36 1001 ELKINS, JAMES; RAY, ERIC; MOORE, FRED; MACTAGGART, DOUG; DUTTON, GEOFF U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION LACE, WB-57 ACCENT 1 1 1999 09 15 2000 01 07 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 14 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) CO MIXING RATIO (PPB) CO ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) 7 Error bars quoted include all the statistical error occurred in going from raw integrations to final calibrated numbers. In addition there is the following error associated with the accuracy of our calibration tanks: F11+-1%, F113+-2%, F12+-2%, H1211+-3%, SF6+-3%, N2o+-2%. -------------- -- - 1 GMTs F11 F11e F12 F12e H1211 H1211e CH4 CH4e CO COe SF6 SF6e N2O N2Oe 55583 273.5344 6.3536 9999 999 9999 999 9999 999 43.3752 7.4156 9999 999 9999 999 55653 270.4356 6.2588 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 55723 267.7840 6.1794 9999 999 3.8922 0.0560 9999 999 42.2181 7.4118 9999 999 9999 999 55793 267.5378 6.1721 546.7878 7.0521 3.9199 0.0561 9999 999 9999 999 4.5279 0.0497 332.6029 6.8420 55933 265.0237 6.0983 536.0313 6.8736 3.9866 0.0562 9999 999 9999 999 4.2906 0.0496 307.5790 5.7697 56003 263.0856 6.0423 535.4143 6.8635 3.9401 0.0561 1744.6173 22.5394 33.2456 7.3865 4.1753 0.0495 311.2183 5.9131 56073 262.5133 6.0260 533.7463 6.8364 3.9665 0.0561 9999 999 9999 999 4.2083 0.0495 313.6407 6.0108 56143 259.3484 5.9366 531.1391 6.7943 3.9603 0.0561 1723.2158 22.5350 25.4501 7.3695 4.1460 0.0495 314.7115 6.0546 56213 257.8687 5.8956 528.0960 6.7456 3.8973 0.0560 9999 999 9999 999 4.1285 0.0494 314.3087 6.0381 56353 254.5192 5.8043 523.9636 6.6801 3.8093 0.0558 9999 999 9999 999 4.0573 0.0494 312.2374 5.9540 56423 251.5763 5.7260 520.3840 6.6242 3.8835 0.0560 1729.4441 22.5363 10.1449 7.3474 4.0853 0.0494 311.7500 5.9344 56493 250.2063 5.6902 521.7266 6.6451 3.7879 0.0558 9999 999 9999 999 4.1034 0.0494 312.2250 5.9535 56563 258.5164 5.9135 521.4749 6.6412 3.8667 0.0560 1717.5299 22.5339 11.6002 7.3489 4.0767 0.0494 311.0280 5.9055 56633 260.4655 5.9679 530.4601 6.7834 3.9468 0.0561 9999 999 9999 999 4.0915 0.0494 310.9809 5.9036 56773 261.1697 5.9878 528.8521 6.7576 4.0499 0.0563 9999 999 9999 999 4.0497 0.0494 310.5071 5.8848 56843 261.7291 6.0036 533.5810 6.8337 3.9893 0.0562 1728.1466 22.5360 6.4071 7.3440 4.0713 0.0494 310.0417 5.8663 56913 261.9504 6.0099 530.6298 6.7861 3.9198 0.0561 9999 999 9999 999 4.0930 0.0494 309.5037 5.8450 56983 261.9357 6.0095 532.8506 6.8219 3.9817 0.0562 1725.3165 22.5355 1.6326 7.3408 4.0784 0.0494 310.6642 5.8910 57053 261.6697 6.0019 529.7354 6.7718 3.9544 0.0561 9999 999 9999 999 4.0800 0.0494 310.6934 5.8922 57193 262.2909 6.0196 531.1765 6.7949 4.0363 0.0563 9999 999 9999 999 4.1013 0.0494 309.7367 5.8542 57263 261.5706 5.9991 533.0320 6.8248 4.0717 0.0563 1742.9298 22.5390 8.3033 7.3457 4.1004 0.0494 310.1977 5.8725 57333 262.0166 6.0118 531.7349 6.8039 3.9898 0.0562 9999 999 9999 999 4.1314 0.0495 310.3693 5.8793 57403 260.1938 5.9603 532.1684 6.8109 4.0165 0.0562 1747.3986 22.5400 9.3662 7.3466 4.1270 0.0494 310.1363 5.8700 57473 261.8881 6.0082 532.4955 6.8162 4.0667 0.0563 9999 999 9999 999 4.1485 0.0495 310.2354 5.8740 57613 262.2555 6.0186 534.1738 6.8433 4.0478 0.0563 9999 999 9999 999 4.1442 0.0495 311.5304 5.9256 57683 260.7113 5.9748 535.4045 6.8633 4.0034 0.0562 1752.8694 22.5411 -2.0760 7.3390 4.1767 0.0495 311.3667 5.9190 57753 262.0471 6.0127 535.2210 6.8604 4.0056 0.0562 9999 999 9999 999 4.1905 0.0495 310.5952 5.8883 57823 262.7499 6.0327 535.3734 6.8628 4.1181 0.0564 1728.7285 22.5361 -1.6721 7.3397 4.1352 0.0495 311.9827 5.9437 57893 261.2531 5.9901 534.0570 6.8414 4.0199 0.0562 9999 999 9999 999 4.0900 0.0494 311.1597 5.9108 58033 262.3865 6.0223 536.0159 6.8733 4.0705 0.0563 9999 999 9999 999 4.1261 0.0494 311.9682 5.9431 58103 262.4222 6.0234 534.2737 6.8450 4.0500 0.0563 1736.9642 22.5378 5.4533 7.3433 4.1757 0.0495 312.5209 5.9654 58173 262.0736 6.0134 534.8602 6.8545 4.0997 0.0564 9999 999 9999 999 4.1139 0.0494 311.8235 5.9373 58243 263.0984 6.0427 535.1315 6.8589 4.1101 0.0564 1740.0443 22.5385 4.4808 7.3426 4.1169 0.0494 312.4384 5.9621 58313 262.6501 6.0299 537.6163 6.8995 4.1709 0.0565 9999 999 9999 999 4.1260 0.0494 312.3576 5.9588 58453 263.5994 6.0571 536.6216 6.8832 4.1205 0.0564 9999 999 9999 999 4.1395 0.0495 312.7263 5.9737 58523 264.1815 6.0739 538.9929 6.9222 4.2390 0.0567 1737.2494 22.5379 6.9216 7.3445 4.0996 0.0494 314.6285 6.0512 58593 263.7627 6.0618 537.7272 6.9013 4.1117 0.0564 9999 999 9999 999 4.1782 0.0495 313.4378 6.0025 58663 263.1205 6.0433 536.3715 6.8791 4.1073 0.0564 1727.4985 22.5359 11.2150 7.3485 4.1458 0.0495 314.4843 6.0452 58733 263.9916 6.0684 535.5601 6.8659 4.0173 0.0562 9999 999 9999 999 4.0461 0.0494 313.4500 6.0030 58873 264.7878 6.0915 533.2985 6.8291 3.9772 0.0562 9999 999 9999 999 4.1261 0.0494 314.1646 6.0322 58943 264.9134 6.0951 536.9671 6.8889 4.1217 0.0564 1744.6611 22.5394 15.5451 7.3536 4.1551 0.0495 314.2188 6.0344 59013 264.8874 6.0943 537.3887 6.8958 4.0143 0.0562 9999 999 9999 999 4.1508 0.0495 315.3154 6.0794 59083 262.4921 6.0254 537.0847 6.8908 4.0672 0.0563 1731.0625 22.5366 13.4669 7.3510 4.1198 0.0494 314.4451 6.0436 59153 262.1325 6.0151 532.5222 6.8166 4.0105 0.0562 9999 999 9999 999 4.1333 0.0495 313.3325 5.9983 59293 260.1574 5.9593 531.1263 6.7941 3.9485 0.0561 9999 999 9999 999 4.0660 0.0494 311.0438 5.9061 59363 260.8220 5.9780 533.3120 6.8294 3.9400 0.0561 1735.3650 22.5375 9.0599 7.3464 4.1018 0.0494 312.0684 5.9472 59433 264.5832 6.0855 536.3982 6.8796 4.0043 0.0562 9999 999 9999 999 4.1791 0.0495 313.4527 6.0031 59503 265.9846 6.1264 539.6116 6.9324 4.0809 0.0564 1737.6598 22.5380 6.1488 7.3438 4.1384 0.0495 314.2839 6.0370 59573 265.6119 6.1155 537.5475 6.8984 4.0433 0.0563 9999 999 9999 999 4.1131 0.0494 313.8413 6.0190 59713 264.6051 6.0862 536.5175 6.8815 4.0096 0.0562 9999 999 9999 999 4.1329 0.0495 313.7249 6.0142 59783 264.6395 6.0872 535.8702 6.8709 4.0710 0.0563 1751.8026 22.5409 9.0323 7.3463 4.1292 0.0494 313.0888 5.9884 59853 263.6452 6.0584 533.2520 6.8284 3.9537 0.0561 9999 999 9999 999 4.0966 0.0494 312.3970 5.9604 59923 263.2544 6.0472 534.3651 6.8464 3.9054 0.0560 1746.0112 22.5397 14.8587 7.3527 4.1114 0.0494 312.7929 5.9764 59993 262.4828 6.0251 532.0445 6.8089 3.9448 0.0561 9999 999 9999 999 4.0867 0.0494 310.8887 5.8999 60133 262.3710 6.0219 531.8652 6.8060 3.9458 0.0561 9999 999 9999 999 4.1352 0.0495 311.0160 5.9050 60203 262.3855 6.0223 530.6185 6.7859 3.9561 0.0561 1748.2264 22.5401 9.7112 7.3470 4.0338 0.0494 310.9602 5.9028 60273 261.3383 5.9926 528.5905 6.7535 3.9077 0.0560 9999 999 9999 999 4.0885 0.0494 310.2844 5.8759 60343 260.8279 5.9781 529.7150 6.7714 3.9699 0.0561 1752.5782 22.5410 14.5543 7.3524 4.0924 0.0494 310.5446 5.8862 60413 262.0813 6.0136 528.4025 6.7505 3.9334 0.0561 9999 999 9999 999 4.0463 0.0494 309.3246 5.8380 60553 262.2874 6.0195 531.2353 6.7958 3.8559 0.0559 9999 999 9999 999 4.1131 0.0494 311.7315 5.9336 60623 261.0804 5.9853 529.1466 6.7623 3.9474 0.0561 1764.2723 22.5434 16.4310 7.3548 4.0019 0.0494 309.0393 5.8268 60693 264.4805 6.0825 531.4830 6.7998 3.9256 0.0561 9999 999 9999 999 4.1269 0.0494 311.3111 5.9168 60763 260.4063 5.9663 528.0490 6.7448 3.8864 0.0560 1731.7706 22.5368 5.7360 7.3435 4.0490 0.0494 309.9390 5.8622 60833 262.6286 6.0293 532.0897 6.8096 3.8553 0.0559 9999 999 9999 999 4.1032 0.0494 310.5490 5.8864 60973 264.6330 6.0870 532.8773 6.8223 4.0524 0.0563 9999 999 9999 999 4.0864 0.0494 312.3996 5.9605 61043 255.2559 5.8242 521.6527 6.6439 3.7779 0.0558 1725.5220 22.5355 -3.7861 7.3389 3.9611 0.0493 306.2451 5.7181 61113 250.0955 5.6873 518.3392 6.5925 3.7180 0.0557 9999 999 9999 999 3.9454 0.0493 304.2953 5.6437 61183 248.5182 5.6465 515.0280 6.5416 3.6181 0.0555 1699.7098 22.5303 0.8054 7.3403 3.9655 0.0493 301.7606 5.5486 61253 246.1849 5.5871 513.4011 6.5168 3.6114 0.0555 9999 999 9999 999 3.9125 0.0493 300.3125 5.4951 61393 245.7046 5.5750 513.8682 6.5239 3.6125 0.0555 9999 999 9999 999 3.9136 0.0493 302.2207 5.5658 61463 243.3827 5.5172 511.1904 6.4833 3.6192 0.0555 1693.7245 22.5291 -4.0140 7.3383 3.9812 0.0493 299.2474 5.4562 61533 242.8847 5.5049 508.1976 6.4383 3.5620 0.0554 9999 999 9999 999 3.8955 0.0493 299.0696 5.4497 61603 245.5076 5.5701 512.9999 6.5107 3.6223 0.0555 1684.2264 22.5272 3.8692 7.3422 3.8963 0.0493 300.6996 5.5094 61673 244.8917 5.5547 510.7000 6.4759 3.5635 0.0554 9999 999 9999 999 3.8905 0.0493 299.3208 5.4588 61813 242.2981 5.4906 507.8477 6.4330 3.5252 0.0553 9999 999 9999 999 3.8742 0.0493 300.5238 5.5029 61883 242.7118 5.5007 510.4383 6.4719 3.5814 0.0554 1665.2170 22.5235 3.9511 7.3422 3.8892 0.0493 299.0635 5.4495 61953 242.1750 5.4875 506.8609 6.4183 3.5592 0.0554 9999 999 9999 999 3.9105 0.0493 297.6276 5.3975 62023 240.2940 5.4419 507.5541 6.4287 3.5522 0.0554 1675.3433 22.5255 3.9686 7.3422 3.8957 0.0493 297.2257 5.3831 62093 242.1629 5.4872 506.9330 6.4194 3.4062 0.0551 9999 999 9999 999 3.9082 0.0493 297.1424 5.3801 62233 241.4745 5.4705 507.6424 6.4300 3.5070 0.0553 9999 999 9999 999 3.9303 0.0493 297.4334 5.3905 62303 242.1187 5.4862 508.2023 6.4383 3.4875 0.0553 1669.6359 22.5243 -7.4321 7.3377 3.8910 0.0493 298.3376 5.4231 62373 242.0007 5.4833 510.0381 6.4659 3.5976 0.0555 9999 999 9999 999 3.9771 0.0493 296.7711 5.3668 62443 241.6942 5.4758 505.7140 6.4013 3.4999 0.0553 1666.0763 22.5237 -1.5535 7.3397 3.9550 0.0493 298.0078 5.4112 62513 242.6730 5.4997 507.5619 6.4288 3.5191 0.0553 9999 999 9999 999 3.8831 0.0493 298.1321 5.4157 62653 245.8945 5.5798 513.8947 6.5243 3.5282 0.0553 9999 999 9999 999 3.9359 0.0493 301.2647 5.5302 62723 244.4226 5.5430 510.5684 6.4739 3.4571 0.0552 1667.1204 22.5239 -1.8716 7.3398 3.9610 0.0493 299.4034 5.4618 62793 245.0840 5.5595 511.4810 6.4876 3.5005 0.0553 9999 999 9999 999 3.9118 0.0493 299.3180 5.4587 62863 243.9043 5.5301 511.2034 6.4834 3.6020 0.0555 1662.1633 22.5229 1.9888 7.3410 3.9141 0.0493 298.0581 5.4130 62933 244.4132 5.5427 510.0387 6.4659 3.4842 0.0553 9999 999 9999 999 3.9109 0.0493 298.2011 5.4182 63073 246.3361 5.5910 514.0240 6.5262 3.5967 0.0555 9999 999 9999 999 3.9758 0.0493 300.0751 5.4864 63143 245.6021 5.5725 511.6935 6.4909 3.5554 0.0554 1674.0812 22.5252 0.8051 7.3403 3.9078 0.0493 300.1635 5.4897 63213 237.4938 5.3752 501.2383 6.3353 3.3807 0.0551 9999 999 9999 999 3.8307 0.0492 294.0769 5.2715 63283 236.4494 5.3507 500.8611 6.3298 3.3610 0.0551 1639.3359 22.5185 4.9792 7.3429 3.8514 0.0493 293.9632 5.2675 63353 237.3441 5.3717 502.3824 6.3521 3.3522 0.0550 9999 999 9999 999 3.8699 0.0493 294.4918 5.2860 63493 237.6686 5.3793 504.7780 6.3874 3.3398 0.0550 9999 999 9999 999 3.9176 0.0493 295.6170 5.3257 63563 236.8601 5.3603 503.6670 6.3710 3.4245 0.0552 1647.0409 22.5199 4.1964 7.3424 3.8747 0.0493 293.1822 5.2402 63633 237.7635 5.3816 503.5885 6.3698 3.4039 0.0551 9999 999 9999 999 3.9009 0.0493 294.3530 5.2811 63703 237.4145 5.3734 503.1907 6.3640 3.3877 0.0551 1638.0471 22.5182 -3.0915 7.3387 3.9017 0.0493 294.5779 5.2890 63773 238.9238 5.4091 505.1217 6.3925 3.3811 0.0551 9999 999 9999 999 3.8676 0.0493 295.2511 5.3128 63913 238.2083 5.3921 504.7418 6.3869 3.3649 0.0551 9999 999 9999 999 3.9207 0.0493 295.9524 5.3376 63983 236.9970 5.3636 501.3959 6.3376 3.3502 0.0550 1644.2338 22.5194 -7.4947 7.3377 3.8096 0.0492 294.7031 5.2934 64053 233.1067 5.2738 498.6337 6.2974 3.2639 0.0549 9999 999 9999 999 3.8403 0.0493 292.0000 5.1993 64123 231.6361 5.2406 497.5651 6.2820 3.3043 0.0550 1640.8884 22.5188 -9.2809 7.3374 3.8783 0.0493 291.4918 5.1818 64193 233.5112 5.2830 500.3728 6.3227 3.2812 0.0549 9999 999 9999 999 3.8518 0.0493 292.4371 5.2144 64333 230.5134 5.2155 496.3581 6.2646 3.3280 0.0550 9999 999 9999 999 3.7408 0.0492 289.9784 5.1302 64403 226.3669 5.1249 493.5503 6.2243 3.1819 0.0548 1618.8960 22.5145 -3.6994 7.3389 3.8110 0.0492 289.7332 5.1219 64473 225.1053 5.0979 489.1067 6.1615 3.0786 0.0546 9999 999 9999 999 3.8001 0.0492 288.4752 5.0795 64543 213.5414 4.8642 477.9761 6.0081 2.9535 0.0544 1573.6431 22.5060 0.0171 7.3399 3.7133 0.0492 280.2469 4.8122 64613 214.6714 4.8860 477.3757 6.0000 2.9539 0.0544 9999 999 9999 999 3.7543 0.0492 279.7932 4.7980 64753 223.5511 5.0651 485.3527 6.1091 2.9789 0.0545 9999 999 9999 999 3.8051 0.0492 286.6564 5.0190 64823 215.7333 4.9067 481.2285 6.0523 3.1148 0.0547 1588.3879 22.5088 0.2537 7.3400 3.6850 0.0492 281.6827 4.8576 64893 225.6541 5.1096 488.4867 6.1528 3.1649 0.0547 9999 999 9999 999 3.7913 0.0492 287.3913 5.0433 64963 214.9781 4.8919 479.4075 6.0275 3.1354 0.0547 1591.6320 22.5094 -3.4088 7.3388 3.7928 0.0492 283.0256 4.9006 65033 224.7765 5.0909 487.7900 6.1430 3.0296 0.0545 9999 999 9999 999 3.7338 0.0492 287.0464 5.0319 65173 224.6197 5.0876 489.8303 6.1716 3.1203 0.0547 9999 999 9999 999 3.7482 0.0492 288.4621 5.0791 65243 225.9160 5.1152 490.2322 6.1773 3.1482 0.0547 1612.5566 22.5133 -3.9296 7.3390 3.7700 0.0492 288.8344 5.0916 65313 222.9385 5.0523 486.8714 6.1302 3.0495 0.0546 9999 999 9999 999 3.8073 0.0492 286.4481 5.0121 65383 223.6243 5.0667 485.8688 6.1162 3.0973 0.0546 1604.1245 22.5117 -8.6336 7.3376 3.7640 0.0492 287.1089 5.0339 65453 217.8831 4.9492 480.1718 6.0379 2.9410 0.0544 9999 999 9999 999 3.7495 0.0492 283.4528 4.9143 65593 238.4040 5.3967 502.7397 6.3574 3.3258 0.0550 9999 999 9999 999 3.8341 0.0492 295.2906 5.3142 65663 249.4637 5.6709 514.0245 6.5262 3.6076 0.0555 1687.0991 22.5278 -7.7720 7.3378 3.9750 0.0493 301.8885 5.5534 65733 259.9135 5.9524 525.7489 6.7083 3.7168 0.0557 9999 999 9999 999 3.9946 0.0494 307.4557 5.7649 65803 267.5204 6.1716 531.2204 6.7956 3.9516 0.0561 1723.5575 22.5351 16.1207 7.3544 4.0808 0.0494 311.8277 5.9375 65873 267.9033 6.1829 533.6195 6.8343 3.9641 0.0561 9999 999 9999 999 4.1056 0.0494 312.1968 5.9523 66013 264.7057 6.0891 528.8421 6.7575 3.8468 0.0559 9999 999 9999 999 4.0726 0.0494 309.7665 5.8554 66083 266.2318 6.1336 531.8784 6.8062 3.9700 0.0561 1746.7596 22.5398 14.5507 7.3524 4.0732 0.0494 311.8038 5.9365 66153 264.2603 6.0762 526.8038 6.7250 3.8485 0.0559 9999 999 9999 999 4.0860 0.0494 309.6628 5.8513 66223 266.9737 6.1554 533.0077 6.8244 3.9959 0.0562 1741.0496 22.5387 19.1929 7.3588 4.1216 0.0494 310.8624 5.8989 66293 268.2430 6.1930 530.7947 6.7888 3.8626 0.0559 9999 999 9999 999 4.1026 0.0494 312.4925 5.9643 66433 268.1911 6.1915 528.7750 6.7564 3.9534 0.0561 9999 999 9999 999 4.0885 0.0494 311.5368 5.9258 66503 267.2881 6.1647 530.3225 6.7812 3.9842 0.0562 1738.4620 22.5381 18.6415 7.3579 4.1171 0.0494 311.7596 5.9348 66573 267.9989 6.1858 530.9788 6.7917 3.9084 0.0560 9999 999 9999 999 4.1456 0.0495 311.6376 5.9299 66643 267.7421 6.1782 531.9366 6.8071 3.8802 0.0560 1716.2976 22.5336 16.3762 7.3547 4.0999 0.0494 312.3534 5.9586 66713 269.1020 6.2187 531.4401 6.7991 3.9042 0.0560 9999 999 9999 999 4.1297 0.0494 311.1197 5.9092 66853 267.5107 6.1713 531.5944 6.8016 3.9376 0.0561 9999 999 9999 999 4.1119 0.0494 311.9815 5.9437 66923 267.2680 6.1641 529.3372 6.7654 3.9071 0.0560 1725.1207 22.5354 10.3996 7.3477 4.1248 0.0494 310.7736 5.8954 66993 267.3744 6.1673 530.5437 6.7847 3.8951 0.0560 9999 999 9999 999 4.1202 0.0494 310.2505 5.8746 67063 268.0179 6.1863 531.0032 6.7921 3.8688 0.0560 1724.9814 22.5354 9.5759 7.3468 4.1660 0.0495 311.6151 5.9290 67133 267.7398 6.1781 531.5050 6.8002 3.8422 0.0559 9999 999 9999 999 4.1426 0.0495 312.0555 5.9467 67273 267.6830 6.1764 531.8323 6.8054 3.9044 0.0560 9999 999 9999 999 4.1218 0.0494 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