 87390 700 3075 87418 616 3100 87441 675 3073 87464 709 2913 87492 684 3271 87515 720 2973 87538 694 3087 87566 636 3961 87589 807 3165 87612 630 3335 87640 680 3427 87663 643 3256 87686 671 3307 87714 719 3022 87737 582 3110 87760 626 3197 87788 648 3135 87811 617 3045 87834 741 2762 87862 663 2945 87885 572 2788 87908 605 2726 87936 644 2593 87959 598 2468 87982 601 2692 88010 590 2409 88033 590 2803 88056 582 2654 88084 575 2702 88107 632 2802 88130 627 2905 88158 596 3179 88181 606 3030 88204 592 3018 88232 647 2646 88255 625 2676 88278 647 2674 88306 560 2659 88329 623 2640 88352 580 2668 88380 605 2554 88403 642 2603 88426 580 2679 88454 553 2796 88477 605 2612 88500 608 2665 88528 591 2714 88551 655 2631 88574 526 2758 88602 626 2797 88625 598 2767 88648 581 2756 88965 502 2784 88988 554 2777 89011 536 2768 89039 538 2601 89062 575 2696 89085 566 2650 89113 554 2783 89136 497 2656 89159 480 2689 89187 535 2657 89210 503 2644 89233 570 2648 89261 528 2580 89284 526 2600 89307 524 2463 89335 479 2580 89358 495 2469 89381 542 2611 89409 585 2493 89432 482 2661 89455 577 2427 89483 550 2590 89506 511 2634 89529 508 2661 89557 582 2460 89580 583 2547 89603 540 2573 89631 585 2326 89654 581 2320 89677 545 2516 89705 545 2487 89728 550 2526 89751 493 2523 89779 578 2441 89802 568 2346 89825 540 2471 89853 432 2453 89876 505 2466 89899 501 2408 89927 499 2339 89950 457 2520 89973 474 2425 90001 468 2358 90024 509 2363 90047 559 2171 90075 523 2191 90098 517 2206 90121 488 2418 90149 488 2278 90172 502 2427 90195 521 2389 90223 513 2311 90246 489 2329 90269 602 2188 90297 475 2321 90320 476 2394 90343 505 2417 90371 516 2531 90394 495 2623 90417 539 2637 90445 486 2588 90468 530 2707 90491 502 2795 90519 516 2357 90542 508 2477 90565 574 2109 90593 485 2495 90616 495 2365 90639 432 2415 90667 554 2261 90690 487 2245 90713 499 2450 90741 476 2652 90764 547 2630 90787 536 2567 90815 537 2321 90838 529 2610 90861 556 2498 90889 463 2532 90912 495 2423 90935 457 2445 91252 562 2278 91275 537 2325 91298 467 2446 91326 474 2508 91349 484 2363 91372 480 2332 91400 440 2311 91423 467 2329 91446 463 2367 91474 485 2166 91497 478 2061 91520 458 2142 91548 459 2047 91571 443 2101 91594 459 2149 91622 447 2069 91645 394 2162 91668 456 2196 91696 411 2139 91719 453 2108 91742 450 1884 91770 436 2042 91793 412 1828 91816 383 1944 91844 413 1986 91867 448 2038 91890 406 1987 91918 424 1859 91941 379 1917 91964 434 1897 91992 396 1888 92015 438 1903 92038 398 1919 92066 455 1858 92089 414 1836 92112 409 1781 92140 379 1898 92163 375 1900 92186 410 1914 92214 373 1850 92237 402 1955 92260 452 1830 92288 383 1838 92311 426 1852 92334 436 1928 92362 369 1892 92385 414 1910 92408 403 1930 92436 410 2060 92459 394 2016 92482 463 1907 92510 422 1890 92533 445 1952 92556 456 1874 92584 380 1979 92607 407 2050 92630 429 1838 92658 406 1944 92681 394 2060 92704 346 2025 92732 366 1903 92755 400 1889 92778 362 1963 92806 291 2008 92829 367 1814 92852 368 2021 92880 392 1911 92903 317 1915 92926 329 2066 92954 375 1770 92977 346 1909 93000 363 2003 93028 393 1813 93051 394 1789 93074 397 1685 93102 334 1953 93125 359 1785 93148 326 1901 93176 385 1708 93199 335 1658 93222 352 1679 93539 306 1684 93562 332 1550 93585 335 1597 93613 280 1751 93636 317 1526 93659 295 1787 93687 286 1673 93710 299 1529 93733 351 1532 93761 305 1525 93784 274 1541 93807 318 1663 93835 301 1595 93858 347 1466 93881 298 1563 93909 318 1517 93932 315 1426 93955 335 1357 93983 337 1526 94006 320 1521 94029 274 1446 94057 318 1526 94080 284 1608 94103 247 1661 94131 344 1521 94154 276 1574 94177 318 1533 94205 306 1607 94228 283 1614 94251 312 1664 94279 324 1546 94302 278 1658 94325 300 1597 94353 289 1488 94376 278 1520 94399 315 1560 94427 265 1544 94450 345 1487 94473 237 1558 94501 240 1473 94524 285 1499 94547 299 1459 94575 261 1587 94598 261 1607 94621 232 1612 94649 242 1632 94672 301 1451 94695 293 1523 94723 286 1428 94746 282 1350 94769 260 1476 94797 241 1343 94820 290 1399 94843 305 1278 94871 217 1304 94894 288 1276 94917 227 1462 94945 311 1363 94968 220 1304 94991 258 1311 95019 257 2512 95042 755 1006 95065 307 1471 95093 213 1465 95116 323 1439 95139 220 1369 95167 222 1261 95190 278 1212 95213 238 1218 95241 238 1191 95264 241 1196 95287 235 1211 95315 198 1387 95338 197 1379 95361 243 1120 95389 219 1223 95412 234 1258 95435 222 1315 95463 239 1246 95486 185 1262 95509 213 1298 95826 205 1116 95849 211 1160 95872 180 1148 95900 192 1287 95923 191 1206 95946 212 1126 95974 236 1044 95997 185 1196 96020 215 1167 96048 248 1030 96071 203 1087 96094 194 1139 96122 197 1110 96145 184 1157 96168 224 1116 96196 193 1110 96219 210 1106 96242 202 1160 96270 191 1215 96293 165 1239 96316 209 1113 96344 246 1119 96367 186 1188 96390 203 1096 96418 205 1190 96441 166 1082 96464 155 1082 96492 130 1054 96515 123 1055 96538 160 1007 96566 126 1078 96589 167 1002 96612 193 911 96640 146 1043 96663 176 1012 96686 185 961 96714 159 835 96737 142 897 96760 152 896 96788 139 1010 96811 184 855 96834 145 893 96862 171 937 96885 121 906 96908 83 865 96936 139 822 96959 124 892 96982 120 889 97010 136 832 97033 104 837 97056 133 792 97084 91 907 97107 112 867 97130 96 884 97158 100 763 97181 109 731 97204 103 685 97232 124 733 97255 94 787 97278 126 682 97306 121 737 97329 106 756 97352 116 734 97380 86 672 97403 56 702 97426 55 800 97454 58 667 97477 104 603 97500 89 630 97528 97 596 97551 80 660 97574 87 530 97602 60 577 97625 53 645 97648 107 569 97676 24 649 97699 82 566 97722 57 520 97750 37 632 97773 59 490 97796 57 507 98113 98 999999 98136 20 999999 98159 7 999999 98187 -11 999999 98210 34 999999 98233 42 999999 98261 -12 999999 98284 22 345 98307 35 999999 98335 -12 351 98358 26 227 98381 52 999999 98409 20 262 98432 -17 306 98455 -18 220 98483 -26 230 98506 -4 999999 98529 16 182 98557 17 202 98580 34 187 98603 37 175 98631 13 175 98654 9 168 98677 3 234 98705 -1 154 98728 -0 169 98751 20 999999 98779 -11 154 98802 58 999999 98825 38 999999 98853 -5 999999 98876 12 999999 98899 3 999999 98927 -12 999999 98950 12 999999 98973 55 999999 99001 2 999999 99024 -26 999999 99047 0 999999 99075 3 999999 99098 14 999999 99121 9 999999 99149 2 999999 99172 5 999999 99195 37 999999 99223 -14 999999 99246 -4 999999 99269 -26 999999 99297 23 999999 99320 9 999999 99343 -41 999999 99371 9 999999 99394 -23 999999 99417 45 999999 99445 -9 999999 99468 47 999999 99491 29 999999 99519 -1 999999 99542 35 999999 99565 50 999999 99593 -7 999999 99616 -40 999999 99639 -2 999999 99667 -7 999999 99690 37 999999 99713 -16 999999 99741 35 999999 99764 33 999999 99787 23 999999 99815 -19 999999 99838 28 999999 99861 15 999999 99889 17 999999 99912 -12 999999 99935 -9 999999 99963 41 999999 99986 -10 999999 100009 18 999999 100037 -8 999999 100060 -19 999999 100083 -35 999999 100400 -55 999999 100423 5 999999 100446 10 999999 100474 -32 999999 100497 48 999999 100520 5 999999 100548 -43 999999 100571 -8 999999 100594 -35 999999 100622 33 999999 100645 4 999999 100668 14 999999 100696 30 999999 100719 21 999999 100742 -32 999999 100770 1 999999 100793 23 999999 100816 -30 999999 100844 4 999999 100867 43 999999 100890 44 999999 100918 5 999999 100941 12 999999 100964 -7 999999 100992 21 999999 101015 8 999999 101038 19 999999 101066 5 999999 101089 2 999999 101112 12 999999 101140 38 999999 101163 -4 999999 101186 12 999999 101214 3 999999 101237 -7 999999 101260 4 999999 101288 36 999999 101311 -1 999999 101334 -19 999999 101362 5 999999 101385 44 999999 101408 -7 999999 101436 -39 999999 101459 18 999999 101482 15 999999 101510 -34 999999 101533 7 999999 101556 18 999999 101584 -2 999999 101607 16 999999 101630 -15 999999 101658 9 999999 101681 18 999999 101704 -9 999999 101732 -23 999999 101755 20 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103501 -2 999999 103524 -8 999999 103547 30 999999 103575 -3 999999 103598 48 999999 103621 -50 999999 103649 48 999999 103672 9 999999 103695 -5 999999 103723 -3 999999 103746 17 999999 103769 14 999999 103797 -42 999999 103820 -31 999999 103843 -33 999999 103871 13 999999 103894 4 999999 103917 -13 999999 103945 14 999999 103968 40 999999 103991 -5 999999 104019 15 999999 104042 19 999999 104065 -30 999999 104093 38 999999 104116 9 999999 104139 1 999999 104167 6 999999 104190 -6 999999 104213 -14 999999 104241 5 999999 104264 9 999999 104287 -22 999999 104315 42 999999 104338 3 999999 104361 2 999999 104389 21 999999 104412 35 999999 104435 -10 999999 104463 25 999999 104486 -35 999999 104509 13 999999 104537 11 999999 104560 23 999999 104583 -1 999999 104611 22 999999 104634 -6 999999 104657 -5 999999 104974 17 999999 104997 0 999999 105020 11 999999 105048 -15 999999 105071 11 999999 105094 -11 999999 105122 41 999999 105145 39 999999 105168 0 999999 105196 41 999999 105219 12 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