55 1001 ELKINS, JAMES; HURST, DALE; ROMASHKIN, PAVEL U.S. DEPT OF COMMERCE, NOAA / CMDL / HALOCARBONS AND OTHER ATMOSPHERIC TRACE SPECIES GROUP ACATS IV, ER-2 SOLVE 1 1 2000 01 14 2000 08 01 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 22 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CHCl3 (CF) MIXING RATIO (PPT) CHCl3 (CF) ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) 18 Overall median errors for SOLVE mission are as follows: N2O 1.0 ppb SF6 0.11 ppt F12 2.6 ppt H1211 0.06 ppt F11 1.0 ppt F113 0.4 ppt CHCl3 3.2 ppt CH3CCl3 0.5 ppt CCl4 0.6 ppt CH4 9 ppb H2 42 ppb The errors reported for each measurement reflect the precision of measurements of a calibration standard during that period of the flight, the precision of measurements of a suite of calibration standards in the laboratory, and random errors in the values assigned to our calibration standards. The reported errors DO NOT reflect possible inaccuracies in the calibration scales developed and maintained by NOAA/CMDL. To account for the transit time of air samples through the pump, sampling lines, and sample loops, timestamps for this flight have been reduced by 33 seconds. No CH4 and H2 due to ECD heater failure. 1 GMTs N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e F11 F11e F113 F113e CF CFe MC MCe CT CTe CH4 CH4e H2 H2e 45305 299.9 1.5 4.32 0.14 507.6 4.0 3.63 0.10 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 45375 287.5 1.4 4.23 0.13 487.4 3.8 3.10 0.09 218.7 7.7 74.0 0.6 0.9 2.0 46.80 0.46 84.85 0.49 9999 999 9999 999 45445 281.3 1.4 4.18 0.13 474.1 3.7 2.73 0.08 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 45515 270.6 1.3 3.97 0.13 450.7 3.5 2.33 0.07 186.8 4.6 67.7 0.6 0.0 2.0 40.87 0.42 72.18 0.45 9999 999 9999 999 45585 288.6 1.4 4.20 0.13 485.9 3.8 3.09 0.09 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 45655 293.5 1.5 4.24 0.14 495.8 3.9 3.25 0.09 229.2 9.5 75.8 0.7 2.1 2.0 46.82 0.46 88.18 0.50 9999 999 9999 999 45725 302.0 1.5 4.40 0.14 514.0 4.0 3.60 0.10 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 45865 297.2 1.5 4.28 0.14 501.5 3.9 3.37 0.10 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 45935 295.2 1.5 4.35 0.14 496.7 3.9 3.18 0.09 229.9 9.7 76.3 0.7 0.7 2.0 47.50 0.46 88.95 0.51 9999 999 9999 999 46005 292.1 1.5 4.25 0.14 490.3 3.8 3.00 0.08 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 46075 292.1 1.5 4.23 0.13 489.9 3.8 3.02 0.08 221.6 8.1 75.2 0.7 1.6 2.0 46.64 0.46 86.03 0.50 9999 999 9999 999 46145 294.9 1.5 4.23 0.13 495.8 3.9 3.13 0.09 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 46215 291.4 1.5 4.19 0.13 489.4 3.8 3.00 0.08 220.8 8.0 74.8 0.7 2.3 2.0 46.04 0.45 85.88 0.49 9999 999 9999 999 46285 270.5 1.3 4.02 0.13 448.3 3.5 2.17 0.06 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 46425 254.9 1.3 4.00 0.13 419.0 3.3 1.64 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 46495 254.6 1.3 3.86 0.12 418.6 3.3 1.56 0.05 155.0 3.0 61.6 0.5 0.0 2.0 34.01 0.39 59.52 0.43 9999 999 9999 999 46565 253.3 1.3 3.90 0.12 415.4 3.3 1.54 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 46705 249.8 1.3 3.91 0.12 410.7 3.3 1.45 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 46775 245.5 1.2 3.95 0.12 401.4 3.2 1.27 0.05 136.2 2.4 57.7 0.5 0.0 2.0 29.22 0.37 51.22 0.41 9999 999 9999 999 46845 245.9 1.2 3.88 0.12 400.5 3.2 1.34 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 46985 235.9 1.2 3.82 0.12 382.8 3.1 0.97 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 47055 235.2 1.2 3.76 0.12 381.6 3.1 0.95 0.05 121.7 2.0 55.0 0.5 0.0 2.0 25.77 0.36 46.16 0.41 9999 999 9999 999 47125 237.4 1.2 3.81 0.12 385.0 3.1 1.06 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 47195 233.9 1.2 3.79 0.12 377.9 3.1 0.92 0.05 119.1 2.0 54.7 0.5 0.0 2.0 24.54 0.36 46.24 0.41 9999 999 9999 999 47265 231.6 1.2 3.70 0.12 372.3 3.0 0.86 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 47335 234.5 1.2 3.74 0.12 378.8 3.1 0.87 0.05 120.0 2.0 55.2 0.5 0.0 2.0 24.30 0.36 47.21 0.41 9999 999 9999 999 47405 227.3 1.2 3.68 0.12 365.8 3.0 0.79 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 47545 222.0 1.1 3.66 0.11 354.0 2.9 0.61 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 47615 230.1 1.2 3.68 0.12 368.1 3.0 0.77 0.04 106.7 1.7 52.5 0.4 0.0 2.0 21.16 0.35 41.58 0.40 9999 999 9999 999 47685 232.8 1.2 3.76 0.12 375.7 3.1 0.85 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 47755 231.8 1.2 3.70 0.12 372.1 3.0 0.82 0.05 114.3 1.8 54.2 0.5 0.0 2.0 22.41 0.35 45.11 0.40 9999 999 9999 999 47825 227.7 1.2 3.72 0.12 363.6 3.0 0.71 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 47895 229.0 1.2 3.67 0.11 367.7 3.0 0.74 0.04 110.8 1.8 53.7 0.5 0.0 2.0 21.18 0.35 44.22 0.40 9999 999 9999 999 47965 224.2 1.2 3.72 0.12 359.2 3.0 0.68 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 48105 219.1 1.1 3.67 0.11 348.6 2.9 0.56 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 48175 216.4 1.1 3.61 0.11 342.3 2.9 0.54 0.04 91.0 1.4 49.0 0.4 0.0 2.0 17.07 0.34 36.44 0.39 9999 999 9999 999 48245 216.1 1.1 3.65 0.11 342.9 2.9 0.51 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 48315 217.3 1.1 3.62 0.11 345.2 2.9 0.51 0.04 93.1 1.4 49.6 0.4 0.0 2.0 17.85 0.34 37.71 0.40 9999 999 9999 999 48385 217.5 1.1 3.65 0.11 344.9 2.9 0.62 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 48455 217.7 1.1 3.61 0.11 345.7 2.9 0.45 0.04 92.9 1.4 49.7 0.4 0.0 2.0 17.16 0.34 37.75 0.40 9999 999 9999 999 48525 222.3 1.1 3.62 0.11 354.5 2.9 0.65 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 48665 217.7 1.1 3.60 0.11 346.5 2.9 0.51 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 48735 216.9 1.1 3.68 0.12 344.2 2.9 0.49 0.04 91.7 1.4 49.1 0.4 0.0 2.0 16.61 0.34 37.08 0.40 9999 999 9999 999 48805 215.3 1.1 3.59 0.11 341.7 2.9 0.54 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 48875 215.8 1.1 3.63 0.11 341.7 2.9 0.43 0.04 91.1 1.4 49.2 0.4 0.0 2.0 16.50 0.34 37.30 0.40 9999 999 9999 999 48945 223.1 1.1 3.75 0.12 355.0 3.0 0.68 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 49015 225.2 1.2 3.71 0.12 361.2 3.0 0.67 0.04 106.1 1.7 52.8 0.4 0.0 2.0 19.63 0.34 43.35 0.40 9999 999 9999 999 49085 232.1 1.2 3.76 0.12 373.1 3.0 0.92 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 49225 234.3 1.2 3.76 0.12 377.9 3.1 0.91 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 49295 231.1 1.2 3.72 0.12 371.8 3.0 0.80 0.05 111.7 1.8 54.1 0.5 0.0 2.0 21.45 0.35 45.22 0.40 9999 999 9999 999 49365 224.7 1.2 3.67 0.11 359.4 3.0 0.74 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 49505 227.0 1.2 3.70 0.12 363.6 3.0 0.81 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 49575 226.5 1.2 3.68 0.11 363.7 3.0 0.69 0.04 105.6 1.7 52.6 0.4 0.0 2.0 19.94 0.34 42.47 0.40 9999 999 9999 999 49645 230.1 1.2 3.75 0.12 368.1 3.0 0.80 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 49785 229.0 1.2 3.79 0.12 367.6 3.0 0.84 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 49855 224.1 1.2 3.75 0.12 357.5 3.0 0.60 0.04 102.2 1.6 51.8 0.4 0.0 2.0 18.87 0.34 40.85 0.40 9999 999 9999 999 49925 225.3 1.2 3.75 0.12 359.8 3.0 0.73 0.04 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 49995 233.9 1.2 3.78 0.12 377.5 3.1 0.87 0.05 119.2 2.0 55.6 0.5 0.0 2.0 21.93 0.35 48.19 0.41 9999 999 9999 999 50065 237.2 1.2 3.77 0.12 382.7 3.1 1.10 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 50135 237.0 1.2 3.78 0.12 383.9 3.1 1.04 0.05 124.5 2.1 56.9 0.5 0.0 2.0 24.26 0.36 50.30 0.41 9999 999 9999 999 50205 239.1 1.2 3.84 0.12 386.9 3.1 1.04 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 50345 232.7 1.2 3.80 0.12 373.9 3.0 0.82 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 50415 238.9 1.2 3.82 0.12 386.7 3.1 1.05 0.05 124.1 2.1 56.6 0.5 0.0 2.0 22.92 0.35 50.02 0.41 9999 999 9999 999 50485 246.3 1.2 3.91 0.12 401.9 3.2 1.23 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 50625 246.8 1.2 3.84 0.12 402.0 3.2 1.41 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 50695 248.8 1.2 3.82 0.12 406.1 3.2 1.44 0.05 145.2 2.7 60.9 0.5 0.0 2.0 28.39 0.37 58.50 0.43 9999 999 9999 999 50765 243.3 1.2 3.85 0.12 395.2 3.2 1.40 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 50905 242.2 1.2 3.85 0.12 393.2 3.2 1.27 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 50975 244.0 1.2 3.83 0.12 397.7 3.2 1.34 0.05 140.3 2.5 59.4 0.5 0.0 2.0 26.48 0.36 56.50 0.42 9999 999 9999 999 51045 241.8 1.2 3.85 0.12 393.7 3.2 1.30 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 51115 243.4 1.2 3.77 0.12 396.3 3.2 1.35 0.05 137.4 2.4 58.8 0.5 0.0 2.0 25.99 0.36 55.57 0.42 9999 999 9999 999 51185 242.0 1.2 3.84 0.12 393.2 3.2 1.40 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 51255 243.8 1.2 3.83 0.12 396.1 3.2 1.33 0.05 139.2 2.5 59.1 0.5 0.0 2.0 26.18 0.36 56.80 0.42 9999 999 9999 999 51325 237.6 1.2 3.82 0.12 383.8 3.1 1.18 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 51465 238.9 1.2 3.78 0.12 387.3 3.1 1.21 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 51535 239.4 1.2 3.82 0.12 387.4 3.1 1.34 0.05 132.2 2.3 57.5 0.5 0.0 2.0 24.57 0.36 54.01 0.42 9999 999 9999 999 51605 237.8 1.2 3.77 0.12 385.5 3.1 1.25 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 51675 245.9 1.2 3.84 0.12 400.6 3.2 1.35 0.05 141.6 2.6 59.8 0.5 0.0 2.0 26.28 0.36 57.57 0.42 9999 999 9999 999 51745 248.0 1.2 3.80 0.12 405.5 3.2 1.47 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 51815 245.8 1.2 3.83 0.12 400.9 3.2 1.27 0.05 140.7 2.5 59.6 0.5 0.0 2.0 26.55 0.36 57.60 0.42 9999 999 9999 999 51885 245.7 1.2 3.84 0.12 399.4 3.2 1.39 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 52025 241.5 1.2 3.84 0.12 392.3 3.2 1.33 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 52095 243.6 1.2 3.82 0.12 397.0 3.2 1.37 0.05 138.7 2.5 59.0 0.5 0.0 2.0 26.12 0.36 56.42 0.42 9999 999 9999 999 52165 241.3 1.2 3.82 0.12 390.9 3.1 1.25 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 52305 251.0 1.3 3.82 0.12 411.7 3.3 1.46 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 52375 250.9 1.3 3.85 0.12 411.8 3.3 1.21 0.05 144.2 2.6 61.4 0.5 0.0 2.0 26.67 0.36 57.72 0.42 9999 999 9999 999 52445 252.6 1.3 3.85 0.12 412.4 3.3 1.35 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 52585 252.5 1.3 3.95 0.12 414.6 3.3 1.44 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 52655 254.9 1.3 3.94 0.12 417.9 3.3 1.35 0.05 150.4 2.9 63.0 0.5 0.0 2.0 28.33 0.37 60.10 0.43 9999 999 9999 999 52725 254.5 1.3 3.81 0.12 417.8 3.3 1.40 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 52795 254.3 1.3 3.83 0.12 416.6 3.3 1.43 0.05 150.1 2.8 62.6 0.5 0.0 2.0 27.73 0.37 60.06 0.43 9999 999 9999 999 52865 254.3 1.3 3.86 0.12 416.7 3.3 1.40 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 52935 254.3 1.3 3.88 0.12 416.9 3.3 1.33 0.05 150.4 2.9 62.7 0.5 0.0 2.0 28.50 0.37 60.42 0.43 9999 999 9999 999 53005 254.7 1.3 3.88 0.12 417.3 3.3 1.44 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 53145 255.6 1.3 3.93 0.12 420.3 3.3 1.57 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 53215 257.7 1.3 3.93 0.12 422.7 3.3 1.52 0.05 156.0 3.1 63.7 0.5 0.0 2.0 28.81 0.37 62.14 0.43 9999 999 9999 999 53285 257.8 1.3 3.94 0.12 422.6 3.3 1.46 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 53355 260.0 1.3 3.87 0.12 427.9 3.4 1.55 0.05 160.6 3.3 64.8 0.6 0.0 2.0 29.93 0.38 65.02 0.44 9999 999 9999 999 53425 258.8 1.3 3.93 0.12 422.8 3.3 1.56 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 53495 257.8 1.3 3.95 0.12 424.0 3.3 1.66 0.05 157.5 3.1 64.1 0.5 0.0 2.0 29.14 0.37 63.44 0.43 9999 999 9999 999 53565 257.9 1.3 3.86 0.12 422.8 3.3 1.61 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 53705 257.3 1.3 3.89 0.12 420.9 3.3 1.64 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 53775 257.9 1.3 3.92 0.12 424.3 3.3 1.59 0.05 158.3 3.2 64.3 0.5 0.0 2.0 29.03 0.37 63.55 0.44 9999 999 9999 999 53845 258.3 1.3 3.89 0.12 423.6 3.3 1.58 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 53985 258.1 1.3 3.91 0.12 422.7 3.3 1.61 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 54055 257.0 1.3 3.94 0.12 421.6 3.3 1.48 0.05 155.8 3.1 63.8 0.5 0.0 2.0 28.68 0.37 62.03 0.43 9999 999 9999 999 54125 255.7 1.3 3.95 0.12 419.4 3.3 1.56 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 54265 254.3 1.3 3.89 0.12 417.3 3.3 1.46 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 54335 254.7 1.3 3.98 0.13 417.0 3.3 1.41 0.05 150.6 2.9 62.4 0.5 0.0 2.0 29.40 0.37 60.91 0.43 9999 999 9999 999 54405 254.1 1.3 3.85 0.12 415.1 3.3 1.46 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 54475 252.3 1.3 3.90 0.12 413.4 3.3 1.32 0.05 147.4 2.8 62.0 0.5 0.0 2.0 27.30 0.37 59.73 0.43 9999 999 9999 999 54545 253.8 1.3 3.95 0.12 414.2 3.3 1.43 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 54615 253.6 1.3 3.88 0.12 413.2 3.3 1.34 0.05 146.4 2.7 61.8 0.5 0.0 2.0 27.62 0.37 60.09 0.43 9999 999 9999 999 54685 250.5 1.3 3.81 0.12 408.6 3.2 1.33 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 54825 249.6 1.3 3.82 0.12 408.1 3.2 1.29 0.05 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 54895 249.5 1.3 3.74 0.12 408.0 3.2 1.28 0.05 141.9 2.6 60.7 0.5 0.0 2.0 26.65 0.36 57.64 0.42 9999 999 9999 999 54965 252.2 1.3 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