36 1001 ELKINS, JAMES; RAY, ERIC; MOORE, FRED; MACTAGGART, DOUG; DUTTON, GEOFF U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION LACE, WB-57 ACCENT 1 1 1999 09 24 2000 01 07 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 14 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) CO MIXING RATIO (PPB) CO ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) 7 Error bars quoted include all the statistical error occurred in going from raw integrations to final calibrated numbers. In addition there is the following error associated with the accuracy of our calibration tanks: F11+-1%, F113+-2%, F12+-2%, H1211+-3%, SF6+-3%, N2o+-2%. -------------- -- - 1 GMTs F11 F11e F12 F12e H1211 H1211e CH4 CH4e CO COe SF6 SF6e N2O N2Oe 52725 9999 999 545.5439 6.2735 9999 999 9999 999 9999 999 9999 999 9999 999 52795 9999 999 530.9622 6.0035 4.4153 0.0319 9999 999 9999 999 9999 999 9999 999 52865 9999 999 527.5162 5.9411 4.3639 0.0317 9999 999 9999 999 9999 999 9999 999 52935 9999 999 526.6249 5.9251 4.0083 0.0304 9999 999 9999 999 9999 999 9999 999 53005 262.9349 5.1300 533.2311 6.0449 4.1428 0.0309 9999 999 9999 999 4.2612 0.0362 9999 999 53145 269.9270 5.3703 541.7682 6.2027 4.1572 0.0310 9999 999 9999 999 9999 999 9999 999 53215 271.6503 5.4309 554.2488 6.4392 4.0284 0.0305 9999 999 40.9279 7.8461 9999 999 9999 999 53285 272.4291 5.4585 546.5230 6.2919 4.1384 0.0309 9999 999 9999 999 3.8089 0.0358 323.0387 6.2051 53355 272.3958 5.4574 555.6119 6.4654 3.9733 0.0303 1681.5010 7.2848 24.7160 7.8087 3.9944 0.0359 309.6493 5.6284 53425 272.2062 5.4506 541.2579 6.1931 4.1326 0.0309 9999 999 9999 999 4.1185 0.0361 326.8726 6.3808 53565 271.5409 5.4271 537.9647 6.1320 4.1822 0.0311 9999 999 9999 999 4.2237 0.0362 319.2447 6.0360 53635 270.4836 5.3898 553.0302 6.4158 4.2112 0.0312 1832.0629 7.3803 44.0059 7.8554 4.2266 0.0362 310.4802 5.6626 53705 270.8499 5.4027 533.2213 6.0447 4.1378 0.0309 9999 999 9999 999 4.2576 0.0362 305.9344 5.4779 53775 266.2652 5.2433 543.2529 6.2304 4.0483 0.0306 1780.2626 7.3466 33.9775 7.8278 4.1660 0.0361 311.7496 5.7152 53845 265.1326 5.2045 525.9052 5.9121 3.9767 0.0303 9999 999 9999 999 4.1388 0.0361 314.3394 5.8241 53985 262.1089 5.1022 517.0624 5.7550 3.8498 0.0299 9999 999 9999 999 4.0917 0.0360 317.6237 5.9651 54055 259.9235 5.0293 527.2053 5.9355 3.8937 0.0300 1737.3955 7.3194 25.4337 7.8100 4.0734 0.0360 315.9034 5.8909 54125 254.7160 4.8591 508.5230 5.6065 3.7026 0.0294 9999 999 9999 999 4.0375 0.0360 310.8954 5.6797 54195 250.4441 4.7231 514.4168 5.7087 3.6385 0.0291 1699.0314 7.2955 18.5525 7.7990 3.9668 0.0359 308.2535 5.5714 54265 249.0036 4.6780 502.5481 5.5045 3.5155 0.0287 9999 999 9999 999 3.8957 0.0359 305.9469 5.4784 54405 251.3499 4.7517 503.5712 5.5218 3.5654 0.0289 9999 999 9999 999 3.9460 0.0359 307.4905 5.5405 54475 250.6210 4.7287 511.3994 5.6562 3.7020 0.0294 1708.6602 7.3015 20.8812 7.8024 3.9384 0.0359 306.5152 5.5012 54545 252.1423 4.7768 505.9238 5.5619 3.6668 0.0292 9999 999 9999 999 3.9810 0.0359 307.2606 5.5312 54615 248.7702 4.6707 509.0417 5.6154 3.6200 0.0291 1691.0603 7.2906 28.0054 7.8148 3.9587 0.0359 305.3037 5.4528 54685 251.3725 4.7524 501.5670 5.4878 3.6508 0.0292 9999 999 9999 999 3.9397 0.0359 305.7543 5.4707 54825 251.1169 4.7443 502.5718 5.5049 3.5418 0.0288 9999 999 9999 999 4.0009 0.0360 304.0206 5.4020 54895 250.3200 4.7192 510.0754 5.6333 3.6666 0.0292 1697.3994 7.2945 24.9597 7.8091 3.9662 0.0359 303.9490 5.3991 54965 250.4303 4.7227 505.7330 5.5587 3.6138 0.0291 9999 999 9999 999 3.9957 0.0359 304.0652 5.4037 55035 250.0006 4.7092 511.9478 5.6657 3.5890 0.0290 1702.7031 7.2978 25.2070 7.8096 3.9889 0.0359 303.4937 5.3812 55105 250.8309 4.7353 508.6060 5.6079 3.5562 0.0289 9999 999 9999 999 3.9915 0.0359 303.9707 5.4000 55245 252.0440 4.7737 511.1323 5.6516 3.6268 0.0291 9999 999 9999 999 3.9991 0.0360 305.0950 5.4445 55314 249.6205 4.6973 514.2882 5.7064 3.5864 0.0290 1697.5238 7.2946 19.5325 7.8004 3.9830 0.0359 302.8138 5.3546 55385 250.6288 4.7289 511.0870 5.6508 3.6229 0.0291 9999 999 9999 999 3.9991 0.0360 303.2396 5.3713 55455 252.0042 4.7724 517.2616 5.7585 3.6192 0.0291 1718.2499 7.3074 22.2521 7.8045 4.0073 0.0360 304.5696 5.4236 55525 252.3351 4.7829 514.9352 5.7177 3.5777 0.0289 9999 999 9999 999 3.9963 0.0359 303.9211 5.3980 55665 252.1446 4.7768 516.8704 5.7516 3.6325 0.0291 9999 999 9999 999 4.0042 0.0360 303.7820 5.3926 55735 249.5494 4.6950 515.7653 5.7323 3.5459 0.0288 1708.9287 7.3017 18.4114 7.7988 4.0049 0.0360 302.4529 5.3405 55805 247.6531 4.6360 510.6092 5.6425 3.4826 0.0286 9999 999 9999 999 3.9779 0.0359 300.8285 5.2775 55875 248.1775 4.6523 513.8802 5.6993 3.4237 0.0284 1693.4778 7.2921 22.6879 7.8052 3.9896 0.0359 301.2115 5.2923 55945 247.2612 4.6239 511.4622 5.6573 3.4773 0.0286 9999 999 9999 999 3.9290 0.0359 300.1865 5.2529 56085 245.1065 4.5577 511.0354 5.6499 3.3710 0.0282 9999 999 9999 999 3.9578 0.0359 299.6223 5.2313 56155 240.3344 4.4140 505.4565 5.5539 3.3644 0.0282 1670.4852 7.2781 22.5873 7.8051 3.9429 0.0359 296.5882 5.1166 56225 243.6516 4.5135 505.5064 5.5548 3.2921 0.0280 9999 999 9999 999 3.9171 0.0359 297.5274 5.1518 56365 245.4688 4.5688 511.9785 5.6662 3.4181 0.0284 9999 999 9999 999 3.9907 0.0359 300.2365 5.2548 56505 251.2819 4.7495 516.0954 5.7380 3.5477 0.0288 9999 999 9999 999 4.0347 0.0360 304.3973 5.4168 56575 249.8276 4.7038 516.0256 5.7368 3.6369 0.0291 1693.1232 7.2919 26.7944 7.8125 3.9690 0.0359 302.5007 5.3424 56645 250.5925 4.7278 515.3738 5.7254 3.5439 0.0288 9999 999 9999 999 4.0096 0.0360 302.8229 5.3549 56715 249.5788 4.6960 515.4545 5.7268 3.5679 0.0289 1692.3969 7.2915 19.6538 7.8005 3.9881 0.0359 303.0947 5.3656 56785 247.9853 4.6463 510.8017 5.6458 3.4547 0.0285 9999 999 9999 999 3.9873 0.0359 300.4659 5.2636 56925 248.9118 4.6751 514.4258 5.7088 3.4890 0.0286 9999 999 9999 999 4.0009 0.0360 303.6117 5.3859 56995 247.8966 4.6436 511.6271 5.6601 3.4575 0.0285 1712.7264 7.3040 13.7432 7.7929 3.9519 0.0359 300.4775 5.2640 57065 246.1198 4.5887 508.2105 5.6011 3.4342 0.0285 9999 999 9999 999 3.9526 0.0359 299.1930 5.2149 57135 246.5896 4.6032 508.8688 5.6125 3.4529 0.0285 1714.5280 7.3051 23.2519 7.8062 3.9245 0.0359 300.5167 5.2655 57205 246.6611 4.6054 508.4294 5.6049 3.3816 0.0283 9999 999 9999 999 3.9876 0.0359 300.2602 5.2557 57345 243.8154 4.5185 505.6160 5.5567 3.3921 0.0283 9999 999 9999 999 3.8982 0.0359 299.0181 5.2082 57415 242.3719 4.4749 504.2067 5.5326 3.3754 0.0283 1673.6871 7.2800 14.0020 7.7932 3.9009 0.0359 297.5795 5.1538 57485 248.6606 4.6673 511.5225 5.6583 3.4726 0.0286 9999 999 9999 999 3.9318 0.0359 301.2325 5.2931 57555 249.9898 4.7088 511.0823 5.6507 3.5510 0.0288 1702.5679 7.2977 18.9728 7.7995 3.9710 0.0359 301.8847 5.3184 57625 249.8139 4.7033 508.9142 5.6132 3.4891 0.0286 9999 999 9999 999 3.9797 0.0359 301.7405 5.3128 57765 253.8653 4.8317 515.9019 5.7347 3.5883 0.0290 9999 999 9999 999 3.9913 0.0359 305.6435 5.4663 57835 248.3216 4.6568 510.5985 5.6423 3.4590 0.0285 1709.4735 7.3020 22.1714 7.8044 3.9469 0.0359 300.9427 5.2819 57905 249.2031 4.6842 509.8414 5.6292 3.4488 0.0285 9999 999 9999 999 4.0099 0.0360 301.6695 5.3100 57975 245.1865 4.5602 506.0741 5.5645 3.4098 0.0284 1687.5771 7.2885 22.1263 7.8043 3.9050 0.0359 299.4564 5.2249 58045 245.9315 4.5830 504.9608 5.5455 3.3737 0.0283 9999 999 9999 999 3.9266 0.0359 298.9754 5.2066 58185 242.6836 4.4843 505.0599 5.5472 3.3407 0.0281 9999 999 9999 999 3.9309 0.0359 296.9349 5.1295 58255 241.2238 4.4405 501.4451 5.4858 3.2840 0.0280 1673.5771 7.2799 18.2025 7.7985 3.8765 0.0358 296.2153 5.1026 58325 242.9583 4.4926 502.1134 5.4971 3.3203 0.0281 9999 999 9999 999 3.8877 0.0358 296.7902 5.1241 58395 243.9922 4.5238 506.0245 5.5636 3.3457 0.0282 1677.9146 7.2826 18.9366 7.7995 3.8823 0.0358 297.7554 5.1604 58465 222.8935 3.9211 479.9843 5.1326 2.9158 0.0268 9999 999 9999 999 3.7853 0.0358 283.2377 4.6400 58605 228.7326 4.0806 488.9797 5.2783 3.0652 0.0273 9999 999 9999 999 3.8175 0.0358 288.8926 4.8364 58675 234.8692 4.2542 494.5774 5.3707 3.1395 0.0275 1658.5961 7.2709 16.8637 7.7967 3.8691 0.0358 291.4463 4.9277 58745 237.1553 4.3205 496.4798 5.4024 3.1670 0.0276 9999 999 9999 999 3.8704 0.0358 292.6756 4.9722 58815 228.0370 4.0614 486.4053 5.2363 3.0182 0.0271 1633.0447 7.2555 21.0713 7.8027 3.8212 0.0358 287.2284 4.7778 58885 233.9925 4.2290 492.6639 5.3390 3.1163 0.0274 9999 999 9999 999 3.8528 0.0358 289.8795 4.8715 59025 242.8636 4.4897 506.0128 5.5634 3.2755 0.0279 9999 999 9999 999 3.9191 0.0359 297.8144 5.1626 59095 238.9507 4.3731 500.1304 5.4636 3.1845 0.0277 1656.9701 7.2699 16.9315 7.7968 3.8871 0.0358 294.2579 5.0301 59165 238.2156 4.3515 496.1938 5.3976 3.1504 0.0275 9999 999 9999 999 3.8683 0.0358 292.0969 4.9512 59235 236.3530 4.2971 497.9193 5.4264 3.1705 0.0276 1649.6938 7.2655 23.8175 7.8071 3.8581 0.0358 292.0631 4.9500 59305 238.9080 4.3718 499.1399 5.4469 3.2564 0.0279 9999 999 9999 999 3.8969 0.0359 293.8907 5.0166 59445 238.9367 4.3727 499.9830 5.4611 3.1961 0.0277 9999 999 9999 999 3.8789 0.0358 293.9766 5.0198 59515 241.6451 4.4531 505.0038 5.5462 3.2734 0.0279 1666.5526 7.2757 19.1735 7.7998 3.9040 0.0359 295.8411 5.0887 59585 242.4222 4.4764 505.5668 5.5558 3.2265 0.0278 9999 999 9999 999 3.9189 0.0359 295.9502 5.0927 59655 243.2327 4.5008 506.3020 5.5684 3.3467 0.0282 1667.2992 7.2761 22.8037 7.8054 3.9242 0.0359 296.7807 5.1238 59725 244.4073 4.5364 507.1808 5.5834 3.3374 0.0281 9999 999 9999 999 3.9222 0.0359 297.0658 5.1344 59865 244.3853 4.5358 507.5098 5.5891 3.2814 0.0280 9999 999 9999 999 3.9314 0.0359 298.0671 5.1722 59935 243.5059 4.5091 505.2230 5.5500 3.2954 0.0280 1675.1136 7.2809 15.0860 7.7944 3.9186 0.0359 295.9874 5.0941 60005 241.4970 4.4487 503.4485 5.5197 3.2333 0.0278 9999 999 9999 999 3.9153 0.0359 295.2078 5.0652 60075 240.6713 4.4241 502.6234 5.5057 3.2454 0.0278 1663.0521 7.2736 19.8520 7.8008 3.8873 0.0358 294.5895 5.0423 60145 242.2390 4.4709 504.4730 5.5372 3.2460 0.0278 9999 999 9999 999 3.8982 0.0359 295.2722 5.0676 60285 240.5745 4.4212 504.5833 5.5390 3.2035 0.0277 9999 999 9999 999 3.9077 0.0359 296.4423 5.1111 60355 239.5698 4.3914 500.6075 5.4716 3.1908 0.0277 1656.7307 7.2697 21.7184 7.8037 3.8913 0.0359 293.6600 5.0082 60425 239.6160 4.3927 500.0241 5.4618 3.2189 0.0278 9999 999 9999 999 3.8642 0.0358 294.0798 5.0236 60565 240.0130 4.4045 503.4946 5.5205 3.1882 0.0277 9999 999 9999 999 3.9148 0.0359 295.4557 5.0744 60705 239.8875 4.4008 500.4542 5.4690 3.2192 0.0278 9999 999 9999 999 3.9320 0.0359 296.0013 5.0947 60775 238.0470 4.3465 499.2150 5.4482 3.1742 0.0276 1644.6155 7.2624 21.3605 7.8031 3.8929 0.0359 293.2584 4.9935 60845 237.7495 4.3378 496.1105 5.3962 3.1471 0.0275 9999 999 9999 999 3.8653 0.0358 293.0341 4.9853 60915 236.2869 4.2952 496.9816 5.4107 3.1677 0.0276 1640.3027 7.2599 24.0746 7.8076 3.9028 0.0359 292.0872 4.9509 60985 235.6113 4.2756 495.6238 5.3881 3.1028 0.0274 9999 999 9999 999 3.8453 0.0358 292.4033 4.9623 61125 237.6243 4.3342 498.5024 5.4362 3.1709 0.0276 9999 999 9999 999 3.9114 0.0359 294.3283 5.0327 61195 235.8535 4.2826 496.9125 5.4096 3.0932 0.0274 1642.5137 7.2612 24.0328 7.8075 3.8744 0.0358 292.8379 4.9781 61265 235.7891 4.2808 494.0079 5.3612 3.1328 0.0275 9999 999 9999 999 3.9006 0.0359 292.2488 4.9567 61335 234.8164 4.2527 495.0901 5.3792 3.0879 0.0274 1640.3925 7.2599 20.1099 7.8012 3.8820 0.0358 291.7444 4.9385 61405 234.4705 4.2428 492.6754 5.3391 3.1552 0.0276 9999 999 9999 999 3.9136 0.0359 291.9729 4.9467 61545 236.7911 4.3099 496.8037 5.4078 3.1352 0.0275 9999 999 9999 999 3.8979 0.0359 294.2023 5.0281 61615 236.2474 4.2941 494.5996 5.3710 3.1156 0.0274 1655.1119 7.2688 19.9606 7.8010 3.8934 0.0359 292.6705 4.9720 61685 236.7181 4.3077 496.7473 5.4068 3.1713 0.0276 9999 999 9999 999 3.8745 0.0358 293.5074 5.0026 61755 235.8781 4.2833 494.6924 5.3726 3.1056 0.0274 1645.4988 7.2630 18.9333 7.7995 3.8768 0.0358 292.9707 4.9830 61825 235.5219 4.2730 493.8801 5.3591 3.0897 0.0274 9999 999 9999 999 3.9113 0.0359 292.1725 4.9540 61965 238.2547 4.3526 498.3171 5.4331 3.1245 0.0275 9999 999 9999 999 3.9240 0.0359 294.9926 5.0572 62035 238.5778 4.3621 497.3871 5.4175 3.1744 0.0276 1662.6506 7.2733 20.6895 7.8021 3.8811 0.0358 294.2193 5.0287 62105 239.5823 4.3918 496.7777 5.4073 3.1855 0.0277 9999 999 9999 999 3.9053 0.0359 293.9598 5.0192 62175 236.0570 4.2885 495.2374 5.3816 3.1037 0.0274 1659.7628 7.2716 22.3822 7.8047 3.8829 0.0358 292.2930 4.9583 62245 235.2942 4.2665 493.1298 5.3467 3.1121 0.0274 9999 999 9999 999 3.8989 0.0359 291.3600 4.9246 62385 235.6523 4.2768 496.9036 5.4094 3.0852 0.0273 9999 999 9999 999 3.8945 0.0359 293.0745 4.9868 62455 234.6926 4.2491 495.4666 5.3855 3.1351 0.0275 1644.5524 7.2624 23.9883 7.8074 3.8489 0.0358 292.0629 4.9500 62525 235.9520 4.2855 492.9409 5.3435 3.0734 0.0273 9999 999 9999 999 3.8929 0.0359 292.0142 4.9482 62595 234.6828 4.2489 493.9975 5.3610 3.0781 0.0273 1643.0303 7.2615 24.5626 7.8084 3.9039 0.0359 291.5247 4.9305 62665 234.6849 4.2489 494.0916 5.3626 3.0816 0.0273 9999 999 9999 999 3.8922 0.0359 291.8431 4.9420 62805 235.2735 4.2659 496.9795 5.4107 3.0601 0.0273 9999 999 9999 999 3.8742 0.0358 292.4610 4.9644 62875 234.4756 4.2429 494.6674 5.3722 3.0788 0.0273 1646.1804 7.2634 18.6830 7.7991 3.8857 0.0358 291.6368 4.9346 62945 233.8790 4.2258 494.8589 5.3754 3.0524 0.0272 9999 999 9999 999 3.8999 0.0359 291.7949 4.9403 63015 233.6624 4.2196 493.8231 5.3582 3.1046 0.0274 1646.8162 7.2638 17.9609 7.7981 3.8546 0.0358 291.4978 4.9296 63085 233.2614 4.2081 492.7900 5.3410 3.0715 0.0273 9999 999 9999 999 3.8793 0.0358 291.3480 4.9242 63225 232.7541 4.1937 495.7646 5.3904 3.0270 0.0272 9999 999 9999 999 3.8938 0.0359 292.3732 4.9612 63295 231.0339 4.1450 491.2397 5.3154 3.0136 0.0271 1645.5718 7.2630 19.9178 7.8009 3.8809 0.0358 289.7802 4.8680 63365 230.4940 4.1298 491.0274 5.3119 2.9935 0.0271 9999 999 9999 999 3.8601 0.0358 289.5280 4.8590 63435 230.5721 4.1320 492.5073 5.3364 3.0093 0.0271 1650.3116 7.2659 21.2551 7.8029 3.8610 0.0358 289.0478 4.8419 63505 229.7759 4.1097 490.3901 5.3015 2.9590 0.0270 9999 999 9999 999 3.8784 0.0358 289.6653 4.8639 63645 228.7675 4.0816 490.3412 5.3007 2.9611 0.0270 9999 999 9999 999 3.8278 0.0358 289.5740 4.8606 63715 230.3049 4.1245 493.7846 5.3575 3.0326 0.0272 1648.9495 7.2651 23.3905 7.8064 3.8976 0.0359 290.4621 4.8923 63785 230.3451 4.1257 491.2898 5.3163 3.0429 0.0272 9999 999 9999 999 3.8876 0.0358 289.5984 4.8615 63855 229.4751 4.1013 491.2686 5.3159 2.9984 0.0271 1650.2198 7.2658 24.6717 7.8086 3.8381 0.0358 289.2105 4.8477 63925 230.0394 4.1171 489.6757 5.2897 2.9508 0.0269 9999 999 9999 999 3.8994 0.0359 289.1743 4.8464 64065 231.1563 4.1485 492.6769 5.3392 2.9774 0.0270 9999 999 9999 999 3.9023 0.0359 290.3142 4.8870 64135 233.0288 4.2015 497.0423 5.4118 3.0907 0.0274 1642.8392 7.2614 23.7264 7.8070 3.9100 0.0359 292.3943 4.9620 64205 232.0742 4.1744 493.5283 5.3533 3.0538 0.0272 9999 999 9999 999 3.9130 0.0359 291.4656 4.9284 64275 229.1592 4.0925 492.4371 5.3352 3.0300 0.0272 1631.0029 7.2543 21.9365 7.8040 3.8596 0.0358 288.1932 4.8117 64345 232.0844 4.1747 493.1397 5.3468 3.0695 0.0273 9999 999 9999 999 3.9113 0.0359 290.2954 4.8864 64485 227.5575 4.0481 491.1099 5.3133 2.9829 0.0270 9999 999 9999 999 3.9031 0.0359 290.1812 4.8823 64555 228.5029 4.0743 488.5013 5.2705 2.9602 0.0270 1647.4475 7.2641 22.2749 7.8046 3.8421 0.0358 288.2805 4.8148 64625 231.3074 4.1527 493.4418 5.3518 3.0620 0.0273 9999 999 9999 999 3.8521 0.0358 289.4915 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