39 1001 MOORE, FRED; ELKINS, JAMES; DUTTON, GEOFF U.S. DEPT OF COMMERCE, NOAA / CMDL / HATS PANTHER SOLVE-II 1 1 2003 01 09 2004 05 18 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 16 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) H2 MIXING RATIO (PPT) H2 ERROR 1-sd (PPT) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 8 PANTHER data taken via Electron Capture Detectors on DC-8 (Mass Spec data is in MS file) Data normalized with two in-flight calibration gases and then calibrated using a six point cal-curve generated in the lab on 03/01/30. Quoted errors include the one sigma statistical spread of the normalized in-flight calibration gas taken in quadrature with the fitted uncertainty in the generated calibration curve. 1 GMTs SF6 SF6e N2O N2Oe F11 F11e F113 F113e MC MCe CT CTe H2 H2e CH4 CH4e 3001 9999 999 9999 999 245.46 4.9093 9999 999 9999 999 97.405 2.275 9999 999 1801.5 44.073 3281 9999 999 9999 999 262.51 5.2503 9999 999 9999 999 99.005 2.3315 523.73 10.468 1760.4 43.045 3421 9999 999 9999 999 258.15 5.1629 9999 999 9999 999 98.498 2.3135 528.14 10.528 1775.4 43.419 3561 9999 999 9999 999 262.79 5.2558 9999 999 9999 999 99.74 2.3578 522.24 10.448 1786.6 43.699 3701 9999 999 9999 999 255.7 5.1139 9999 999 9999 999 98.972 2.3303 510.58 10.29 1767.8 43.23 3841 9999 999 9999 999 251.02 5.0204 9999 999 9999 999 98.381 2.3093 520.32 10.422 1770 43.283 4121 9999 999 9999 999 249.32 4.9863 9999 999 9999 999 98.696 2.3205 519.64 10.413 1761.7 43.077 4261 9999 999 9999 999 243.97 4.8794 9999 999 9999 999 96.754 2.2523 520.71 10.427 1773.6 43.375 4401 5.0047 0.1977 9999 999 253.52 5.0704 9999 999 9999 999 97.02 2.2616 533.39 10.6 1767.9 43.231 4541 5.1622 0.1977 9999 999 252.5 5.0499 9999 999 9999 999 96.745 2.252 529.13 10.542 1795.4 43.92 4681 5.0115 0.1977 318.45 10.536 243.38 4.8675 9999 999 9999 999 95.158 2.1975 517.78 10.388 1741.9 42.586 4961 5.1219 0.1977 319.58 10.536 258.07 5.1613 79.105 2.3676 9999 999 96.41 2.2404 523.43 10.464 1747.5 42.726 5101 5.1241 0.1977 317.41 10.536 256.43 5.1287 79.478 2.3867 9999 999 95.465 2.208 531.57 10.575 1767.3 43.216 5241 5.0002 0.1977 321.69 10.537 262.9 5.258 79.909 2.409 9999 999 95.492 2.2089 528.92 10.539 1766 43.183 5969 5.0466 0.1977 9999 999 251.88 5.0375 78 2.3118 9999 999 96.611 2.2474 538.92 10.676 1785.5 43.671 6109 4.8441 0.1977 9999 999 249.26 4.9852 77.954 2.3094 9999 999 95.413 2.2062 521.44 10.437 1769.8 43.278 6249 4.8677 0.1977 320.87 10.537 250.5 5.0101 78.688 2.3464 9999 999 95.268 2.2012 519.99 10.418 1748.1 42.741 6389 5.0849 0.1977 316.16 10.536 253.54 5.0708 78.691 2.3465 9999 999 95.49 2.2088 520.75 10.428 1743 42.615 6669 5.0263 0.1977 312.42 10.536 251.15 5.0229 78.482 2.336 9999 999 95.427 2.2067 520.5 10.424 1739.6 42.531 6809 4.961 0.1977 312.59 10.536 248.46 4.9691 77.891 2.3063 9999 999 95.202 2.199 527.38 10.518 1773 43.358 6949 5.0899 0.1977 310.42 10.535 252.78 5.0555 78.162 2.3199 9999 999 95.586 2.2121 519.9 10.416 1748.7 42.756 7540 5.1575 0.1977 320.36 10.537 259.09 5.1817 78.212 2.3223 9999 999 96.802 2.254 533.15 10.597 1781.1 43.56 7680 5.1429 0.1977 313.91 10.536 256.19 5.1237 78.853 2.3548 9999 999 96.322 2.2374 524.63 10.481 1750.3 42.794 7820 5.1006 0.1977 314.34 10.536 255.89 5.1178 78.876 2.3559 9999 999 96.496 2.2434 521.88 10.443 1759.3 43.018 7960 5.1628 0.1977 316.62 10.536 259.29 5.1857 79.679 2.3971 9999 999 96.896 2.2573 520.87 10.429 1777.7 43.476 8240 4.8085 0.1977 315.5 10.536 258.2 5.1639 80.021 2.4149 9999 999 97.413 2.2753 527.64 10.522 1771.6 43.323 8380 4.9558 0.1977 308.12 10.535 260.44 5.2087 79.82 2.4044 9999 999 97.188 2.2674 523.95 10.471 1767.9 43.232 8520 4.9042 0.1977 305.15 10.535 263.87 5.2774 80.394 2.4343 9999 999 97.326 2.2722 523.9 10.471 1782.6 43.598 9117 5.3567 0.1977 321.98 10.537 262.63 5.2525 79.948 2.4111 9999 999 97.78 2.2882 529.37 10.545 1759.4 43.02 9257 5.3697 0.1977 320.03 10.536 259.36 5.1871 79.619 2.394 9999 999 96.377 2.2393 522.53 10.452 1760.6 43.051 9397 5.1458 0.1977 316.15 10.536 257.84 5.1569 79.096 2.3671 9999 999 96.346 2.2382 531.41 10.573 1781.5 43.572 9537 5.0118 0.1977 317.14 10.536 254.79 5.0958 78.403 2.332 9999 999 95.913 2.2233 528.55 10.534 1743.2 42.618 9817 5.192 0.1977 320.03 10.536 256.92 5.1384 79.056 2.3651 9999 999 96.562 2.2457 528.35 10.531 1749 42.762 9957 5.2269 0.1977 320.48 10.537 255.29 5.1059 79.047 2.3646 9999 999 96.151 2.2315 522.18 10.447 1759.8 43.031 10097 5.1812 0.1977 314.84 10.536 253.83 5.0766 78.541 2.339 9999 999 96.096 2.2296 523.21 10.461 1758.6 42.999 10237 5.3356 0.1977 314.13 10.536 255.39 5.1079 78.764 2.3502 9999 999 94.934 2.1899 527.9 10.525 1802.6 44.101 10377 5.1949 0.1977 313.73 10.536 244.57 4.8913 76.867 2.2558 29.357 0.9799 91.97 2.0911 528.92 10.539 1748.9 42.758 10657 5.2986 0.1977 315.02 10.536 253.28 5.0655 78.007 2.3121 28.64 0.978 92.421 2.1059 534.39 10.614 1758.7 43.003 10797 5.0429 0.1977 307.81 10.535 244.88 4.8975 77.141 2.2692 29.079 0.9792 91.901 2.0889 533.77 10.605 1746.5 42.7 10937 5.102 0.1977 313.43 10.536 246.67 4.9334 77.47 2.2854 29.39 0.98 91.276 2.0685 531.57 10.575 1753.7 42.879 11077 4.9643 0.1977 312.96 10.536 239.04 4.7809 76.479 2.237 29.617 0.9806 90.161 2.0326 528.36 10.532 1715.9 41.947 11217 4.8285 0.1977 307.93 10.535 236.88 4.7376 75.964 2.2121 29.441 0.9801 89.246 2.0035 533.39 10.6 1709.3 41.786 11497 4.9889 0.1977 303.55 10.535 240.53 4.8106 76.405 2.2334 9999 999 90.611 2.047 530.54 10.561 1727.7 42.235 11637 4.931 0.1977 311.61 10.536 240.24 4.8049 77.187 2.2715 29.184 0.9795 90.156 2.0324 536.14 10.638 1755.7 42.928 11777 4.8196 0.1977 313.15 10.536 240.11 4.8022 77.254 2.2748 29.526 0.9804 88.528 1.9809 537.41 10.655 1720.8 42.066 11917 4.7746 0.1977 301.91 10.535 236.87 4.7373 76.657 2.2456 28.618 0.978 89.161 2.0008 536.43 10.642 1725.3 42.178 12057 4.8686 0.1977 305.26 10.535 244.28 4.8855 75.969 2.2124 29.028 0.979 90.65 2.0483 534.92 10.621 1709 41.779 12337 5.0334 0.1977 310.86 10.535 246.44 4.9288 77.903 2.3069 28.475 0.9776 92.925 2.1225 537.74 10.66 1740.5 42.552 12477 4.9321 0.1977 308.14 10.535 242.4 4.848 77.058 2.2651 29.265 0.9797 91.265 2.0682 533.24 10.598 1721.3 42.079 12617 4.923 0.1977 299.41 10.534 241.14 4.8228 77.548 2.2893 29.993 0.9816 91.355 2.0711 536.84 10.648 1714.8 41.919 12757 5.0587 0.1977 303.88 10.535 243.43 4.8686 76.794 2.2523 30.281 0.9824 90.283 2.0365 538.42 10.669 1741.5 42.575 12897 5.0531 0.1977 308.41 10.535 240.12 4.8025 76.192 2.2231 28.033 0.9765 90.54 2.0447 551.35 10.847 1741.6 42.579 13177 4.8606 0.1977 308.62 10.535 242.75 4.855 76.689 2.2471 28.917 0.9788 91.16 2.0647 548.27 10.805 1735.1 42.419 13317 4.787 0.1977 292.14 10.534 224.09 4.4819 73.641 2.1036 28.915 0.9787 84.735 1.8649 537.77 10.66 1694.1 41.416 13457 4.7343 0.1977 300.1 10.534 225.24 4.5049 73.611 2.1022 28.045 0.9765 84.166 1.848 549.05 10.816 1689.7 41.308 13597 4.6298 0.1977 304.38 10.535 224.99 4.4999 73.67 2.1049 28.291 0.9771 83.992 1.8428 536.9 10.648 1683.5 41.158 13737 4.6278 0.1977 299.5 10.534 226.29 4.5258 73.852 2.1132 29.106 0.9793 84.735 1.8649 543.32 10.737 1674.2 40.934 14017 4.8163 0.1977 295.38 10.534 225.93 4.5185 73.26 2.0862 28.655 0.9781 84.899 1.8698 539.2 10.68 1671.3 40.864 14157 4.6542 0.1977 304.54 10.535 225.59 4.5119 74.008 2.1204 28.284 0.9771 83.638 1.8324 539.7 10.687 1707.1 41.731 14297 4.6985 0.1977 303.44 10.535 219.77 4.3955 72.912 2.0705 28.566 0.9778 81.636 1.7742 535.83 10.634 1680.6 41.089 14437 4.7554 0.1977 293.42 10.534 218.82 4.3764 72.648 2.0587 28.099 0.9766 81.946 1.7831 548.07 10.802 1684.3 41.178 14577 4.722 0.1977 296.74 10.534 221.16 4.4232 72.998 2.0744 28.156 0.9768 81.712 1.7764 539.79 10.688 1686.1 41.221 14857 4.8304 0.1977 301.8 10.535 220.96 4.4193 73.54 2.0989 28.789 0.9784 82.445 1.7975 545.83 10.771 1720.6 42.062 14997 4.7567 0.1977 304.96 10.535 219.19 4.3838 72.922 2.071 27.887 0.9761 82.887 1.8104 541.87 10.717 1687.6 41.258 15137 4.7027 0.1977 296.5 10.534 219.56 4.3912 72.717 2.0618 28.205 0.9769 83.703 1.8343 542.52 10.725 1694.3 41.421 15277 4.7501 0.1977 299.33 10.534 215.72 4.3145 72.31 2.0437 9999 999 82.088 1.7872 530.94 10.567 1696.5 41.472 15417 4.8724 0.1977 301.18 10.534 216.56 4.3312 72.933 2.0715 27.799 0.9759 82.43 1.7971 547.67 10.796 1721.4 42.08 15697 4.7354 0.1977 300.93 10.534 224.04 4.4807 74.476 2.142 28.503 0.9777 84.505 1.858 542.31 10.723 1680.6 41.088 15837 4.7179 0.1977 298.71 10.534 228.42 4.5683 75.299 2.1805 29.865 0.9813 86.757 1.926 531.43 10.573 1715.3 41.931 15977 4.6228 0.1977 301.8 10.535 224.31 4.4862 75.166 2.1742 28.703 0.9782 83.496 1.8282 538.6 10.672 1691.8 41.359 16117 4.8525 0.1977 304.44 10.535 223.1 4.4621 74.43 2.1399 29.484 0.9803 83.908 1.8403 535.62 10.631 1699.2 41.539 16257 4.7089 0.1977 299.07 10.534 222.75 4.455 75.04 2.1683 27.965 0.9763 83.365 1.8244 536.13 10.638 1695.8 41.456 16537 4.6338 0.1977 291.65 10.534 216.11 4.3222 73.265 2.0865 29.435 0.9801 82.262 1.7923 535.67 10.631 1706 41.705 16677 4.6274 0.1977 299.98 10.534 215.86 4.3172 74.227 2.1305 28.548 0.9778 81.605 1.7733 532.28 10.585 1679.5 41.062 16817 4.5729 0.1976 302.71 10.535 217.62 4.3525 74.365 2.1368 29.907 0.9814 81.945 1.7831 530.35 10.559 1684.6 41.184 16957 4.4435 0.1976 297.97 10.534 219.63 4.3926 73.857 2.1134 27.751 0.9757 83.075 1.8159 529.44 10.546 1672.3 40.888 17097 4.6656 0.1977 298.63 10.534 223.94 4.4787 73.953 2.1178 29.436 0.9801 83.083 1.8161 529.39 10.546 1710.4 41.811 17377 4.772 0.1977 299.82 10.534 224.52 4.4904 74.308 2.1342 28.709 0.9782 84.167 1.848 521.7 10.441 1682 41.121 17517 4.8822 0.1977 295.79 10.534 224.31 4.4863 73.807 2.1111 28.31 0.9772 83.436 1.8264 530.97 10.567 1705.2 41.685 17657 4.8619 0.1977 291.03 10.533 222.87 4.4575 73.231 2.0849 28.88 0.9787 83.992 1.8428 530.72 10.564 1705.5 41.693 17797 4.9542 0.1977 294.13 10.534 224.73 4.4945 73.067 2.0775 29.787 0.9811 83.485 1.8279 528.53 10.534 1704.1 41.658 17937 4.9348 0.1977 299.9 10.534 226.69 4.5338 73.411 2.0931 9999 999 84.773 1.866 535.02 10.623 1738.7 42.507 18217 4.7784 0.1977 306.66 10.535 229.74 4.5947 73.491 2.0967 28.094 0.9766 84.576 1.8601 540.44 10.697 1730.4 42.303 18357 4.8409 0.1977 307.48 10.535 228.82 4.5764 9999 999 29.849 0.9812 86.177 1.9083 532.81 10.592 1708 41.753 18497 4.8867 0.1977 9999 999 9999 999 9999 999 28.018 0.9764 85.657 1.8926 521.66 10.44 1709.9 41.799 18637 4.9371 0.1977 9999 999 9999 999 9999 999 29.229 0.9796 84.804 1.8669 519.07 10.405 1712.2 41.857 19332 4.5959 0.1977 301.9 10.535 221.99 4.4398 9999 999 29.165 0.9794 89.255 2.0038 532.72 10.591 1736.9 42.462 19472 4.6446 0.1977 296.27 10.534 222.09 4.4419 9999 999 29.436 0.9801 87.269 1.9418 527.48 10.519 1712.1 41.853 19612 4.6224 0.1977 299.13 10.534 230.46 4.6093 9999 999 29.421 0.9801 89.696 2.0178 534.26 10.612 1736.2 42.445 19752 4.684 0.1977 302 10.535 235.77 4.7154 9999 999 29.519 0.9804 90.916 2.0568 523.67 10.468 1732 42.341 20032 4.8117 0.1977 306.08 10.535 236.67 4.7335 9999 999 29.948 0.9815 90.95 2.058 531.78 10.578 1727.1 42.221 20172 4.632 0.1977 306.47 10.535 232.67 4.6533 9999 999 29.16 0.9794 89.921 2.0249 531.94 10.58 1754.9 42.909 20312 4.7056 0.1977 306.74 10.535 233.1 4.662 9999 999 28.837 0.9785 90.322 2.0377 528.78 10.537 1732.5 42.354 20452 4.6281 0.1977 307.73 10.535 232.57 4.6514 9999 999 29.654 0.9807 90.312 2.0374 530.19 10.556 1740.5 42.551 20592 4.6789 0.1977 306.21 10.535 227.27 4.5453 9999 999 29.299 0.9798 89.366 2.0073 530.53 10.561 1740.7 42.556 20872 4.6909 0.1977 305.71 10.535 224.36 4.4872 9999 999 29.388 0.98 88.345 1.9752 518.91 10.403 1714.9 41.923 21012 4.8711 0.1977 306.35 10.535 229.07 4.5814 9999 999 28.159 0.9768 89.084 1.9984 532.01 10.581 1737.8 42.485 21152 4.8367 0.1977 305.8 10.535 230.28 4.6055 9999 999 28.137 0.9767 88.89 1.9923 528.95 10.54 1742.4 42.6 21292 4.964 0.1977 305.1 10.535 230.01 4.6003 9999 999 29.346 0.9799 87.412 1.9462 532.59 10.589 1718.6 42.014 21432 4.8703 0.1977 304.17 10.535 230.58 4.6117 9999 999 28.391 0.9774 86.7 1.9243 528.66 10.536 9999 999 21712 4.9948 0.1977 306.64 10.535 238.08 4.7616 9999 999 28.674 0.9781 88.928 1.9934 531.99 10.581 9999 999 21852 5.0157 0.1977 306.8 10.535 238.47 4.7695 9999 999 28.5 0.9777 88.656 1.9849 530.88 10.566 9999 999 21992 4.9972 0.1977 305.5 10.535 238.79 4.7757 9999 999 28.591 0.9779 88.682 1.9857 534.18 10.611 9999 999 22132 4.7435 0.1977 304.49 10.535 233.59 4.6719 9999 999 28.467 0.9776 87.53 1.9498 529.74 10.55 9999 999