40 1001 ELKINS, JAMES; FAHEY, DAVID; MOORE, FRED; DUTTON, GEOFF; DUNN, RAY; VOLK, MICHAEL U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION LACE GC OMS 1 1 1997 02 14 1998 03 13 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 14 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 11 This submittal is only a time shift form previous submittal by -10 sec to sync to O3 time. F113 data was removed when it fell more than 10 sigma away from neighboring points. Usually larger than twice tropospheric values. This is presumably due to bubbles of trapped gas randomly working into the pump through the seals. F113 contamination in the hangar was more 100 times the tropospheric value. When the F113 contamination was particularly large, the neighboring F11 peak was affected and was also removed form the data set. The other missing data points are associated with zero air and calibration injections. Error bars quoted include all the statistical error occurred in going from raw integrations to final calibrated numbers. In addition there is the following error associated with the accuracy of our calibration tanks: F11+-1.1%, F113+-2.0%, F12+-2.0%, H1211+-3%, SF6+-3%. 1 GMTs F11 F11e F113 F113e SF6 SF6e F12 F12e H1211 H1211e N2O N2Oe CH4 CH4e 17046 271.8 8.2 9999 999 9999 999 531.0 10.2 3.78 0.07 9999 999 9999 999 17116 267.7 8.0 9999 999 9999 999 530.9 10.2 3.69 0.07 9999 999 9999 999 17186 273.5 8.2 9999 999 9999 999 9999 999 3.80 0.07 9999 999 9999 999 17256 271.2 8.1 9999 999 9999 999 530.6 10.2 3.73 0.07 9999 999 9999 999 17396 273.7 8.2 9999 999 9999 999 532.7 10.2 3.80 0.07 9999 999 9999 999 17466 267.8 8.0 9999 999 9999 999 533.9 10.2 3.75 0.07 9999 999 9999 999 17536 270.5 8.1 9999 999 9999 999 534.1 10.2 3.75 0.07 9999 999 9999 999 17605 268.0 8.0 9999 999 9999 999 534.8 10.2 3.68 0.07 9999 999 9999 999 17745 262.8 7.9 9999 999 9999 999 536.0 10.2 3.70 0.07 9999 999 9999 999 17816 268.7 8.1 87.7 1.6 3.67 0.08 537.7 10.3 3.70 0.07 9999 999 9999 999 17885 265.5 8.0 90.2 1.6 3.64 0.08 538.0 10.3 3.67 0.07 9999 999 9999 999 17956 268.0 8.0 86.9 1.6 3.57 0.08 536.8 10.3 3.72 0.07 9999 999 9999 999 18096 266.7 8.0 87.0 1.6 3.63 0.08 536.5 10.3 3.61 0.07 9999 999 9999 999 18166 261.3 7.8 86.9 1.6 3.61 0.08 534.4 10.2 3.56 0.07 9999 999 9999 999 18235 260.6 7.8 9999 999 3.61 0.08 532.7 10.2 3.58 0.07 9999 999 9999 999 18306 265.7 8.0 9999 999 3.66 0.08 536.7 10.3 3.65 0.07 9999 999 9999 999 18446 265.9 8.0 9999 999 3.69 0.08 9999 999 3.59 0.07 9999 999 9999 999 18516 262.4 7.9 88.3 1.6 3.68 0.08 536.9 10.3 3.63 0.07 9999 999 9999 999 18586 264.1 7.9 88.9 1.6 3.69 0.08 9999 999 3.59 0.07 9999 999 9999 999 18655 260.0 7.8 88.5 1.6 3.67 0.08 535.0 10.2 3.50 0.07 9999 999 9999 999 18795 260.7 7.8 89.0 1.6 3.65 0.08 534.5 10.2 3.53 0.07 9999 999 9999 999 18866 265.3 8.0 9999 999 3.71 0.08 540.2 10.3 3.54 0.07 9999 999 9999 999 18936 262.3 7.9 89.5 1.6 3.68 0.08 532.9 10.2 3.45 0.07 9999 999 9999 999 19005 257.0 7.7 88.6 1.6 3.60 0.08 526.4 10.2 3.34 0.07 9999 999 9999 999 19145 253.2 7.6 87.8 1.6 3.63 0.08 525.9 10.2 3.19 0.07 9999 999 9999 999 19216 250.0 7.5 9999 999 3.65 0.08 524.1 10.2 3.22 0.07 9999 999 9999 999 19285 248.9 7.5 9999 999 3.67 0.08 525.5 10.2 3.16 0.07 9999 999 9999 999 19356 245.7 7.4 86.2 1.6 3.60 0.08 515.8 10.2 2.86 0.07 9999 999 9999 999 19496 237.4 7.1 84.6 1.6 3.60 0.08 509.5 10.1 2.65 0.07 9999 999 9999 999 19566 224.6 6.7 82.8 1.6 3.55 0.08 499.2 10.1 2.25 0.07 9999 999 9999 999 19636 224.9 6.7 82.8 1.6 3.52 0.08 499.1 10.1 2.10 0.07 9999 999 9999 999 19706 226.1 6.8 83.2 1.6 3.52 0.08 500.6 10.1 2.12 0.07 9999 999 9999 999 19846 213.6 6.4 9999 999 3.46 0.07 491.1 10.1 1.69 0.06 9999 999 9999 999 19915 202.1 6.1 78.6 1.5 3.38 0.07 481.3 10.0 1.42 0.06 9999 999 9999 999 19986 207.6 6.2 80.3 1.5 3.44 0.07 488.8 10.1 1.38 0.06 9999 999 9999 999 20055 203.7 6.1 80.1 1.5 3.42 0.07 487.4 10.0 1.38 0.06 9999 999 9999 999 20195 169.8 5.1 9999 999 3.24 0.07 461.7 9.9 0.78 0.06 9999 999 9999 999 20266 188.2 5.6 77.8 1.5 3.33 0.07 474.6 10.0 0.87 0.06 9999 999 9999 999 20336 166.2 5.0 74.3 1.5 3.23 0.07 458.3 9.9 0.44 0.06 9999 999 9999 999 20405 157.1 4.7 72.6 1.5 3.24 0.07 457.7 9.9 0.30 0.06 9999 999 9999 999 20545 140.4 4.2 70.4 1.5 3.23 0.07 445.7 9.9 0.12 0.06 9999 999 9999 999 20616 132.0 4.0 69.0 1.4 3.18 0.07 437.1 9.9 0.05 0.06 9999 999 9999 999 20685 128.3 4.0 67.7 1.4 3.14 0.07 436.9 9.9 -0.03 0.06 9999 999 9999 999 20756 118.5 4.0 66.4 1.4 3.15 0.07 425.4 9.8 -0.10 0.06 9999 999 9999 999 20896 104.4 4.0 9999 999 3.15 0.07 433.2 9.8 -0.03 0.06 9999 999 9999 999 20965 94.2 4.0 63.9 1.4 3.11 0.07 411.7 9.8 -0.07 0.06 9999 999 9999 999 21036 81.6 4.0 9999 999 3.05 0.07 404.1 9.7 -0.15 0.06 9999 999 9999 999 21106 82.8 4.0 60.9 1.4 3.05 0.07 400.0 9.7 -0.15 0.06 9999 999 9999 999 21246 67.0 4.0 58.2 1.4 3.03 0.07 389.4 9.7 -0.24 0.06 9999 999 9999 999 21315 58.8 4.0 9999 999 2.99 0.07 382.2 9.7 9999 999 9999 999 9999 999 21386 61.1 4.0 61.9 1.4 3.02 0.07 415.5 9.8 9999 999 9999 999 9999 999 21455 51.5 4.0 63.7 1.4 2.94 0.07 371.2 9.6 9999 999 9999 999 9999 999 21595 45.9 3.0 9999 999 2.92 0.07 374.7 9.7 9999 999 9999 999 9999 999 21666 35.5 3.0 52.6 1.3 2.97 0.07 355.5 9.6 9999 999 9999 999 9999 999 21735 36.1 3.0 53.1 1.3 2.94 0.07 364.6 9.6 9999 999 9999 999 9999 999 21806 31.9 3.0 52.8 1.3 2.95 0.07 346.5 9.6 9999 999 9999 999 9999 999 21945 23.7 3.0 47.1 1.3 2.86 0.07 329.3 9.5 9999 999 9999 999 9999 999 22016 22.8 3.0 9999 999 2.89 0.07 323.7 9.5 9999 999 9999 999 9999 999 22086 16.9 3.0 55.4 1.3 2.87 0.07 314.6 9.5 9999 999 9999 999 9999 999 22156 15.7 3.0 45.0 1.3 2.87 0.07 309.5 9.5 9999 999 9999 999 9999 999 22296 12.9 3.0 9999 999 2.88 0.07 304.9 9.5 9999 999 9999 999 9999 999 22365 10.6 2.0 9999 999 2.86 0.07 294.8 9.4 9999 999 9999 999 9999 999 22436 9.4 2.0 41.2 1.2 2.90 0.07 291.3 9.4 9999 999 9999 999 9999 999 22505 9.5 2.0 40.2 1.2 2.88 0.07 285.7 9.4 9999 999 9999 999 9999 999 22646 6.5 2.0 9999 999 2.81 0.07 272.6 9.4 9999 999 9999 999 9999 999 22715 8.2 2.0 9999 999 2.81 0.07 317.2 9.5 9999 999 9999 999 9999 999 22786 5.8 2.0 9999 999 2.81 0.07 279.0 9.4 9999 999 9999 999 9999 999 22855 4.3 1.0 9999 999 2.86 0.07 261.9 9.4 9999 999 9999 999 9999 999 22995 3.5 1.0 9999 999 2.87 0.07 255.1 9.4 9999 999 9999 999 9999 999 23066 3.1 1.0 9999 999 2.84 0.07 249.8 9.4 9999 999 9999 999 9999 999 23136 2.6 1.0 37.7 1.2 2.83 0.07 241.0 9.3 9999 999 9999 999 9999 999 23206 2.5 1.0 9999 999 2.84 0.07 239.5 9.3 9999 999 9999 999 9999 999 23346 2.4 1.0 30.5 1.2 2.84 0.07 240.4 9.3 9999 999 9999 999 9999 999 23416 10.4 2.0 9999 999 2.83 0.07 277.0 9.4 9999 999 9999 999 9999 999 23486 5.5 2.0 33.9 1.2 2.87 0.07 248.1 9.3 9999 999 9999 999 9999 999 23556 2.6 1.0 29.9 1.2 2.87 0.07 241.0 9.3 9999 999 9999 999 9999 999 23696 2.6 1.0 29.8 1.2 3.02 0.07 239.1 9.3 9999 999 9999 999 9999 999 23836 2.4 1.0 29.4 1.2 2.95 0.07 234.4 9.3 9999 999 9999 999 9999 999 23905 9999 999 36.3 1.2 2.84 0.07 242.6 9.3 9999 999 9999 999 9999 999 24045 2.1 1.0 28.7 1.2 2.83 0.07 233.6 9.3 9999 999 9999 999 9999 999 24186 9999 999 9999 999 9999 999 251.0 9.4 9999 999 9999 999 9999 999 24255 13.2 2.0 9999 999 2.88 0.07 239.7 9.3 9999 999 9999 999 9999 999 24396 2.0 1.0 28.1 1.2 2.81 0.07 233.5 9.3 9999 999 9999 999 9999 999 24466 4.5 1.0 35.3 1.2 2.83 0.07 238.7 9.3 9999 999 9999 999 9999 999 24536 2.5 1.0 29.5 1.2 2.91 0.07 244.5 9.3 9999 999 9999 999 9999 999 24606 2.5 1.0 28.8 1.2 2.88 0.07 241.2 9.3 9999 999 9999 999 9999 999 24746 2.4 1.0 29.0 1.2 2.82 0.07 241.4 9.3 9999 999 9999 999 9999 999 24815 2.4 1.0 29.1 1.2 2.79 0.07 240.9 9.3 9999 999 9999 999 9999 999 24886 2.4 1.0 28.9 1.2 2.85 0.07 242.3 9.3 9999 999 9999 999 9999 999 24956 2.6 1.0 29.0 1.2 2.85 0.07 242.6 9.3 9999 999 9999 999 9999 999 25096 8.7 1.0 37.9 1.2 2.81 0.07 258.8 9.4 9999 999 9999 999 9999 999 25165 3.0 1.0 29.7 1.2 2.84 0.07 248.6 9.3 9999 999 9999 999 9999 999 25236 3.4 1.0 30.1 1.2 2.87 0.07 251.8 9.4 9999 999 9999 999 9999 999 25305 3.4 1.0 30.1 1.2 2.85 0.07 254.2 9.4 9999 999 9999 999 9999 999 25446 5.3 1.0 32.8 1.2 2.80 0.07 266.7 9.4 9999 999 9999 999 9999 999 25516 6.0 2.0 33.6 1.2 2.86 0.07 272.2 9.4 9999 999 9999 999 9999 999 25586 6.7 2.0 35.2 1.2 2.82 0.07 272.9 9.4 9999 999 9999 999 9999 999 25656 7.7 2.0 35.5 1.2 2.84 0.07 278.5 9.4 9999 999 9999 999 9999 999 25796 9.6 2.0 37.3 1.2 2.85 0.07 293.2 9.4 9999 999 9999 999 9999 999 25866 10.5 2.0 37.9 1.2 2.87 0.07 296.0 9.4 9999 999 9999 999 9999 999 25935 11.1 2.0 38.4 1.2 2.89 0.07 299.6 9.5 9999 999 9999 999 9999 999 26006 12.6 3.0 39.1 1.2 2.83 0.07 303.5 9.5 9999 999 9999 999 9999 999 26146 15.0 3.0 40.5 1.2 2.93 0.07 312.1 9.5 9999 999 9999 999 9999 999 26215 17.5 3.0 41.6 1.2 2.94 0.07 318.2 9.5 9999 999 9999 999 9999 999 26286 22.7 3.0 44.0 1.3 2.95 0.07 329.1 9.5 9999 999 9999 999 9999 999 26355 24.5 3.0 52.4 1.3 2.99 0.07 336.4 9.5 9999 999 9999 999 9999 999 26496 30.7 3.0 47.9 1.3 3.02 0.07 350.7 9.6 9999 999 9999 999 9999 999 26565 31.2 3.0 47.9 1.3 3.00 0.07 354.5 9.6 9999 999 9999 999 9999 999 26636 33.5 3.0 48.9 1.3 3.04 0.07 356.1 9.6 9999 999 9999 999 9999 999 26705 39.0 3.0 49.2 1.3 2.96 0.07 356.7 9.6 9999 999 9999 999 9999 999 26846 46.7 4.0 53.5 1.3 3.04 0.07 379.2 9.7 9999 999 9999 999 9999 999 26916 49.2 4.0 53.5 1.3 3.03 0.07 377.0 9.7 9999 999 9999 999 9999 999 26985 56.6 4.0 55.1 1.3 3.07 0.07 388.0 9.7 9999 999 9999 999 9999 999 27056 66.7 4.0 57.3 1.4 3.04 0.07 398.1 9.7 9999 999 9999 999 9999 999 27196 76.2 4.0 58.7 1.4 3.04 0.07 404.8 9.7 9999 999 9999 999 9999 999 27266 80.3 4.0 57.7 1.4 3.02 0.07 403.2 9.7 9999 999 9999 999 9999 999 27335 84.1 4.0 59.1 1.4 3.03 0.07 411.8 9.8 -0.04 0.06 9999 999 9999 999 27406 85.3 2.6 60.3 1.4 3.04 0.07 414.4 9.8 -0.14 0.06 9999 999 9999 999 27546 87.2 4.0 60.2 1.4 3.09 0.07 417.8 9.8 -0.06 0.06 9999 999 9999 999 27615 95.1 4.0 62.3 1.4 3.05 0.07 428.0 9.8 -0.12 0.06 9999 999 9999 999 27686 103.1 4.0 63.4 1.4 3.10 0.07 433.8 9.8 -0.13 0.06 9999 999 9999 999 27755 104.4 4.0 64.2 1.4 3.06 0.07 429.7 9.8 -0.11 0.06 9999 999 9999 999 27896 109.5 4.0 64.6 1.4 3.06 0.07 436.7 9.8 -0.06 0.06 9999 999 9999 999 27965 115.3 4.0 65.3 1.4 3.04 0.07 437.4 9.8 -0.09 0.06 9999 999 9999 999 28036 127.6 4.0 67.8 1.4 3.13 0.07 449.9 9.9 0.00 0.06 9999 999 9999 999 28106 131.0 4.0 67.9 1.4 3.12 0.07 451.4 9.9 -0.00 0.06 9999 999 9999 999 28245 140.6 4.2 71.7 1.5 3.14 0.07 460.8 9.9 0.10 0.06 9999 999 9999 999 28316 148.0 4.4 70.0 1.5 3.19 0.07 464.9 9.9 0.17 0.06 9999 999 9999 999 28385 149.5 4.5 71.0 1.5 3.22 0.07 468.2 10.0 0.15 0.06 9999 999 9999 999 28456 155.7 4.7 72.3 1.5 3.22 0.07 470.4 10.0 0.24 0.06 9999 999 9999 999 28596 164.3 4.9 72.2 1.5 3.25 0.07 473.2 10.0 0.35 0.06 9999 999 9999 999 28666 173.4 5.2 74.1 1.5 3.29 0.07 483.3 10.0 0.51 0.06 9999 999 9999 999 28735 171.0 5.1 73.3 1.5 3.21 0.07 476.2 10.0 0.55 0.06 9999 999 9999 999 28806 169.4 5.1 73.0 1.5 3.22 0.07 472.4 10.0 0.55 0.06 9999 999 9999 999 28946 180.1 5.4 74.2 1.5 3.21 0.07 479.7 10.0 0.78 0.06 9999 999 9999 999 29015 197.1 5.9 77.9 1.5 3.32 0.07 502.0 10.1 1.14 0.06 9999 999 9999 999 29086 202.7 6.1 79.4 1.5 3.36 0.07 504.6 10.1 1.26 0.06 9999 999 9999 999 29156 200.4 6.0 79.3 1.5 3.35 0.07 503.4 10.1 1.26 0.06 9999 999 9999 999 29295 199.5 6.0 77.4 1.5 3.36 0.07 497.6 10.1 1.36 0.06 9999 999 9999 999 29366 203.3 6.1 78.5 1.5 3.31 0.07 496.9 10.1 1.43 0.06 9999 999 9999 999 29436 209.0 6.3 79.4 1.5 3.36 0.07 505.3 10.1 1.61 0.06 9999 999 9999 999 29505 210.9 6.3 80.2 1.5 3.41 0.07 506.9 10.1 1.66 0.06 9999 999 9999 999 29645 211.1 6.3 79.9 1.5 3.39 0.07 508.2 10.1 1.76 0.06 9999 999 9999 999 29716 214.1 6.4 80.1 1.5 3.39 0.07 509.6 10.1 1.78 0.07 9999 999 9999 999 29785 221.4 6.6 81.3 1.6 3.43 0.07 515.6 10.1 2.07 0.07 9999 999 9999 999 29856 229.4 6.9 81.3 1.6 3.49 0.08 522.2 10.2 2.33 0.07 9999 999 9999 999 29996 231.3 6.9 82.9 1.6 3.54 0.08 524.0 10.2 2.39 0.07 9999 999 9999 999 30065 230.5 6.9 82.7 1.6 3.53 0.08 523.6 10.2 2.45 0.07 9999 999 9999 999 30136 235.5 7.1 85.9 1.6 3.54 0.08 524.4 10.2 2.52 0.07 9999 999 9999 999 30206 233.7 7.0 83.5 1.6 3.52 0.08 524.6 10.2 2.54 0.07 9999 999 9999 999 30346 241.2 7.2 83.9 1.6 3.60 0.08 529.0 10.2 2.83 0.07 9999 999 9999 999 30416 242.9 7.3 85.0 1.6 3.63 0.08 532.8 10.2 2.91 0.07 9999 999 9999 999 30486 247.0 7.4 84.1 1.6 3.68 0.08 535.3 10.2 3.08 0.07 9999 999 9999 999 30555 246.3 7.4 84.7 1.6 3.68 0.08 535.3 10.2 3.06 0.07 9999 999 9999 999 30695 247.2 7.4 85.1 1.6 3.71 0.08 535.0 10.2 3.04 0.07 9999 999 9999 999 30766 249.0 7.5 85.7 1.6 3.68 0.08 531.5 10.2 3.15 0.07 9999 999 9999 999 30835 250.8 7.5 86.0 1.6 3.71 0.08 535.1 10.2 3.20 0.07 9999 999 9999 999 30906 253.0 7.6 86.9 1.6 3.65 0.08 533.3 10.2 3.21 0.07 9999 999 9999 999 31045 256.7 7.7 87.2 1.6 3.70 0.08 538.5 10.2 3.44 0.07 9999 999 9999 999 31116 257.5 7.7 87.5 1.6 3.71 0.08 539.5 10.2 3.50 0.07 9999 999 9999 999 31185 258.1 7.7 87.2 1.6 3.69 0.08 537.2 10.2 3.46 0.07 9999 999 9999 999 31256 261.1 7.8 87.3 1.6 3.70 0.08 534.2 10.2 3.49 0.07 9999 999 9999 999 31396 262.0 7.9 86.9 1.6 3.74 0.08 534.7 10.2 3.56 0.07 9999 999 9999 999 31466 260.8 7.8 87.2 1.6 3.73 0.08 533.7 10.2 3.49 0.07 9999 999 9999 999 31536 263.8 7.9 87.7 1.6 3.73 0.08 533.6 10.2 3.65 0.07 9999 999 9999 999 31605 261.4 7.8 87.1 1.6 3.72 0.08 534.2 10.2 3.56 0.07 9999 999 9999 999 31746 261.1 7.8 86.5 1.6 3.72 0.08 530.2 10.2 3.54 0.07 9999 999 9999 999 31815 263.0 7.9 86.9 1.6 3.68 0.08 531.3 10.2 3.62 0.07 9999 999 9999 999 31886 265.3 8.0 86.4 1.6 3.74 0.08 531.0 10.2 3.71 0.07 9999 999 9999 999 31955 265.0 7.9 86.9 1.6 3.76 0.08 530.5 10.2 3.64 0.07 9999 999 9999 999 32095 266.9 8.0 86.9 1.6 3.75 0.08 531.4 10.2 3.72 0.07 9999 999 9999 999 32166 273.4 8.2 87.8 1.6 3.69 0.08 529.2 10.2 3.76 0.07 9999 999 9999 999 32235 268.7 8.1 87.1 1.6 3.67 0.08 528.2 10.2 3.70 0.07 9999 999 9999 999 32306 271.0 8.1 87.2 1.6 3.70 0.08 537.5 10.2 3.72 0.07 9999 999 9999 999 32446 274.2 8.2 87.4 1.6 3.79 0.08 534.3 10.2 3.79 0.07 9999 999 9999 999 32516 272.4 8.2 87.4 1.6 3.83 0.08 535.8 10.2 3.85 0.08 9999 999 9999 999 32585 269.8 8.1 86.8 1.6 3.74 0.08 531.8 10.2 3.82 0.07 9999 999 9999 999 32656 273.8 8.2 87.1 1.6 3.72 0.08 525.4 10.2 3.86 0.08 9999 999 9999 999 32796 275.2 8.3 87.1 1.6 3.75 0.08 524.6 10.2 3.96 0.08 9999 999 9999 999 32865 272.7 8.2 87.3 1.6 3.73 0.08 525.8 10.2 9999 999 9999 999 9999 999