52 1001 ELKINS, JAMES; FAHEY, DAVID; WAMSLEY, PAULA; DUTTON, GEOFF; BARING, THOMAS; ROMASHKIN, PAVEL; HURST, DALE; DUNN, RAY U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS IV, ER-2 STRAT 1 1 1996 07 22 1997 11 05 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 17 The errors reported for each measurement were propagated in quadrature from the following uncertainties: in-flight precision: our ability to make repeatable measurements of calibration gas during each flight calibration precision: our ability to make repeatable measurements of calibration standards during laboratory calibrations of the instrument calibration curve fits: our ability to calculate in-flight mixing ratios using first or second order polynomial curve fits to laboratory calibration measurements Hence, the total errors represent our ability to make in-flight and laboratory calibration measurements, and to apply laboratory calibration curves to the in-flight measurements. They DO NOT reflect inaccuracies of the calibration values assigned to our standards. 1 GMTs F11 F11e F113 F113e MC MCe CT CTe N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e 54445 275.5 6.9 83.8 1.6 91.4 3.6 102.9 2.7 9999 999 9999 999 535.3 8.6 3.82 0.13 9999 999 9999 999 54625 273.0 6.7 81.7 1.5 89.4 3.5 104.3 2.7 311.8 4.9 3.76 0.03 529.1 8.4 3.75 0.13 9999 999 1768 36 54805 273.5 6.8 82.2 1.5 88.1 3.5 102.9 2.7 9999 999 9999 999 530.4 8.5 3.72 0.13 9999 999 1727 36 54985 270.3 6.5 82.1 1.5 85.7 3.4 106.8 2.8 312.8 5.0 3.69 0.03 529.0 8.4 3.77 0.13 9999 999 1782 37 55345 256.8 5.7 78.8 1.5 77.8 3.2 96.4 2.5 299.6 4.6 3.52 0.03 504.0 7.7 3.30 0.11 9999 999 1671 34 55525 250.7 5.4 78.4 1.5 77.5 3.2 94.5 2.5 9999 999 9999 999 500.7 7.6 3.07 0.11 9999 999 1668 34 55705 245.8 5.1 78.2 1.5 79.4 3.3 93.6 2.5 295.8 4.5 3.40 0.03 493.6 7.4 3.10 0.11 9999 999 1652 34 55885 240.7 4.9 76.7 1.4 75.7 3.2 90.1 2.4 9999 999 9999 999 491.5 7.3 2.99 0.10 9999 999 1662 34 56245 232.7 4.5 75.6 1.4 72.9 3.1 85.3 2.2 9999 999 9999 999 479.1 7.0 2.78 0.10 9999 999 1589 33 56425 216.9 4.0 72.3 1.4 68.9 3.0 77.9 2.1 278.9 4.1 3.24 0.03 459.9 6.5 2.42 0.09 9999 999 1571 32 56605 206.0 3.6 69.9 1.3 64.8 2.9 74.5 2.0 9999 999 9999 999 449.1 6.2 2.38 0.09 9999 999 1551 32 56785 205.7 3.6 69.9 1.3 65.0 2.9 74.5 2.0 272.4 4.0 3.20 0.03 447.8 6.2 2.39 0.09 9999 999 1555 32 57145 206.8 3.7 70.6 1.3 65.2 2.9 74.4 2.0 271.6 3.9 3.23 0.03 450.3 6.2 2.37 0.09 9999 999 1557 32 57325 200.0 3.5 69.5 1.3 64.1 2.9 72.1 2.0 9999 999 9999 999 440.7 6.0 2.32 0.08 9999 999 1534 32 57505 198.7 3.5 68.3 1.3 63.3 2.9 70.3 1.9 267.9 3.9 3.13 0.03 438.2 5.9 2.23 0.08 9999 999 1532 32 57685 200.9 3.5 70.2 1.3 65.1 2.9 73.7 2.0 9999 999 9999 999 439.8 6.0 2.29 0.08 9999 999 1527 32 58045 191.7 3.3 67.3 1.3 61.1 2.9 68.9 1.9 9999 999 9999 999 428.9 5.7 2.08 0.08 9999 999 1512 31 58225 191.0 3.3 67.9 1.3 61.7 2.9 68.9 1.9 264.4 3.8 3.06 0.03 427.9 5.7 2.06 0.08 9999 999 1520 31 58405 188.7 3.2 66.2 1.3 59.5 2.8 68.4 1.9 9999 999 9999 999 424.0 5.6 2.11 0.08 9999 999 1487 31 58945 182.8 3.1 65.2 1.2 60.8 2.9 65.8 1.8 257.3 3.6 3.07 0.03 418.6 5.5 2.01 0.08 9999 999 1473 31 59125 179.1 3.0 64.4 1.2 56.4 2.8 66.1 1.9 9999 999 9999 999 411.5 5.4 1.93 0.07 9999 999 1448 30 59305 179.8 3.0 64.7 1.2 57.8 2.8 65.7 1.8 253.6 3.6 3.08 0.03 413.6 5.4 1.94 0.07 9999 999 1455 30 59485 181.0 3.1 64.8 1.2 58.2 2.8 65.5 1.8 9999 999 9999 999 414.7 5.4 1.96 0.08 9999 999 1475 31 59845 171.0 2.9 62.8 1.2 55.2 2.8 62.9 1.8 9999 999 9999 999 403.1 5.2 1.89 0.07 9999 999 1421 30 60025 180.5 3.1 65.4 1.2 59.1 2.8 9999 999 254.4 3.6 3.02 0.03 414.9 5.4 1.94 0.07 9999 999 1450 30 60205 180.5 3.0 65.1 1.2 58.1 2.8 65.7 1.8 9999 999 9999 999 416.2 5.5 1.97 0.08 9999 999 1462 30 60745 178.8 3.0 63.7 1.2 59.6 2.8 66.1 1.9 250.4 3.5 3.02 0.03 407.8 5.3 1.92 0.07 9999 999 1430 30 60925 160.8 2.7 60.5 1.2 53.3 2.7 59.3 1.7 9999 999 9999 999 390.6 5.0 1.65 0.07 9999 999 1401 29 61105 164.0 2.8 61.3 1.2 54.3 2.7 60.6 1.8 242.9 3.4 2.90 0.03 392.6 5.0 1.74 0.07 9999 999 1420 30 61285 168.2 2.8 62.5 1.2 53.9 2.7 9999 999 9999 999 9999 999 398.7 5.1 1.79 0.07 9999 999 1453 30 61645 177.0 3.0 64.0 1.2 57.5 2.8 9999 999 9999 999 9999 999 413.0 5.4 1.85 0.07 9999 999 1485 31 62005 174.5 2.9 63.5 1.2 55.2 2.8 9999 999 9999 999 9999 999 408.3 5.3 1.83 0.07 9999 999 1492 31 62185 172.5 2.9 62.7 1.2 58.4 2.8 9999 999 249.1 3.5 2.99 0.03 404.4 5.2 1.78 0.07 9999 999 1438 30 62545 174.4 2.9 63.8 1.2 58.2 2.8 9999 999 249.6 3.5 2.99 0.03 407.3 5.3 1.88 0.07 9999 999 1472 30 62725 174.1 2.9 63.3 1.2 56.0 2.8 9999 999 9999 999 9999 999 409.2 5.3 1.87 0.07 9999 999 1451 30 62905 176.5 3.0 63.2 1.2 57.5 2.8 9999 999 251.7 3.5 3.04 0.03 409.6 5.3 1.86 0.07 9999 999 1450 30 63085 177.6 3.0 65.1 1.2 59.9 2.8 9999 999 9999 999 9999 999 412.5 5.4 1.79 0.07 9999 999 1463 30 63445 175.3 3.0 63.7 1.2 56.0 2.8 9999 999 9999 999 9999 999 408.5 5.3 1.89 0.07 9999 999 1439 30 63625 154.9 2.6 61.0 1.2 53.2 2.7 9999 999 237.7 3.3 2.86 0.03 381.5 4.8 1.49 0.07 9999 999 1408 29 63805 151.1 2.6 60.1 1.2 50.7 2.7 9999 999 9999 999 9999 999 377.1 4.7 1.40 0.06 9999 999 1363 29 63985 154.0 2.6 60.8 1.2 52.5 2.7 9999 999 237.4 3.2 2.89 0.03 384.0 4.8 1.58 0.07 9999 999 1400 29 64345 164.5 2.8 62.0 1.2 52.6 2.7 9999 999 244.3 3.4 2.87 0.03 393.5 5.0 1.64 0.07 9999 999 1436 30 64525 166.5 2.8 62.5 1.2 59.8 2.8 9999 999 9999 999 9999 999 394.6 5.0 1.73 0.07 9999 999 1426 30 64705 162.4 2.7 62.6 1.2 52.9 2.7 9999 999 242.0 3.3 2.88 0.03 387.8 4.9 1.68 0.07 9999 999 1411 29 65245 169.9 2.9 63.4 1.2 57.5 2.8 9999 999 9999 999 9999 999 402.1 5.2 1.73 0.07 9999 999 1450 30 65425 169.1 2.8 61.8 1.2 55.7 2.8 9999 999 247.8 3.4 2.86 0.03 400.6 5.2 1.75 0.07 9999 999 1435 30 65605 173.3 2.9 63.7 1.2 60.2 2.8 9999 999 9999 999 9999 999 405.6 5.3 1.78 0.07 9999 999 1428 30 65785 196.5 3.4 70.4 1.3 69.1 3.0 9999 999 264.2 3.8 3.08 0.03 434.6 5.9 2.32 0.08 9999 999 1506 31 66145 238.9 4.8 76.6 1.4 79.3 3.3 9999 999 292.2 4.4 3.30 0.03 486.8 7.2 2.98 0.10 9999 999 1609 33 66325 220.5 4.1 72.7 1.4 73.5 3.1 9999 999 9999 999 9999 999 460.9 6.5 2.65 0.09 9999 999 1557 32 66505 193.5 3.3 66.4 1.3 65.8 3.0 9999 999 260.2 3.7 3.06 0.03 425.5 5.7 2.11 0.08 9999 999 1485 31 66685 175.6 3.0 64.3 1.2 58.4 2.8 9999 999 9999 999 9999 999 406.7 5.3 1.89 0.07 9999 999 1441 30 67045 159.6 2.7 61.5 1.2 54.7 2.8 9999 999 9999 999 9999 999 386.2 4.9 1.59 0.07 9999 999 1395 29 67225 149.6 2.6 57.9 1.1 48.6 2.7 9999 999 235.1 3.2 2.85 0.03 373.7 4.6 1.40 0.06 9999 999 1369 29 67405 143.7 2.5 57.1 1.1 43.2 2.6 9999 999 9999 999 9999 999 367.5 4.5 1.35 0.06 9999 999 1360 29 67585 144.9 2.5 57.4 1.1 50.8 2.7 9999 999 231.3 3.1 2.85 0.03 368.8 4.6 1.36 0.06 9999 999 1359 28 67945 138.9 2.4 56.3 1.1 46.6 2.6 9999 999 228.2 3.1 2.86 0.03 362.9 4.5 1.25 0.06 9999 999 1347 28 68125 136.0 2.4 54.6 1.1 42.0 2.6 9999 999 9999 999 9999 999 356.8 4.4 1.22 0.06 9999 999 1329 28 68305 133.8 2.4 54.6 1.1 38.4 2.5 9999 999 225.2 3.0 2.82 0.03 357.7 4.4 1.24 0.06 9999 999 1326 28 68485 134.3 2.4 55.2 1.1 42.4 2.6 9999 999 9999 999 9999 999 356.1 4.3 1.25 0.06 9999 999 1337 28 68845 122.4 2.3 53.4 1.1 39.2 2.5 9999 999 9999 999 9999 999 345.0 4.2 1.05 0.06 9999 999 1311 28 69025 119.0 2.3 52.6 1.0 38.8 2.5 9999 999 217.4 2.9 2.80 0.03 343.6 4.1 0.92 0.06 9999 999 1292 27 69205 119.4 2.3 53.0 1.1 37.4 2.5 9999 999 9999 999 9999 999 345.2 4.2 0.99 0.06 9999 999 1313 28 69385 119.9 2.3 54.3 1.1 42.6 2.6 9999 999 217.6 2.9 2.73 0.03 344.1 4.2 0.93 0.06 9999 999 1313 28 69745 109.2 2.2 49.2 1.0 38.0 2.5 9999 999 208.4 2.7 2.73 0.03 326.7 3.9 0.86 0.06 9999 999 1270 27 69925 116.3 2.2 51.7 1.0 38.0 2.5 9999 999 9999 999 9999 999 336.1 4.0 0.92 0.06 9999 999 1291 27 70105 111.1 2.2 53.3 1.1 37.7 2.5 9999 999 212.2 2.8 2.76 0.03 331.4 4.0 0.88 0.06 9999 999 1282 27 70645 112.4 2.2 50.9 1.0 39.0 2.5 9999 999 9999 999 9999 999 328.3 3.9 0.94 0.06 9999 999 1268 27 70825 114.9 2.2 53.1 1.1 35.3 2.5 9999 999 213.4 2.8 2.79 0.03 335.8 4.0 1.01 0.06 9999 999 1295 27 71005 125.4 2.3 52.3 1.0 39.9 2.5 9999 999 9999 999 9999 999 347.1 4.2 1.12 0.06 9999 999 1311 28 71185 125.6 2.3 53.4 1.1 44.6 2.6 9999 999 217.4 2.9 2.80 0.03 345.2 4.2 1.07 0.06 9999 999 1308 28 71545 122.4 2.3 52.7 1.1 39.9 2.5 9999 999 218.6 2.9 2.80 0.03 342.8 4.1 1.07 0.06 9999 999 1295 27 71725 125.7 2.3 53.6 1.1 43.2 2.6 9999 999 9999 999 9999 999 346.3 4.2 1.07 0.06 9999 999 1318 28 71905 121.7 2.3 53.3 1.1 35.2 2.5 9999 999 216.5 2.9 2.76 0.03 341.7 4.1 1.06 0.06 9999 999 1300 28 72085 115.1 2.2 50.8 1.0 37.2 2.5 9999 999 9999 999 9999 999 328.7 3.9 0.95 0.06 9999 999 1267 27 72445 124.4 2.3 53.6 1.1 40.9 2.6 9999 999 9999 999 9999 999 343.3 4.1 1.07 0.06 9999 999 1323 28 72625 123.9 2.3 53.8 1.1 43.3 2.6 9999 999 217.0 2.9 2.75 0.03 342.5 4.1 1.09 0.06 9999 999 1314 28 72805 127.4 2.3 54.3 1.1 42.8 2.6 9999 999 9999 999 9999 999 348.0 4.2 1.15 0.06 9999 999 1321 28 72985 125.5 2.3 54.3 1.1 41.8 2.6 9999 999 219.0 2.9 2.81 0.03 345.6 4.2 1.13 0.06 9999 999 1323 28 73345 128.2 2.3 54.2 1.1 42.5 2.6 9999 999 218.7 2.9 2.78 0.03 347.8 4.2 1.11 0.06 9999 999 1313 28 73525 126.5 2.3 54.3 1.1 44.6 2.6 9999 999 9999 999 9999 999 346.4 4.2 1.12 0.06 9999 999 1311 28 73706 129.0 2.3 53.9 1.1 40.3 2.5 9999 999 219.6 2.9 2.86 0.03 349.8 4.2 1.10 0.06 9999 999 1325 28 73885 126.4 2.3 53.3 1.1 39.1 2.5 9999 999 9999 999 9999 999 347.5 4.2 1.11 0.06 9999 999 1326 28 74245 135.1 2.4 56.0 1.1 44.8 2.6 9999 999 9999 999 9999 999 359.9 4.4 1.20 0.06 9999 999 1329 28 74425 130.8 2.4 54.4 1.1 44.7 2.6 9999 999 221.2 3.0 2.79 0.03 351.9 4.3 1.18 0.06 9999 999 1324 28 74605 122.0 2.3 52.3 1.0 40.2 2.5 9999 999 9999 999 9999 999 341.4 4.1 1.06 0.06 9999 999 1306 28 74785 122.5 2.3 53.4 1.1 40.6 2.5 9999 999 214.5 2.8 2.70 0.03 339.3 4.1 1.03 0.06 9999 999 1301 28 75145 120.0 2.3 52.1 1.0 41.0 2.6 9999 999 212.3 2.8 2.75 0.03 337.8 4.1 1.00 0.06 9999 999 1292 27 75325 116.7 2.2 51.9 1.0 38.4 2.5 9999 999 9999 999 9999 999 335.3 4.0 0.91 0.06 9999 999 1310 28 75505 124.8 2.3 54.0 1.1 42.6 2.6 9999 999 218.2 2.9 2.79 0.03 345.7 4.2 1.04 0.06 9999 999 1311 28 76045 121.8 2.3 53.2 1.1 41.0 2.6 9999 999 9999 999 9999 999 341.1 4.1 1.07 0.06 9999 999 1314 28 76225 127.5 2.3 55.6 1.1 42.4 2.6 9999 999 219.4 2.9 2.85 0.03 347.6 4.2 1.09 0.06 9999 999 1327 28 76405 126.0 2.3 54.4 1.1 42.8 2.6 9999 999 9999 999 9999 999 347.9 4.2 1.11 0.06 9999 999 1329 28 76585 126.5 2.3 54.3 1.1 43.0 2.6 9999 999 218.7 2.9 2.83 0.03 346.3 4.2 1.06 0.06 9999 999 1318 28 76945 130.4 2.4 56.1 1.1 42.8 2.6 9999 999 222.3 3.0 2.84 0.03 353.1 4.3 1.13 0.06 9999 999 1343 28 77125 127.3 2.3 53.9 1.1 40.8 2.5 9999 999 9999 999 9999 999 348.6 4.2 1.13 0.06 9999 999 1317 28 77305 121.5 2.3 53.9 1.1 39.8 2.5 9999 999 213.9 2.8 2.73 0.03 337.9 4.1 1.00 0.06 9999 999 1309 28 77485 125.9 2.3 54.2 1.1 42.0 2.6 9999 999 9999 999 9999 999 344.9 4.2 1.11 0.06 9999 999 1317 28 77845 131.0 2.4 55.2 1.1 42.7 2.6 9999 999 9999 999 9999 999 356.5 4.4 1.17 0.06 9999 999 1346 28 78025 123.6 2.3 53.5 1.1 41.8 2.6 9999 999 216.8 2.9 2.76 0.03 343.7 4.1 1.01 0.06 9999 999 1305 28 78205 134.6 2.4 55.6 1.1 42.8 2.6 9999 999 9999 999 9999 999 358.2 4.4 1.25 0.06 9999 999 1351 28 78385 123.3 2.3 53.4 1.1 40.7 2.5 9999 999 214.2 2.8 2.74 0.03 340.8 4.1 1.05 0.06 9999 999 1307 28 78745 136.1 2.4 56.4 1.1 49.0 2.7 9999 999 225.1 3.0 2.87 0.03 358.4 4.4 1.22 0.06 9999 999 1345 28 78925 131.1 2.4 55.6 1.1 44.2 2.6 9999 999 9999 999 9999 999 354.9 4.3 1.19 0.06 9999 999 1347 28 79106 129.9 2.4 55.3 1.1 42.1 2.6 9999 999 221.3 3.0 2.82 0.03 352.5 4.3 1.10 0.06 9999 999 1321 28 79285 129.0 2.3 54.9 1.1 42.6 2.6 9999 999 9999 999 9999 999 353.0 4.3 1.17 0.06 9999 999 1330 28 79645 133.3 2.4 55.3 1.1 44.1 2.6 9999 999 9999 999 9999 999 355.3 4.3 1.17 0.06 9999 999 1348 28 79825 135.1 2.4 55.6 1.1 49.0 2.7 9999 999 223.0 3.0 2.89 0.03 356.8 4.4 1.22 0.06 9999 999 1352 28 80005 133.3 2.4 55.6 1.1 45.3 2.6 9999 999 9999 999 9999 999 355.5 4.3 1.16 0.06 9999 999 1345 28 80185 134.3 2.4 56.4 1.1 46.3 2.6 9999 999 223.3 3.0 2.77 0.03 356.9 4.4 1.26 0.06 9999 999 1328 28 80545 180.6 3.1 65.3 1.2 60.6 2.9 9999 999 252.3 3.5 3.08 0.03 411.4 5.4 1.94 0.07 9999 999 1430 30 80725 252.8 5.5 78.8 1.5 84.4 3.4 9999 999 9999 999 9999 999 501.4 7.6 3.22 0.11 9999 999 1641 34 80905 275.5 6.9 83.0 1.6 89.2 3.5 9999 999 310.1 4.9 3.71 0.03 531.1 8.5 3.75 0.13 9999 999 1774 37 81085 277.8 7.1 84.2 1.6 90.7 3.5 9999 999 9999 999 9999 999 533.3 8.6 3.77 0.13 9999 999 1769 36 81445 281.2 7.4 84.0 1.6 89.9 3.5 9999 999 9999 999 9999 999 534.8 8.6 3.81 0.13 9999 999 9999 999