52 1001 ELKINS, JAMES; FAHEY, DAVID; WAMSLEY, PAULA; DUTTON, GEOFF; BARING, THOMAS; ROMASHKIN, PAVEL; HURST, DALE; DUNN, RAY U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS IV, ER-2 STRAT 1 1 1995 11 09 1997 11 05 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) CCl2FCClF2 (F113) MIXING RATIO (PPT) CCl2FCClF2 (F113) ERROR 1-sd (PPT) CH3CCl3 (MC) MIXING RATIO (PPT) CH3CCl3 (MC) ERROR 1-sd (PPT) CCl4 (CT) MIXING RATIO (PPT) CCl4 (CT) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) 17 The errors reported for each measurement were propagated in quadrature from the following uncertainties: in-flight precision: our ability to make repeatable measurements of calibration gas during each flight calibration precision: our ability to make repeatable measurements of calibration standards during laboratory calibrations of the instrument calibration curve fits: our ability to calculate in-flight mixing ratios using first or second order polynomial curve fits to laboratory calibration measurements Hence, the total errors represent our ability to make in-flight and laboratory calibration measurements, and to apply laboratory calibration curves to the in-flight measurements. They DO NOT reflect inaccuracies of the calibration values assigned to our standards. 1 GMTs F11 F11e F113 F113e MC MCe CT CTe N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e 68257 9999 999 85.1 1.4 9999 999 9999 999 9999 999 9999 999 565.3 17.7 3.96 0.22 618 27 1771 84 68437 9999 999 87.5 1.4 104.6 1.7 105.4 4.1 9999 999 3.66 0.04 566.9 17.8 3.94 0.22 590 27 1756 84 68617 269.4 9.9 83.6 1.4 101.8 1.7 106.1 4.1 9999 999 9999 999 563.7 17.6 3.89 0.22 587 27 1756 84 68797 260.9 9.1 82.2 1.3 97.2 1.7 98.3 4.0 306.1 4.5 3.39 0.04 535.2 16.2 3.73 0.21 594 27 1747 83 69157 242.4 7.6 78.5 1.3 9999 999 9999 999 314.9 4.7 3.49 0.04 505.6 14.8 3.31 0.20 563 27 1711 82 69337 231.5 6.9 77.1 1.2 92.4 1.6 86.6 3.9 9999 999 9999 999 457.0 13.0 2.69 0.19 590 27 1662 80 69517 242.5 7.6 80.2 1.3 98.1 1.7 92.2 3.9 309.3 4.6 3.30 0.04 478.3 13.8 2.86 0.19 570 27 1697 81 69697 218.7 6.1 74.3 1.2 89.8 1.6 82.4 3.8 9999 999 9999 999 454.3 12.9 2.60 0.18 563 27 1624 78 70057 211.3 5.8 72.6 1.2 9999 999 9999 999 9999 999 9999 999 444.3 12.6 2.36 0.18 595 27 1589 76 70237 209.4 5.7 72.9 1.2 85.2 1.6 77.9 3.8 280.4 4.1 3.07 0.04 440.1 12.5 2.13 0.18 535 26 1577 76 70417 198.4 5.2 70.5 1.1 81.1 1.6 72.4 3.8 9999 999 9999 999 427.7 12.1 2.06 0.17 9999 999 1553 75 70597 186.5 4.8 67.3 1.1 76.1 1.5 67.8 3.8 263.4 3.8 2.99 0.04 429.2 12.2 2.02 0.17 545 27 1549 75 70957 195.8 5.1 69.8 1.1 9999 999 9999 999 276.7 4.0 3.05 0.04 435.9 12.4 2.24 0.18 562 27 1563 75 71137 200.0 5.3 70.7 1.1 9999 999 9999 999 9999 999 9999 999 437.3 12.4 1.87 0.17 9999 999 1553 75 71317 198.6 5.3 70.4 1.1 9999 999 9999 999 273.9 3.9 3.06 0.04 435.8 12.4 2.06 0.17 518 26 1570 76 71497 197.7 5.2 70.3 1.1 9999 999 9999 999 9999 999 9999 999 437.4 12.4 1.94 0.17 530 26 1574 76 71857 194.2 5.1 69.5 1.1 9999 999 9999 999 9999 999 9999 999 433.3 12.3 2.06 0.17 536 26 1564 75 72037 188.4 4.9 68.5 1.1 9999 999 9999 999 271.6 3.9 3.06 0.04 423.2 12.0 1.96 0.17 526 26 1550 75 72217 181.6 4.7 67.0 1.1 9999 999 9999 999 9999 999 9999 999 420.4 11.9 1.92 0.17 533 26 1534 74 72757 161.4 4.1 62.4 1.0 9999 999 9999 999 252.9 3.6 2.85 0.04 395.2 11.3 1.62 0.17 587 27 1485 72 72937 160.4 4.1 61.8 1.0 9999 999 9999 999 9999 999 9999 999 394.3 11.3 1.63 0.17 548 27 1471 72 73117 158.0 4.0 61.0 1.0 9999 999 9999 999 250.9 3.6 2.80 0.04 395.3 11.3 1.53 0.17 584 27 1485 72 73297 164.4 4.2 63.1 1.0 9999 999 9999 999 9999 999 9999 999 401.3 11.4 1.60 0.17 583 27 1503 73 73657 158.9 4.0 61.6 1.0 9999 999 9999 999 9999 999 9999 999 383.8 11.0 1.55 0.17 558 27 1481 72 73837 162.8 4.1 62.4 1.0 9999 999 9999 999 256.8 3.7 2.81 0.04 391.7 11.2 1.82 0.17 545 27 1502 73 74017 163.0 4.1 62.9 1.0 9999 999 9999 999 9999 999 9999 999 385.3 11.0 1.49 0.17 577 27 1483 72 74557 158.5 4.0 62.0 1.0 9999 999 9999 999 252.8 3.6 2.88 0.04 386.6 11.1 1.54 0.17 561 27 1468 72 74737 161.2 4.1 62.6 1.0 9999 999 9999 999 9999 999 9999 999 393.4 11.2 1.62 0.17 590 27 1481 72 74917 169.9 4.3 64.4 1.0 9999 999 9999 999 263.3 3.8 2.90 0.04 404.9 11.5 1.74 0.17 543 26 1512 73 75097 168.0 4.3 64.2 1.0 9999 999 9999 999 9999 999 9999 999 400.1 11.4 1.68 0.17 534 26 1480 72 75457 152.9 3.9 60.4 1.0 9999 999 9999 999 9999 999 9999 999 381.6 11.0 1.43 0.17 576 27 1467 72 75817 155.9 3.9 61.1 1.0 9999 999 9999 999 9999 999 9999 999 385.1 11.0 1.48 0.17 567 27 1452 71 75997 157.1 4.0 61.2 1.0 9999 999 9999 999 245.4 3.5 2.80 0.04 385.9 11.1 1.44 0.17 551 27 1487 72 76357 171.2 4.3 64.1 1.0 9999 999 9999 999 259.7 3.7 2.93 0.04 414.3 11.8 1.87 0.17 536 26 1513 73 76537 160.1 4.0 61.8 1.0 9999 999 9999 999 9999 999 9999 999 391.2 11.2 1.54 0.17 574 27 1478 72 76717 155.1 3.9 60.8 1.0 9999 999 9999 999 252.2 3.6 2.88 0.04 384.9 11.0 1.60 0.17 570 27 1468 72 76897 153.6 3.9 60.6 1.0 9999 999 9999 999 9999 999 9999 999 382.8 11.0 1.57 0.17 538 26 1469 72 77257 150.5 3.8 60.0 1.0 9999 999 9999 999 9999 999 9999 999 377.7 10.9 1.52 0.17 541 26 1453 71 77437 151.4 3.8 60.2 1.0 9999 999 9999 999 242.4 3.5 2.75 0.04 379.2 10.9 1.43 0.17 576 27 1450 71 77617 162.9 4.1 62.9 1.0 9999 999 9999 999 9999 999 9999 999 399.0 11.4 1.60 0.17 537 26 1494 73 77797 169.2 4.3 64.7 1.1 9999 999 9999 999 256.5 3.7 2.88 0.04 404.5 11.5 1.73 0.17 527 26 1520 74 78157 178.1 4.5 66.7 1.1 9999 999 9999 999 262.1 3.7 2.93 0.04 410.0 11.6 1.45 0.17 569 27 1542 75 78337 191.1 5.0 70.0 1.1 9999 999 9999 999 9999 999 9999 999 441.8 12.5 2.09 0.18 559 27 1570 76 78517 206.8 5.6 73.0 1.2 9999 999 9999 999 281.7 4.1 3.04 0.04 457.0 13.0 2.19 0.18 569 27 1598 77 79057 183.0 4.7 67.9 1.1 9999 999 9999 999 9999 999 9999 999 433.6 12.3 1.75 0.17 556 27 1530 74 79237 179.5 4.6 66.7 1.1 9999 999 9999 999 262.3 3.7 2.89 0.04 430.0 12.2 1.54 0.17 550 27 1542 75 79417 195.2 5.1 71.0 1.1 9999 999 9999 999 9999 999 9999 999 460.5 13.1 1.92 0.17 563 27 1568 76 79597 203.7 5.5 73.1 1.2 9999 999 9999 999 278.1 4.0 3.04 0.04 454.0 12.9 1.93 0.17 555 27 1581 76 79957 201.3 5.4 72.7 1.2 9999 999 9999 999 282.8 4.1 3.03 0.04 457.8 13.1 2.18 0.18 546 27 1583 76 80137 200.5 5.3 72.7 1.2 9999 999 9999 999 9999 999 9999 999 462.3 13.2 1.94 0.17 553 27 1584 76 80317 199.4 5.3 72.6 1.2 9999 999 9999 999 279.8 4.0 3.01 0.04 458.7 13.1 2.00 0.17 550 27 1594 77 80497 198.6 5.2 72.8 1.2 9999 999 9999 999 9999 999 9999 999 470.4 13.5 2.30 0.18 572 27 1609 77 80857 202.5 5.4 73.7 1.2 9999 999 9999 999 9999 999 9999 999 469.5 13.5 1.86 0.17 580 27 1602 77 81037 213.8 5.9 73.2 1.2 9999 999 9999 999 288.2 4.2 3.18 0.04 479.8 13.8 2.46 0.18 560 27 1613 77 81217 210.7 5.8 72.1 1.2 9999 999 9999 999 9999 999 9999 999 456.6 13.0 2.42 0.18 584 27 1592 77 81397 268.9 9.9 82.7 1.3 103.8 1.7 108.3 4.1 317.1 4.8 3.45 0.04 521.9 15.5 3.65 0.21 575 27 1728 82 81757 273.4 10.4 83.3 1.4 103.8 1.7 102.9 4.0 312.3 4.7 3.47 0.04 522.1 15.6 3.51 0.21 550 27 1729 82 81937 246.5 7.9 79.4 1.3 9999 999 9999 999 9999 999 9999 999 489.5 14.2 3.00 0.19 557 27 1677 80 82117 224.0 6.4 74.9 1.2 9999 999 9999 999 289.1 4.2 3.16 0.04 475.0 13.7 2.72 0.19 527 26 1621 78 82297 216.1 6.0 73.6 1.2 9999 999 9999 999 9999 999 9999 999 460.4 13.1 2.47 0.18 582 27 1600 77 82657 191.5 5.0 69.0 1.1 9999 999 9999 999 9999 999 9999 999 429.8 12.2 9999 999 550 27 1570 76 82837 161.2 4.1 62.5 1.0 9999 999 9999 999 250.9 3.6 2.91 0.04 398.0 11.3 1.62 0.17 530 26 1489 72 83017 152.5 3.9 60.6 1.0 9999 999 9999 999 9999 999 9999 999 378.7 10.9 1.46 0.17 539 26 1437 70 83197 160.1 4.0 62.7 1.0 9999 999 9999 999 252.5 3.6 2.90 0.04 388.0 11.1 1.30 0.17 548 27 1488 72 83557 132.5 3.5 55.4 0.9 9999 999 9999 999 233.4 3.3 2.73 0.04 352.7 10.4 9999 999 550 27 1400 69 83737 141.4 3.6 57.8 1.0 9999 999 9999 999 9999 999 9999 999 371.0 10.7 1.44 0.17 553 27 1433 70 83917 141.0 3.6 57.9 1.0 9999 999 9999 999 239.3 3.4 2.82 0.04 368.2 10.7 1.44 0.17 574 27 1426 70 84457 142.9 3.7 58.2 1.0 9999 999 9999 999 9999 999 9999 999 380.5 10.9 1.36 0.17 550 27 1428 70 84637 142.6 3.7 58.6 1.0 9999 999 9999 999 242.0 3.5 2.82 0.04 382.4 11.0 1.41 0.17 555 27 1443 71 84817 140.2 3.6 57.8 1.0 9999 999 9999 999 9999 999 9999 999 371.8 10.8 1.46 0.17 577 27 1429 70 84997 139.4 3.6 57.8 1.0 9999 999 9999 999 236.7 3.4 2.82 0.04 373.0 10.8 1.29 0.17 575 27 1407 69 85357 133.6 3.5 56.0 0.9 9999 999 9999 999 234.3 3.3 2.71 0.04 363.9 10.6 1.28 0.17 562 27 1416 70 85537 131.7 3.5 55.6 0.9 9999 999 9999 999 9999 999 9999 999 360.1 10.5 1.12 0.17 548 27 1393 69 85717 134.3 3.5 56.1 0.9 9999 999 9999 999 230.9 3.3 2.82 0.04 366.7 10.6 0.90 0.16 550 27 1403 69 85897 141.1 3.6 57.9 1.0 9999 999 9999 999 9999 999 9999 999 371.9 10.8 1.38 0.17 547 27 1428 70 86257 156.3 4.0 61.6 1.0 9999 999 9999 999 9999 999 9999 999 394.8 11.3 1.55 0.17 562 27 1460 71 86437 165.9 4.2 63.4 1.0 9999 999 9999 999 248.3 3.5 2.92 0.04 399.4 11.4 1.77 0.17 566 27 1480 72 86617 238.6 7.3 77.9 1.3 9999 999 9999 999 9999 999 9999 999 492.7 14.3 3.24 0.20 574 27 1687 81 86797 273.1 10.3 84.0 1.4 105.3 1.7 109.4 4.1 311.6 4.7 3.42 0.04 525.3 15.7 3.53 0.21 556 27 1727 82 87157 278.9 11.1 84.9 1.4 106.3 1.8 109.6 4.1 314.5 4.7 3.50 0.04 521.5 15.5 3.47 0.20 576 27 1731 83 87337 282.0 11.5 85.2 1.4 105.9 1.8 110.0 4.1 9999 999 9999 999 531.3 16.0 3.30 0.20 556 27 1742 83 87517 283.2 11.6 85.7 1.4 9999 999 9999 999 315.1 4.7 3.60 0.04 527.7 15.8 3.64 0.21 540 26 1727 82 87697 289.4 12.5 86.4 1.4 9999 999 9999 999 9999 999 9999 999 517.7 15.4 9999 999 9999 999 9999 999