52 1001 ELKINS, JAMES; FAHEY, DAVID; WAMSLEY, PAULA; DUTTON, GEOFF; BARING, THOMAS; ROMASHKIN, PAVEL; HURST, DALE; DUNN, RAY U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS IV, ER-2 STRAT 1 1 1996 08 01 1997 11 05 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 17 The errors reported for each measurement were propagated in quadrature from the following uncertainties: in-flight precision: our ability to make repeatable measurements of calibration gas during each flight calibration precision: our ability to make repeatable measurements of calibration standards during laboratory calibrations of the instrument calibration curve fits: our ability to calculate in-flight mixing ratios using first or second order polynomial curve fits to laboratory calibration measurements Hence, the total errors represent our ability to make in-flight and laboratory calibration measurements, and to apply laboratory calibration curves to the in-flight measurements. They DO NOT reflect inaccuracies of the calibration values assigned to our standards. 1 GMTs F11 F11e F113 F113e MC MCe CT CTe N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e 72418 281.1 7.2 84.8 1.5 89.8 2.9 106.3 2.8 9999 999 9999 999 528.5 8.5 3.61 0.12 9999 999 9999 999 72599 284.5 7.5 85.3 1.5 91.3 3.0 106.4 2.8 306.0 4.8 3.65 0.06 527.2 8.5 3.67 0.12 9999 999 9999 999 72779 275.8 6.8 85.0 1.5 89.9 3.0 106.4 2.8 9999 999 9999 999 528.4 8.5 3.72 0.13 9999 999 9999 999 72959 273.7 6.6 84.5 1.5 88.8 2.9 105.3 2.7 304.3 4.7 3.64 0.06 525.0 8.4 3.74 0.13 9999 999 9999 999 73319 270.3 6.4 85.2 1.5 87.5 2.9 104.2 2.7 304.7 4.8 3.60 0.06 524.5 8.4 3.66 0.12 9999 999 1715 35 73499 265.5 6.0 84.2 1.5 87.3 2.9 103.4 2.7 9999 999 9999 999 521.7 8.3 3.56 0.12 9999 999 1709 35 73679 260.3 5.7 83.4 1.5 86.1 2.8 99.8 2.6 303.9 4.7 3.50 0.06 513.1 8.0 3.36 0.11 9999 999 1676 34 73859 243.2 4.7 79.9 1.4 80.6 2.7 92.5 2.4 9999 999 9999 999 489.4 7.4 3.02 0.10 9999 999 1650 34 74219 242.9 4.7 80.2 1.4 80.6 2.7 92.5 2.4 9999 999 9999 999 491.5 7.4 3.02 0.10 9999 999 1646 33 74399 237.6 4.5 79.1 1.4 80.3 2.7 90.6 2.3 295.4 4.5 3.40 0.06 483.0 7.2 2.92 0.10 9999 999 1656 34 74578 232.4 4.2 77.8 1.4 78.6 2.6 88.8 2.3 9999 999 9999 999 475.3 7.0 2.80 0.09 9999 999 1634 33 74759 232.5 4.2 78.4 1.4 79.3 2.6 89.1 2.3 292.3 4.4 3.37 0.06 475.3 7.0 2.85 0.10 9999 999 1639 33 75119 235.6 4.4 79.1 1.4 79.4 2.6 88.6 2.3 293.6 4.5 3.43 0.06 480.2 7.1 2.81 0.09 9999 999 1640 33 75299 236.3 4.4 79.2 1.4 79.8 2.6 90.2 2.3 9999 999 9999 999 481.8 7.2 2.77 0.09 9999 999 1647 34 75479 240.6 4.6 80.1 1.4 81.7 2.7 92.8 2.4 295.9 4.5 3.35 0.06 486.5 7.3 2.88 0.10 9999 999 1652 34 75658 241.8 4.7 80.3 1.4 82.5 2.7 94.4 2.4 9999 999 9999 999 488.8 7.3 2.92 0.10 9999 999 1646 33 76019 242.9 4.7 80.5 1.4 82.6 2.7 95.0 2.4 9999 999 9999 999 492.9 7.5 2.90 0.10 9999 999 1674 34 76199 243.5 4.8 80.3 1.4 82.6 2.7 9999 999 298.0 4.6 3.40 0.06 492.3 7.4 2.95 0.10 9999 999 1660 34 76379 243.3 4.7 80.9 1.4 83.0 2.7 9999 999 9999 999 9999 999 494.8 7.5 2.95 0.10 9999 999 1692 34 76919 240.1 4.6 79.6 1.4 82.7 2.7 9999 999 297.5 4.6 9999 999 489.9 7.4 2.85 0.10 9999 999 1655 34 77099 243.8 4.8 80.6 1.4 84.4 2.8 9999 999 9999 999 9999 999 496.0 7.5 2.93 0.10 9999 999 1673 34 77279 244.5 4.8 80.4 1.4 85.0 2.8 9999 999 298.7 4.6 3.35 0.06 494.5 7.5 2.99 0.10 9999 999 1662 34 77459 242.3 4.7 80.0 1.4 84.2 2.8 9999 999 9999 999 9999 999 492.2 7.4 2.92 0.10 9999 999 1644 33 77818 242.4 4.7 80.2 1.4 83.8 2.8 9999 999 9999 999 9999 999 493.5 7.5 2.92 0.10 9999 999 1660 34 77999 242.3 4.7 80.3 1.4 83.2 2.7 9999 999 300.4 4.6 3.39 0.06 493.8 7.5 2.93 0.10 9999 999 1669 34 78179 243.1 4.7 80.3 1.4 82.9 2.7 9999 999 9999 999 9999 999 494.4 7.5 2.92 0.10 9999 999 1662 34 78719 242.4 4.7 80.1 1.4 83.7 2.8 9999 999 299.6 4.6 3.36 0.06 495.2 7.5 2.85 0.10 9999 999 1660 34 78899 243.4 4.8 80.7 1.4 83.6 2.8 9999 999 9999 999 9999 999 496.4 7.6 2.89 0.10 9999 999 1666 34 79079 243.2 4.7 80.0 1.4 83.4 2.7 9999 999 299.9 4.6 3.39 0.06 494.6 7.5 2.88 0.10 9999 999 1677 34 79259 243.2 4.7 80.4 1.4 82.9 2.7 9999 999 9999 999 9999 999 496.2 7.5 2.86 0.10 9999 999 1666 34 79619 243.7 4.8 80.0 1.4 83.9 2.8 9999 999 9999 999 9999 999 496.9 7.6 2.87 0.10 9999 999 1652 34 79978 243.5 4.8 80.1 1.4 83.0 2.7 9999 999 9999 999 9999 999 495.2 7.5 2.93 0.10 9999 999 1680 34 80159 243.2 4.7 80.0 1.4 84.5 2.8 9999 999 297.9 4.6 3.31 0.06 493.2 7.5 2.94 0.10 9999 999 1671 34 80519 244.7 4.8 80.4 1.4 84.0 2.8 9999 999 296.0 4.5 3.23 0.06 495.2 7.5 2.97 0.10 9999 999 1663 34 80699 246.1 4.9 80.4 1.4 84.7 2.8 9999 999 9999 999 9999 999 496.6 7.6 3.02 0.10 9999 999 1663 34 80879 246.7 4.9 80.2 1.4 86.6 2.8 9999 999 298.1 4.6 3.26 0.06 497.0 7.6 3.05 0.10 9999 999 1661 34 81059 245.9 4.9 80.5 1.4 84.7 2.8 9999 999 9999 999 9999 999 496.7 7.6 3.01 0.10 9999 999 1688 34 81419 244.7 4.8 80.2 1.4 85.3 2.8 9999 999 9999 999 9999 999 495.6 7.5 2.98 0.10 9999 999 1668 34 81599 257.4 5.5 82.3 1.5 89.5 2.9 9999 999 306.9 4.8 3.44 0.06 508.9 7.9 3.24 0.11 9999 999 1701 35 81779 255.9 5.4 82.2 1.5 87.9 2.9 9999 999 9999 999 9999 999 509.5 7.9 3.20 0.11 9999 999 1681 34 81959 250.9 5.1 81.3 1.5 87.9 2.9 9999 999 304.1 4.7 9999 999 503.0 7.7 3.08 0.10 9999 999 1673 34 82319 249.9 5.1 81.3 1.5 86.6 2.8 9999 999 302.5 4.7 3.37 0.06 502.2 7.7 3.06 0.10 9999 999 1677 34 82499 251.5 5.2 81.4 1.5 87.0 2.9 9999 999 9999 999 9999 999 504.1 7.8 3.05 0.10 9999 999 1698 35 82679 249.0 5.0 81.1 1.5 85.7 2.8 9999 999 302.5 4.7 3.37 0.06 501.4 7.7 3.07 0.10 9999 999 1676 34 83218 248.3 5.0 81.1 1.5 85.3 2.8 9999 999 9999 999 9999 999 502.2 7.7 3.03 0.10 9999 999 1683 34 83399 248.6 5.0 81.3 1.5 85.4 2.8 9999 999 302.8 4.7 3.41 0.06 501.6 7.7 3.03 0.10 9999 999 1681 34 83579 248.8 5.0 81.2 1.5 85.5 2.8 9999 999 9999 999 9999 999 504.1 7.8 3.03 0.10 9999 999 1685 34 83759 247.1 4.9 81.2 1.5 85.5 2.8 9999 999 303.6 4.7 3.41 0.06 502.0 7.7 2.93 0.10 9999 999 1683 34 84119 249.5 5.1 81.3 1.5 86.5 2.8 9999 999 304.3 4.7 3.42 0.06 505.0 7.8 3.04 0.10 9999 999 1690 34 84299 250.0 5.1 81.7 1.5 85.5 2.8 9999 999 9999 999 9999 999 503.3 7.8 3.03 0.10 9999 999 1694 34 84479 249.3 5.1 81.6 1.5 85.5 2.8 9999 999 304.5 4.8 3.38 0.06 502.4 7.7 2.97 0.10 9999 999 1702 35 84659 249.3 5.1 81.3 1.5 85.1 2.8 98.5 2.5 9999 999 9999 999 504.9 7.8 2.96 0.10 9999 999 1684 34 85019 247.3 4.9 81.1 1.5 85.5 2.8 9999 999 9999 999 9999 999 502.2 7.7 2.99 0.10 9999 999 1670 34 85199 249.4 5.1 81.1 1.5 86.0 2.8 9999 999 305.5 4.8 3.47 0.06 504.4 7.8 3.00 0.10 9999 999 1680 34 85378 248.7 5.0 81.3 1.5 85.4 2.8 96.8 2.5 9999 999 9999 999 504.9 7.8 2.95 0.10 9999 999 1694 34 85559 250.1 5.1 81.7 1.5 85.7 2.8 96.4 2.5 304.9 4.8 3.41 0.06 504.2 7.8 2.99 0.10 9999 999 1670 34 85919 249.8 5.1 81.5 1.5 85.5 2.8 98.1 2.5 305.1 4.8 3.41 0.06 504.8 7.8 3.04 0.10 9999 999 1684 34 86099 247.3 5.0 80.8 1.4 84.8 2.8 97.3 2.5 9999 999 9999 999 501.7 7.7 2.96 0.10 9999 999 1678 34 86279 247.9 5.0 81.2 1.5 85.4 2.8 96.7 2.5 304.8 4.8 3.43 0.06 503.0 7.7 2.99 0.10 9999 999 1689 34 86458 245.9 4.9 80.5 1.4 85.1 2.8 95.0 2.4 9999 999 9999 999 502.1 7.7 2.95 0.10 9999 999 1681 34 86819 247.0 4.9 81.0 1.4 84.6 2.8 96.3 2.5 9999 999 9999 999 504.5 7.8 3.01 0.10 9999 999 1688 34 86999 251.0 5.1 81.3 1.5 86.0 2.8 98.5 2.5 306.6 4.8 3.47 0.06 505.7 7.8 3.12 0.10 9999 999 1702 35 87179 260.3 5.7 82.4 1.5 90.0 3.0 98.7 2.5 9999 999 9999 999 515.9 8.1 3.33 0.11 9999 999 1716 35 87359 267.4 6.2 83.4 1.5 92.6 3.0 99.4 2.6 315.8 5.1 3.61 0.06 522.1 8.3 3.56 0.12 9999 999 1736 35 87719 266.6 6.1 83.3 1.5 91.2 3.0 100.0 2.6 311.9 4.9 3.56 0.06 520.2 8.3 3.51 0.12 9999 999 1718 35 87899 258.3 5.6 82.2 1.5 89.4 2.9 98.5 2.5 9999 999 9999 999 512.2 8.0 3.26 0.11 9999 999 1712 35 88079 245.1 4.8 79.9 1.4 84.7 2.8 94.7 2.4 300.2 4.6 3.37 0.06 498.7 7.6 2.99 0.10 9999 999 1682 34 88618 237.8 4.5 79.5 1.4 79.9 2.6 91.8 2.4 9999 999 9999 999 494.2 7.5 2.73 0.09 9999 999 1689 34 88799 232.5 4.2 79.0 1.4 78.3 2.6 9999 999 297.1 4.6 3.39 0.06 489.7 7.4 2.63 0.09 9999 999 1667 34 88979 230.2 4.1 78.9 1.4 77.9 2.6 9999 999 9999 999 9999 999 489.0 7.3 2.52 0.09 9999 999 1654 34 89159 225.1 3.9 78.2 1.4 76.1 2.5 9999 999 294.1 4.5 3.30 0.06 484.5 7.2 2.45 0.08 9999 999 1649 34 89519 223.7 3.9 77.9 1.4 77.5 2.6 9999 999 292.7 4.5 3.32 0.06 482.6 7.2 2.42 0.08 9999 999 1644 33 89699 223.6 3.9 77.5 1.4 75.8 2.5 9999 999 9999 999 9999 999 483.5 7.2 2.41 0.08 9999 999 1648 34 89879 223.9 3.9 77.7 1.4 75.6 2.5 9999 999 294.6 4.5 3.31 0.06 484.0 7.2 2.39 0.08 9999 999 1640 33 90059 221.8 3.8 77.1 1.4 75.8 2.5 9999 999 9999 999 9999 999 479.8 7.1 2.36 0.08 9999 999 1654 34 90419 222.4 3.8 77.8 1.4 74.5 2.5 9999 999 9999 999 9999 999 481.6 7.1 2.39 0.08 9999 999 1642 33 90599 222.0 3.8 77.3 1.4 74.6 2.5 9999 999 293.5 4.5 3.34 0.06 481.4 7.1 2.39 0.08 9999 999 1643 33 90778 221.6 3.8 77.4 1.4 75.9 2.5 9999 999 9999 999 9999 999 481.3 7.1 2.37 0.08 9999 999 1645 33 90959 221.5 3.8 77.7 1.4 76.2 2.5 9999 999 293.7 4.5 3.30 0.06 480.3 7.1 2.40 0.08 9999 999 1643 33 91319 219.4 3.7 77.0 1.4 74.0 2.5 9999 999 290.4 4.4 3.30 0.06 477.8 7.0 2.32 0.08 9999 999 1648 34 91499 216.5 3.6 76.0 1.4 73.2 2.4 9999 999 9999 999 9999 999 474.7 7.0 2.33 0.08 9999 999 1645 33 91679 210.0 3.4 74.8 1.3 72.3 2.4 9999 999 284.0 4.2 3.31 0.06 463.5 6.7 2.25 0.08 9999 999 1590 32 91858 206.4 3.3 73.5 1.3 70.8 2.4 9999 999 9999 999 9999 999 461.2 6.6 2.17 0.08 9999 999 1596 32 92219 203.6 3.2 73.6 1.3 68.6 2.3 9999 999 9999 999 9999 999 458.2 6.6 2.09 0.07 9999 999 1617 33 92399 202.3 3.2 72.5 1.3 68.5 2.3 9999 999 276.3 4.1 3.27 0.06 452.9 6.4 2.21 0.08 9999 999 1598 33 92579 204.2 3.2 73.3 1.3 70.2 2.4 9999 999 9999 999 9999 999 457.9 6.5 2.11 0.07 9999 999 1600 33 92759 204.9 3.2 73.7 1.3 70.1 2.4 9999 999 279.3 4.1 3.28 0.06 458.1 6.5 2.12 0.08 9999 999 1595 32 93119 194.0 2.9 71.1 1.3 65.7 2.2 9999 999 272.1 4.0 3.18 0.06 442.7 6.2 2.00 0.07 9999 999 1563 32 93299 193.5 2.9 70.7 1.3 66.4 2.3 9999 999 9999 999 9999 999 442.5 6.2 1.98 0.07 9999 999 1564 32 93479 196.0 3.0 71.3 1.3 67.0 2.3 9999 999 273.5 4.0 3.13 0.06 445.2 6.2 1.98 0.07 9999 999 1564 32 94018 191.1 2.8 70.0 1.2 63.5 2.2 9999 999 9999 999 9999 999 438.4 6.1 1.95 0.07 9999 999 1555 32 94199 189.8 2.8 69.7 1.2 64.7 2.2 9999 999 268.9 3.9 3.20 0.06 437.3 6.1 1.96 0.07 9999 999 1559 32 94379 187.3 2.8 69.4 1.2 63.4 2.2 9999 999 9999 999 9999 999 435.2 6.0 1.92 0.07 9999 999 1530 31 94559 183.1 2.6 68.7 1.2 61.1 2.1 9999 999 266.0 3.8 3.16 0.06 429.4 5.9 1.84 0.07 9999 999 1523 31 94919 179.8 2.6 67.4 1.2 60.8 2.1 9999 999 262.2 3.8 3.10 0.06 422.1 5.7 1.82 0.07 9999 999 1510 31 95098 179.5 2.6 67.7 1.2 61.0 2.1 9999 999 9999 999 9999 999 424.9 5.8 1.74 0.07 9999 999 1506 31 95279 182.3 2.6 68.5 1.2 60.9 2.1 9999 999 266.2 3.8 3.16 0.06 429.2 5.9 1.76 0.07 9999 999 1521 31 95459 184.1 2.7 69.1 1.2 62.4 2.2 9999 999 9999 999 9999 999 434.1 6.0 1.80 0.07 9999 999 1525 31 95819 189.1 2.8 70.8 1.3 62.4 2.2 9999 999 9999 999 9999 999 442.5 6.2 1.82 0.07 9999 999 1565 32 95999 189.5 2.8 71.1 1.3 63.6 2.2 9999 999 272.2 4.0 3.15 0.06 441.6 6.2 1.80 0.07 9999 999 1559 32 96179 187.6 2.8 70.3 1.2 63.6 2.2 9999 999 9999 999 9999 999 440.7 6.1 1.80 0.07 9999 999 1562 32 96359 188.4 2.8 70.7 1.3 63.0 2.2 9999 999 272.7 4.0 3.25 0.06 442.2 6.2 1.79 0.07 9999 999 1548 32 96719 177.3 2.5 67.3 1.2 60.9 2.1 9999 999 263.2 3.8 3.15 0.06 423.0 5.8 1.63 0.06 9999 999 1503 31 96899 172.9 2.4 66.1 1.2 58.3 2.0 9999 999 9999 999 9999 999 415.3 5.6 1.61 0.06 9999 999 1502 31 97079 174.8 2.5 66.3 1.2 59.3 2.1 9999 999 261.7 3.7 3.17 0.06 414.2 5.6 1.68 0.07 9999 999 1486 30 97258 176.1 2.5 66.8 1.2 60.7 2.1 9999 999 9999 999 9999 999 416.6 5.6 1.72 0.07 9999 999 1497 31 97619 176.2 2.5 66.7 1.2 59.9 2.1 9999 999 9999 999 9999 999 415.1 5.6 1.73 0.07 9999 999 1510 31 97799 180.6 2.6 67.5 1.2 60.2 2.1 9999 999 9999 999 9999 999 417.8 5.6 1.87 0.07 9999 999 1507 31 97979 248.2 5.0 80.3 1.4 85.9 2.8 91.8 2.4 9999 999 9999 999 500.1 7.7 3.07 0.10 9999 999 1697 35 98159 271.1 6.4 84.4 1.5 96.0 3.2 99.0 2.6 9999 999 9999 999 522.2 8.3 3.67 0.12 9999 999 1769 36 98519 280.0 7.1 85.1 1.5 97.1 3.2 111.4 2.9 9999 999 9999 999 529.0 8.5 3.69 0.12 9999 999 1739 35 98699 283.0 7.4 85.7 1.5 91.7 3.0 104.7 2.7 9999 999 9999 999 531.3 8.6 3.70 0.12 9999 999 1663 34