42 1001 ELKINS, JAMES; WAMSLEY, PAULA; DUTTON, GEOFF; ROMASHKIN, PAVEL; HURST, DALE; DUNN, RAY U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS IV, ER-2 POLARIS 1 1 1997 04 18 1998 09 09 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 22 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CHCL3 MIXING RATIO (PPT) CHCL3 ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 5 Methyl chloroform and CFC-11 are re-calculated to remove minor contamination from the pump. Time is corrected for pump delay using O3 data by Proffitt et al. CFC-11 uses Poly4 calibration curves for the mixing ratios but Poly3 curve for standard deviations. Therefore, CFC-11 std. deviation provided may be exaggerated for some tropospheric data points. Time is not adjusted for this flight. 1 GMTs F11 F11e F113 F113e CHCl3 CHCl3e MC MCe CT CTe N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e 66939 272.2 6.1 85.9 2.6 7.17 0.42 75.75 0.80 96.51 0.70 9999 999 9999 999 549.5 5.9 3.63 0.13 9999 999 9999 999 67064 270.8 5.9 86.6 2.6 6.31 0.40 77.04 0.81 98.40 0.71 9999 999 9999 999 550.9 5.9 3.73 0.14 9999 999 9999 999 67189 263.2 5.3 85.2 2.5 4.54 0.37 76.11 0.80 96.72 0.70 9999 999 9999 999 538.0 5.7 3.54 0.13 9999 999 9999 999 67564 244.0 4.0 80.4 2.3 2.87 0.36 73.15 0.77 91.50 0.67 300.9 3.0 9999 999 502.7 5.0 3.24 0.12 281 15 1707 42 67689 233.5 3.5 77.7 2.2 2.19 0.35 69.43 0.73 85.28 0.64 9999 999 9999 999 484.1 4.7 2.99 0.11 544 16 1674 41 67814 239.4 3.8 79.5 2.3 2.50 0.35 71.49 0.75 88.14 0.65 297.6 2.9 9999 999 494.3 4.9 3.05 0.11 484 16 1694 42 67939 241.3 3.9 80.0 2.3 2.48 0.35 71.70 0.76 89.06 0.66 9999 999 9999 999 498.0 5.0 3.13 0.11 562 16 1633 41 68189 211.2 2.7 72.4 1.9 1.43 0.35 61.52 0.66 72.54 0.58 9999 999 9999 999 454.1 4.3 2.46 0.09 564 16 1543 39 68314 196.4 2.3 68.4 1.8 1.08 0.35 56.71 0.62 64.95 0.55 261.7 2.3 3.18 0.14 429.7 3.9 2.06 0.09 600 17 1530 38 68439 130.2 1.2 52.8 1.2 0.87 0.35 35.17 0.49 36.23 0.48 9999 999 9999 999 344.7 3.0 1.12 0.07 635 17 1311 34 68564 130.2 1.2 53.4 1.3 0.58 0.34 35.06 0.49 35.96 0.48 218.6 1.7 2.84 0.12 347.8 3.0 1.14 0.07 783 22 1387 36 68814 134.4 1.2 54.6 1.3 0.63 0.34 35.34 0.49 37.33 0.48 223.3 1.8 2.79 0.12 355.2 3.1 1.17 0.07 553 16 1394 36 68939 129.1 1.2 53.8 1.3 0.58 0.34 33.41 0.48 35.27 0.48 9999 999 9999 999 348.8 3.0 1.05 0.07 616 17 1347 35 69064 134.2 1.2 54.8 1.3 0.53 0.34 34.17 0.48 37.30 0.48 223.4 1.8 2.78 0.12 355.2 3.1 1.10 0.07 668 18 1363 35 69189 133.5 1.2 54.6 1.3 0.64 0.34 34.23 0.48 37.02 0.48 9999 999 9999 999 354.7 3.1 1.09 0.07 662 18 1380 36 69439 135.0 1.2 55.2 1.3 0.55 0.34 33.89 0.48 37.51 0.48 9999 999 9999 999 358.7 3.1 1.21 0.07 603 17 1376 36 69564 117.3 1.0 51.2 1.2 0.55 0.34 28.52 0.46 31.28 0.47 214.9 1.7 2.87 0.12 337.0 2.9 1.00 0.07 543 16 1371 35 69689 112.8 1.0 49.9 1.1 0.40 0.34 27.07 0.45 29.50 0.47 9999 999 9999 999 333.2 2.9 0.92 0.07 615 17 1334 35 70064 104.4 0.9 48.2 1.1 0.47 0.34 24.55 0.44 26.39 0.47 208.7 1.6 2.82 0.12 321.6 2.7 0.87 0.07 600 17 1334 35 70189 104.9 0.9 48.1 1.1 0.44 0.34 24.49 0.44 26.52 0.47 9999 999 9999 999 322.1 2.8 0.86 0.07 560 16 1317 34 70314 107.7 0.9 48.5 1.1 0.33 0.34 25.07 0.44 27.57 0.47 209.8 1.6 2.87 0.12 325.4 2.8 0.88 0.07 587 17 1355 35 70439 107.7 0.9 48.6 1.1 0.29 0.34 25.07 0.44 27.55 0.47 9999 999 9999 999 326.1 2.8 0.84 0.07 561 16 1300 34 70689 115.8 1.0 50.4 1.2 0.48 0.34 27.61 0.45 30.59 0.47 9999 999 9999 999 336.1 2.9 0.93 0.07 551 16 1334 35 70814 113.5 1.0 50.0 1.2 0.50 0.34 27.11 0.45 29.86 0.47 213.7 1.7 2.89 0.12 333.7 2.9 0.90 0.07 526 16 1346 35 70939 100.2 0.9 47.3 1.1 0.60 0.34 23.25 0.44 25.22 0.46 9999 999 9999 999 319.7 2.7 0.71 0.07 547 16 1290 34 71314 117.3 1.0 51.1 1.2 0.97 0.35 28.80 0.46 31.34 0.47 215.0 1.7 2.83 0.12 339.6 2.9 0.88 0.07 516 16 1348 35 71439 119.3 1.0 51.5 1.2 0.66 0.34 28.71 0.46 32.09 0.47 9999 999 9999 999 340.9 2.9 0.93 0.07 535 16 1334 35 71564 116.4 1.0 50.9 1.2 0.74 0.35 27.95 0.45 30.91 0.47 214.0 1.7 2.89 0.12 338.9 2.9 0.94 0.07 583 17 1360 35 71689 117.8 1.0 51.2 1.2 0.82 0.35 28.39 0.46 31.44 0.47 9999 999 9999 999 339.5 2.9 0.92 0.07 551 16 1335 35 71939 119.6 1.0 51.7 1.2 0.76 0.35 29.09 0.46 32.02 0.47 9999 999 9999 999 341.7 2.9 0.93 0.07 532 16 1311 34 72189 127.0 1.1 53.4 1.3 0.88 0.35 30.72 0.47 34.66 0.48 9999 999 9999 999 351.3 3.0 1.04 0.07 556 16 1336 35 72314 130.7 1.2 54.4 1.3 1.04 0.35 32.06 0.47 36.04 0.48 221.9 1.7 2.95 0.13 355.6 3.1 1.05 0.07 519 16 1381 36 72564 137.0 1.2 55.7 1.3 1.03 0.35 34.31 0.48 38.47 0.48 227.6 1.8 2.97 0.13 364.6 3.2 1.12 0.07 527 16 1405 36 72689 142.1 1.3 57.0 1.4 1.23 0.35 35.71 0.49 40.47 0.48 9999 999 9999 999 371.1 3.2 1.23 0.07 523 16 1384 36 72814 144.7 1.3 57.8 1.4 1.36 0.35 36.82 0.49 41.66 0.49 233.1 1.9 2.99 0.13 373.9 3.3 1.14 0.07 516 16 1403 36 72939 146.2 1.4 58.0 1.4 1.09 0.35 37.14 0.50 42.19 0.49 9999 999 9999 999 375.6 3.3 1.23 0.07 500 16 1402 36 73189 135.4 1.2 55.3 1.3 1.38 0.35 34.12 0.48 38.05 0.48 9999 999 9999 999 362.5 3.1 1.12 0.07 518 16 1363 35 73314 140.3 1.3 56.5 1.3 1.22 0.35 35.36 0.49 39.67 0.48 230.3 1.8 2.98 0.13 369.2 3.2 1.16 0.07 526 16 1395 36 73439 131.4 1.2 54.4 1.3 1.43 0.35 32.71 0.47 36.48 0.48 9999 999 9999 999 358.0 3.1 1.02 0.07 508 16 1363 35 73564 135.0 1.2 55.4 1.3 1.11 0.35 33.76 0.48 37.93 0.48 226.1 1.8 2.95 0.13 362.0 3.1 1.13 0.07 499 16 1387 36 73814 135.3 1.2 55.4 1.3 1.18 0.35 34.21 0.48 37.97 0.48 227.6 1.8 2.98 0.13 363.1 3.1 1.09 0.07 532 16 1404 36 73939 134.8 1.2 55.3 1.3 0.91 0.35 34.12 0.48 37.71 0.48 9999 999 9999 999 362.2 3.1 1.08 0.07 544 16 1399 36 74064 137.9 1.3 56.1 1.3 1.23 0.35 34.79 0.48 39.04 0.48 231.0 1.8 2.93 0.13 366.3 3.2 1.11 0.07 524 16 1404 36 74439 142.8 1.3 57.2 1.4 1.24 0.35 36.40 0.49 40.96 0.49 9999 999 9999 999 371.7 3.2 1.18 0.07 535 16 1380 36 74564 143.5 1.3 57.5 1.4 1.33 0.35 37.17 0.50 41.10 0.49 233.7 1.9 2.97 0.13 373.0 3.3 1.21 0.07 533 16 1409 36 74689 136.9 1.2 55.9 1.3 1.43 0.35 34.56 0.48 38.69 0.48 9999 999 9999 999 364.5 3.2 1.15 0.07 530 16 1350 35 74814 139.1 1.3 56.4 1.3 1.67 0.35 35.29 0.49 39.51 0.48 229.1 1.8 2.95 0.13 367.5 3.2 1.14 0.07 518 16 1412 36 75064 140.4 1.3 56.8 1.4 1.83 0.35 35.74 0.49 40.11 0.48 230.1 1.8 3.01 0.13 369.3 3.2 1.17 0.07 525 16 1420 36 75189 135.9 1.2 55.6 1.3 1.54 0.35 34.37 0.48 38.24 0.48 9999 999 9999 999 362.8 3.1 1.12 0.07 536 16 1378 36 75314 138.5 1.3 56.3 1.3 1.13 0.35 35.01 0.49 39.37 0.48 231.4 1.9 2.98 0.13 367.2 3.2 1.19 0.07 534 16 1420 36 75439 136.4 1.2 55.7 1.3 1.25 0.35 34.92 0.48 38.47 0.48 9999 999 9999 999 363.9 3.2 1.15 0.07 541 16 1386 36 75689 155.6 1.5 58.7 1.4 1.48 0.35 40.71 0.52 47.16 0.50 9999 999 9999 999 381.3 3.3 1.44 0.08 529 16 1419 36 75814 202.2 2.5 69.3 1.8 1.90 0.35 56.96 0.62 69.04 0.56 266.2 2.3 3.27 0.15 440.4 4.1 2.31 0.09 527 16 1562 39 75939 204.0 2.5 68.9 1.8 2.02 0.35 55.56 0.61 70.19 0.57 9999 999 9999 999 443.6 4.1 2.43 0.09 530 16 1556 39 76064 241.2 3.9 79.5 2.2 2.54 0.35 69.42 0.73 90.51 0.66 295.9 2.9 3.56 0.17 496.2 4.9 3.16 0.12 506 16 1639 41 76314 237.3 3.7 78.2 2.2 2.06 0.35 68.28 0.72 88.09 0.65 291.8 2.8 3.50 0.16 489.5 4.8 3.10 0.11 519 16 1639 41 76439 149.5 1.4 55.8 1.3 1.37 0.35 39.31 0.51 46.52 0.50 9999 999 9999 999 362.4 3.1 1.47 0.08 518 16 1364 35 76564 204.8 2.5 69.9 1.8 1.93 0.35 57.66 0.63 70.74 0.57 268.2 2.4 3.29 0.15 443.2 4.1 2.35 0.09 510 16 1541 39 76689 202.6 2.5 69.5 1.8 1.66 0.35 56.47 0.62 70.08 0.57 9999 999 9999 999 443.7 4.1 2.35 0.09 516 16 1518 38 76939 169.3 1.7 61.7 1.5 0.98 0.35 45.87 0.55 53.63 0.51 9999 999 9999 999 397.3 3.5 1.65 0.08 515 16 1460 37 77064 129.1 1.2 53.3 1.2 1.45 0.35 32.86 0.48 36.81 0.48 223.2 1.8 2.83 0.12 351.6 3.0 1.13 0.07 518 16 1373 35 77189 132.4 1.2 54.2 1.3 1.42 0.35 33.32 0.48 37.70 0.48 9999 999 9999 999 356.5 3.1 1.10 0.07 532 16 1383 36 77314 120.4 1.1 52.0 1.2 1.27 0.35 29.63 0.46 33.20 0.47 217.3 1.7 2.77 0.12 343.6 3.0 0.91 0.07 504 16 1367 35 77564 136.2 1.2 55.5 1.3 1.49 0.35 35.20 0.49 39.16 0.48 225.4 1.8 2.86 0.12 361.5 3.1 1.12 0.07 527 16 1451 37 77689 138.4 1.3 56.2 1.3 1.48 0.35 35.55 0.49 39.77 0.48 9999 999 9999 999 364.8 3.2 1.16 0.07 505 16 1398 36 77814 131.1 1.2 54.4 1.3 1.61 0.35 33.34 0.48 37.21 0.48 224.7 1.8 2.88 0.12 357.6 3.1 0.97 0.07 527 16 1403 36 78189 102.9 0.9 48.9 1.1 2.06 0.35 24.49 0.44 27.11 0.47 9999 999 9999 999 325.6 2.8 0.78 0.07 529 16 1323 35 78314 97.9 0.8 48.0 1.1 1.85 0.35 22.77 0.44 25.14 0.46 207.8 1.6 2.87 0.12 321.3 2.7 0.69 0.07 523 16 1343 35 78439 100.1 0.9 48.6 1.1 2.22 0.35 23.18 0.44 25.81 0.46 9999 999 9999 999 323.7 2.8 0.69 0.07 533 16 1311 34 78564 101.7 0.9 48.9 1.1 2.65 0.35 24.30 0.44 26.37 0.47 211.6 1.6 2.96 0.13 325.6 2.8 0.75 0.07 525 16 1321 35 78814 110.4 1.0 51.1 1.2 1.46 0.35 26.73 0.45 29.22 0.47 215.9 1.7 2.91 0.12 337.5 2.9 0.82 0.07 553 16 1348 35 78939 110.7 1.0 50.7 1.2 1.77 0.35 26.72 0.45 29.47 0.47 9999 999 9999 999 336.0 2.9 0.79 0.07 546 16 1327 35 79064 109.6 1.0 50.6 1.2 1.51 0.35 27.31 0.45 29.25 0.47 214.3 1.7 2.84 0.12 334.0 2.9 0.77 0.07 539 16 1342 35 79189 112.1 1.0 51.3 1.2 2.42 0.35 27.16 0.45 29.88 0.47 9999 999 9999 999 337.0 2.9 0.81 0.07 541 16 1338 35 79439 121.6 1.1 53.3 1.3 1.87 0.35 29.94 0.46 33.36 0.47 9999 999 9999 999 348.9 3.0 0.94 0.07 533 16 1334 35 79564 125.9 1.1 54.3 1.3 2.00 0.35 31.59 0.47 34.72 0.48 225.4 1.8 2.96 0.13 355.5 3.1 0.97 0.07 545 16 1379 36 79689 117.6 1.0 52.8 1.2 1.90 0.35 28.49 0.46 31.71 0.47 9999 999 9999 999 346.5 3.0 0.87 0.07 552 16 1353 35 79814 111.8 1.0 51.3 1.2 2.07 0.35 27.09 0.45 29.84 0.47 218.0 1.7 2.93 0.12 338.4 2.9 0.74 0.07 546 16 1359 35 80064 114.2 1.0 51.7 1.2 2.11 0.35 27.70 0.45 30.91 0.47 216.3 1.7 2.86 0.12 339.6 2.9 0.88 0.07 559 16 1366 35 80189 106.8 0.9 49.8 1.1 1.91 0.35 25.42 0.45 28.41 0.47 9999 999 9999 999 329.0 2.8 0.79 0.07 564 16 1312 34 80314 109.0 0.9 50.3 1.2 1.68 0.35 26.08 0.45 29.15 0.47 214.0 1.7 2.92 0.12 332.2 2.8 0.83 0.07 556 16 1376 36 80439 118.6 1.0 52.7 1.2 1.91 0.35 28.73 0.46 32.27 0.47 9999 999 9999 999 346.5 3.0 0.89 0.07 543 16 1364 35 80689 104.6 0.9 49.4 1.1 2.37 0.35 24.85 0.44 27.54 0.47 9999 999 9999 999 328.0 2.8 0.78 0.07 543 16 1313 34 80814 109.8 1.0 50.6 1.2 2.04 0.35 26.38 0.45 29.34 0.47 214.0 1.7 2.85 0.12 334.9 2.9 0.83 0.07 523 16 1346 35 80939 112.0 1.0 51.1 1.2 1.79 0.35 26.98 0.45 29.94 0.47 9999 999 9999 999 338.7 2.9 0.82 0.07 525 16 1314 34 81064 116.1 1.0 52.0 1.2 2.32 0.35 28.15 0.46 31.37 0.47 218.2 1.7 2.76 0.11 343.2 2.9 0.85 0.07 511 16 1349 35 81314 124.0 1.1 53.7 1.3 1.95 0.35 30.47 0.46 34.06 0.47 222.6 1.8 2.88 0.12 353.8 3.1 0.93 0.07 508 16 1372 35 81439 119.5 1.0 52.8 1.2 1.72 0.35 29.09 0.46 32.64 0.47 9999 999 9999 999 347.3 3.0 0.93 0.07 515 16 1351 35 81564 112.8 1.0 51.2 1.2 1.64 0.35 27.13 0.45 30.41 0.47 215.8 1.7 2.91 0.12 338.4 2.9 0.86 0.07 526 16 1375 35 81939 122.9 1.1 53.5 1.3 1.88 0.35 29.90 0.46 33.97 0.47 9999 999 9999 999 350.6 3.0 0.91 0.07 551 16 1350 35 82064 117.4 1.0 52.1 1.2 2.18 0.35 28.44 0.46 31.90 0.47 219.0 1.7 2.90 0.12 345.4 3.0 0.91 0.07 492 16 1367 35 82189 114.8 1.0 51.7 1.2 1.93 0.35 28.13 0.46 31.32 0.47 9999 999 9999 999 336.4 2.9 0.84 0.07 505 16 1332 35 82314 102.7 0.9 48.8 1.1 1.83 0.35 24.41 0.44 27.39 0.47 209.6 1.6 2.83 0.12 324.3 2.8 0.76 0.07 518 16 1319 34 82564 119.5 1.0 52.9 1.2 1.74 0.35 28.53 0.46 32.68 0.47 222.4 1.7 2.88 0.12 347.8 3.0 0.87 0.07 514 16 1377 36 82689 117.7 1.0 52.4 1.2 2.07 0.35 28.43 0.46 31.91 0.47 9999 999 9999 999 344.3 3.0 0.84 0.07 499 16 1367 35 82814 124.5 1.1 54.4 1.3 1.96 0.35 30.72 0.47 34.46 0.48 222.8 1.8 2.93 0.12 354.3 3.1 0.92 0.07 531 16 1382 36 82939 128.2 1.1 54.9 1.3 2.26 0.35 32.04 0.47 35.67 0.48 9999 999 9999 999 357.6 3.1 1.00 0.07 537 16 1371 35 83189 140.7 1.3 56.3 1.3 1.69 0.35 36.02 0.49 41.08 0.49 9999 999 9999 999 367.6 3.2 1.20 0.07 533 16 1360 35 83314 130.1 1.2 53.6 1.3 1.99 0.35 32.68 0.47 37.52 0.48 222.2 1.7 2.97 0.13 352.9 3.0 1.12 0.07 540 16 1353 35 83439 102.0 0.9 46.4 1.1 1.95 0.35 24.04 0.44 28.19 0.47 9999 999 9999 999 312.3 2.7 0.86 0.07 533 16 1275 34 83564 233.8 3.5 77.9 2.2 2.31 0.35 66.84 0.71 85.72 0.64 288.3 2.7 3.47 0.16 489.0 4.8 2.92 0.11 517 16 1620 40 83814 243.4 4.0 80.2 2.3 2.72 0.36 71.54 0.75 92.98 0.68 298.3 2.9 3.40 0.16 500.1 5.0 3.19 0.12 591 17 1589 40 83939 261.9 5.2 85.7 2.6 9.20 0.47 77.04 0.81 102.71 0.74 9999 999 9999 999 530.9 5.6 3.92 0.15 486 16 1624 40 84064 258.2 4.9 84.0 2.5 11.25 0.53 76.81 0.81 103.50 0.74 316.5 3.3 3.55 0.17 529.4 5.5 3.84 0.14 547 16 1617 40