42 1001 ELKINS, JAMES; WAMSLEY, PAULA; DUTTON, GEOFF; ROMASHKIN, PAVEL; HURST, DALE; DUNN, RAY U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS IV, ER-2 POLARIS 1 1 1997 06 30 1998 09 09 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 22 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CHCL3 MIXING RATIO (PPT) CHCL3 ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 5 Methyl chloroform and CFC-11 are re-calculated to remove minor contamination from the pump. Time is corrected for pump delay using O3 data by Proffitt et al. CFC-11 uses Poly4 calibration curves for the mixing ratios but Poly3 curve for standard deviations. Therefore, CFC-11 std. deviation provided may be exaggerated for some tropospheric data points. For this flight time is adjusted by subtracting (17) sec. 1 GMTs F11 F11e F113 F113e CHCl3 CHCl3e MC MCe CT CTe N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e 72344 276.0 999 85.1 1.8 8.32 0.56 78.17 1.65 101.84 0.92 9999 999 9999 999 9999 999 4.16 0.10 9999 999 9999 999 72469 275.4 999 85.4 1.9 7.11 0.47 77.55 1.64 102.04 0.92 9999 999 9999 999 9999 999 4.00 0.10 9999 999 9999 999 72594 276.2 999 85.4 1.9 7.13 0.47 77.70 1.64 103.10 0.93 9999 999 9999 999 9999 999 4.07 0.10 9999 999 9999 999 72969 274.5 71.2 84.7 1.8 7.89 0.53 79.49 1.68 103.83 0.93 327.5 3.2 9999 999 542.7 9.1 4.07 0.10 789 36 1774 25 73094 276.3 999 84.7 1.8 7.86 0.52 79.29 1.68 104.18 0.94 9999 999 9999 999 543.3 9.1 4.01 0.10 561 21 1775 25 73219 276.7 999 85.1 1.8 7.78 0.52 78.99 1.67 103.93 0.94 324.4 3.2 9999 999 542.0 9.1 4.00 0.10 601 22 1759 25 73344 277.1 999 85.2 1.9 8.06 0.54 79.27 1.68 103.86 0.93 9999 999 9999 999 540.7 9.0 4.02 0.10 9999 999 1777 25 73594 277.6 999 85.3 1.9 7.92 0.53 79.75 1.69 103.74 0.93 9999 999 9999 999 541.6 9.1 4.05 0.10 719 28 1762 25 73719 276.2 999 84.7 1.8 7.12 0.47 78.78 1.67 103.14 0.93 319.7 3.2 4.61 0.75 542.2 9.1 3.98 0.10 668 24 1758 25 73844 276.8 999 85.0 1.8 7.80 0.52 79.33 1.68 103.18 0.93 9999 999 9999 999 542.7 9.1 4.07 0.10 9999 999 1761 25 73969 275.0 40.9 85.1 1.8 7.76 0.52 78.71 1.66 102.57 0.93 318.1 3.2 4.69 0.82 542.9 9.1 4.00 0.10 749 31 1770 25 74219 272.3 40.7 84.2 1.8 7.80 0.52 78.14 1.65 102.14 0.92 318.1 3.2 4.61 0.75 541.2 9.1 4.13 0.10 870 60 1803 25 74344 273.3 49.2 84.6 1.8 7.80 0.52 78.50 1.66 102.00 0.92 9999 999 9999 999 541.5 9.1 4.09 0.10 686 25 1764 25 74469 267.0 23.1 83.2 1.8 5.97 0.40 76.37 1.61 99.65 0.91 312.2 3.1 4.18 0.52 524.9 8.6 3.92 0.09 675 25 1746 25 74594 247.1 10.8 79.6 1.7 2.47 0.29 71.66 1.49 92.01 0.86 9999 999 9999 999 499.7 7.9 3.40 0.08 640 23 1660 24 74844 246.8 10.8 79.4 1.7 2.74 0.30 71.52 1.49 92.61 0.87 9999 999 9999 999 497.2 7.8 3.34 0.08 580 21 1662 24 74969 246.1 10.6 79.3 1.7 2.79 0.30 71.57 1.49 92.42 0.87 300.8 3.0 3.61 0.34 499.9 7.9 3.32 0.08 794 37 1671 24 75094 243.6 10.0 78.9 1.7 2.66 0.30 71.23 1.49 91.04 0.86 9999 999 9999 999 494.6 7.7 3.19 0.08 608 22 1674 24 75469 244.1 10.1 78.9 1.7 2.34 0.29 70.91 1.48 91.01 0.86 298.6 3.0 3.54 0.32 494.2 7.7 3.17 0.08 543 20 1656 24 75594 244.0 10.1 78.8 1.7 2.43 0.29 70.93 1.48 91.36 0.86 9999 999 9999 999 494.9 7.7 3.26 0.08 555 20 1676 24 75719 244.4 10.2 78.9 1.7 2.46 0.29 70.55 1.47 91.17 0.86 298.8 3.0 3.66 0.35 499.3 7.8 3.24 0.08 668 24 1661 24 75844 242.8 9.8 78.5 1.7 2.39 0.29 69.85 1.45 89.92 0.85 9999 999 9999 999 494.8 7.7 3.21 0.08 554 20 1659 24 76094 246.9 10.8 79.2 1.7 2.89 0.30 71.44 1.49 91.46 0.86 9999 999 9999 999 505.5 8.0 3.29 0.08 556 21 1701 24 76219 238.3 8.9 77.8 1.7 2.16 0.29 69.68 1.45 88.38 0.85 296.4 3.0 3.74 0.37 489.0 7.6 3.10 0.08 521 20 1633 23 76344 242.6 9.7 78.7 1.7 2.42 0.29 70.58 1.47 90.15 0.85 9999 999 9999 999 500.4 7.9 3.20 0.08 536 20 1642 23 76719 225.5 7.1 75.3 1.6 1.98 0.28 65.24 1.36 83.17 0.82 288.1 2.9 3.53 0.32 490.6 7.6 2.98 0.07 599 22 1618 23 76844 227.6 7.3 75.8 1.6 1.81 0.28 66.05 1.37 83.84 0.82 9999 999 9999 999 490.2 7.6 2.70 0.07 604 22 1603 23 76969 217.9 6.3 73.9 1.6 1.84 0.28 63.13 1.31 80.16 0.81 283.6 2.9 3.51 0.31 457.3 6.9 2.56 0.07 607 22 1591 23 77094 226.1 7.1 75.4 1.6 1.74 0.28 65.43 1.36 83.48 0.82 9999 999 9999 999 469.2 7.1 2.78 0.07 599 22 1606 23 77344 220.6 6.5 74.3 1.6 1.90 0.28 63.87 1.33 80.98 0.81 9999 999 9999 999 463.4 7.0 2.89 0.07 573 21 1601 23 77594 228.4 7.4 75.9 1.6 2.09 0.29 65.66 1.36 84.19 0.83 9999 999 9999 999 475.7 7.3 2.96 0.07 588 21 1631 23 77719 219.8 6.4 74.2 1.6 1.69 0.28 63.52 1.32 80.78 0.81 283.6 2.9 3.43 0.30 462.6 7.0 2.81 0.07 556 21 1612 23 77969 235.5 8.4 77.3 1.6 2.08 0.29 67.96 1.41 87.09 0.84 294.0 3.0 3.56 0.32 485.4 7.5 3.02 0.07 641 23 1617 23 78094 222.9 6.8 75.0 1.6 2.01 0.28 64.77 1.35 82.06 0.82 9999 999 9999 999 465.8 7.0 2.74 0.07 623 22 1601 23 78219 214.1 5.9 73.2 1.5 1.85 0.28 63.04 1.31 79.30 0.80 281.8 2.9 3.39 0.29 458.3 6.9 2.68 0.07 656 24 1599 23 78344 216.7 6.1 73.8 1.6 1.70 0.28 63.31 1.32 79.85 0.81 9999 999 9999 999 463.8 7.0 2.69 0.07 639 23 1587 23 78594 198.9 4.8 70.3 1.5 1.48 0.28 58.58 1.23 72.83 0.78 9999 999 9999 999 438.3 6.5 2.35 0.06 600 22 1535 22 78719 186.6 4.1 68.0 1.4 1.40 0.28 55.24 1.17 67.47 0.76 262.6 2.7 3.25 0.26 424.6 6.2 2.20 0.06 604 22 1506 22 78844 158.7 3.0 62.2 1.3 1.07 0.27 46.97 1.04 56.32 0.73 9999 999 9999 999 388.1 5.6 1.79 0.06 570 21 1444 21 78969 155.1 2.9 61.4 1.3 0.97 0.27 45.42 1.01 54.48 0.72 240.1 2.6 3.01 0.22 383.2 5.5 1.77 0.06 577 21 1426 21 79219 154.1 2.9 61.0 1.3 0.89 0.27 45.40 1.01 54.53 0.72 240.3 2.6 2.97 0.21 382.4 5.5 1.75 0.06 649 23 1427 21 79344 154.8 2.9 61.3 1.3 0.94 0.27 45.60 1.02 54.75 0.72 9999 999 9999 999 382.6 5.5 1.77 0.06 577 21 1427 21 79469 155.6 2.9 61.4 1.3 1.03 0.27 45.91 1.02 55.10 0.72 241.2 2.6 2.99 0.22 384.9 5.5 1.78 0.06 598 22 1442 21 79844 158.7 3.0 61.9 1.3 1.14 0.27 46.89 1.04 55.79 0.73 9999 999 9999 999 388.4 5.6 1.80 0.06 595 21 1422 21 79969 154.1 2.9 60.7 1.3 1.08 0.27 45.20 1.01 54.52 0.72 241.3 2.6 3.00 0.22 381.1 5.5 1.75 0.06 632 23 1425 21 80094 153.8 2.9 60.6 1.3 1.15 0.27 45.16 1.01 54.18 0.72 9999 999 9999 999 381.9 5.5 1.72 0.06 636 23 1423 21 80219 149.4 2.7 59.5 1.3 1.15 0.27 44.30 1.00 52.48 0.72 237.8 2.6 2.89 0.20 375.4 5.4 1.68 0.06 617 22 1409 21 80469 156.0 2.9 61.1 1.3 1.09 0.27 45.66 1.02 54.70 0.72 241.9 2.6 2.99 0.22 384.6 5.5 1.79 0.06 644 23 1419 21 80594 151.9 2.8 59.8 1.3 1.18 0.27 44.51 1.00 53.40 0.72 9999 999 9999 999 378.8 5.5 1.75 0.06 596 21 1415 21 80719 2.5 1.0 9999 999 9999 999 25.95 0.80 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 80844 160.4 3.1 62.9 1.3 1.24 0.27 47.23 1.04 55.96 0.73 9999 999 9999 999 394.2 5.7 1.76 0.06 576 21 1433 21 81094 173.0 3.5 66.9 1.4 1.50 0.28 50.33 1.09 59.71 0.74 9999 999 9999 999 419.1 6.1 1.86 0.06 618 22 1486 22 81219 173.4 3.5 67.0 1.4 1.43 0.28 52.22 1.12 59.93 0.74 260.6 2.7 3.16 0.24 417.9 6.1 1.83 0.06 602 22 1507 22 81344 172.5 3.5 66.7 1.4 1.28 0.27 50.37 1.09 59.17 0.73 9999 999 9999 999 417.5 6.1 1.86 0.06 600 22 1495 22 81469 173.0 3.5 66.8 1.4 1.29 0.27 50.61 1.09 59.68 0.74 260.7 2.7 3.11 0.24 419.3 6.1 1.86 0.06 591 21 1510 22 81719 174.0 3.6 66.9 1.4 1.40 0.28 50.68 1.09 60.79 0.74 261.2 2.7 3.15 0.24 419.7 6.1 1.83 0.06 598 22 1508 22 81844 173.1 3.5 66.8 1.4 1.41 0.28 51.13 1.10 60.28 0.74 9999 999 9999 999 419.4 6.1 1.81 0.06 580 21 1501 22 81969 172.0 3.5 66.6 1.4 1.39 0.28 50.46 1.09 59.62 0.74 259.3 2.7 3.09 0.23 417.4 6.1 1.80 0.06 581 21 1493 22 82094 170.5 3.4 66.3 1.4 1.54 0.28 50.08 1.08 58.89 0.73 9999 999 9999 999 416.8 6.1 1.83 0.06 575 21 1489 22 82344 162.8 3.1 64.2 1.3 1.42 0.28 47.56 1.05 55.47 0.72 9999 999 9999 999 406.4 5.9 1.76 0.06 557 21 1460 21 82469 162.1 3.1 64.0 1.3 1.32 0.28 47.48 1.04 55.56 0.72 252.0 2.7 3.13 0.24 403.9 5.8 1.72 0.06 527 20 1448 21 82594 161.6 3.1 63.9 1.3 1.53 0.28 47.09 1.04 55.14 0.72 9999 999 9999 999 406.0 5.9 1.75 0.06 540 20 1457 21 82719 167.7 3.3 65.4 1.4 1.49 0.28 48.95 1.07 57.32 0.73 257.8 2.7 3.16 0.24 411.0 6.0 1.76 0.06 567 21 1486 22 82969 170.0 3.4 66.1 1.4 1.40 0.28 49.33 1.07 57.70 0.73 259.0 2.7 3.11 0.24 413.9 6.0 1.83 0.06 564 21 1497 22 83094 159.3 3.0 63.8 1.3 1.39 0.28 46.56 1.03 53.77 0.72 9999 999 9999 999 399.6 5.8 1.72 0.06 522 20 1445 21 83219 115.7 2.0 53.5 1.1 1.25 0.27 33.44 0.87 37.73 0.69 219.9 2.5 2.82 0.19 339.2 4.9 1.18 0.05 541 20 1357 20 83594 64.4 1.3 38.8 0.9 1.12 0.27 19.10 0.75 20.00 0.67 9999 999 9999 999 255.6 4.1 0.71 0.05 556 21 1136 18 83719 65.4 1.3 39.5 0.9 1.09 0.27 19.10 0.75 20.12 0.67 173.8 2.4 2.63 0.17 259.1 4.1 0.71 0.05 568 21 1138 18 83844 63.8 1.3 38.9 0.9 1.20 0.27 18.44 0.75 19.77 0.67 9999 999 9999 999 254.6 4.1 0.69 0.05 591 21 1128 18 83969 28.0 1.1 21.6 0.7 1.08 0.27 8.93 0.71 9.36 0.67 110.6 2.2 2.39 0.14 153.8 3.5 0.45 0.05 562 21 873 16 84219 9.3 1.0 10.5 0.7 0.95 0.27 3.55 0.70 3.44 0.67 72.5 2.2 2.36 0.14 89.4 3.2 0.29 0.05 520 20 746 16 84344 12.5 1.0 12.4 0.7 1.09 0.27 4.75 0.70 4.53 0.67 9999 999 9999 999 96.3 3.2 0.32 0.05 531 20 728 16 84469 14.1 1.0 13.4 0.7 1.06 0.27 5.18 0.70 5.06 0.67 81.4 2.2 2.35 0.14 100.0 3.2 0.33 0.05 518 20 737 16 84594 15.6 1.0 14.4 0.7 0.99 0.27 5.50 0.70 5.44 0.67 9999 999 9999 999 112.1 3.3 0.31 0.05 544 20 770 16 84844 30.6 1.1 22.6 0.7 1.24 0.27 9.84 0.71 10.01 0.67 9999 999 9999 999 157.2 3.5 0.43 0.05 529 20 886 17 84969 34.6 1.1 24.4 0.8 1.24 0.27 10.79 0.71 11.26 0.67 118.0 2.2 2.44 0.15 167.4 3.5 0.46 0.05 543 20 894 17 85094 36.3 1.1 25.5 0.8 1.54 0.28 11.36 0.72 11.67 0.67 9999 999 9999 999 170.5 3.5 0.44 0.05 570 21 904 17 85219 42.2 1.2 28.4 0.8 1.23 0.27 13.02 0.72 13.39 0.67 131.7 2.3 2.48 0.15 191.7 3.7 0.52 0.05 512 20 965 17 85469 46.9 1.2 30.9 0.8 1.26 0.27 14.19 0.73 14.58 0.67 140.9 2.3 2.45 0.15 205.0 3.7 0.54 0.05 544 20 995 17 85594 20.8 1.1 17.1 0.7 1.09 0.27 7.18 0.70 7.18 0.67 9999 999 9999 999 123.5 3.3 0.37 0.05 515 20 802 16 85719 28.5 1.1 21.1 0.7 1.00 0.27 9.13 0.71 9.51 0.67 108.3 2.2 2.44 0.15 147.4 3.4 0.41 0.05 520 20 871 16 85844 28.4 1.1 21.2 0.7 1.40 0.28 9.16 0.71 9.47 0.67 9999 999 9999 999 149.7 3.4 0.43 0.05 529 20 880 17 86094 17.2 1.0 14.9 0.7 1.47 0.28 6.29 0.70 6.23 0.67 9999 999 9999 999 108.2 3.3 0.34 0.05 515 20 779 16 86219 39.8 1.1 26.2 0.8 1.31 0.27 11.86 0.72 12.79 0.67 120.3 2.2 2.43 0.15 193.5 3.7 0.55 0.05 559 21 1029 17 86344 123.6 2.1 55.2 1.2 1.53 0.28 36.07 0.90 40.56 0.70 9999 999 9999 999 350.5 5.1 1.23 0.05 567 21 1333 20 86469 172.3 3.5 66.3 1.4 1.71 0.28 50.52 1.09 59.44 0.73 256.4 2.7 3.14 0.24 418.2 6.1 1.91 0.06 549 20 1487 22 86719 146.0 2.6 58.0 1.2 1.56 0.28 42.93 0.98 50.83 0.71 234.2 2.6 2.93 0.21 369.1 5.3 1.66 0.06 592 21 1392 21 86844 189.7 4.3 67.9 1.4 2.01 0.28 55.55 1.17 68.98 0.76 9999 999 9999 999 430.2 6.3 2.30 0.06 594 21 1506 22 86969 216.3 6.1 73.5 1.6 2.41 0.29 62.52 1.30 80.11 0.81 278.5 2.8 3.45 0.30 467.4 7.1 2.74 0.07 592 21 1566 22 87344 269.2 27.6 84.4 1.8 7.99 0.53 77.15 1.63 102.28 0.92 9999 999 9999 999 533.7 8.8 3.82 0.09 549 20 1751 25 87469 265.1 20.6 83.9 1.8 7.45 0.49 76.06 1.60 102.05 0.92 323.1 3.2 4.22 0.54 526.0 8.6 3.94 0.10 527 20 1750 25