42 1001 ELKINS, JAMES; WAMSLEY, PAULA; DUTTON, GEOFF; ROMASHKIN, PAVEL; HURST, DALE; DUNN, RAY U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS IV, ER-2 POLARIS 1 1 1997 09 11 1998 09 09 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 22 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CHCL3 MIXING RATIO (PPT) CHCL3 ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 5 Methyl chloroform and CFC-11 are re-calculated to remove minor contamination from the pump. Time is corrected for pump delay using O3 data by Proffitt et al. CFC-11 uses Poly4 calibration curves for the mixing ratios but Poly3 curve for standard deviations. Therefore, CFC-11 std. deviation provided may be exaggerated for some tropospheric data points. For this flight time is adjusted by subtracting (20) sec. 1 GMTs F11 F11e F113 F113e CHCl3 CHCl3e MC MCe CT CTe N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e 9011 266.8 7.3 83.6 1.5 12.77 0.94 76.70 1.25 103.19 0.70 9999 999 9999 999 552.7 5.8 3.91 0.12 9999 999 1733 37 9136 267.1 7.4 84.1 1.5 9.34 0.70 75.88 1.23 103.22 0.70 9999 999 9999 999 551.1 5.8 3.94 0.12 890 43 1713 37 9261 259.3 6.3 82.6 1.5 5.14 0.50 74.91 1.21 99.64 0.68 9999 999 9999 999 533.3 5.3 3.73 0.11 680 18 9999 999 9636 234.5 4.2 77.3 1.4 2.39 0.43 70.10 1.12 86.88 0.61 9999 999 9999 999 486.5 4.3 2.99 0.09 788 25 1568 34 9761 243.6 4.8 79.3 1.4 3.29 0.45 71.60 1.15 90.42 0.62 9999 999 9999 999 500.7 4.6 3.17 0.09 723 20 9999 999 9886 234.4 4.2 77.3 1.4 2.11 0.43 69.28 1.11 85.86 0.60 9999 999 9999 999 488.2 4.3 2.95 0.09 691 19 1608 35 10011 214.0 3.2 73.0 1.3 1.04 0.42 63.21 1.00 75.83 0.55 9999 999 9999 999 458.0 3.8 2.61 0.08 688 19 1525 34 10261 194.7 2.5 68.6 1.2 1.04 0.42 57.84 0.91 66.37 0.51 9999 999 9999 999 430.5 3.4 2.27 0.07 689 19 1499 33 10386 179.9 2.2 65.2 1.1 0.54 0.41 52.93 0.83 60.38 0.49 258.5 2.4 3.13 0.12 411.3 3.1 2.03 0.06 688 19 1456 33 10511 170.3 2.0 63.1 1.1 0.43 0.41 49.05 0.78 55.06 0.47 9999 999 9999 999 399.6 2.9 1.80 0.06 670 18 1447 32 10636 175.3 2.1 64.8 1.1 0.48 0.41 51.31 0.81 57.35 0.48 255.0 2.4 3.13 0.12 406.5 3.0 1.86 0.06 629 17 1461 33 10886 147.3 1.6 58.5 1.0 0.25 0.41 43.64 0.71 45.97 0.45 232.3 2.3 3.01 0.12 366.6 2.6 1.47 0.06 618 17 1370 31 11011 138.3 1.4 56.6 0.9 0.34 0.41 9999 999 41.91 0.44 9999 999 9999 999 355.6 2.5 1.31 0.05 656 17 1346 31 11136 129.0 1.3 54.3 0.9 0.06 0.41 38.31 0.64 38.46 0.44 218.8 2.3 2.95 0.11 342.8 2.3 1.25 0.05 680 18 1295 30 11261 130.5 1.3 54.9 0.9 0.37 0.41 38.41 0.65 39.11 0.44 9999 999 9999 999 345.0 2.4 1.27 0.05 630 17 1338 31 11511 129.4 1.3 54.6 0.9 0.21 0.41 38.30 0.64 38.84 0.44 9999 999 9999 999 343.4 2.3 1.22 0.05 634 17 1355 31 11636 130.9 1.3 54.9 0.9 0.75 0.41 38.59 0.65 39.52 0.44 220.7 2.3 2.98 0.11 346.0 2.4 1.26 0.05 614 17 1366 31 11761 131.5 1.3 55.0 0.9 0.68 0.41 38.44 0.65 39.62 0.44 9999 999 9999 999 345.8 2.4 1.24 0.05 618 17 1347 31 12136 137.4 1.4 56.4 0.9 0.78 0.41 39.99 0.66 41.65 0.44 225.8 2.3 3.00 0.11 355.5 2.5 1.30 0.05 621 17 1345 31 12261 135.8 1.4 55.9 0.9 0.31 0.41 39.60 0.66 40.78 0.44 9999 999 9999 999 355.4 2.5 1.31 0.05 644 17 1386 32 12386 137.8 1.4 56.3 0.9 0.94 0.42 39.88 0.66 41.72 0.44 226.1 2.3 2.99 0.11 355.2 2.5 1.30 0.05 569 16 1374 31 12511 140.0 1.4 56.8 0.9 0.48 0.41 40.29 0.67 42.46 0.44 9999 999 9999 999 358.1 2.5 1.33 0.05 656 18 1365 31 12761 137.7 1.4 56.4 0.9 0.53 0.41 39.91 0.66 41.75 0.44 9999 999 9999 999 356.4 2.5 1.30 0.05 583 16 1355 31 12886 134.3 1.4 55.7 0.9 0.57 0.41 38.99 0.65 40.75 0.44 223.2 2.3 2.86 0.11 349.7 2.4 1.25 0.05 585 16 1343 31 13011 127.4 1.3 54.0 0.9 0.44 0.41 36.53 0.62 38.06 0.44 9999 999 9999 999 341.1 2.3 1.18 0.05 628 17 1316 31 13386 128.5 1.3 54.3 0.9 0.28 0.41 37.26 0.63 38.18 0.44 217.7 2.3 2.95 0.11 343.9 2.3 1.22 0.05 559 16 1321 31 13511 135.1 1.4 55.8 0.9 0.45 0.41 38.91 0.65 40.64 0.44 9999 999 9999 999 353.1 2.4 1.32 0.05 586 16 1376 31 13636 138.2 1.4 56.3 0.9 0.55 0.41 40.06 0.66 41.70 0.44 224.9 2.3 2.97 0.11 358.1 2.5 1.34 0.05 574 16 1382 31 13761 135.2 1.4 55.7 0.9 0.52 0.41 39.03 0.65 40.64 0.44 9999 999 9999 999 350.9 2.4 1.28 0.05 601 16 1338 31 14011 121.6 1.2 52.6 0.9 0.55 0.41 35.03 0.61 35.38 0.43 9999 999 9999 999 336.5 2.3 1.14 0.05 598 16 1320 31 14261 124.7 1.3 53.3 0.9 0.26 0.41 35.76 0.62 36.73 0.43 9999 999 9999 999 338.6 2.3 1.19 0.05 595 16 1325 31 14386 126.0 1.3 53.6 0.9 0.41 0.41 36.28 0.62 37.46 0.43 216.8 2.3 2.96 0.11 339.8 2.3 1.20 0.05 578 16 1347 31 14636 127.9 1.3 54.0 0.9 0.36 0.41 37.08 0.63 38.35 0.44 217.7 2.3 2.88 0.11 340.9 2.3 1.20 0.05 540 15 1341 31 14761 129.9 1.3 54.7 0.9 0.23 0.41 37.50 0.63 39.14 0.44 9999 999 9999 999 345.4 2.4 1.23 0.05 577 16 1316 31 14886 131.4 1.3 54.9 0.9 0.22 0.41 37.82 0.64 39.78 0.44 221.3 2.3 3.01 0.11 347.6 2.4 1.24 0.05 559 16 1348 31 15011 122.7 1.2 53.2 0.9 0.27 0.41 35.45 0.61 36.48 0.43 9999 999 9999 999 335.3 2.3 1.16 0.05 555 16 1313 30 15261 132.1 1.3 55.2 0.9 0.45 0.41 38.04 0.64 39.85 0.44 9999 999 9999 999 348.2 2.4 1.24 0.05 543 16 1332 31 15386 134.1 1.4 55.9 0.9 0.17 0.41 38.52 0.65 40.54 0.44 222.6 2.3 2.97 0.11 349.6 2.4 1.24 0.05 545 16 1329 31 15511 142.4 1.5 57.9 1.0 0.30 0.41 40.89 0.67 43.43 0.45 9999 999 9999 999 362.2 2.5 1.37 0.05 556 16 1361 31 15636 139.0 1.4 56.9 0.9 0.51 0.41 39.94 0.66 42.11 0.44 226.2 2.3 2.94 0.11 357.7 2.5 1.29 0.05 577 16 1357 31 15886 129.5 1.3 54.6 0.9 0.31 0.41 37.50 0.64 38.69 0.44 218.5 2.3 2.84 0.10 343.6 2.3 1.19 0.05 538 15 1311 30 16011 132.4 1.4 55.4 0.9 0.32 0.41 38.11 0.64 39.54 0.44 9999 999 9999 999 346.1 2.4 1.24 0.05 585 16 1322 31 16136 128.9 1.3 54.5 0.9 0.54 0.41 37.20 0.63 38.49 0.44 219.0 2.3 2.87 0.11 340.1 2.3 1.18 0.05 570 16 1340 31 16511 131.8 1.3 54.9 0.9 0.52 0.41 38.05 0.64 39.81 0.44 9999 999 9999 999 347.4 2.4 1.28 0.05 571 16 1341 31 16636 130.9 1.3 54.7 0.9 0.33 0.41 38.04 0.64 39.67 0.44 219.8 2.3 2.79 0.10 344.7 2.4 1.24 0.05 549 16 1317 31 16761 129.5 1.3 54.5 0.9 0.30 0.41 37.47 0.63 38.98 0.44 9999 999 9999 999 343.7 2.3 1.25 0.05 591 16 1317 31 16886 120.0 1.2 52.2 0.9 0.33 0.41 34.73 0.61 35.77 0.43 212.8 2.3 2.86 0.11 331.4 2.2 1.13 0.05 618 17 1298 30 17136 131.4 1.3 54.8 0.9 0.37 0.41 38.25 0.64 39.83 0.44 221.1 2.3 2.93 0.11 346.1 2.4 1.24 0.05 578 16 1335 31 17261 128.0 1.3 54.1 0.9 0.18 0.41 36.79 0.63 38.40 0.44 9999 999 9999 999 341.6 2.3 1.19 0.05 595 16 1311 30 17386 125.2 1.3 53.4 0.9 0.43 0.41 35.62 0.61 37.17 0.43 215.4 2.3 2.89 0.11 338.1 2.3 1.21 0.05 555 16 1284 30 17511 124.8 1.3 53.3 0.9 0.32 0.41 35.68 0.62 36.73 0.43 9999 999 9999 999 338.6 2.3 1.16 0.05 579 16 1299 30 17761 127.1 1.3 53.7 0.9 0.38 0.41 36.25 0.62 37.50 0.43 9999 999 9999 999 340.3 2.3 1.20 0.05 590 16 1297 30 17886 125.6 1.3 53.3 0.9 0.16 0.41 35.86 0.62 37.12 0.43 216.4 2.3 2.91 0.11 338.6 2.3 1.14 0.05 571 16 1305 30 18011 126.5 1.3 53.6 0.9 0.35 0.41 36.25 0.62 37.45 0.43 9999 999 9999 999 338.1 2.3 1.16 0.05 588 16 1301 30 18136 132.3 1.3 54.8 0.9 0.60 0.41 37.68 0.64 39.72 0.44 221.1 2.3 2.87 0.11 347.4 2.4 1.28 0.05 576 16 1319 31 18386 133.3 1.4 55.1 0.9 0.71 0.41 37.97 0.64 40.39 0.44 221.5 2.3 2.99 0.11 351.0 2.4 1.29 0.05 589 16 1342 31 18511 132.2 1.3 54.9 0.9 0.43 0.41 37.94 0.64 40.28 0.44 9999 999 9999 999 347.5 2.4 1.26 0.05 568 16 1295 30 18636 125.9 1.3 53.4 0.9 0.48 0.41 36.25 0.62 37.67 0.44 216.4 2.3 2.83 0.10 338.3 2.3 1.18 0.05 558 16 1290 30 18761 126.0 1.3 53.4 0.9 0.50 0.41 36.34 0.62 37.54 0.44 9999 999 9999 999 337.7 2.3 1.18 0.05 600 16 1295 30 19011 124.0 1.3 52.8 0.9 0.27 0.41 35.19 0.61 36.83 0.43 9999 999 9999 999 339.0 2.3 1.15 0.05 658 18 1303 30 19136 126.2 1.3 53.4 0.9 0.41 0.41 36.21 0.62 37.75 0.44 216.0 2.3 2.90 0.11 339.8 2.3 1.21 0.05 606 16 1296 30 19261 127.2 1.3 53.6 0.9 0.32 0.41 36.31 0.62 37.67 0.44 9999 999 9999 999 341.4 2.3 1.22 0.05 542 16 1308 30 19386 136.4 1.4 55.7 0.9 0.44 0.41 39.07 0.65 41.27 0.44 223.2 2.3 2.85 0.11 353.1 2.4 1.29 0.05 619 17 1334 31 19636 119.1 1.2 51.5 0.8 0.34 0.41 34.30 0.60 34.92 0.43 211.6 2.3 2.87 0.11 328.4 2.2 1.12 0.05 624 17 1285 30 19761 117.1 1.2 51.4 0.8 0.21 0.41 33.55 0.59 33.86 0.43 9999 999 9999 999 327.9 2.2 0.99 0.05 634 17 1271 30 19886 110.2 1.1 49.6 0.8 0.42 0.41 31.42 0.57 31.67 0.43 204.7 2.2 2.85 0.11 318.2 2.1 0.98 0.05 560 16 1269 30 20261 124.3 1.3 52.6 0.9 0.56 0.41 35.72 0.62 37.04 0.43 9999 999 9999 999 337.6 2.3 1.20 0.05 605 16 1337 31 20386 134.1 1.4 54.7 0.9 0.79 0.41 38.23 0.64 40.77 0.44 223.5 2.3 2.94 0.11 350.0 2.4 1.24 0.05 588 16 1335 31 20511 131.9 1.3 54.3 0.9 0.96 0.42 37.53 0.64 40.23 0.44 9999 999 9999 999 347.7 2.4 1.28 0.05 584 16 1352 31 20636 125.5 1.3 52.8 0.9 0.71 0.41 35.82 0.62 37.67 0.44 217.8 2.3 2.87 0.11 338.8 2.3 1.23 0.05 567 16 1319 31 20886 120.7 1.2 51.8 0.8 0.76 0.41 34.60 0.60 35.70 0.43 212.5 2.3 2.93 0.11 332.4 2.2 1.04 0.05 536 15 1303 30 21011 123.8 1.3 52.5 0.9 0.69 0.41 35.15 0.61 36.55 0.43 9999 999 9999 999 337.6 2.3 1.14 0.05 586 16 1305 30 21136 124.2 1.3 52.5 0.9 0.52 0.41 35.34 0.61 36.97 0.43 214.9 2.3 2.94 0.11 336.5 2.3 1.11 0.05 623 17 1315 31 21261 127.7 1.3 53.5 0.9 0.47 0.41 36.33 0.62 37.88 0.44 9999 999 9999 999 342.9 2.3 1.14 0.05 581 16 1322 31 21511 133.2 1.4 54.3 0.9 0.89 0.42 37.73 0.64 40.01 0.44 9999 999 9999 999 348.5 2.4 1.28 0.05 606 16 1319 31 21636 129.8 1.3 53.5 0.9 0.85 0.42 36.56 0.62 39.03 0.44 218.8 2.3 2.99 0.11 343.4 2.3 1.13 0.05 631 17 1281 30 21761 166.9 1.9 62.0 1.0 0.90 0.42 47.34 0.76 53.54 0.47 9999 999 9999 999 398.1 2.9 1.79 0.06 594 16 1439 32 21886 173.7 2.0 62.9 1.0 0.98 0.42 49.73 0.79 57.08 0.48 247.5 2.4 3.18 0.13 403.0 3.0 1.95 0.06 602 16 1484 33 22136 217.3 3.3 72.9 1.3 2.05 0.43 63.21 1.00 78.46 0.56 279.6 2.6 3.42 0.14 466.6 3.9 2.68 0.08 586 16 1658 36 22261 240.0 4.6 77.8 1.4 2.88 0.44 69.44 1.11 90.61 0.63 9999 999 9999 999 498.5 4.5 3.21 0.09 579 16 1680 36 22386 233.4 4.1 76.2 1.3 2.10 0.43 68.14 1.08 86.94 0.61 292.1 2.6 3.57 0.16 489.8 4.4 3.18 0.09 595 16 1683 36 22511 247.5 5.1 79.4 1.4 2.53 0.44 71.50 1.15 94.53 0.65 9999 999 9999 999 509.9 4.8 3.44 0.10 547 16 1653 36