52 1001 ELKINS, JAMES; FAHEY, DAVID; WAMSLEY, PAULA; DUTTON, GEOFF; BARING, THOMAS; ROMASHKIN, PAVEL; HURST, DALE; DUNN, RAY U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS IV, ER-2 STRAT 1 1 1996 02 13 1997 11 05 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 17 The errors reported for each measurement were propagated in quadrature from the following uncertainties: in-flight precision: our ability to make repeatable measurements of calibration gas during each flight calibration precision: our ability to make repeatable measurements of calibration standards during laboratory calibrations of the instrument calibration curve fits: our ability to calculate in-flight mixing ratios using first or second order polynomial curve fits to laboratory calibration measurements Hence, the total errors represent our ability to make in-flight and laboratory calibration measurements, and to apply laboratory calibration curves to the in-flight measurements. They DO NOT reflect inaccuracies of the calibration values assigned to our standards. 1 GMTs F11 F11e F113 F113e MC MCe CT CTe N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e 72452 287.6 9.6 83.1 1.3 95.7 1.7 107.8 2.8 9999 999 9999 999 527.6 14.0 3.71 0.28 9999 999 9999 999 72632 286.1 9.4 84.5 1.3 97.2 1.7 107.6 2.8 318.2 5.4 3.72 0.07 540.1 14.7 3.80 0.29 9999 999 9999 999 72812 278.9 8.5 83.2 1.3 96.1 1.7 106.2 2.8 9999 999 9999 999 543.5 14.9 3.74 0.29 9999 999 9999 999 72992 279.1 8.6 84.4 1.3 97.4 1.7 107.3 2.8 315.5 5.4 3.63 0.07 543.4 14.9 3.72 0.28 9999 999 9999 999 73352 272.7 7.9 82.9 1.3 97.0 1.7 107.0 2.8 312.4 5.3 3.65 0.07 538.0 14.6 3.67 0.28 541 13 1702 21 73532 271.5 7.8 82.1 1.3 97.1 1.7 105.4 2.8 9999 999 9999 999 534.5 14.4 3.54 0.26 543 13 1706 21 73712 269.4 7.6 82.4 1.3 96.9 1.7 105.8 2.8 309.6 5.2 3.63 0.07 525.6 13.9 3.52 0.26 542 13 1697 21 73892 271.4 7.8 82.7 1.3 97.9 1.7 105.8 2.8 9999 999 9999 999 522.6 13.8 3.47 0.25 545 13 1691 21 74252 269.4 7.6 82.0 1.3 97.9 1.7 105.8 2.8 9999 999 9999 999 521.2 13.7 3.54 0.26 551 13 1701 21 74432 271.9 7.8 83.0 1.3 97.5 1.7 105.0 2.8 306.6 5.1 3.58 0.07 519.2 13.6 3.55 0.26 543 13 1694 21 74612 269.5 7.6 82.5 1.3 97.3 1.7 104.4 2.8 9999 999 9999 999 524.8 13.9 3.51 0.25 545 13 1720 21 74792 270.3 7.7 82.8 1.3 96.4 1.7 105.0 2.8 309.6 5.2 3.57 0.07 518.2 13.5 3.45 0.25 546 13 1702 21 75152 243.0 5.6 78.2 1.2 89.5 1.6 90.7 2.6 292.7 4.8 3.33 0.06 488.9 12.1 2.96 0.19 549 13 1648 20 75332 216.6 4.3 73.7 1.1 80.9 1.6 80.3 2.4 9999 999 9999 999 453.9 10.7 2.49 0.15 555 13 1567 19 75512 214.4 4.2 72.8 1.1 79.8 1.5 80.7 2.4 271.5 4.4 3.07 0.06 448.6 10.5 2.40 0.15 544 13 1547 19 75692 210.8 4.1 72.0 1.1 79.9 1.5 9999 999 9999 999 9999 999 449.5 10.5 2.37 0.14 552 13 1558 19 76052 211.7 4.1 72.2 1.1 80.6 1.6 9999 999 9999 999 9999 999 446.0 10.4 2.38 0.14 550 13 1540 19 76232 209.0 4.0 71.9 1.1 79.0 1.5 9999 999 269.3 4.4 3.04 0.06 441.9 10.2 2.34 0.14 560 13 1543 19 76412 201.8 3.8 70.4 1.1 77.3 1.5 9999 999 9999 999 9999 999 435.2 10.0 2.17 0.13 547 13 1515 18 76952 201.4 3.8 70.0 1.1 79.4 1.5 9999 999 264.6 4.3 2.99 0.06 428.7 9.7 2.11 0.13 552 13 1507 18 77132 214.5 4.2 72.5 1.1 80.9 1.6 9999 999 9999 999 9999 999 450.7 10.5 2.33 0.14 558 13 1554 19 77312 223.8 4.6 74.2 1.1 85.9 1.6 9999 999 280.8 4.6 3.09 0.06 464.6 11.1 2.56 0.16 559 13 1595 19 77492 218.3 4.4 73.2 1.1 84.5 1.6 9999 999 9999 999 9999 999 462.4 11.0 2.57 0.16 559 13 1575 19 77852 219.7 4.4 73.6 1.1 84.5 1.6 9999 999 9999 999 9999 999 461.9 11.0 2.48 0.15 563 13 1593 19 78032 238.3 5.3 77.2 1.2 91.0 1.6 9999 999 293.1 4.9 3.26 0.06 483.5 11.9 2.79 0.18 547 13 1621 20 78212 241.1 5.5 78.2 1.2 91.3 1.6 9999 999 9999 999 9999 999 483.7 11.9 2.73 0.17 547 13 1622 20 78752 241.1 5.5 77.6 1.2 90.9 1.6 9999 999 291.6 4.8 3.22 0.06 485.3 12.0 2.85 0.18 537 13 1629 20 78932 242.0 5.6 78.2 1.2 91.2 1.6 9999 999 9999 999 9999 999 491.0 12.2 2.84 0.18 562 13 1657 20 79112 240.2 5.4 78.2 1.2 91.0 1.6 9999 999 295.2 4.9 3.25 0.06 478.9 11.7 2.71 0.17 547 13 1624 20 79292 226.8 4.8 75.1 1.2 88.1 1.6 9999 999 9999 999 9999 999 466.8 11.2 2.48 0.15 547 13 1582 19 79652 232.2 5.0 76.5 1.2 88.6 1.6 9999 999 9999 999 9999 999 475.9 11.6 2.64 0.17 573 13 1617 20 80012 239.6 5.4 77.8 1.2 90.8 1.6 9999 999 9999 999 9999 999 489.0 12.1 2.82 0.18 575 13 1656 20 80192 242.2 5.6 78.3 1.2 91.9 1.6 9999 999 295.1 4.9 3.30 0.06 486.2 12.0 2.91 0.19 562 13 1648 20 80552 244.7 5.7 79.3 1.2 92.5 1.6 9999 999 296.6 4.9 3.30 0.06 491.5 12.3 2.89 0.19 556 13 1665 20 80732 245.3 5.7 79.2 1.2 92.3 1.6 9999 999 9999 999 9999 999 492.3 12.3 2.94 0.19 9999 999 1651 20 80912 246.7 5.8 78.8 1.2 91.0 1.6 9999 999 293.9 4.9 3.20 0.06 489.7 12.2 2.93 0.19 564 13 1638 20 81092 244.2 5.7 79.1 1.2 91.6 1.6 9999 999 9999 999 9999 999 490.1 12.2 2.95 0.19 557 13 1659 20 81452 251.8 6.2 80.5 1.3 93.2 1.6 9999 999 9999 999 9999 999 499.3 12.6 2.93 0.19 548 13 1662 20 81632 248.8 6.0 80.1 1.2 93.8 1.7 9999 999 299.9 5.0 3.32 0.06 498.7 12.6 2.87 0.19 553 13 1667 20 81812 248.0 5.9 80.2 1.2 92.3 1.6 9999 999 9999 999 9999 999 496.1 12.5 2.90 0.19 549 13 1643 20 81992 252.9 6.2 81.4 1.3 94.0 1.7 9999 999 300.3 5.0 3.18 0.06 499.9 12.7 2.85 0.18 536 13 1666 20 82352 246.4 5.8 80.1 1.2 94.8 1.7 9999 999 300.6 5.0 3.23 0.06 493.1 12.3 2.92 0.19 541 13 1666 20 82532 249.1 6.0 80.4 1.3 94.4 1.7 9999 999 9999 999 9999 999 498.4 12.6 2.89 0.19 536 13 1660 20 82712 245.2 5.7 80.4 1.3 90.3 1.6 9999 999 299.7 5.0 3.28 0.06 497.6 12.5 2.80 0.18 558 13 1683 20 83252 240.1 5.4 79.6 1.2 92.2 1.6 9999 999 9999 999 9999 999 495.4 12.4 2.66 0.17 554 13 1676 20 83432 235.9 5.2 78.6 1.2 90.5 1.6 9999 999 294.4 4.9 3.25 0.06 487.3 12.1 2.62 0.16 545 13 1644 20 83612 236.2 5.2 79.1 1.2 87.8 1.6 9999 999 9999 999 9999 999 487.6 12.1 2.53 0.16 540 13 1631 20 83792 240.2 5.4 79.0 1.2 89.5 1.6 9999 999 296.0 4.9 3.20 0.06 492.9 12.3 2.61 0.16 559 13 1666 20 84152 243.9 5.7 80.4 1.2 90.7 1.6 9999 999 299.5 5.0 3.34 0.06 497.0 12.5 2.56 0.16 559 13 1654 20 84332 244.3 5.7 80.2 1.2 91.1 1.6 9999 999 9999 999 9999 999 502.8 12.8 2.60 0.16 538 13 1681 20 84512 243.0 5.6 80.0 1.2 91.2 1.6 9999 999 300.4 5.0 3.28 0.06 496.4 12.5 2.65 0.17 542 13 1672 20 84692 246.8 5.8 80.4 1.2 92.2 1.6 9999 999 9999 999 9999 999 499.0 12.6 2.72 0.17 537 13 1666 20 85052 241.2 5.5 80.3 1.2 89.6 1.6 9999 999 9999 999 9999 999 499.8 12.6 2.61 0.16 552 13 1675 20 85232 249.7 6.0 81.3 1.3 91.5 1.6 9999 999 302.7 5.1 3.33 0.06 503.5 12.8 2.70 0.17 540 13 1677 20 85412 244.2 5.7 80.7 1.3 90.8 1.6 9999 999 9999 999 9999 999 502.6 12.8 2.72 0.17 549 13 1694 21 85592 244.1 5.7 80.2 1.2 90.1 1.6 9999 999 300.4 5.0 3.29 0.06 501.1 12.7 2.72 0.17 548 13 1679 20 85952 240.5 5.5 80.3 1.2 89.5 1.6 9999 999 299.4 5.0 3.29 0.06 502.6 12.8 2.62 0.16 542 13 1679 20 86132 240.2 5.4 80.9 1.3 89.0 1.6 9999 999 9999 999 9999 999 502.6 12.8 2.60 0.16 551 13 1682 20 86312 240.4 5.5 80.6 1.3 90.1 1.6 9999 999 298.5 5.0 3.26 0.06 498.3 12.6 2.55 0.16 548 13 1657 20 86492 241.4 5.5 80.6 1.3 89.3 1.6 9999 999 9999 999 9999 999 504.7 12.9 2.60 0.16 535 13 1672 20 86852 250.6 6.1 81.3 1.3 92.9 1.6 9999 999 9999 999 9999 999 507.3 13.0 2.91 0.19 534 13 1664 20 87032 265.5 7.2 82.2 1.3 93.7 1.7 107.3 2.8 309.0 5.2 3.45 0.07 520.2 13.6 3.19 0.22 535 13 1705 21 87212 272.1 7.8 82.8 1.3 95.0 1.7 9999 999 9999 999 9999 999 527.5 14.0 3.65 0.27 535 13 1694 21 87392 274.9 8.1 82.7 1.3 96.7 1.7 9999 999 312.3 5.3 3.62 0.07 521.7 13.7 3.67 0.28 533 13 1666 20 87752 267.0 7.4 82.2 1.3 97.9 1.7 105.4 2.8 310.6 5.2 3.36 0.07 511.1 13.2 3.33 0.23 545 13 1698 21 87932 262.5 7.0 82.5 1.3 95.5 1.7 9999 999 9999 999 9999 999 505.9 12.9 3.13 0.21 543 13 1670 20 88112 255.8 6.5 81.0 1.3 93.3 1.7 102.7 2.7 304.3 5.1 3.38 0.07 500.9 12.7 3.01 0.20 542 13 1681 20 88652 243.9 5.7 80.5 1.3 91.9 1.6 9999 999 9999 999 9999 999 495.6 12.5 2.71 0.17 543 13 1671 20 88832 240.0 5.4 80.4 1.2 89.4 1.6 9999 999 302.2 5.0 3.29 0.06 490.6 12.2 2.45 0.15 546 13 1662 20 89012 237.8 5.3 81.1 1.3 89.3 1.6 9999 999 9999 999 9999 999 489.1 12.2 2.41 0.15 553 13 1650 20 89192 235.8 5.2 80.5 1.3 85.9 1.6 9999 999 298.7 5.0 3.28 0.06 487.6 12.1 2.37 0.14 535 13 1648 20 89552 232.8 5.0 78.8 1.2 88.4 1.6 9999 999 296.2 4.9 3.27 0.06 481.7 11.8 2.35 0.14 542 13 1627 20 89732 231.4 5.0 79.6 1.2 87.3 1.6 9999 999 9999 999 9999 999 485.1 12.0 2.37 0.14 549 13 1636 20 89912 231.3 5.0 78.8 1.2 87.1 1.6 9999 999 297.5 4.9 3.27 0.06 483.4 11.9 2.40 0.15 556 13 1648 20 90092 228.4 4.8 79.8 1.2 86.6 1.6 9999 999 9999 999 9999 999 481.3 11.8 2.33 0.14 554 13 1615 20 90452 228.9 4.9 78.3 1.2 88.5 1.6 9999 999 9999 999 9999 999 483.6 11.9 2.34 0.14 555 13 1635 20 90632 231.1 5.0 78.8 1.2 86.3 1.6 9999 999 296.3 4.9 3.20 0.06 481.8 11.8 2.35 0.14 549 13 1629 20 90812 230.4 4.9 79.0 1.2 86.1 1.6 9999 999 9999 999 9999 999 484.4 11.9 2.38 0.14 547 13 1636 20 90992 231.9 5.0 78.3 1.2 86.1 1.6 9999 999 294.3 4.9 3.18 0.06 479.5 11.7 2.44 0.15 549 13 1641 20 91352 224.1 4.6 75.9 1.2 84.9 1.6 9999 999 286.4 4.7 3.11 0.06 465.6 11.1 2.39 0.15 529 13 1589 19 91532 220.5 4.5 75.8 1.2 83.0 1.6 9999 999 9999 999 9999 999 465.0 11.1 2.35 0.14 551 13 1598 19 91712 219.9 4.4 74.7 1.1 83.2 1.6 9999 999 284.9 4.7 3.11 0.06 460.8 10.9 2.32 0.14 546 13 1585 19 91892 216.8 4.3 74.8 1.2 81.5 1.6 9999 999 9999 999 9999 999 456.1 10.8 2.31 0.14 533 13 1559 19 92252 215.9 4.3 74.6 1.1 82.4 1.6 9999 999 9999 999 9999 999 455.4 10.7 2.23 0.13 554 13 1570 19 92432 210.6 4.1 72.8 1.1 79.0 1.5 9999 999 275.3 4.5 3.02 0.06 448.5 10.5 2.20 0.13 547 13 1553 19 92612 199.7 3.7 71.1 1.1 75.7 1.5 9999 999 9999 999 9999 999 434.0 9.9 2.08 0.12 559 13 1519 18 92792 194.7 3.5 69.7 1.1 73.2 1.5 9999 999 264.6 4.3 2.96 0.06 425.2 9.6 1.99 0.12 553 13 1514 18 93152 187.1 3.3 67.9 1.0 70.9 1.5 9999 999 259.3 4.2 2.90 0.06 418.2 9.4 1.83 0.11 549 13 1492 18 93332 197.4 3.6 70.9 1.1 75.4 1.5 9999 999 9999 999 9999 999 430.1 9.8 2.05 0.12 561 13 1511 18 93512 196.5 3.6 69.8 1.1 76.3 1.5 9999 999 266.3 4.3 2.93 0.06 426.7 9.7 2.00 0.12 551 13 1527 18 94052 196.2 3.6 70.2 1.1 76.0 1.5 9999 999 9999 999 9999 999 427.5 9.7 1.97 0.12 548 13 1485 18 94232 184.7 3.3 67.7 1.0 69.7 1.5 9999 999 257.9 4.2 2.90 0.06 414.2 9.2 1.80 0.11 544 13 1497 18 94412 185.1 3.3 68.4 1.0 70.4 1.5 9999 999 9999 999 9999 999 415.7 9.3 1.68 0.10 551 13 1480 18 94592 188.5 3.4 68.5 1.0 72.9 1.5 9999 999 260.6 4.2 2.90 0.06 415.1 9.2 1.87 0.11 552 13 1505 18 94952 184.4 3.3 67.4 1.0 69.5 1.5 9999 999 258.1 4.2 2.84 0.06 414.0 9.2 1.81 0.11 561 13 1477 18 95132 182.8 3.2 68.7 1.0 70.5 1.5 9999 999 9999 999 9999 999 412.9 9.2 1.75 0.10 557 13 1468 18 95312 182.0 3.2 67.9 1.0 69.2 1.5 9999 999 255.3 4.1 2.90 0.06 409.6 9.1 1.72 0.10 549 13 1501 18 95492 180.5 3.2 68.4 1.0 68.7 1.5 9999 999 9999 999 9999 999 411.2 9.1 1.71 0.10 560 13 1481 18 95852 180.5 3.2 67.9 1.0 69.5 1.5 9999 999 9999 999 9999 999 407.3 9.0 1.72 0.10 560 13 1449 18 96032 178.5 3.1 67.3 1.0 67.9 1.5 9999 999 254.1 4.1 2.86 0.06 407.7 9.0 1.65 0.10 563 13 1515 18 96212 177.5 3.1 68.1 1.0 67.5 1.5 9999 999 9999 999 9999 999 405.7 8.9 1.65 0.10 562 13 1465 18 96392 179.6 3.1 67.9 1.0 68.0 1.5 9999 999 254.2 4.1 2.86 0.06 406.8 9.0 1.68 0.10 562 13 1530 18 96752 171.7 3.0 65.9 1.0 64.6 1.5 9999 999 250.2 4.1 2.78 0.06 397.9 8.7 1.57 0.10 561 13 1467 18 96932 172.6 3.0 66.5 1.0 67.0 1.5 9999 999 9999 999 9999 999 397.8 8.7 1.55 0.09 556 13 1429 17 97112 165.6 2.8 65.1 1.0 63.1 1.4 9999 999 244.7 4.0 2.83 0.06 389.6 8.4 1.45 0.09 558 13 9999 999 97292 161.4 2.7 64.9 1.0 61.1 1.4 9999 999 9999 999 9999 999 385.0 8.3 1.44 0.09 555 13 1436 17 97652 164.7 2.8 65.2 1.0 64.2 1.5 9999 999 9999 999 9999 999 387.6 8.4 1.49 0.09 546 13 1417 17 97832 162.3 2.8 64.2 1.0 62.1 1.4 9999 999 239.9 3.9 9999 999 384.4 8.3 1.42 0.09 555 13 9999 999 98012 161.6 2.7 64.9 1.0 61.7 1.4 9999 999 9999 999 9999 999 384.0 8.3 1.41 0.09 560 13 1483 18 98192 178.1 3.1 67.9 1.0 69.3 1.5 9999 999 250.7 4.1 9999 999 408.7 9.0 1.75 0.10 563 13 9999 999 98552 268.0 7.4 82.0 1.3 95.3 1.7 104.7 2.8 302.2 5.1 9999 999 512.7 13.3 3.46 0.25 567 13 9999 999 98732 279.9 8.7 82.9 1.3 98.8 1.7 9999 999 9999 999 9999 999 522.6 13.8 3.66 0.27 552 13 9999 999 98912 281.0 8.8 82.5 1.3 98.2 1.7 9999 999 308.7 5.2 9999 999 522.5 13.8 3.76 0.29 558 13 9999 999 99092 278.4 8.5 82.2 1.3 99.5 1.7 9999 999 9999 999 9999 999 523.6 13.8 3.80 0.29 557 13 9999 999