45 1001 MOORE, FRED; DUTTON, GEOFF; ELKINS, JAMES; HALL, BRAD; HURST, DALE U.S. DEPT OF COMMERCE, NOAA / CMDL / HALOCARBONS AND OTHER ATMOSPHERIC TRACE SPECIES GROUP PANTHER CR-AVE 1 1 2006 01 30 2006 11 11 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 18 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) PAN MIXING RATIO (PPT) PAN ERROR 1-sd (PPT) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CO MIXING RATIO (PPB) CO ERROR 1-sd (PPB) 12 Preliminary data: Still needs to be synchronized to O3 time stamp. Some bad data points need to be removed. : An approximate 3 sec. wide air sample is analyzed for each data point. Air is sampled through an inlet 14 inch above the fuselage, several feet prior to the jet engine exhaust point. : Except for PAN, calibration gas is analyzed every 3-th injection. Data nomalized to this calibration gas is transferd onto a 4 point calibration curve generated in the lab. : Intermittent electrometer noise during flight compromised most of the CH4, CO, and H2 data. : PAN is calibrated in flight 4-th injection via production from an NO standard using UV and Acetone. Possibility of PAN loss on inlet is being investigated 1 GMTs F11 F11e H1211 H1211e F12 F12e SF6 SF6e N2O N2Oe PAN PANe CH4 CH4e H2 H2e CO COe 57772 9999 999 9999 999 9999 999 9999 999 9999 999 29.7 8.1 9999 999 9999 999 9999 999 57912 9999 999 9999 999 9999 999 9999 999 9999 999 12.5 8.1 9999 999 9999 999 9999 999 58332 9999 999 9999 999 9999 999 9999 999 9999 999 55.3 8.2 9999 999 9999 999 9999 999 58472 9999 999 9999 999 9999 999 9999 999 9999 999 30.8 8.1 9999 999 9999 999 9999 999 58682 255.6 4.4 4.198 0.083 547.9 8.8 5.797 0.065 321.4 3.6 9999 999 9999 999 9999 999 9999 999 58752 250.2 4.3 4.270 0.085 543.3 8.6 5.779 0.065 319.8 3.6 9999 999 9999 999 9999 999 9999 999 58892 252.5 4.3 4.350 0.086 537.1 8.5 5.784 0.065 319.1 3.6 24.4 8.1 9999 999 9999 999 9999 999 58962 253.7 4.4 4.520 0.089 538.1 8.5 5.754 0.064 318.8 3.6 9999 999 9999 999 9999 999 9999 999 59032 9999 999 9999 999 9999 999 9999 999 9999 999 12.8 8.1 9999 999 9999 999 9999 999 59102 9999 999 4.474 0.088 518.2 7.9 5.837 0.065 320.0 3.6 9999 999 9999 999 9999 999 9999 999 59172 9999 999 4.823 0.094 530.2 8.3 5.814 0.065 320.7 3.6 20.1 8.1 9999 999 9999 999 9999 999 59312 252.4 4.3 4.249 0.084 531.4 8.3 5.751 0.064 319.4 3.6 9999 999 9999 999 9999 999 9999 999 59382 250.5 4.3 4.556 0.089 536.2 8.4 5.753 0.064 319.4 3.6 9999 999 9999 999 9999 999 9999 999 59452 9999 999 9999 999 9999 999 9999 999 9999 999 46.2 8.2 9999 999 9999 999 9999 999 59522 250.7 4.3 9999 999 535.5 8.4 5.694 0.064 318.9 3.6 9999 999 9999 999 9999 999 9999 999 59592 248.7 4.2 9999 999 513.7 7.8 5.664 0.064 318.6 3.6 41.7 8.2 9999 999 9999 999 9999 999 59732 247.1 4.2 9999 999 538.8 8.5 5.674 0.064 319.4 3.6 33.5 8.1 9999 999 9999 999 9999 999 59802 250.1 4.3 4.044 0.081 527.1 8.2 5.729 0.064 320.2 3.6 9999 999 9999 999 9999 999 9999 999 59942 247.2 4.2 9999 999 526.4 8.2 5.680 0.064 319.5 3.6 9999 999 9999 999 9999 999 9999 999 60012 247.5 4.2 4.272 0.085 525.9 8.1 5.698 0.064 320.6 3.6 29.3 8.1 9999 999 9999 999 9999 999 60152 248.6 4.2 4.584 0.090 527.3 8.2 5.702 0.064 319.9 3.6 27.9 8.1 9999 999 9999 999 9999 999 60222 247.2 4.2 4.003 0.080 535.5 8.4 5.726 0.064 319.6 3.6 9999 999 9999 999 9999 999 9999 999 60292 9999 999 9999 999 9999 999 9999 999 9999 999 26.9 8.1 9999 999 9999 999 9999 999 60362 250.6 4.3 4.242 0.084 528.8 8.2 5.785 0.065 318.5 3.6 9999 999 9999 999 9999 999 9999 999 60432 249.4 4.2 3.966 0.080 534.0 8.4 5.740 0.064 317.6 3.6 9999 999 9999 999 9999 999 9999 999 60572 250.3 4.3 4.339 0.086 526.2 8.1 5.762 0.064 320.1 3.6 43.6 8.2 9999 999 9999 999 9999 999 60642 249.4 4.2 9999 999 525.7 8.1 5.750 0.064 320.2 3.6 9999 999 9999 999 9999 999 9999 999 60712 9999 999 9999 999 9999 999 9999 999 9999 999 27.7 8.1 9999 999 9999 999 9999 999 60782 250.3 4.3 9999 999 9999 999 5.705 0.064 321.4 3.6 9999 999 9999 999 9999 999 9999 999 60852 248.2 4.2 4.683 0.091 529.0 8.2 5.707 0.064 320.0 3.6 26.8 8.1 9999 999 9999 999 9999 999 60992 246.4 4.2 4.819 0.093 525.1 8.1 5.691 0.064 316.8 3.5 9999 999 9999 999 9999 999 9999 999 61062 248.1 4.2 9999 999 523.2 8.1 5.740 0.064 318.9 3.6 9999 999 9999 999 9999 999 9999 999 61132 9999 999 9999 999 9999 999 9999 999 9999 999 28.3 8.1 9999 999 9999 999 9999 999 61202 245.8 4.2 4.052 0.081 530.4 8.3 5.774 0.064 319.8 3.6 9999 999 9999 999 9999 999 9999 999 61272 248.1 4.2 9999 999 533.0 8.3 5.788 0.065 319.5 3.6 25.7 8.1 9999 999 9999 999 9999 999 61412 250.6 4.3 4.157 0.083 532.6 8.3 5.767 0.064 320.9 3.6 30.8 8.1 9999 999 9999 999 9999 999 61482 250.0 4.3 4.140 0.082 529.6 8.2 5.686 0.064 319.9 3.6 9999 999 9999 999 9999 999 9999 999 61622 251.6 4.3 3.826 0.077 535.0 8.4 5.729 0.064 318.4 3.6 9999 999 9999 999 9999 999 9999 999 61692 249.0 4.2 4.154 0.083 535.6 8.4 5.740 0.064 320.0 3.6 27.6 8.1 9999 999 9999 999 9999 999 61832 249.4 4.2 3.938 0.079 535.0 8.4 5.779 0.065 318.8 3.6 27.5 8.1 9999 999 9999 999 9999 999 61902 246.6 4.2 4.354 0.086 533.7 8.4 5.689 0.064 318.2 3.6 9999 999 9999 999 9999 999 9999 999 61972 9999 999 9999 999 9999 999 9999 999 9999 999 24.9 8.1 9999 999 9999 999 9999 999 62042 249.3 4.2 4.451 0.087 539.4 8.5 5.752 0.064 319.6 3.6 9999 999 9999 999 9999 999 9999 999 62112 251.0 4.3 4.526 0.089 540.1 8.6 5.807 0.065 321.5 3.6 9999 999 9999 999 9999 999 9999 999 62252 240.0 4.0 9999 999 541.1 8.6 5.763 0.064 323.8 3.6 28.5 8.1 9999 999 9999 999 9999 999 62322 247.7 4.2 4.518 0.089 530.6 8.3 5.803 0.065 320.9 3.6 9999 999 9999 999 9999 999 9999 999 62462 251.8 4.3 4.203 0.083 532.5 8.3 5.724 0.064 321.0 3.6 9999 999 9999 999 9999 999 9999 999 62532 252.9 4.3 4.316 0.085 532.0 8.3 9999 999 9999 999 32.7 8.1 9999 999 9999 999 9999 999 62672 9999 999 9999 999 9999 999 5.748 0.064 320.6 3.6 9999 999 9999 999 9999 999 9999 999 62742 248.7 4.2 4.327 0.085 527.3 8.2 5.708 0.064 318.5 3.6 9999 999 9999 999 9999 999 9999 999 62812 9999 999 9999 999 9999 999 9999 999 9999 999 37.1 8.1 9999 999 9999 999 9999 999 62882 249.7 4.3 4.597 0.090 536.3 8.4 5.771 0.064 320.0 3.6 9999 999 9999 999 9999 999 9999 999 62952 250.2 4.3 4.118 0.082 539.7 8.5 5.729 0.064 319.1 3.6 32.1 8.1 9999 999 9999 999 9999 999 63092 250.3 4.3 3.966 0.080 534.3 8.4 5.736 0.064 317.9 3.6 40.1 8.1 9999 999 9999 999 9999 999 63162 246.4 4.2 3.988 0.080 537.1 8.5 5.690 0.064 318.0 3.6 9999 999 9999 999 9999 999 9999 999 63302 244.2 4.1 4.083 0.082 525.1 8.1 5.715 0.064 317.5 3.6 9999 999 9999 999 9999 999 9999 999 63372 243.5 4.1 4.344 0.086 528.6 8.2 5.707 0.064 320.1 3.6 41.6 8.2 9999 999 9999 999 9999 999 63512 251.1 4.3 4.477 0.088 529.3 8.2 5.736 0.064 317.6 3.6 62.6 8.3 9999 999 9999 999 9999 999 63582 256.5 4.4 4.888 0.095 535.7 8.4 5.755 0.064 319.5 3.6 9999 999 9999 999 9999 999 9999 999 63652 9999 999 9999 999 9999 999 9999 999 9999 999 55.9 8.2 9999 999 9999 999 9999 999 63722 249.6 4.3 4.576 0.089 544.5 8.7 5.874 0.065 323.7 3.6 9999 999 9999 999 9999 999 9999 999 63792 247.6 4.2 4.341 0.086 534.0 8.4 5.814 0.065 321.3 3.6 9999 999 9999 999 9999 999 9999 999 63932 248.7 4.2 9999 999 550.0 8.9 5.799 0.065 321.4 3.6 70.2 8.4 9999 999 9999 999 9999 999 64002 246.8 4.2 4.816 0.093 538.0 8.5 5.758 0.064 320.9 3.6 9999 999 9999 999 9999 999 9999 999 64072 9999 999 9999 999 9999 999 9999 999 9999 999 43.4 8.2 9999 999 9999 999 9999 999 64142 254.3 4.4 4.278 0.085 543.5 8.7 5.712 0.064 322.0 3.6 9999 999 9999 999 9999 999 9999 999 64212 249.0 4.2 4.254 0.084 537.5 8.5 5.747 0.064 320.7 3.6 50.9 8.2 9999 999 9999 999 9999 999 64352 249.3 4.2 4.275 0.085 531.4 8.3 5.696 0.064 320.3 3.6 9999 999 9999 999 9999 999 9999 999 64422 251.3 4.3 4.475 0.088 534.3 8.4 5.791 0.065 323.1 3.6 9999 999 9999 999 9999 999 9999 999 64492 9999 999 9999 999 9999 999 9999 999 9999 999 55.8 8.2 9999 999 9999 999 9999 999 64562 248.1 4.2 4.475 0.088 529.4 8.2 5.883 0.065 321.8 3.6 9999 999 9999 999 9999 999 9999 999 64632 248.1 4.2 4.211 0.084 530.7 8.3 5.875 0.065 321.2 3.6 62.3 8.3 9999 999 9999 999 9999 999 64772 258.6 4.5 4.321 0.085 545.9 8.7 5.858 0.065 321.5 3.6 58.6 8.3 9999 999 9999 999 9999 999 64842 250.0 4.3 4.724 0.092 539.2 8.5 5.946 0.066 322.8 3.6 9999 999 9999 999 9999 999 9999 999 64982 255.0 4.4 4.853 0.094 538.4 8.5 5.788 0.065 320.3 3.6 9999 999 9999 999 9999 999 9999 999 65052 245.8 4.2 4.283 0.085 520.2 8.0 5.726 0.064 318.8 3.6 61.0 8.3 9999 999 9999 999 9999 999 65192 253.1 4.3 4.698 0.091 529.7 8.2 5.891 0.065 322.8 3.6 65.0 8.3 9999 999 9999 999 9999 999 65262 9999 999 4.636 0.090 534.6 8.4 5.825 0.065 322.3 3.6 9999 999 9999 999 9999 999 9999 999 65332 9999 999 9999 999 9999 999 9999 999 9999 999 54.5 8.2 9999 999 9999 999 9999 999 65402 250.5 4.3 4.587 0.090 535.2 8.4 5.878 0.065 319.5 3.6 9999 999 9999 999 9999 999 9999 999 65472 251.8 4.3 4.122 0.082 533.3 8.4 5.849 0.065 320.6 3.6 9999 999 9999 999 9999 999 9999 999 65612 252.9 4.3 4.055 0.081 535.6 8.4 5.765 0.064 322.6 3.6 139.5 9.3 9999 999 9999 999 9999 999 65682 249.7 4.3 4.474 0.088 538.4 8.5 5.775 0.064 320.9 3.6 9999 999 9999 999 9999 999 9999 999 65752 9999 999 9999 999 9999 999 9999 999 9999 999 91.3 8.6 9999 999 9999 999 9999 999 65822 259.4 4.5 4.458 0.088 554.5 9.0 5.831 0.065 323.2 3.6 9999 999 9999 999 9999 999 9999 999 65892 254.4 4.4 4.404 0.087 533.4 8.4 5.897 0.066 323.0 3.6 87.7 8.5 9999 999 9999 999 9999 999 66032 249.1 4.2 4.547 0.089 541.4 8.6 5.817 0.065 321.5 3.6 9999 999 9999 999 9999 999 9999 999 66102 251.9 4.3 4.917 0.095 531.8 8.3 5.950 0.066 324.5 3.6 9999 999 9999 999 9999 999 9999 999 66242 245.5 4.1 9999 999 531.5 8.3 5.842 0.065 319.5 3.6 9999 999 9999 999 9999 999 9999 999 66312 252.6 4.3 4.219 0.084 521.3 8.0 5.784 0.065 319.9 3.6 83.9 8.5 9999 999 9999 999 9999 999 66452 254.5 4.4 4.071 0.081 530.0 8.3 5.641 0.063 319.4 3.6 57.9 8.3 9999 999 9999 999 9999 999 66522 253.5 4.4 4.271 0.085 532.1 8.3 5.821 0.065 322.5 3.6 9999 999 9999 999 9999 999 9999 999 66662 243.2 4.1 4.087 0.082 524.4 8.1 5.681 0.064 318.7 3.6 9999 999 9999 999 9999 999 9999 999 66732 238.0 4.0 3.708 0.076 526.8 8.2 5.664 0.064 319.5 3.6 45.5 8.2 9999 999 9999 999 9999 999 66872 241.4 4.0 4.506 0.088 537.6 8.5 5.662 0.064 320.3 3.6 68.3 8.3 9999 999 9999 999 9999 999 66942 246.8 4.2 4.242 0.084 531.1 8.3 5.737 0.064 321.0 3.6 9999 999 9999 999 9999 999 9999 999 67012 9999 999 9999 999 9999 999 9999 999 9999 999 30.7 8.1 9999 999 9999 999 9999 999 67082 248.4 4.2 4.111 0.082 531.3 8.3 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 67152 249.1 4.2 4.595 0.090 541.5 8.6 5.776 0.064 316.0 3.5 9999 999 9999 999 9999 999 9999 999 67292 247.0 4.2 4.143 0.082 532.3 8.3 5.710 0.064 321.3 3.6 19.4 8.1 9999 999 9999 999 9999 999 67362 253.6 4.4 4.184 0.083 550.6 8.9 5.890 0.065 322.6 3.6 9999 999 9999 999 9999 999 9999 999 67502 251.0 4.3 4.297 0.085 537.9 8.5 5.699 0.064 322.9 3.6 9999 999 9999 999 9999 999 9999 999 67572 248.5 4.2 4.297 0.085 529.2 8.2 5.663 0.064 320.5 3.6 6.0 8.0 9999 999 9999 999 9999 999 67712 245.5 4.1 4.136 0.082 528.8 8.2 5.704 0.064 317.1 3.6 9999 999 9999 999 9999 999 9999 999 67782 244.6 4.1 4.113 0.082 527.8 8.2 5.647 0.063 316.4 3.5 9999 999 9999 999 9999 999 9999 999 67852 9999 999 9999 999 9999 999 9999 999 9999 999 24.4 8.1 9999 999 9999 999 9999 999 67922 238.5 4.0 3.931 0.079 523.5 8.1 5.686 0.064 314.0 3.5 9999 999 9999 999 9999 999 9999 999 67992 238.8 4.0 3.844 0.078 522.4 8.0 5.675 0.064 313.3 3.5 17.1 8.1 9999 999 9999 999 9999 999 68132 239.5 4.0 3.993 0.080 525.2 8.1 5.606 0.063 315.8 3.5 54.3 8.2 9999 999 9999 999 9999 999 68202 241.0 4.0 4.045 0.081 530.1 8.3 5.692 0.064 317.7 3.6 9999 999 9999 999 9999 999 9999 999 68342 235.2 3.9 3.711 0.076 519.7 8.0 5.591 0.063 313.4 3.5 9999 999 9999 999 9999 999 9999 999 68412 238.5 4.0 3.895 0.079 523.1 8.1 5.591 0.063 316.4 3.5 21.1 8.1 9999 999 9999 999 9999 999 68552 236.3 3.9 3.816 0.077 519.7 8.0 5.654 0.063 316.6 3.5 12.6 8.1 9999 999 9999 999 9999 999 68622 237.7 4.0 3.916 0.079 523.3 8.1 5.664 0.064 317.5 3.6 9999 999 9999 999 9999 999 9999 999 68692 9999 999 9999 999 9999 999 9999 999 9999 999 34.7 8.1 9999 999 9999 999 9999 999 68762 237.6 3.9 4.253 0.084 531.4 8.3 5.748 0.064 318.3 3.6 9999 999 9999 999 9999 999 9999 999 68832 238.9 4.0 3.973 0.080 524.2 8.1 5.777 0.065 317.5 3.6 9999 999 9999 999 9999 999 9999 999 68972 237.6 3.9 3.859 0.078 520.6 8.0 5.555 0.063 314.5 3.5 21.1 8.1 9999 999 9999 999 9999 999 69042 236.1 3.9 3.847 0.078 522.6 8.0 5.713 0.064 313.6 3.5 9999 999 9999 999 9999 999 9999 999 69112 9999 999 9999 999 9999 999 9999 999 9999 999 22.3 8.1 9999 999 9999 999 9999 999 69182 237.1 3.9 3.918 0.079 518.8 7.9 5.586 0.063 314.3 3.5 9999 999 9999 999 9999 999 9999 999 69252 237.4 3.9 4.071 0.081 518.5 7.9 5.545 0.063 314.8 3.5 21.8 8.1 9999 999 9999 999 9999 999 69392 238.2 4.0 3.941 0.079 524.2 8.1 5.611 0.063 315.6 3.5 9999 999 9999 999 9999 999 9999 999 69462 244.4 4.1 4.230 0.084 526.3 8.2 5.678 0.064 316.6 3.5 9999 999 9999 999 9999 999 9999 999 69532 9999 999 9999 999 9999 999 9999 999 9999 999 16.2 8.1 9999 999 9999 999 9999 999 69602 247.4 4.2 3.898 0.079 532.8 8.3 5.860 0.065 319.2 3.6 9999 999 9999 999 9999 999 9999 999 69672 247.3 4.2 3.746 0.076 533.1 8.3 5.817 0.065 320.1 3.6 20.7 8.1 9999 999 9999 999 9999 999 69812 244.9 4.1 3.698 0.075 537.6 8.5 5.697 0.064 320.8 3.6 23.9 8.1 9999 999 9999 999 9999 999 69882 248.7 4.2 4.057 0.081 533.5 8.4 5.772 0.064 319.2 3.6 9999 999 9999 999 9999 999 9999 999 70022 251.7 4.3 4.068 0.081 540.1 8.6 5.650 0.063 321.7 3.6 9999 999 9999 999 9999 999 9999 999 70092 254.6 4.4 4.689 0.091 527.4 8.2 5.583 0.063 318.2 3.6 20.4 8.1 9999 999 9999 999 9999 999 70232 248.8 4.2 4.156 0.083 516.1 7.9 5.645 0.063 318.4 3.6 25.1 8.1 9999 999 9999 999 9999 999 70302 240.0 4.0 3.821 0.077 524.5 8.1 5.565 0.063 317.6 3.6 9999 999 9999 999 9999 999 9999 999 70372 9999 999 9999 999 9999 999 9999 999 9999 999 28.5 8.1 9999 999 9999 999 9999 999 70442 245.3 4.1 3.939 0.079 520.5 8.0 5.737 0.064 316.8 3.5 9999 999 9999 999 9999 999 9999 999 70512 247.5 4.2 3.816 0.077 530.3 8.3 5.772 0.064 319.1 3.6 9999 999 9999 999 9999 999 9999 999 70652 9999 999 4.080 0.081 9999 999 5.632 0.063 319.6 3.6 85.9 8.5 9999 999 9999 999 9999 999 70722 251.2 4.3 4.495 0.088 541.6 8.6 5.700 0.064 320.5 3.6 9999 999 9999 999 9999 999 9999 999 70792 9999 999 9999 999 9999 999 9999 999 9999 999 39.4 8.1 9999 999 9999 999 9999 999 70862 252.9 4.3 4.579 0.090 538.6 8.5 5.716 0.064 321.4 3.6 9999 999 9999 999 9999 999 9999 999 70932 253.0 4.3 4.459 0.088 541.5 8.6 5.729 0.064 323.6 3.6 37.2 8.1 9999 999 9999 999 9999 999 71072 250.0 4.3 4.284 0.085 534.7 8.4 5.728 0.064 320.2 3.6 9999 999 9999 999 9999 999 9999 999 71142 252.8 4.3 4.381 0.086 542.3 8.6 5.746 0.064 320.6 3.6 9999 999 9999 999 9999 999 9999 999 71212 9999 999 9999 999 9999 999 9999 999 9999 999 52.8 8.2 9999 999 9999 999 9999 999 71282 252.4 4.3 4.377 0.086 533.2 8.3 5.831 0.065 321.1 3.6 9999 999 9999 999 9999 999 9999 999 71352 253.1 4.3 4.559 0.089 546.2 8.7 5.868 0.065 320.0 3.6 52.8 8.2 9999 999 9999 999 9999 999 71492 9999 999 9999 999 9999 999 9999 999 9999 999 64.4 8.3 9999 999 9999 999 9999 999