27 1001 Wennberg,P.O., Cohen,R.C., and J.G. Anderson Harvard University, Cambridge, MA 02138, Tel (617) 495-5922 HOx SPADE 1 1 1993 05 07 1994 1 3 0 Elapsed time (sec) from 0 GMT on flight day 2 1 1 999999 999999 OH Volume Mixing Ratio (x 1e15) HO2 Volume Mixing Ratio (x 1e15) 0 11 ***** Final Data - Software version 2.2 ***** OH and HO2 measurements are taken within 10 sec of timestamp Absolute Uncertainties (2-sigma) are approximately +/- 30 percent +/- .01 ppt for OH; +/- 40 percent +/- .01 ppt for HO2 Absolute Uncertainty for the ratio: OH/HO2 is approximately 25 percent Reported HO2 will contain a fractional contribution from RO2. R=CH3,C2H5 HO2 reported = [HO2] + (.4 - .6)[RO2] for pressures less than 150 torr ***** Final Data - Software version 2.2 ***** Time OH HO2 78384 516 2203 78407 489 2728 78430 602 2387 78458 537 2390 78481 576 2490 78504 664 2566 78532 618 2683 78555 664 2677 78578 672 2759 78606 784 2221 78629 693 2092 78652 771 2240 78680 642 2540 78703 674 2213 78726 715 2174 78754 681 2059 78777 671 2148 78800 722 2168 78828 641 2289 78851 632 2412 78874 667 2153 78902 707 2283 78925 663 2308 78948 775 2423 78976 670 2686 78999 703 2509 79022 789 2471 79050 791 2375 79073 728 2353 79096 747 2113 79124 762 2448 79147 799 2248 79170 778 2263 79198 862 1909 79221 883 1841 79244 701 1977 79272 741 2013 79295 743 1988 79318 840 2000 79346 702 2395 79369 753 2224 79392 783 2483 79420 775 2425 79443 864 2353 79466 845 2431 79494 843 2352 79517 825 2686 79540 893 2612 79568 896 3024 79591 832 3235 79614 936 3009 79642 845 3543 79665 857 3491 79688 852 3643 79716 861 3826 79739 830 3887 79762 862 3863 79790 823 3689 79813 842 3471 79836 874 3699 79864 838 3836 79887 828 3789 79910 833 4031 79938 847 3661 79961 879 3514 79984 774 3944 80012 873 3801 80035 875 3914 80058 876 4030 80086 914 3776 80109 845 3764 80132 893 3592 80160 880 3433 80183 961 3501 80206 854 3816 80234 862 3608 80257 843 3832 80280 858 3788 80308 959 3810 80331 979 4249 80354 1021 4139 80671 898 4143 80694 908 4008 80717 951 3910 80745 882 4322 80768 972 4235 80791 975 4085 80819 904 4435 80842 958 4302 80865 937 4438 80893 818 4361 80916 899 4356 80939 919 4399 80967 824 4237 80990 883 4064 81013 821 4378 81041 902 4290 81064 810 4045 81087 851 4317 81115 844 4526 81138 955 4372 81161 816 4446 81189 957 4066 81212 937 4335 81235 972 4467 81263 932 4472 81286 1010 4050 81309 914 4085 81337 909 4346 81360 874 4022 81383 911 4103 81411 908 4196 81434 934 4120 81457 901 3995 81485 929 3918 81508 904 4033 81531 907 4075 81559 871 4220 81582 959 4117 81605 957 4230 81633 855 4171 81656 937 4244 81679 961 4126 81707 897 4145 81730 911 4200 81753 862 4103 81781 907 4029 81804 911 4187 81827 913 4229 81855 812 4262 81878 849 4157 81901 833 3917 81929 862 4341 81952 856 4096 81975 889 4214 82003 891 3963 82026 860 4011 82049 826 4142 82077 897 3975 82100 904 4229 82123 882 4097 82151 886 3913 82174 908 4091 82197 924 3836 82225 748 3935 82248 876 3858 82271 907 3905 82299 831 4134 82322 924 3743 82345 860 3951 82373 851 3873 82396 839 4150 82419 910 3987 82447 904 4182 82470 852 4337 82493 940 4294 82521 938 4279 82544 844 4320 82567 941 4158 82595 864 4277 82618 823 4038 82641 839 4207 82958 846 3806 82981 791 3724 83004 820 3656 83032 850 3874 83055 866 3869 83078 828 3852 83106 807 4297 83129 858 4279 83152 918 3981 83180 756 3896 83203 795 3614 83226 721 3629 83254 826 3498 83277 806 3478 83300 769 3404 83328 836 3312 83351 787 3407 83374 797 3382 83402 794 3445 83425 724 3530 83448 798 3546 83476 781 3542 83499 733 3514 83522 834 3470 83550 781 3476 83573 850 3338 83596 769 3276 83624 792 3283 83647 763 3121 83670 763 3188 83698 732 3539 83721 742 3262 83744 714 3399 83772 813 3224 83795 736 3030 83818 730 3545 83846 774 3305 83869 766 3536 83892 795 3524 83920 708 3620 83943 779 3355 83966 738 3333 83994 688 3514 84017 850 3498 84040 786 3607 84068 778 3752 84091 879 3463 84114 853 3506 84142 716 3641 84165 723 3613 84188 710 3593 84216 695 3439 84239 731 3402 84262 788 3323 84290 763 3364 84313 672 3548 84336 811 3459 84364 739 3430 84387 722 3561 84410 747 3396 84438 725 3558 84461 777 3385 84484 813 3352 84512 652 3462 84535 700 3484 84558 754 3481 84586 743 3291 84609 784 3385 84632 766 3253 84660 684 3322 84683 732 3146 84706 738 3294 84734 705 3386 84757 720 3371 84780 721 3252 84808 714 3320 84831 700 3728 84854 759 3617 84882 835 3524 84905 798 3409 84928 769 3267 85245 669 3185 85268 672 3264 85291 742 3274 85319 725 3160 85342 715 3191 85365 734 3161 85393 741 3356 85416 676 3319 85439 678 3266 85467 666 2953 85490 699 3054 85513 741 3114 85541 686 3135 85564 676 3005 85587 719 3361 85615 707 3109 85638 644 3249 85661 690 3338 85689 716 3342 85712 779 3406 85735 718 3299 85763 637 3321 85786 654 3477 85809 687 3563 85837 686 3411 85860 720 3454 85883 685 3385 85911 698 3387 85934 699 3229 85957 728 3216 85985 670 3076 86008 658 3046 86031 678 2926 86059 637 3209 86082 642 3002 86105 674 3081 86133 621 3131 86156 649 3100 86179 662 2957 86207 639 3015 86230 627 2857 86253 654 2798 86281 596 2901 86304 670 2868 86327 674 2788 86355 642 3070 86378 705 2924 86401 661 3022 86429 671 2829 86452 638 2774 86475 625 2787 86503 635 3059 86526 643 3048 86549 736 2956 86577 686 2816 86600 623 2670 86623 612 2873 86651 666 2982 86674 666 2705 86697 620 2982 86725 634 2897 86748 670 2746 86771 702 2826 86799 707 2718 86822 655 2789 86845 688 2690 86873 675 2748 86896 617 2761 86919 621 2671 86947 633 2730 86970 705 2713 86993 596 2835 87021 660 2819 87044 638 3003 87067 681 2897 87095 747 2884 87118 680 3153 87141 654 3088 87169 671 3033 87192 643 3164 87215 754 3063 87532 557 2965 87555 615 2811 87578 598 3062 87606 617 2739 87629 543 3127 87652 616 2747 87680 581 2828 87703 658 2874 87726 629 2875 87754 510 2965 87777 623 2824 87800 560 2751 87828 566 2941 87851 601 2829 87874 585 2685 87902 564 2834 87925 582 2889 87948 610 2725 87976 576 2666 87999 587 2718 88022 570 2779 88050 540 2794 88073 552 2736 88096 573 2767 88124 567 2717 88147 577 2760 88170 536 2742 88198 553 2626 88221 605 2807 88244 503 2855 88272 489 2732 88295 596 2613 88318 509 2701 88346 618 2712 88369 560 2848 88392 545 2668 88420 550 2597 88443 613 2511 88466 591 2586 88494 534 2686 88517 551 2595 88540 525 2501 88568 552 2600 88591 519 2498 88614 508 2641 88642 579 2783 88665 600 2569 88688 583 2529 88716 550 2842 88739 535 2858 88762 562 2623 88790 581 2548 88813 544 2617 88836 540 2660 88864 546 2461 88887 498 2638 88910 498 2446 88938 566 2374 88961 577 2544 88984 562 2573 89012 513 2527 89035 557 2644 89058 480 2516 89086 501 2434 89109 474 2536 89132 546 2476 89160 502 2469 89183 534 2637 89206 556 2384 89234 465 2597 89257 514 2575 89280 531 2539 89308 484 2649 89331 578 2666 89354 494 2612 89382 534 2562 89405 564 2487 89428 531 2624 89456 488 2506 89479 556 2368 89502 495 2499 89819 520 2219 89842 523 2228 89865 559 2080 89893 418 2351 89916 506 2072 89939 471 2196 89967 519 2115 89990 518 2376 90013 522 2130 90041 516 2166 90064 450 2106 90087 469 2132 90115 466 2135 90138 487 2013 90161 497 2034 90189 434 2031 90212 471 2119 90235 453 2236 90263 472 2066 90286 453 2170 90309 459 1839 90337 438 2180 90360 443 2146 90383 523 2333 90411 440 2444 90434 484 2352 90457 510 2273 90485 524 2192 90508 528 2243 90531 465 2322 90559 494 2330 90582 495 2250 90605 458 2230 90633 454 2423 90656 479 2220 90679 497 2214 90707 527 2218 90730 438 1911 90753 434 1977 90781 430 2085 90804 432 2167 90827 390 2009 90855 426 2098 90878 457 1931 90901 462 2019 90929 397 2055 90952 428 2091 90975 477 2046 91003 428 2160 91026 425 2186 91049 447 2394 91077 435 2323 91100 414 2154 91123 385 2223 91151 430 2281 91174 426 2368 91197 405 2377 91225 454 2156 91248 451 2169 91271 421 2126 91299 416 2015 91322 446 2082 91345 368 2354 91373 391 2120 91396 426 2196 91419 408 2108 91447 429 2089 91470 443 1998 91493 388 1991 91521 386 2102 91544 417 2001 91567 421 1920 91595 433 1940 91618 368 2130 91641 424 2085 91669 393 2083 91692 443 2039 91715 410 1953 91743 417 1983 91766 366 2077 91789 383 1952 92106 312 1876 92129 386 1907 92152 378 1925 92180 370 1967 92203 354 2026 92226 434 1887 92254 397 1801 92277 326 1912 92300 380 1829 92328 353 1927 92351 346 1832 92374 329 1806 92402 368 1848 92425 359 1838 92448 360 1774 92476 355 1999 92499 328 1875 92522 372 1766 92550 379 1812 92573 354 1839 92596 352 1773 92624 288 1938 92647 316 1840 92670 317 1826 92698 479 1581 92721 357 1728 92744 333 1687 92772 337 1664 92795 374 1664 92818 322 1570 92846 291 1637 92869 288 1627 92892 322 1562 92920 349 1467 92943 368 1521 92966 359 1504 92994 382 1530 93017 371 1502 93040 344 1450 93068 272 1539 93091 317 1552 93114 334 1504 93142 286 1433 93165 293 1480 93188 294 1472 93216 280 1531 93239 283 1552 93262 264 1548 93290 370 1443 93313 335 1470 93336 342 1459 93364 307 1280 93387 325 1457 93410 275 1561 93438 246 1523 93461 296 1544 93484 324 1466 93512 293 1272 93535 310 1479 93558 291 1436 93586 289 1292 93609 273 1702 93632 331 1581 93660 252 1597 93683 289 1574 93706 319 1383 93734 288 1507 93757 325 1252 93780 268 1444 93808 311 1407 93831 302 1539 93854 316 1614 93882 303 1486 93905 310 1520 93928 282 1591 93956 325 1455 93979 317 1516 94002 313 1381 94030 275 1309 94053 288 1288 94076 348 1617 94393 248 1336 94416 231 1426 94439 244 1266 94467 282 1386 94490 285 1379 94513 245 1443 94541 242 1492 94564 274 1470 94587 333 1223 94615 245 1446 94638 270 1301 94661 229 1431 94689 255 1403 94712 233 1299 94735 274 1286 94763 214 1379 94786 201 1275 94809 247 1285 94837 208 1343 94860 207 1344 94883 220 1190 94911 222 1119 94934 189 1103 94957 227 1101 94985 200 1108 95008 186 1137 95031 184 1310 95059 251 1213 95082 243 1240 95105 242 1346 95133 257 1226 95156 260 1314 95179 254 1214 95207 192 1333 95230 196 1378 95253 231 1239 95281 212 1164 95304 214 1201 95327 246 1280 95355 242 1156 95378 210 1241 95401 210 1224 95429 245 1134 95452 221 1135 95475 195 1085 95503 203 1236 95526 221 1152 95549 208 1183 95577 226 1112 95600 194 1175 95623 185 1070 95651 195 1110 95674 178 1108 95697 194 1047 95725 143 1038 95748 183 972 95771 171 970 95799 176 960 95822 194 932 95845 173 1000 95873 152 997 95896 163 919 95919 200 869 95947 109 950 95970 178 893 95993 176 964 96021 147 988 96044 164 905 96067 198 899 96095 183 899 96118 141 897 96141 157 878 96169 129 943 96192 118 862 96215 105 949 96243 129 905 96266 182 844 96289 142 801 96317 136 970 96340 167 896 96363 187 856 96680 168 797 96703 159 701 96726 132 833 96754 111 862 96777 139 816 96800 100 888 96828 153 913 96851 122 845 96874 131 912 96902 175 883 96925 189 803 96948 162 827 96976 110 746 96999 92 736 97022 135 680 97050 111 646 97073 42 684 97096 88 687 97124 82 741 97147 130 604 97170 91 603 97198 111 648 97221 85 629 97244 104 669 97272 96 742 97295 85 663 97318 79 669 97346 109 526 97369 82 448 97392 48 620 97420 136 540 97443 63 630 97466 49 492 97494 50 456 97517 108 425 97540 86 570 97568 21 599 97591 75 539 97614 35 566 97642 45 507 97665 43 474 97688 68 377 97716 22 457 97739 22 419 97762 11 471 97790 33 371 97813 6 428 97836 51 396 97864 -26 458 97887 29 383 97910 25 340 97938 27 352 97961 10 324 97984 46 236 98012 15 239 98035 10 260 98058 -36 283 98086 56 214 98109 6 175 98132 33 208 98160 19 233 98183 34 222 98206 1 999999 98234 31 999999 98257 38 999999 98280 27 999999 98308 13 999999 98331 6 173 98354 13 999999 98382 6 999999 98405 10 999999 98428 30 174 98456 22 999999 98479 16 999999 98502 16 212 98530 40 999999 98553 34 999999 98576 -9 226 98604 3 999999 98627 -8 163 98650 34 999999 98967 32 999999 98990 16 999999 99013 -0 999999 99041 61 999999 99064 13 999999 99087 4 999999 99115 10 999999 99138 16 999999 99161 -28 999999 99189 32 999999 99212 16 999999 99235 34 999999 99263 -45 999999 99286 0 999999 99309 27 999999 99337 15 999999 99360 13 999999 99383 20 999999 99411 -17 999999 99434 14 999999 99457 10 999999 99485 21 999999 99508 42 999999 99531 -40 999999 99559 21 999999 99582 8 999999 99605 -19 999999 99633 -4 999999 99656 -7 999999 99679 24 999999 99707 -3 999999 99730 21 999999 99753 9 999999 99781 23 999999 99804 29 999999 99827 33 999999 99855 -9 999999 99878 30 999999 99901 -1 999999 99929 13 999999 99952 -11 999999 99975 24 999999 100003 10 999999 100026 4 999999 100049 -13 999999 100077 -19 999999 100100 -2 999999 100123 16 999999 100151 22 999999 100174 0 999999 100197 -14 999999 100225 -23 999999 100248 -28 999999 100271 -27 999999 100299 38 999999 100322 -2 999999 100345 -2 999999 100373 34 999999 100396 29 999999 100419 28 999999 100447 -2 999999 100470 4 999999 100493 17 999999 100521 40 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-35 999999 104031 13 999999 104059 7 999999 104082 25 999999 104105 21 999999 104133 24 999999 104156 -24 999999 104179 1 999999 104207 -5 999999 104230 40 999999 104253 8 999999 104281 3 999999 104304 -13 999999 104327 28 999999 104663 19 999999 104686 7 999999 104709 -14 999999 104737 -8 999999 104760 -1 999999