50 1001 FRED MOORE, GEOFF DUTTON, JAMES ELKINS, BREAD HALL, DALE HURST U.S. DEPT OF COMMERCE, NOAA / CMDL / HALOCARBONS AND OTHER ATMOSPHERIC TRACE SPECIES GROUP PANTHER CR-AVE 1 1 2006 02 07 2006 11 13 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 18 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CH3CL MIXING RATIO (PPT) CH3CL ERROR 1-sd (PPT) CH3BR MIXING RATIO (PPT) CH3BR ERROR 1-sd (PPT) CS2 MIXING RATIO (PPT) CS2 ERROR 1-sd (PPT) HCFC22 MIXING RATIO (PPT) HCFC22 ERROR 1-sd (PPT) HCFC141B MIXING RATIO (PPT) HCFC141B ERROR 1-sd (PPT) COS MIXING RATIO (PPT) COS ERROR 1-sd (PPT) CH3I MIXING RATIO (PPT) CH3I ERROR 1-sd (PPT) HCFC142B MIXING RATIO (PPT) HCFC142B ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) 17 This is a first pass at integration for the MSD data. : Data is normalized to an in flight calibration gas. Laboratory cal curves are applied. : Quoted uncertainties represent the statistical spread around a smooth fit to the measured calibration gases in flight, combined with the statistical uncertainty of a calibration curve generated in the lab. : Recalibration of CS2 and CH3I is in progress. HFC134a data has been removed because of a semi-colluded contamination peak. Acetone production in the trap is preventing acquisition of this molecule. Inlet CS2 contamination possibilities are being investigated. : Two independent channels of near identical chromatography are combined into one exchange file. On a flight-by-flight basis each channel may have independent sections of questionable data associated with trap temperature changes due to the changes in the 6 foot pallet ram airflow. The 6 foot pallet is directly in front of the aft pallet where the PANTHER resides. 1 GMTs CH3Cl CH3Cle CH3Br CH3Bre CS2 CS2e HCFC22 HCFC22e HCFC141b HCFC141be COS COSe CH3I CH3Ie HCFC142b HCFC142be F12 F12e 59166 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 14.6 0.3 9999 999 59886 9999 999 7.32 0.38 4.38 0.11 161.86 2.93 17.51 0.88 9999 999 0.03 0.02 14.6 0.3 9999 999 60246 9999 999 7.05 0.37 4.99 0.12 163.03 2.95 17.31 0.87 503.0 10.7 0.03 0.02 14.7 0.3 9999 999 60966 0.3 0.0 7.49 0.39 5.71 0.13 161.01 2.92 16.77 0.84 552.7 11.6 0.10 0.03 15.1 0.3 514.7122 7.2705 61326 0.3 0.0 7.40 0.38 3.54 0.09 164.73 2.97 17.83 0.90 530.1 11.2 0.02 0.02 15.4 0.3 515.7823 7.2855 62046 0.3 0.0 8.15 0.42 3.82 0.09 164.95 2.97 17.84 0.90 534.0 11.2 0.05 0.03 15.1 0.3 518.7459 7.3270 62406 0.3 0.0 7.75 0.40 3.73 0.09 165.25 2.98 17.23 0.87 520.5 11.0 0.01 0.02 15.0 0.3 516.5856 7.2967 63126 0.3 0.0 7.87 0.41 3.32 0.08 165.81 2.99 17.45 0.88 522.6 11.0 0.01 0.02 14.8 0.3 517.0647 7.3035 63486 0.3 0.0 7.94 0.41 2.43 0.07 165.09 2.98 17.10 0.86 515.0 10.9 0.00 0.02 14.5 0.3 513.4963 7.2534 64206 0.3 0.0 8.22 0.42 2.67 0.07 168.03 3.02 18.66 0.94 535.0 11.3 0.05 0.03 14.7 0.3 519.7182 7.3407 64566 0.3 0.0 8.07 0.42 1.78 0.06 166.63 3.00 17.79 0.90 513.2 10.9 0.03 0.02 14.8 0.3 516.5391 7.2961 65286 0.3 0.0 9999 999 3.46 0.09 163.79 2.96 9999 999 485.3 10.3 0.12 0.03 14.8 0.3 507.6175 7.1710 65646 0.3 0.0 9999 999 1.63 0.05 167.67 3.01 9999 999 507.0 10.7 0.11 0.03 15.1 0.3 523.1341 7.3886 66366 0.3 0.0 7.88 0.41 1.04 0.05 166.74 3.00 17.39 0.88 510.7 10.8 0.02 0.02 14.9 0.3 513.3904 7.2520 66726 0.3 0.0 7.80 0.40 1.70 0.06 166.84 3.00 17.14 0.86 520.8 11.0 0.02 0.02 15.5 0.3 521.7009 7.3685 67446 0.3 0.0 7.53 0.39 5.47 0.13 167.14 3.01 17.59 0.89 537.7 11.3 0.04 0.03 15.1 0.3 509.0778 7.1915 67806 0.3 0.0 7.69 0.40 6.62 0.15 162.89 2.94 17.42 0.88 539.3 11.3 0.06 0.03 14.9 0.3 516.6822 7.2981 68526 0.3 0.0 7.08 0.37 6.81 0.16 161.56 2.92 16.06 0.81 543.9 11.4 0.04 0.03 14.5 0.3 508.4445 7.1826 68886 0.3 0.0 7.58 0.39 9.02 0.21 163.51 2.95 17.14 0.86 526.0 11.1 -0.03 0.02 14.8 0.3 506.7302 7.1586 69606 0.3 0.0 7.43 0.38 8.85 0.20 163.28 2.95 16.70 0.84 541.4 11.4 0.03 0.02 14.3 0.3 506.9031 7.1610 69966 0.3 0.0 7.68 0.40 9.69 0.22 162.69 2.94 17.17 0.86 538.5 11.3 -0.03 0.02 14.2 0.3 511.0322 7.2189 70686 0.3 0.0 7.44 0.38 9.69 0.22 158.44 2.88 16.40 0.83 545.5 11.5 0.06 0.03 13.9 0.3 506.5038 7.1554 71046 0.3 0.0 7.98 0.41 9.65 0.22 163.99 2.96 17.27 0.87 536.4 11.3 0.13 0.03 14.4 0.3 510.1246 7.2062 71766 0.3 0.0 8.13 0.42 1.98 0.06 165.50 2.98 17.10 0.86 512.8 10.9 0.02 0.02 14.4 0.3 513.3786 7.2518 72126 0.3 0.0 7.75 0.40 2.31 0.07 165.42 2.98 17.57 0.88 529.9 11.2 0.03 0.02 14.5 0.3 522.6128 7.3812