42 1001 ELKINS, JAMES; WAMSLEY, PAULA; DUTTON, GEOFF; ROMASHKIN, PAVEL; HURST, DALE; DUNN, RAY U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS IV, ER-2 POLARIS 1 1 1997 05 11 1998 09 09 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 22 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CHCL3 MIXING RATIO (PPT) CHCL3 ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 5 Methyl chloroform and CFC-11 are re-calculated to remove minor contamination from the pump. Time is corrected for pump delay using O3 data by Proffitt et al. CFC-11 uses Poly4 calibration curves for the mixing ratios but Poly3 curve for standard deviations. Therefore, CFC-11 std. deviation provided may be exaggerated for some tropospheric data points. For this flight time is adjusted by subtracting (31) sec. 1 GMTs F11 F11e F113 F113e CHCl3 CHCl3e MC MCe CT CTe N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e 72284 243.9 2.6 81.0 1.2 5.10 0.42 77.17 0.89 99.65 0.83 9999 999 9999 999 499.8 6.8 3.70 0.15 9999 999 9999 999 72409 240.8 2.5 79.6 1.1 4.65 0.42 74.66 0.87 94.67 0.80 9999 999 9999 999 491.5 6.7 3.44 0.14 9999 999 9999 999 72534 234.6 2.4 77.9 1.1 3.38 0.41 72.51 0.85 90.11 0.77 9999 999 9999 999 484.1 6.6 3.10 0.13 9999 999 9999 999 72909 242.7 2.5 80.1 1.2 4.55 0.42 74.39 0.87 93.12 0.79 313.2 4.1 9999 999 505.2 6.8 3.33 0.14 9999 999 9999 999 73034 245.0 2.6 80.8 1.2 5.03 0.42 74.93 0.87 93.93 0.79 9999 999 9999 999 511.7 6.9 3.36 0.14 9999 999 9999 999 73159 245.0 2.6 80.6 1.2 4.79 0.42 74.32 0.87 93.43 0.79 308.7 4.0 9999 999 510.5 6.9 3.32 0.14 9999 999 9999 999 73284 243.5 2.5 80.2 1.2 4.25 0.42 73.98 0.87 92.09 0.78 9999 999 9999 999 507.5 6.8 3.29 0.14 9999 999 9999 999 73534 239.6 2.5 79.1 1.1 4.19 0.42 73.32 0.86 90.36 0.77 9999 999 9999 999 504.0 6.8 3.29 0.14 9999 999 1626 43 73659 235.7 2.4 78.1 1.1 3.52 0.42 72.47 0.85 89.44 0.77 296.3 3.9 3.57 0.19 483.4 6.6 3.09 0.13 665 24 1626 43 73784 238.1 2.4 78.9 1.1 3.71 0.42 72.48 0.85 90.40 0.77 9999 999 9999 999 501.0 6.8 3.20 0.13 940 42 1625 43 73909 239.7 2.5 79.4 1.1 4.96 0.42 73.79 0.86 93.10 0.79 300.2 3.9 3.60 0.19 492.2 6.7 3.37 0.14 688 25 1651 44 74159 247.1 2.6 81.5 1.2 6.95 0.44 76.06 0.88 97.96 0.82 304.4 4.0 3.73 0.20 506.2 6.8 3.61 0.15 678 25 1717 46 74284 247.6 2.6 81.4 1.2 6.43 0.43 75.63 0.88 96.89 0.81 9999 999 9999 999 516.1 6.9 3.49 0.14 835 30 1727 46 74409 249.8 2.7 82.0 1.2 6.97 0.44 76.13 0.89 98.96 0.82 306.7 4.0 3.88 0.22 515.3 6.9 3.64 0.15 695 25 1766 47 74534 249.7 2.7 82.1 1.2 7.49 0.45 76.12 0.88 98.36 0.82 9999 999 9999 999 515.9 6.9 3.66 0.15 835 30 1713 46 74784 251.5 2.7 82.4 1.2 7.55 0.45 76.59 0.89 99.89 0.83 9999 999 9999 999 515.0 6.9 3.59 0.15 700 25 1755 47 74909 252.0 2.8 82.5 1.2 7.30 0.44 76.35 0.89 98.90 0.82 307.1 4.0 3.85 0.22 526.0 7.0 3.61 0.15 9999 999 1741 46 75034 249.9 2.7 81.8 1.2 7.19 0.44 76.03 0.88 98.91 0.82 9999 999 9999 999 510.7 6.9 3.60 0.15 788 28 1740 46 75409 251.3 2.7 82.4 1.2 7.50 0.45 76.40 0.89 98.56 0.82 307.6 4.0 3.90 0.22 520.6 7.0 3.67 0.15 680 25 1734 46 75534 251.9 2.8 82.5 1.2 7.07 0.44 76.37 0.89 98.85 0.82 9999 999 9999 999 524.7 7.0 3.74 0.15 677 25 1736 46 75659 249.9 2.7 81.9 1.2 6.76 0.44 75.67 0.88 98.48 0.82 307.4 4.0 3.79 0.21 514.3 6.9 3.60 0.15 710 25 1742 46 75784 251.9 2.8 82.5 1.2 7.70 0.45 75.69 0.88 98.66 0.82 9999 999 9999 999 531.4 7.1 3.68 0.15 629 24 1726 46 76034 252.3 2.8 82.7 1.2 7.31 0.44 76.46 0.89 98.93 0.82 9999 999 9999 999 528.8 7.1 3.72 0.15 612 24 1760 47 76159 251.1 2.7 82.8 1.2 8.12 0.45 76.92 0.89 100.42 0.83 308.3 4.0 3.92 0.22 521.9 7.0 3.69 0.15 578 24 1776 47 76284 253.6 2.8 83.1 1.2 9.39 0.47 77.56 0.90 101.23 0.84 9999 999 9999 999 531.1 7.1 3.85 0.16 619 24 1775 47 76659 256.0 2.9 84.0 1.2 8.88 0.46 77.94 0.90 101.55 0.84 311.5 4.1 3.99 0.23 539.1 7.2 3.92 0.16 530 23 1766 47 76784 253.5 2.8 83.3 1.2 8.96 0.46 77.76 0.90 101.67 0.84 9999 999 9999 999 522.7 7.0 3.81 0.16 540 23 1782 47 76909 255.0 2.8 83.7 1.2 8.75 0.46 77.88 0.90 101.35 0.84 311.9 4.1 3.99 0.23 531.5 7.1 3.82 0.16 535 23 1812 48 77034 254.0 2.8 83.4 1.2 9.61 0.47 77.38 0.90 101.41 0.84 9999 999 9999 999 526.7 7.0 3.81 0.16 534 23 1754 47 77284 255.1 2.8 83.7 1.2 8.84 0.46 77.89 0.90 100.96 0.83 9999 999 9999 999 529.2 7.1 3.80 0.16 557 23 1759 47 77534 254.2 2.8 83.6 1.2 8.34 0.46 77.22 0.89 100.60 0.83 9999 999 9999 999 530.5 7.1 3.76 0.15 532 23 1743 46 77659 251.6 2.7 82.9 1.2 8.07 0.45 77.62 0.90 101.41 0.84 311.1 4.1 4.05 0.24 514.1 6.9 3.75 0.15 615 24 1728 46 77909 250.9 2.7 82.7 1.2 10.31 0.49 77.44 0.90 101.17 0.84 311.0 4.1 3.83 0.21 518.9 7.0 3.83 0.16 575 24 1753 47 78034 243.0 2.5 80.4 1.2 5.85 0.43 75.03 0.88 95.05 0.80 9999 999 9999 999 501.2 6.8 3.42 0.14 604 24 1708 45 78159 242.7 2.5 80.4 1.2 5.55 0.43 75.15 0.88 94.48 0.80 301.9 4.0 3.61 0.19 504.5 6.8 3.43 0.14 588 24 1674 45 78284 240.1 2.5 79.6 1.1 5.81 0.43 73.96 0.87 93.72 0.79 9999 999 9999 999 492.2 6.7 3.35 0.14 618 24 1668 44 78534 227.5 2.2 76.2 1.1 3.06 0.41 68.77 0.82 85.63 0.75 9999 999 9999 999 467.5 6.5 2.99 0.13 626 24 1599 43 78659 233.5 2.3 77.4 1.1 3.51 0.41 70.06 0.83 87.38 0.76 291.7 3.8 3.40 0.17 489.6 6.7 3.12 0.13 559 23 1632 43 78784 231.5 2.3 77.0 1.1 2.88 0.41 70.34 0.84 87.58 0.76 9999 999 9999 999 477.3 6.5 3.08 0.13 641 24 1592 42 78909 230.4 2.3 76.7 1.1 2.79 0.41 69.19 0.83 85.63 0.75 290.7 3.8 3.42 0.17 480.0 6.6 3.07 0.13 629 24 1655 44 79159 230.1 2.3 76.4 1.1 3.34 0.41 69.25 0.83 85.79 0.75 291.4 3.8 3.47 0.18 480.6 6.6 3.09 0.13 641 24 1619 43 79284 234.0 2.3 77.5 1.1 3.52 0.42 70.29 0.84 87.80 0.76 9999 999 9999 999 490.6 6.7 3.19 0.13 655 24 1629 43 79409 230.7 2.3 76.7 1.1 3.82 0.42 69.33 0.83 86.73 0.76 291.6 3.8 3.47 0.18 478.0 6.5 3.06 0.13 620 24 1605 43 79784 233.0 2.3 77.1 1.1 3.58 0.42 69.53 0.83 87.34 0.76 9999 999 9999 999 494.3 6.7 3.09 0.13 605 24 1600 43 79909 231.0 2.3 77.1 1.1 3.06 0.41 70.00 0.83 88.14 0.76 292.9 3.9 3.48 0.18 482.3 6.6 3.02 0.13 569 23 1633 43 80034 238.6 2.4 78.9 1.1 4.20 0.42 71.48 0.85 91.72 0.78 9999 999 9999 999 503.1 6.8 3.25 0.14 575 23 1648 44 80159 241.7 2.5 80.0 1.2 5.09 0.42 73.08 0.86 94.64 0.80 301.7 4.0 3.67 0.20 503.8 6.8 3.42 0.14 547 23 1681 45 80409 242.5 2.5 79.9 1.2 4.79 0.42 72.19 0.85 94.03 0.79 301.0 3.9 3.43 0.18 503.3 6.8 3.41 0.14 586 24 1675 45 80534 240.9 2.5 79.8 1.2 4.47 0.42 72.54 0.85 93.27 0.79 9999 999 9999 999 495.5 6.7 3.35 0.14 594 24 1646 44 80659 244.3 2.6 80.4 1.2 4.52 0.42 73.03 0.86 94.44 0.80 301.0 3.9 3.56 0.19 507.8 6.8 3.46 0.14 569 23 1634 43 80784 246.6 2.6 81.3 1.2 5.77 0.43 73.66 0.86 96.85 0.81 9999 999 9999 999 502.9 6.8 3.43 0.14 572 23 1671 44 81034 249.8 2.7 82.4 1.2 6.00 0.43 74.57 0.87 100.03 0.83 9999 999 9999 999 511.3 6.9 3.66 0.15 569 23 1687 45 81159 254.6 2.8 83.7 1.2 5.18 0.42 75.23 0.88 100.71 0.83 310.9 4.1 3.85 0.22 529.9 7.1 3.66 0.15 490 23 1648 44 81284 246.7 2.6 81.6 1.2 4.81 0.42 73.34 0.86 97.45 0.81 9999 999 9999 999 506.2 6.8 3.45 0.14 560 23 1717 46 81409 249.4 2.7 82.2 1.2 4.53 0.42 73.52 0.86 98.14 0.82 307.9 4.0 3.57 0.19 524.2 7.0 3.57 0.15 623 24 1722 46 81659 252.6 2.8 83.2 1.2 5.09 0.42 74.51 0.87 99.77 0.83 311.1 4.1 3.81 0.21 530.6 7.1 3.66 0.15 550 23 1731 46 81784 248.2 2.7 82.0 1.2 4.87 0.42 72.92 0.86 97.92 0.82 9999 999 9999 999 511.8 6.9 3.50 0.14 613 24 1708 45 81909 252.0 2.8 83.2 1.2 5.28 0.43 74.42 0.87 99.71 0.83 309.7 4.1 3.76 0.21 528.5 7.1 3.59 0.15 639 24 1718 46 82034 249.2 2.7 82.5 1.2 4.73 0.42 74.00 0.87 98.80 0.82 9999 999 9999 999 511.9 6.9 3.49 0.14 598 24 1678 45 82284 227.2 2.2 75.8 1.1 4.29 0.42 66.50 0.81 84.73 0.75 9999 999 9999 999 472.9 6.5 2.86 0.12 605 24 1609 43 82409 226.5 2.2 75.5 1.1 3.25 0.41 65.71 0.80 83.72 0.74 286.5 3.8 3.49 0.18 479.4 6.6 2.87 0.12 590 24 1599 43 82534 233.8 2.3 77.9 1.1 3.31 0.41 68.38 0.82 88.57 0.77 9999 999 9999 999 485.9 6.6 3.07 0.13 598 24 1633 43 82659 226.9 2.2 75.7 1.1 3.48 0.41 66.05 0.80 84.16 0.74 286.0 3.8 3.33 0.17 479.8 6.6 2.89 0.12 575 24 1603 43 82909 213.4 2.0 72.0 1.1 2.71 0.41 61.56 0.77 76.46 0.71 274.6 3.7 3.25 0.16 457.1 6.4 2.59 0.12 590 24 1550 41 83034 210.9 1.9 71.1 1.0 2.36 0.41 60.34 0.76 75.03 0.70 9999 999 9999 999 455.7 6.3 2.59 0.12 628 24 1563 42 83159 212.8 2.0 72.0 1.1 2.95 0.41 61.71 0.77 76.75 0.71 275.1 3.7 3.29 0.16 452.4 6.3 2.51 0.11 568 23 1520 41 83534 199.2 1.8 68.8 1.0 2.31 0.41 56.41 0.74 68.55 0.68 9999 999 9999 999 444.8 6.3 2.25 0.11 621 24 1516 41 83659 178.4 1.5 63.4 1.0 1.74 0.41 48.82 0.69 58.61 0.65 252.2 3.5 3.01 0.14 406.4 6.0 1.90 0.10 616 24 1433 39 83784 175.9 1.5 62.9 1.0 2.14 0.41 48.37 0.69 58.26 0.65 9999 999 9999 999 396.2 5.9 1.84 0.10 584 24 1466 39 83909 176.5 1.5 63.2 1.0 2.50 0.41 48.98 0.70 59.27 0.65 258.4 3.5 3.07 0.15 389.7 5.9 1.71 0.10 591 24 1427 38 84159 180.0 1.6 63.8 1.0 1.77 0.41 49.25 0.70 59.87 0.65 249.9 3.4 3.13 0.15 404.5 6.0 2.05 0.10 593 24 1504 40 84284 172.2 1.5 61.7 0.9 2.26 0.41 46.72 0.68 57.20 0.65 9999 999 9999 999 388.4 5.9 1.77 0.10 603 24 1408 38 84409 184.0 1.6 64.7 1.0 2.73 0.41 49.99 0.70 62.39 0.66 252.6 3.5 3.08 0.15 412.7 6.0 1.95 0.10 607 24 1464 39 84534 182.9 1.6 64.3 1.0 3.14 0.41 49.71 0.70 61.83 0.66 9999 999 9999 999 406.7 6.0 1.91 0.10 582 24 1473 39 84784 193.2 1.7 66.8 1.0 2.97 0.41 53.88 0.72 67.59 0.68 9999 999 9999 999 428.2 6.1 2.10 0.11 631 24 1498 40 84909 209.5 1.9 71.2 1.0 3.38 0.41 59.67 0.76 75.61 0.71 273.1 3.6 3.22 0.16 451.8 6.3 2.42 0.11 613 24 1534 41 85034 210.3 1.9 71.3 1.0 3.71 0.42 59.61 0.76 76.21 0.71 9999 999 9999 999 451.2 6.3 2.45 0.11 596 24 1552 41 85159 202.0 1.8 69.5 1.0 3.36 0.41 57.31 0.74 73.01 0.70 266.9 3.6 3.16 0.15 436.1 6.2 2.30 0.11 633 24 1517 41 85409 133.6 1.2 51.7 0.9 3.28 0.41 33.52 0.63 43.53 0.62 216.5 3.2 2.81 0.13 340.8 5.6 1.26 0.09 625 24 1321 36 85534 162.5 1.4 60.1 0.9 3.87 0.42 43.12 0.67 52.92 0.64 9999 999 9999 999 387.7 5.9 1.50 0.10 591 24 1429 38 85659 129.0 1.2 53.3 0.9 3.32 0.41 32.21 0.62 40.72 0.62 223.6 3.2 2.86 0.13 347.5 5.7 1.10 0.09 584 24 1345 37 85784 113.5 1.1 50.2 0.9 2.91 0.41 27.27 0.61 34.08 0.61 9999 999 9999 999 329.5 5.6 0.89 0.09 672 25 1295 35 86034 102.2 1.0 47.0 0.8 3.81 0.42 24.38 0.60 31.49 0.60 9999 999 9999 999 312.1 5.5 0.77 0.09 664 24 1284 35 86159 107.5 1.1 48.2 0.8 3.94 0.42 25.66 0.61 33.82 0.61 207.7 3.1 2.76 0.13 321.5 5.5 0.88 0.09 686 25 1294 35 86284 109.5 1.1 48.5 0.8 2.97 0.41 26.16 0.61 33.67 0.61 9999 999 9999 999 321.6 5.5 0.88 0.09 677 25 1297 36 86409 115.2 1.1 50.0 0.9 4.22 0.42 27.89 0.61 35.81 0.61 213.6 3.2 2.79 0.13 330.9 5.6 0.94 0.09 660 24 1294 35 86659 107.8 1.1 47.6 0.8 4.09 0.42 25.65 0.61 34.09 0.61 206.5 3.1 2.80 0.13 319.4 5.5 0.90 0.09 586 24 1293 35 86784 115.2 1.1 49.4 0.8 2.43 0.41 28.08 0.61 35.17 0.61 9999 999 9999 999 333.6 5.6 0.95 0.09 610 24 1354 37 86909 132.7 1.2 54.2 0.9 2.90 0.41 33.14 0.63 41.45 0.62 227.2 3.3 2.89 0.14 357.4 5.7 1.04 0.09 587 24 1376 37 87284 133.8 1.2 54.3 0.9 2.84 0.41 33.73 0.63 41.29 0.62 9999 999 9999 999 359.3 5.7 1.04 0.09 616 24 1370 37 87409 136.1 1.2 55.0 0.9 3.54 0.42 34.35 0.63 42.59 0.62 228.2 3.3 2.91 0.14 360.1 5.7 1.09 0.09 659 24 1367 37 87534 133.4 1.2 54.2 0.9 2.66 0.41 33.47 0.63 40.80 0.62 9999 999 9999 999 357.5 5.7 1.06 0.09 667 24 1378 37 87659 133.6 1.2 54.1 0.9 4.38 0.42 33.26 0.63 41.47 0.62 226.9 3.3 2.86 0.13 356.9 5.7 1.04 0.09 603 24 1369 37 87909 145.2 1.3 54.3 0.9 3.16 0.41 37.80 0.64 47.53 0.63 223.7 3.2 2.87 0.13 355.6 5.7 1.38 0.10 624 24 1374 37 88034 226.0 2.2 75.3 1.1 4.36 0.42 67.25 0.81 85.70 0.75 9999 999 9999 999 475.8 6.5 2.87 0.12 616 24 1631 43 88159 224.5 2.2 74.5 1.1 3.86 0.42 66.05 0.80 85.45 0.75 283.7 3.8 3.36 0.17 473.9 6.5 2.90 0.12 627 24 1623 43 88284 235.6 2.4 77.6 1.1 4.21 0.42 70.35 0.84 91.60 0.78 9999 999 9999 999 488.4 6.6 3.20 0.13 574 23 1634 43 88534 248.5 2.7 82.4 1.2 8.49 0.46 77.98 0.90 101.67 0.84 9999 999 9999 999 509.0 6.8 3.78 0.16 575 23 1720 46 88659 253.2 2.8 83.8 1.2 13.05 0.54 79.55 0.92 104.24 0.85 313.3 4.1 4.09 0.24 527.6 7.1 3.94 0.16 522 23 1769 47