45 1001 MOORE, FRED; DUTTON, GEOFF; ELKINS, JAMES; HALL, BRAD; HURST, DALE;NANCE, DAVID U.S. DEPT OF COMMERCE, NOAA / CMDL / HALOCARBONS AND OTHER ATMOSPHERIC TRACE SPECIES GROUP PANTHER TC4 1 1 2007 08 13 2007 12 06 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 18 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) PAN MIXING RATIO (PPT) PAN ERROR 1-sd (PPT) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CO MIXING RATIO (PPB) CO ERROR 1-sd (PPB) 12 Preliminary data: Still needs to be synchronized to O3 time stamp. Some bad data points need to be removed. CO and halon-1211 data are of poor quality on this flight. An approximate 3 sec. wide air sample is analyzed for each data point. Air is sampled through an inlet 14 inch above the fuselage, several feet prior to the jet engine exhaust point. : Except for PAN, calibration gas is analyzed every 3-th injection. Data nomalized to this calibration gas is transferd onto a 4 point calibration curve generated in the lab. : PAN is calibrated in flight 4-th injection via production from an NO standard using UV and Acetone. Possibility of PAN loss on inlet is being investigated : : 1 GMTs F11 F11e H1211 H1211e F12 F12e SF6 SF6e N2O N2Oe PAN PANe CH4 CH4e H2 H2e CO COe 56635 245.8 3.1 4.297 0.218 9999 999 6.248 0.125 326.8 3.5 9999 999 9999 999 9999 999 9999 999 56705 9999 999 5.155 0.260 9999 999 6.275 0.125 325.1 3.5 9999 999 1790.2 21.9 529.2 18.9 9999 999 56845 240.8 3.0 4.171 0.212 9999 999 6.432 0.127 319.2 3.5 9999 999 1828.6 22.3 545.1 19.2 107.5702 7.2158 56915 243.2 3.1 4.521 0.229 9999 999 6.382 0.126 320.4 3.5 9999 999 9999 999 9999 999 9999 999 56985 9999 999 9999 999 9999 999 9999 999 9999 999 112.5 6.7 9999 999 9999 999 9999 999 57055 246.3 3.1 3.708 0.189 9999 999 6.397 0.126 323.1 3.5 9999 999 9999 999 9999 999 9999 999 57125 247.0 3.1 4.084 0.207 9999 999 6.399 0.126 324.1 3.5 92.9 5.6 1838.8 22.4 531.8 18.9 81.5144 5.9867 57265 246.0 3.1 4.182 0.212 9999 999 6.351 0.126 324.5 3.5 76.6 4.8 1808.8 22.1 546.1 19.2 64.6082 5.2634 57335 252.2 3.2 4.541 0.230 9999 999 6.323 0.126 324.0 3.5 9999 999 9999 999 9999 999 9999 999 57475 245.9 3.1 3.853 0.196 542.8 6.4 6.276 0.125 321.6 3.5 9999 999 9999 999 9999 999 9999 999 57545 244.6 3.1 4.294 0.218 531.9 6.3 6.283 0.125 321.4 3.5 62.3 4.0 1784.8 21.8 546.4 19.2 66.6927 5.3484 57685 242.7 3.1 4.601 0.233 537.6 6.4 6.314 0.126 322.1 3.5 61.7 4.0 1783.1 21.8 545.8 19.2 65.6619 5.3062 57755 248.7 3.1 4.294 0.218 534.4 6.3 6.339 0.126 322.2 3.5 9999 999 9999 999 9999 999 9999 999 57825 9999 999 9999 999 9999 999 9999 999 9999 999 48.6 3.4 9999 999 9999 999 9999 999 57895 249.6 3.1 4.697 0.238 521.3 6.2 6.401 0.126 321.7 3.5 9999 999 9999 999 9999 999 9999 999 57965 249.3 3.1 4.622 0.234 526.7 6.2 6.382 0.126 319.0 3.5 9999 999 1790.5 21.9 549.1 19.2 67.3254 5.3744 58105 242.8 3.1 4.367 0.221 529.7 6.3 6.369 0.126 319.2 3.5 44.2 3.2 1783.2 21.8 551.5 19.3 62.3093 5.1713 58175 241.2 3.0 4.382 0.222 523.0 6.2 6.199 0.125 320.8 3.5 9999 999 9999 999 9999 999 9999 999 58245 9999 999 9999 999 9999 999 9999 999 9999 999 40.0 3.0 9999 999 9999 999 9999 999 58315 243.6 3.1 4.208 0.213 530.9 6.3 6.322 0.126 321.8 3.5 9999 999 9999 999 9999 999 9999 999 58385 241.5 3.0 4.053 0.206 529.5 6.3 6.294 0.126 320.6 3.5 41.5 3.0 1780.9 21.8 548.1 19.2 61.0849 5.1230 58525 242.3 3.0 4.240 0.215 527.7 6.3 6.276 0.125 320.2 3.5 9999 999 1783.7 21.8 548.5 19.2 64.2285 5.2481 58595 244.3 3.1 4.254 0.216 525.9 6.2 6.258 0.125 320.5 3.5 9999 999 9999 999 9999 999 9999 999 58665 9999 999 9999 999 9999 999 9999 999 9999 999 38.8 2.9 9999 999 9999 999 9999 999 58735 244.3 3.1 4.393 0.223 528.0 6.3 6.224 0.125 320.3 3.5 9999 999 9999 999 9999 999 9999 999 58805 241.0 3.0 4.315 0.219 529.7 6.3 6.197 0.125 319.5 3.5 41.8 3.0 1791.7 21.9 544.4 19.2 62.6260 5.1839 59015 245.8 3.1 4.250 0.215 535.8 6.3 6.240 0.125 319.7 3.5 9999 999 9999 999 9999 999 9999 999 59155 244.8 3.1 3.985 0.202 541.8 6.4 6.212 0.125 319.6 3.5 9999 999 9999 999 9999 999 9999 999 59225 241.5 3.0 4.173 0.212 528.2 6.3 6.221 0.125 319.7 3.5 45.6 3.2 1793.8 21.9 545.4 19.2 64.3281 5.2521 59365 243.3 3.1 4.235 0.215 528.6 6.3 6.181 0.125 319.1 3.5 43.8 3.1 1779.4 21.8 550.0 19.3 58.4439 5.0205 59435 244.1 3.1 3.956 0.201 528.9 6.3 6.233 0.125 319.0 3.5 9999 999 9999 999 9999 999 9999 999 59505 9999 999 9999 999 9999 999 9999 999 9999 999 42.0 3.1 9999 999 9999 999 9999 999 59575 245.5 3.1 4.127 0.209 526.2 6.2 6.240 0.125 320.1 3.5 9999 999 9999 999 9999 999 9999 999 59645 242.5 3.0 4.081 0.207 528.3 6.3 6.262 0.125 319.5 3.5 9999 999 1778.4 21.8 551.4 19.3 61.2250 5.1285 59785 241.9 3.0 4.236 0.215 529.7 6.3 6.289 0.125 320.6 3.5 45.1 3.2 1771.2 21.7 550.7 19.3 58.4993 5.0226 59855 241.5 3.0 4.100 0.208 526.3 6.2 6.248 0.125 319.8 3.5 9999 999 9999 999 9999 999 9999 999 59925 9999 999 9999 999 9999 999 9999 999 9999 999 45.3 3.2 9999 999 9999 999 9999 999 59995 245.6 3.1 3.995 0.203 534.4 6.3 6.252 0.125 320.4 3.5 9999 999 9999 999 9999 999 9999 999 60065 243.7 3.1 4.319 0.219 533.6 6.3 6.170 0.125 318.4 3.5 44.7 3.2 1760.2 21.6 545.4 19.2 64.7875 5.2707 60275 240.7 3.0 4.501 0.228 523.9 6.2 6.182 0.125 318.3 3.5 9999 999 9999 999 9999 999 9999 999 60345 9999 999 9999 999 9999 999 9999 999 9999 999 41.6 3.0 9999 999 9999 999 9999 999 60415 241.2 3.0 4.055 0.206 529.7 6.3 6.181 0.125 319.0 3.5 9999 999 9999 999 9999 999 9999 999 60485 240.4 3.0 4.186 0.212 524.1 6.2 6.131 0.124 318.9 3.5 43.6 3.1 1768.8 21.7 547.1 19.2 58.7073 5.0306 60625 240.8 3.0 3.950 0.201 517.9 6.1 6.269 0.125 318.7 3.5 44.4 3.2 1782.1 21.8 549.5 19.2 44.4274 4.5228 60695 244.6 3.1 3.777 0.192 524.0 6.2 6.217 0.125 319.5 3.5 9999 999 9999 999 9999 999 9999 999 60835 243.4 3.1 3.717 0.189 522.6 6.2 6.211 0.125 318.9 3.5 9999 999 9999 999 9999 999 9999 999 60905 244.6 3.1 4.015 0.204 526.2 6.2 6.228 0.125 320.5 3.5 45.7 3.2 1758.8 21.6 550.2 19.3 58.1356 5.0087 61045 237.5 3.0 3.789 0.193 509.9 6.1 9999 999 318.8 3.5 44.8 3.2 1764.0 21.6 547.9 19.2 52.0233 4.7822 61115 239.1 3.0 4.012 0.204 512.8 6.1 6.195 0.125 319.1 3.5 9999 999 9999 999 9999 999 9999 999 61185 9999 999 9999 999 9999 999 9999 999 9999 999 41.7 3.0 9999 999 9999 999 9999 999 61255 242.2 3.0 4.146 0.210 525.1 6.2 6.146 0.124 319.3 3.5 9999 999 9999 999 9999 999 9999 999 61325 240.3 3.0 4.149 0.210 529.2 6.3 6.143 0.124 316.6 3.5 9999 999 1778.5 21.8 543.9 19.1 67.0994 5.3651 61465 243.9 3.1 4.024 0.204 526.0 6.2 6.181 0.125 318.1 3.5 44.3 3.2 1761.0 21.6 544.6 19.2 52.8115 4.8105 61535 248.4 3.1 4.128 0.209 528.6 6.3 6.181 0.125 318.4 3.5 9999 999 9999 999 9999 999 9999 999 61605 9999 999 9999 999 9999 999 9999 999 9999 999 41.1 3.0 9999 999 9999 999 9999 999 61675 241.5 3.0 4.101 0.208 524.3 6.2 6.107 0.124 317.8 3.5 9999 999 9999 999 9999 999 9999 999 61745 239.5 3.0 4.103 0.208 522.9 6.2 6.107 0.124 319.2 3.5 44.3 3.2 1781.2 21.8 552.3 19.3 52.7458 4.8082 61885 238.2 3.0 4.078 0.207 522.9 6.2 6.163 0.125 318.4 3.5 9999 999 1775.5 21.8 554.9 19.3 43.2457 4.4850 61955 243.5 3.1 4.281 0.217 520.2 6.2 6.223 0.125 319.2 3.5 9999 999 9999 999 9999 999 9999 999 62025 9999 999 9999 999 9999 999 9999 999 9999 999 42.3 3.1 9999 999 9999 999 9999 999 62095 244.2 3.1 3.789 0.193 524.3 6.2 6.214 0.125 320.5 3.5 9999 999 9999 999 9999 999 9999 999 62165 240.8 3.0 4.263 0.216 522.2 6.2 6.217 0.125 322.3 3.5 49.4 3.4 1796.8 22.0 547.9 19.2 59.7587 5.0712 62305 245.3 3.1 4.264 0.216 537.8 6.4 6.307 0.126 322.5 3.5 67.3 4.3 1799.9 22.0 539.4 19.1 64.9324 5.2766 62375 246.0 3.1 4.005 0.203 532.0 6.3 6.186 0.125 321.3 3.5 9999 999 9999 999 9999 999 9999 999 62515 249.8 3.1 4.191 0.213 539.9 6.4 6.241 0.125 324.2 3.5 9999 999 9999 999 9999 999 9999 999 62585 245.5 3.1 4.305 0.218 535.6 6.3 6.322 0.126 322.0 3.5 63.2 4.1 1789.2 21.9 538.8 19.1 78.2488 5.8414 62725 247.8 3.1 4.644 0.235 538.1 6.4 6.296 0.126 327.5 3.5 55.1 3.7 1777.1 21.8 540.4 19.1 77.4463 5.8061 62795 249.2 3.1 4.532 0.229 530.4 6.3 6.230 0.125 323.7 3.5 9999 999 9999 999 9999 999 9999 999 62865 9999 999 9999 999 9999 999 9999 999 9999 999 71.4 4.5 9999 999 9999 999 9999 999 62935 253.2 3.2 4.710 0.238 526.5 6.2 6.248 0.125 323.8 3.5 9999 999 9999 999 9999 999 9999 999 63005 250.1 3.1 4.225 0.214 533.8 6.3 6.255 0.125 324.5 3.5 9999 999 1792.3 21.9 542.0 19.1 72.9428 5.6107 63145 242.4 3.0 4.715 0.239 524.4 6.2 6.135 0.124 318.4 3.5 53.9 3.6 1766.6 21.7 549.7 19.3 50.4804 4.7274 63215 239.6 3.0 4.279 0.217 514.4 6.1 6.185 0.125 317.6 3.5 9999 999 9999 999 9999 999 9999 999 63285 9999 999 9999 999 9999 999 9999 999 9999 999 51.8 3.5 9999 999 9999 999 9999 999 63355 237.3 3.0 4.040 0.205 518.1 6.1 6.132 0.124 315.8 3.5 9999 999 9999 999 9999 999 9999 999 63425 237.1 3.0 3.734 0.190 531.1 6.3 6.134 0.124 317.2 3.5 46.6 3.3 1765.1 21.6 545.8 19.2 74.3171 5.6698 63565 241.4 3.0 4.224 0.214 524.3 6.2 6.147 0.124 316.3 3.5 9999 999 1748.6 21.5 550.0 19.3 48.7215 4.6662 63635 244.5 3.1 3.831 0.195 523.3 6.2 6.044 0.124 315.5 3.5 9999 999 9999 999 9999 999 9999 999 63705 9999 999 9999 999 9999 999 9999 999 9999 999 42.1 3.1 9999 999 9999 999 9999 999 63775 243.3 3.1 3.454 0.176 521.4 6.2 6.116 0.124 315.9 3.5 9999 999 9999 999 9999 999 9999 999 63845 243.1 3.1 3.920 0.199 530.9 6.3 6.136 0.124 318.3 3.5 49.6 3.4 1746.8 21.5 551.8 19.3 70.6237 5.5121 64055 240.4 3.0 3.863 0.196 521.1 6.2 6.145 0.124 318.6 3.5 9999 999 9999 999 9999 999 9999 999 64195 242.8 3.1 3.917 0.199 524.3 6.2 6.099 0.124 318.8 3.5 9999 999 9999 999 9999 999 9999 999 64265 237.8 3.0 3.704 0.188 524.7 6.2 6.146 0.124 319.4 3.5 55.0 3.7 1763.6 21.6 550.8 19.3 61.3192 5.1322 64405 238.6 3.0 3.945 0.200 527.5 6.3 6.158 0.125 317.8 3.5 57.0 3.8 1762.3 21.6 549.4 19.2 46.7200 4.5983 64475 244.7 3.1 4.025 0.204 528.7 6.3 6.284 0.125 321.2 3.5 9999 999 9999 999 9999 999 9999 999 64545 9999 999 9999 999 9999 999 9999 999 9999 999 53.8 3.6 9999 999 9999 999 9999 999 64615 243.7 3.1 4.111 0.209 528.3 6.3 6.234 0.125 319.6 3.5 9999 999 9999 999 9999 999 9999 999 64685 240.4 3.0 3.897 0.198 522.3 6.2 6.205 0.125 319.0 3.5 9999 999 1786.9 21.9 552.6 19.3 66.7085 5.3490 64825 241.2 3.0 4.259 0.216 529.5 6.3 6.257 0.125 319.8 3.5 61.1 4.0 1758.5 21.6 554.6 19.3 57.9353 5.0010 64895 243.3 3.1 4.093 0.208 521.4 6.2 6.144 0.124 319.2 3.5 9999 999 9999 999 9999 999 9999 999 64965 9999 999 9999 999 9999 999 9999 999 9999 999 54.6 3.6 9999 999 9999 999 9999 999 65035 242.9 3.1 3.960 0.201 520.5 6.2 6.187 0.125 318.2 3.5 9999 999 9999 999 9999 999 9999 999 65105 243.4 3.1 4.776 0.242 524.0 6.2 6.186 0.125 320.9 3.5 60.7 3.9 1776.8 21.8 544.2 19.2 73.6657 5.6417 65315 245.6 3.1 4.080 0.207 526.3 6.2 6.181 0.125 319.7 3.5 9999 999 9999 999 9999 999 9999 999 65385 9999 999 9999 999 9999 999 9999 999 9999 999 49.0 3.4 9999 999 9999 999 9999 999 65455 247.1 3.1 4.069 0.207 524.3 6.2 6.193 0.125 319.0 3.5 9999 999 9999 999 9999 999 9999 999 65525 241.9 3.0 4.576 0.232 534.4 6.3 6.145 0.124 318.4 3.5 60.3 3.9 1789.5 21.9 543.4 19.1 77.7804 5.8208 65665 242.4 3.0 4.266 0.216 525.0 6.2 6.172 0.125 317.5 3.5 69.6 4.4 1754.9 21.5 551.9 19.3 44.7930 4.5347 65735 240.8 3.0 3.479 0.177 519.6 6.2 6.254 0.125 319.2 3.5 9999 999 9999 999 9999 999 9999 999 65875 240.2 3.0 3.738 0.190 512.1 6.1 6.175 0.125 320.9 3.5 9999 999 9999 999 9999 999 9999 999 65945 244.4 3.1 4.039 0.205 535.8 6.3 6.142 0.124 320.4 3.5 61.5 4.0 1725.5 21.2 547.3 19.2 76.5336 5.7661 66085 243.1 3.1 3.985 0.202 535.7 6.3 6.191 0.125 320.3 3.5 65.8 4.2 1736.8 21.4 541.1 19.1 58.0275 5.0046 66155 241.0 3.0 3.929 0.200 510.8 6.1 6.123 0.124 317.9 3.5 9999 999 9999 999 9999 999 9999 999 66225 9999 999 9999 999 9999 999 9999 999 9999 999 61.2 4.0 9999 999 9999 999 9999 999 66295 245.4 3.1 3.937 0.200 534.5 6.3 6.092 0.124 317.8 3.5 9999 999 9999 999 9999 999 9999 999 66365 236.4 3.0 3.919 0.199 517.6 6.1 6.115 0.124 317.6 3.5 9999 999 1757.5 21.6 560.3 19.4 64.8673 5.2739 66575 239.8 3.0 3.653 0.186 518.1 6.1 6.049 0.124 316.4 3.5 9999 999 9999 999 9999 999 9999 999 66645 9999 999 9999 999 9999 999 9999 999 9999 999 44.6 3.2 9999 999 9999 999 9999 999 66715 234.9 3.0 3.564 0.182 498.1 5.9 6.098 0.124 315.7 3.5 9999 999 9999 999 9999 999 9999 999 66785 232.7 2.9 3.747 0.191 527.1 6.2 6.060 0.124 316.1 3.5 39.6 2.9 1794.8 21.9 550.7 19.3 44.7074 4.5319 66925 228.6 2.9 3.541 0.180 504.7 6.0 6.056 0.124 315.0 3.5 9999 999 1751.3 21.5 552.4 19.3 47.3423 4.6192 66995 229.8 2.9 3.589 0.183 501.7 6.0 6.008 0.123 312.2 3.5 9999 999 9999 999 9999 999 9999 999 67065 9999 999 9999 999 9999 999 9999 999 9999 999 38.7 2.9 9999 999 9999 999 9999 999 67135 210.3 2.7 3.983 0.202 505.8 6.0 5.865 0.122 297.7 3.4 9999 999 9999 999 9999 999 9999 999 67205 197.5 2.6 3.108 0.159 466.0 5.7 5.734 0.122 290.0 3.4 42.9 3.1 1643.8 20.4 550.8 19.3 65.7591 5.3102 67345 226.6 2.9 2.961 0.152 520.2 6.2 6.030 0.124 313.4 3.5 37.1 2.8 1730.2 21.3 564.8 19.5 40.1615 4.3895 67415 225.6 2.9 4.137 0.210 509.9 6.1 6.009 0.123 314.1 3.5 9999 999 9999 999 9999 999 9999 999 67555 242.3 3.0 3.970 0.202 511.0 6.1 6.269 0.125 321.4 3.5 9999 999 9999 999 9999 999 9999 999 67625 243.2 3.1 4.033 0.205 525.3 6.2 6.315 0.126 323.3 3.5 110.5 6.6 1782.5 21.8 557.4 19.4 66.4035 5.3365 67835 253.1 3.2 4.332 0.220 541.7 6.4 6.342 0.126 323.9 3.5 9999 999 9999 999 9999 999 9999 999 67905 9999 999 9999 999 9999 999 9999 999 9999 999 391.1 22.3 9999 999 9999 999 9999 999 67975 251.5 3.2 3.685 0.188 530.3 6.3 6.401 0.126 325.2 3.5 9999 999 9999 999 9999 999 9999 999 68045 245.8 3.1 4.156 0.211 529.7 6.3 6.327 0.126 324.0 3.5 9999 999 1841.3 22.4 542.7 19.1 128.9069 8.2877 68185 244.9 3.1 4.288 0.217 533.9 6.3 6.399 0.126 325.0 3.5 272.7 15.6 1800.9 22.0 553.3 19.3 64.3239 5.2519 68255 244.7 3.1 4.600 0.233 539.7 6.4 6.343 0.126 321.6 3.5 9999 999 9999 999 9999 999 9999 999 68325 9999 999 9999 999 9999 999 9999 999 9999 999 325.3 18.6 9999 999 9999 999 9999 999 68395 243.6 3.1 3.991 0.203 516.2 6.1 6.319 0.126 322.3 3.5 9999 999 9999 999 9999 999 9999 999 68465 246.0 3.1 4.743 0.240 537.5 6.4 6.390 0.126 9999 999 229.8 13.2 9999 999 9999 999 9999 999