52 1001 ELKINS, JAMES; FAHEY, DAVID; WAMSLEY, PAULA; DUTTON, GEOFF; BARING, THOMAS; ROMASHKIN, PAVEL; HURST, DALE; DUNN, RAY U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS IV, ER-2 STRAT 1 1 1996 08 08 1997 11 05 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 17 The errors reported for each measurement were propagated in quadrature from the following uncertainties: in-flight precision: our ability to make repeatable measurements of calibration gas during each flight calibration precision: our ability to make repeatable measurements of calibration standards during laboratory calibrations of the instrument calibration curve fits: our ability to calculate in-flight mixing ratios using first or second order polynomial curve fits to laboratory calibration measurements Hence, the total errors represent our ability to make in-flight and laboratory calibration measurements, and to apply laboratory calibration curves to the in-flight measurements. They DO NOT reflect inaccuracies of the calibration values assigned to our standards. 1 GMTs F11 F11e F113 F113e MC MCe CT CTe N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e 72438 282.8 7.4 86.2 1.5 89.0 2.9 107.2 2.9 9999 999 9999 999 530.1 8.6 3.76 0.13 9999 999 9999 999 72618 278.0 7.0 85.3 1.5 90.2 2.9 106.2 2.9 304.5 4.8 3.74 0.06 527.6 8.5 3.84 0.13 9999 999 1691 35 72798 272.6 6.5 84.7 1.5 89.4 2.9 106.6 2.9 9999 999 9999 999 529.6 8.6 3.76 0.13 9999 999 1708 35 72978 263.9 5.9 83.8 1.5 88.1 2.8 102.9 2.8 297.7 4.6 3.58 0.06 515.6 8.1 3.59 0.12 9999 999 1712 35 73338 266.7 6.1 84.5 1.5 88.0 2.8 103.8 2.8 303.5 4.7 3.58 0.06 520.5 8.3 3.53 0.12 9999 999 1715 36 73518 257.6 5.5 83.2 1.5 86.7 2.8 100.8 2.7 9999 999 9999 999 512.5 8.0 3.40 0.11 9999 999 1718 36 73698 238.6 4.5 79.6 1.4 82.2 2.7 91.8 2.5 290.0 4.4 3.41 0.06 485.0 7.2 3.07 0.10 9999 999 1662 34 73878 242.0 4.7 80.5 1.4 81.6 2.6 92.3 2.5 9999 999 9999 999 491.9 7.4 3.01 0.10 9999 999 1668 35 74238 230.0 4.1 78.3 1.4 77.0 2.5 85.8 2.3 9999 999 9999 999 476.0 7.0 2.75 0.09 9999 999 1623 34 74418 219.9 3.7 76.0 1.3 75.2 2.4 81.3 2.2 283.3 4.2 3.28 0.06 458.7 6.6 2.48 0.08 9999 999 1586 33 74598 211.8 3.4 74.7 1.3 71.9 2.3 79.0 2.2 9999 999 9999 999 451.2 6.4 2.35 0.08 9999 999 1575 33 74778 213.1 3.5 74.9 1.3 73.4 2.4 9999 999 281.0 4.2 3.27 0.06 452.5 6.4 2.33 0.08 9999 999 1590 33 75138 204.6 3.2 73.6 1.3 71.3 2.3 9999 999 276.3 4.1 3.25 0.06 445.9 6.3 2.25 0.08 9999 999 1553 32 75318 205.8 3.2 73.1 1.3 68.3 2.2 9999 999 9999 999 9999 999 445.5 6.2 2.23 0.08 9999 999 1552 32 75498 203.1 3.2 72.9 1.3 69.6 2.3 9999 999 275.4 4.1 3.22 0.06 443.3 6.2 2.17 0.07 9999 999 1552 32 75678 199.3 3.1 71.9 1.3 66.1 2.2 9999 999 9999 999 9999 999 439.7 6.1 2.17 0.07 9999 999 1551 32 76038 196.4 3.0 70.7 1.2 65.0 2.2 9999 999 9999 999 9999 999 438.0 6.1 2.10 0.07 9999 999 1532 32 76218 196.1 3.0 71.1 1.2 64.5 2.1 9999 999 268.9 3.9 3.18 0.06 435.2 6.0 2.11 0.07 9999 999 1536 32 76398 196.4 3.0 71.0 1.2 63.4 2.1 9999 999 9999 999 9999 999 437.8 6.1 2.06 0.07 9999 999 1531 32 76938 198.8 3.0 71.4 1.2 64.2 2.1 9999 999 272.1 4.0 3.20 0.06 440.1 6.1 2.10 0.07 9999 999 1562 32 77118 201.3 3.1 72.2 1.3 64.3 2.1 9999 999 9999 999 9999 999 446.0 6.3 2.13 0.07 9999 999 1572 33 77298 202.2 3.1 72.4 1.3 63.1 2.1 9999 999 275.8 4.1 3.25 0.06 448.1 6.3 2.15 0.07 9999 999 1557 32 77478 203.0 3.2 72.6 1.3 63.1 2.1 9999 999 9999 999 9999 999 449.7 6.3 2.14 0.07 9999 999 1561 32 77838 206.6 3.3 73.3 1.3 64.7 2.1 9999 999 9999 999 9999 999 455.3 6.5 2.19 0.07 9999 999 1566 32 78018 204.0 3.2 72.6 1.3 62.6 2.1 9999 999 277.0 4.1 3.22 0.06 450.8 6.4 2.10 0.07 9999 999 1567 33 78198 203.2 3.2 72.5 1.3 62.4 2.1 9999 999 9999 999 9999 999 451.2 6.4 2.17 0.07 9999 999 1570 33 78738 207.3 3.3 73.5 1.3 64.2 2.1 9999 999 281.1 4.2 3.19 0.06 457.3 6.5 2.16 0.07 9999 999 1592 33 78918 207.5 3.3 73.7 1.3 64.9 2.2 9999 999 9999 999 9999 999 457.7 6.5 2.14 0.07 9999 999 1599 33 79098 208.2 3.3 73.7 1.3 65.8 2.2 9999 999 281.9 4.2 3.20 0.06 458.4 6.6 2.16 0.07 9999 999 1581 33 79278 210.5 3.4 74.4 1.3 65.7 2.2 9999 999 9999 999 9999 999 464.6 6.7 2.24 0.08 9999 999 1604 33 79638 214.6 3.5 75.3 1.3 67.0 2.2 9999 999 9999 999 9999 999 470.7 6.9 2.27 0.08 9999 999 1613 33 79998 216.0 3.6 75.6 1.3 67.4 2.2 9999 999 9999 999 9999 999 469.2 6.8 2.32 0.08 9999 999 1613 33 80178 215.8 3.6 75.8 1.3 68.8 2.3 9999 999 288.2 4.4 3.30 0.06 470.0 6.8 2.29 0.08 9999 999 1599 33 80538 216.7 3.6 75.7 1.3 67.5 2.2 9999 999 287.5 4.3 3.30 0.06 469.7 6.8 2.35 0.08 9999 999 1616 33 80718 216.5 3.6 75.9 1.3 68.6 2.3 9999 999 9999 999 9999 999 472.1 6.9 2.31 0.08 9999 999 1615 33 80898 216.8 3.6 75.9 1.3 70.1 2.3 9999 999 290.6 4.4 3.35 0.06 470.4 6.9 2.38 0.08 9999 999 1615 33 81078 218.1 3.7 76.1 1.3 69.6 2.3 9999 999 9999 999 9999 999 472.2 6.9 2.36 0.08 9999 999 1608 33 81438 216.2 3.6 75.7 1.3 68.2 2.2 9999 999 9999 999 9999 999 472.4 6.9 2.32 0.08 9999 999 1622 34 81618 216.2 3.6 76.1 1.3 69.6 2.3 9999 999 287.7 4.4 3.31 0.06 469.4 6.8 2.34 0.08 9999 999 1631 34 81798 214.9 3.6 76.2 1.3 69.1 2.3 9999 999 9999 999 9999 999 470.0 6.8 2.30 0.08 9999 999 1632 34 81978 218.5 3.7 76.4 1.3 70.9 2.3 9999 999 287.5 4.3 3.32 0.06 469.7 6.8 2.42 0.08 9999 999 1622 34 82338 240.3 4.6 79.5 1.4 78.7 2.5 9999 999 301.7 4.7 3.43 0.06 494.3 7.5 2.89 0.09 9999 999 1666 34 82518 252.8 5.2 81.4 1.4 84.2 2.7 99.0 2.7 9999 999 9999 999 508.0 7.9 3.20 0.10 9999 999 1698 35 82698 261.4 5.8 82.9 1.5 89.5 2.9 101.1 2.7 310.7 4.9 3.58 0.06 514.6 8.1 3.46 0.11 9999 999 1715 35 83238 267.7 6.2 83.9 1.5 91.8 3.0 101.9 2.7 9999 999 9999 999 522.4 8.3 3.66 0.12 9999 999 1718 36 83418 262.2 5.8 83.0 1.5 86.8 2.8 101.4 2.7 309.4 4.9 3.59 0.06 515.2 8.1 3.52 0.12 9999 999 1698 35 83598 250.3 5.1 81.3 1.4 81.0 2.6 97.2 2.6 9999 999 9999 999 501.9 7.7 3.19 0.10 9999 999 1665 34 83778 243.4 4.7 80.5 1.4 78.2 2.5 93.6 2.5 300.2 4.7 3.46 0.06 495.3 7.5 2.97 0.10 9999 999 1657 34 84138 218.0 3.7 75.7 1.3 68.6 2.3 9999 999 285.8 4.3 3.35 0.06 466.4 6.7 2.42 0.08 9999 999 1618 34 84318 214.9 3.5 75.8 1.3 66.9 2.2 9999 999 9999 999 9999 999 468.5 6.8 2.35 0.08 9999 999 1626 34 84498 210.3 3.4 74.8 1.3 66.9 2.2 9999 999 283.3 4.2 3.30 0.06 461.1 6.6 2.21 0.07 9999 999 1597 33 84678 208.6 3.3 74.7 1.3 65.7 2.2 9999 999 9999 999 9999 999 460.8 6.6 2.23 0.08 9999 999 1607 33 85038 211.5 3.4 75.9 1.3 66.1 2.2 9999 999 9999 999 9999 999 471.2 6.9 2.15 0.07 9999 999 1611 33 85218 198.5 3.0 72.8 1.3 61.5 2.1 9999 999 277.4 4.1 3.23 0.06 449.2 6.3 1.97 0.07 9999 999 1569 33 85398 195.9 3.0 72.1 1.3 61.6 2.1 9999 999 9999 999 9999 999 448.1 6.3 1.98 0.07 9999 999 1559 32 85578 194.9 2.9 71.6 1.3 61.1 2.0 9999 999 274.9 4.1 3.22 0.06 445.3 6.2 1.98 0.07 9999 999 1562 32 85938 192.8 2.9 71.2 1.2 59.6 2.0 9999 999 273.9 4.0 3.27 0.06 441.3 6.2 1.93 0.07 9999 999 1569 33 86118 192.5 2.9 71.3 1.2 60.1 2.0 9999 999 9999 999 9999 999 442.8 6.2 1.93 0.07 9999 999 1554 32 86298 193.2 2.9 71.3 1.2 61.3 2.1 9999 999 273.5 4.0 3.24 0.06 442.5 6.2 1.95 0.07 9999 999 1569 33 86478 193.3 2.9 71.1 1.2 60.6 2.0 9999 999 9999 999 9999 999 443.5 6.2 1.92 0.07 9999 999 1568 33 86838 181.5 2.6 68.7 1.2 55.7 1.9 9999 999 9999 999 9999 999 427.7 5.8 1.70 0.06 9999 999 1521 32 87018 180.4 2.6 68.6 1.2 55.9 1.9 9999 999 263.8 3.8 3.12 0.06 425.4 5.8 1.72 0.06 9999 999 1521 32 87198 181.4 2.6 68.5 1.2 56.9 1.9 9999 999 9999 999 9999 999 427.0 5.8 1.78 0.06 9999 999 1534 32 87378 179.8 2.5 68.1 1.2 56.1 1.9 9999 999 264.1 3.8 3.14 0.06 424.8 5.8 1.69 0.06 9999 999 1533 32 87738 184.4 2.7 68.7 1.2 57.1 1.9 9999 999 266.7 3.9 3.17 0.06 429.0 5.9 1.86 0.07 9999 999 1533 32 87918 178.5 2.5 67.7 1.2 54.8 1.9 9999 999 9999 999 9999 999 421.6 5.7 1.75 0.06 9999 999 1509 31 88098 180.9 2.6 68.3 1.2 55.4 1.9 9999 999 263.7 3.8 3.13 0.06 425.2 5.8 1.79 0.06 9999 999 1521 32 88638 181.8 2.6 68.4 1.2 53.7 1.9 9999 999 9999 999 9999 999 425.9 5.8 1.85 0.07 9999 999 1522 32 88818 178.7 2.5 67.9 1.2 55.5 1.9 9999 999 262.5 3.8 3.13 0.06 422.1 5.7 1.73 0.06 9999 999 1514 32 88998 176.1 2.5 67.3 1.2 54.0 1.9 9999 999 9999 999 9999 999 417.8 5.6 1.69 0.06 9999 999 1521 32 89178 177.6 2.5 67.9 1.2 54.4 1.9 9999 999 261.7 3.8 3.14 0.06 420.8 5.7 1.70 0.06 9999 999 1500 31 89538 176.0 2.5 67.7 1.2 54.5 1.9 9999 999 262.2 3.8 3.12 0.06 420.8 5.7 1.69 0.06 9999 999 1504 31 89718 175.7 2.5 67.1 1.2 52.9 1.8 9999 999 9999 999 9999 999 419.7 5.7 1.67 0.06 9999 999 1512 31 89898 176.2 2.5 67.2 1.2 53.8 1.9 9999 999 260.1 3.7 3.11 0.06 418.5 5.7 1.69 0.06 9999 999 1505 31 90078 185.6 2.7 68.3 1.2 58.0 2.0 9999 999 9999 999 9999 999 427.0 5.8 1.92 0.07 9999 999 1509 31 90438 230.5 4.1 77.3 1.4 73.3 2.4 88.4 2.4 9999 999 9999 999 482.2 7.2 2.79 0.09 9999 999 1648 34 90618 251.7 5.2 81.1 1.4 83.4 2.7 97.0 2.6 303.7 4.7 3.58 0.06 503.3 7.7 3.25 0.11 9999 999 1709 35 90798 265.6 6.0 83.5 1.5 90.8 2.9 101.2 2.7 9999 999 9999 999 519.1 8.2 3.58 0.12 9999 999 1738 36 90978 265.7 6.0 83.6 1.5 91.1 2.9 101.8 2.7 311.8 5.0 3.59 0.06 517.2 8.2 3.56 0.12 9999 999 1737 36 91338 276.5 6.8 85.3 1.5 97.8 3.2 105.4 2.8 315.5 5.1 3.71 0.06 527.7 8.5 3.80 0.13 9999 999 1755 36 91518 280.7 7.2 85.7 1.5 99.2 3.2 107.5 2.9 9999 999 9999 999 529.7 8.6 3.82 0.13 9999 999 9999 999