37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 11 04 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 61588 273.7 0.3 85.4 0.5 116.8 0.7 117.5 1.2 99999 99999 99999 99999 539.1 2.0 3.79 0.07 99999 99999 99999 99999 61768 274.9 0.3 85.5 0.5 116.3 0.7 114.8 1.2 312.1 1.3 3.01 0.02 534.6 1.9 3.64 0.07 99999 99999 99999 99999 61948 275.8 0.3 86.2 0.5 115.3 0.7 114.4 1.2 99999 99999 99999 99999 536.6 2.0 3.67 0.07 99999 99999 99999 99999 62128 275.3 0.3 86.4 0.5 115.8 0.7 113.7 1.2 310.8 1.2 3.08 0.02 533.3 1.9 3.70 0.07 99999 99999 99999 99999 62488 273.1 0.3 84.8 0.5 115.9 0.6 113.0 1.2 309.1 1.1 3.06 0.02 532.9 1.9 3.72 0.07 522 20 1740 30 62668 252.7 0.3 80.4 0.5 107.3 0.6 105.2 1.1 99999 99999 99999 99999 504.0 1.9 3.11 0.06 513 20 1668 29 62848 258.8 0.3 81.4 0.5 109.1 0.6 108.2 1.1 302.7 1.0 2.89 0.02 511.9 1.9 3.30 0.06 532 20 1693 29 63028 253.6 0.3 80.8 0.5 108.5 0.6 105.7 1.1 99999 99999 99999 99999 505.9 1.9 3.08 0.06 530 20 1676 29 63388 232.7 0.3 77.1 0.5 98.8 0.6 95.1 1.1 99999 99999 99999 99999 477.3 2.0 2.64 0.06 513 20 1602 28 63568 232.6 0.3 77.5 0.5 98.7 0.6 95.1 1.1 288.5 1.0 2.75 0.02 477.0 2.0 2.58 0.06 541 20 1605 28 63748 230.8 0.3 77.6 0.5 97.7 0.6 93.8 1.1 99999 99999 99999 99999 476.6 2.0 2.54 0.06 531 20 1600 28 63928 229.9 0.3 76.9 0.5 96.7 0.6 92.2 1.1 288.3 1.0 2.74 0.02 473.2 2.0 2.53 0.06 543 20 1649 28 64288 226.2 0.3 76.1 0.5 95.6 0.6 91.4 1.1 285.2 1.0 2.73 0.02 468.4 2.0 2.51 0.06 549 20 1594 27 64468 224.0 0.3 75.7 0.5 94.3 0.6 90.1 1.1 99999 99999 99999 99999 469.3 2.0 2.40 0.06 519 20 1561 27 64648 212.3 0.3 73.2 0.6 88.0 0.6 84.7 1.0 277.5 1.0 2.67 0.02 451.6 2.1 2.07 0.05 509 20 1576 27 64828 207.0 0.3 72.6 0.6 87.0 0.6 82.1 1.0 99999 99999 99999 99999 446.9 2.1 2.11 0.06 510 20 1529 26 65188 215.5 0.3 74.4 0.6 89.4 0.6 86.3 1.0 99999 99999 99999 99999 457.7 2.1 2.24 0.06 559 20 1549 26 65368 212.9 0.3 73.5 0.6 88.1 0.6 85.1 1.0 279.9 1.0 2.66 0.02 455.1 2.1 2.26 0.06 521 20 1558 26 65548 213.8 0.3 73.7 0.6 88.7 0.6 86.3 1.0 99999 99999 99999 99999 456.1 2.1 2.26 0.06 526 20 1528 26 66088 211.1 0.3 72.3 0.6 88.4 0.6 84.2 1.0 278.6 1.0 2.68 0.02 452.2 2.1 2.23 0.06 523 20 1552 26 66268 205.6 0.3 71.8 0.6 84.9 0.6 81.5 1.0 99999 99999 99999 99999 446.9 2.1 2.11 0.06 550 20 1509 25 66448 204.9 0.3 72.2 0.6 84.7 0.6 80.9 1.0 274.5 1.0 2.68 0.02 445.0 2.1 2.04 0.06 538 20 1534 26 66628 203.0 0.3 71.5 0.6 81.8 0.6 80.1 1.0 99999 99999 99999 99999 444.5 2.1 1.95 0.05 501 20 1506 25 66988 198.5 0.3 70.8 0.6 81.4 0.6 79.3 1.0 99999 99999 99999 99999 437.7 2.1 2.00 0.06 545 20 1499 25 67168 196.9 0.3 69.8 0.6 81.6 0.6 78.1 1.0 270.1 1.1 2.64 0.02 434.6 2.1 1.90 0.05 556 20 1511 26 67348 194.0 0.3 69.6 0.6 79.5 0.6 75.7 1.0 99999 99999 99999 99999 432.7 2.1 1.83 0.05 485 20 1511 26 67888 194.1 0.3 69.6 0.6 80.1 0.6 77.0 1.0 266.9 1.1 2.58 0.02 430.9 2.1 1.89 0.05 586 20 1529 26 68068 187.2 0.3 67.2 0.6 76.6 0.6 73.2 1.0 99999 99999 99999 99999 421.6 2.2 1.90 0.05 540 20 1494 25 68248 156.2 0.3 60.3 0.7 63.6 0.6 61.0 1.0 240.6 1.2 2.47 0.02 376.5 2.1 1.51 0.05 545 20 1415 24 68428 150.0 0.3 57.2 0.7 61.6 0.6 58.4 1.0 99999 99999 99999 99999 368.6 2.0 1.41 0.05 565 20 1355 23 68788 152.2 0.3 57.9 0.7 61.2 0.6 59.8 1.0 99999 99999 99999 99999 372.0 2.0 1.47 0.05 586 20 1386 24 69148 179.4 0.3 66.4 0.6 72.4 0.6 69.5 1.0 99999 99999 99999 99999 412.9 2.2 1.68 0.05 588 20 1456 25 69328 177.2 0.3 64.7 0.7 73.0 0.6 68.0 1.0 254.9 1.1 2.51 0.02 406.8 2.1 1.72 0.05 571 20 1484 25 69688 174.2 0.3 64.1 0.7 71.3 0.6 69.7 1.0 253.3 1.1 2.50 0.02 401.9 2.1 1.66 0.05 540 20 1495 26 69868 166.4 0.3 61.7 0.7 67.6 0.6 64.3 1.0 99999 99999 99999 99999 392.9 2.1 1.58 0.05 511 20 1426 25 70048 151.5 0.3 57.3 0.7 61.3 0.6 56.9 1.0 236.7 1.2 2.45 0.02 372.8 2.1 1.47 0.05 571 20 1394 24 70228 145.9 0.3 56.3 0.7 58.5 0.6 55.8 1.0 99999 99999 99999 99999 363.7 2.0 1.33 0.05 578 20 1378 24 70588 145.1 0.3 56.4 0.7 58.3 0.6 57.4 1.0 99999 99999 99999 99999 364.1 2.0 1.33 0.05 583 19 1382 24 70768 146.0 0.3 56.2 0.7 58.4 0.6 56.2 1.0 233.2 1.2 2.45 0.02 364.0 2.0 1.39 0.05 564 19 1424 25 70948 138.3 0.3 55.8 0.7 54.8 0.6 52.8 1.0 99999 99999 99999 99999 354.3 2.0 1.23 0.05 551 19 1361 24 71128 144.3 0.3 56.7 0.7 58.5 0.6 54.6 1.0 231.9 1.2 2.47 0.02 361.3 2.0 1.22 0.05 533 19 1436 25 71488 154.7 0.3 60.6 0.7 62.6 0.6 60.9 1.0 238.3 1.2 2.45 0.02 367.1 2.0 1.39 0.05 562 19 1402 24 71668 149.0 0.3 58.1 0.7 60.3 0.6 57.5 1.0 99999 99999 99999 99999 370.3 2.0 1.30 0.05 572 19 1434 25 71848 155.0 0.3 60.0 0.7 61.7 0.6 58.5 1.0 241.3 1.2 2.46 0.02 378.7 2.1 1.39 0.05 567 19 1472 25 72388 132.5 0.2 54.5 0.7 52.2 0.6 51.9 1.0 99999 99999 99999 99999 347.5 1.9 1.17 0.05 530 19 1351 23 72568 106.5 0.2 47.5 0.6 41.1 0.6 41.0 0.9 206.4 1.2 2.28 0.02 309.4 1.6 0.94 0.05 541 19 1325 23 72748 120.6 0.2 51.6 0.7 46.8 0.6 45.3 0.9 99999 99999 99999 99999 329.2 1.8 1.06 0.05 551 19 1319 23 72928 118.8 0.2 50.9 0.6 46.0 0.6 43.7 0.9 215.1 1.2 2.29 0.02 326.6 1.8 1.09 0.05 525 19 1257 22 73288 126.0 0.2 53.2 0.7 49.3 0.6 48.7 1.0 219.9 1.2 2.33 0.02 336.9 1.8 1.17 0.05 541 19 1309 23 73468 137.0 0.3 56.1 0.7 54.1 0.6 52.1 1.0 99999 99999 99999 99999 353.6 2.0 1.23 0.05 548 19 1337 23 73648 164.9 0.3 63.1 0.7 67.0 0.6 62.9 1.0 250.4 1.1 2.51 0.02 397.4 2.1 1.51 0.05 536 19 1447 25 73828 117.7 0.2 51.2 0.6 45.2 0.6 44.1 0.9 99999 99999 99999 99999 327.7 1.8 1.09 0.05 534 19 1283 22 74188 81.3 0.2 42.4 0.6 29.6 0.6 32.3 0.9 99999 99999 99999 99999 277.5 1.4 0.76 0.05 545 19 1190 21 74368 69.6 0.2 39.7 0.5 24.1 0.6 26.8 0.9 179.7 1.2 2.22 0.02 259.5 1.3 0.71 0.05 534 19 1185 21 74548 67.4 0.2 38.5 0.5 22.9 0.7 26.5 0.9 99999 99999 99999 99999 255.4 1.3 0.64 0.05 540 19 1135 20 74728 61.3 0.2 37.3 0.5 20.7 0.7 23.9 0.9 172.7 1.2 2.16 0.02 245.1 1.2 0.64 0.05 548 19 1178 21 75088 67.2 0.2 38.7 0.5 23.1 0.7 27.2 0.9 177.3 1.2 2.17 0.02 256.5 1.3 0.65 0.05 556 19 1168 21 75268 68.4 0.2 38.5 0.5 24.7 0.6 27.6 0.9 99999 99999 99999 99999 258.9 1.3 0.65 0.05 582 19 1162 21 75448 68.3 0.2 38.9 0.5 24.1 0.6 26.7 0.9 178.8 1.2 2.24 0.02 257.3 1.3 0.68 0.05 548 19 1185 21 75628 66.0 0.2 37.6 0.5 22.5 0.7 26.1 0.9 99999 99999 99999 99999 252.5 1.3 0.64 0.05 560 19 1102 20 75988 125.7 0.2 53.3 0.7 48.1 0.6 49.6 1.0 99999 99999 99999 99999 331.5 1.8 1.15 0.05 551 19 1364 24 76168 121.7 0.2 50.8 0.6 46.1 0.6 48.2 0.9 216.1 1.2 2.36 0.02 322.7 1.7 1.07 0.05 584 19 1321 23 76348 95.9 0.2 44.2 0.6 34.9 0.6 37.3 0.9 99999 99999 99999 99999 285.1 1.4 0.83 0.05 566 19 1222 22 76528 182.9 0.3 63.8 0.7 74.3 0.7 72.6 1.0 255.7 1.1 2.57 0.02 409.2 2.1 1.84 0.05 576 19 1487 26 76888 107.3 0.2 47.4 0.6 40.0 0.6 42.5 0.9 204.6 1.2 2.28 0.02 304.9 1.6 1.03 0.05 546 19 1268 23 77068 97.3 0.2 44.3 0.6 35.8 0.6 38.1 0.9 99999 99999 99999 99999 294.8 1.5 0.86 0.05 554 19 1219 22 77248 116.2 0.2 49.4 0.6 43.9 0.6 45.4 0.9 210.3 1.2 2.32 0.02 313.2 1.7 1.05 0.05 555 19 1301 23 77788 176.4 0.3 65.6 0.6 71.9 0.7 69.8 1.0 99999 99999 99999 99999 406.7 2.1 1.66 0.05 531 19 1470 26 77968 170.5 0.3 64.4 0.7 69.0 0.6 65.6 1.0 252.3 1.1 2.48 0.02 402.4 2.1 1.52 0.05 535 19 1479 26 78148 116.6 0.2 51.0 0.6 45.3 0.6 43.8 0.9 99999 99999 99999 99999 322.5 1.7 1.05 0.05 544 19 1270 22 78328 118.1 0.2 51.5 0.6 46.2 0.6 44.3 0.9 215.7 1.2 2.30 0.02 329.0 1.8 1.11 0.05 560 19 1334 23 78688 122.2 0.2 53.1 0.7 48.1 0.6 47.5 0.9 217.8 1.2 2.35 0.02 335.9 1.8 1.11 0.05 580 19 1345 23 78868 114.4 0.2 50.9 0.6 45.2 0.6 43.6 0.9 99999 99999 99999 99999 323.0 1.7 1.01 0.05 567 19 1277 22 79048 128.1 0.2 53.9 0.7 50.9 0.6 47.9 0.9 221.9 1.2 2.36 0.02 341.7 1.9 1.12 0.05 559 19 1365 24 79228 147.4 0.3 59.1 0.7 59.5 0.6 55.0 1.0 99999 99999 99999 99999 368.6 2.0 1.30 0.05 581 19 1384 24 79588 153.5 0.3 60.5 0.7 62.0 0.6 59.2 1.0 99999 99999 99999 99999 379.8 2.1 1.39 0.05 559 19 1406 24 79768 155.5 0.3 61.1 0.7 62.4 0.6 58.8 1.0 242.1 1.2 2.45 0.02 378.8 2.1 1.39 0.05 583 19 1430 25 79948 145.4 0.3 58.8 0.7 58.4 0.6 54.7 1.0 99999 99999 99999 99999 369.7 2.0 1.28 0.05 532 20 1377 24 80128 144.9 0.3 57.8 0.7 58.4 0.6 53.8 1.0 234.2 1.2 2.42 0.02 366.4 2.0 1.34 0.05 574 19 1394 24 80488 135.8 0.3 56.1 0.7 54.7 0.6 52.5 1.0 226.7 1.2 2.37 0.02 350.0 1.9 1.32 0.05 591 19 1375 24 80668 133.8 0.2 55.9 0.7 52.9 0.6 50.9 1.0 99999 99999 99999 99999 349.5 1.9 1.19 0.05 555 19 1356 24 80848 123.6 0.2 52.6 0.7 49.1 0.6 46.5 0.9 218.6 1.2 2.35 0.02 331.8 1.8 1.14 0.05 565 19 1338 24 81028 168.0 0.3 62.4 0.7 68.1 0.6 64.4 1.0 99999 99999 99999 99999 393.5 2.1 1.62 0.05 558 20 1435 25 81388 204.3 0.3 69.7 0.6 84.5 0.7 80.9 1.0 99999 99999 99999 99999 438.2 2.1 2.25 0.06 595 20 1508 26 81568 223.3 0.3 73.7 0.6 92.1 0.7 88.8 1.0 282.1 1.0 2.70 0.02 468.2 2.1 2.56 0.06 550 20 1582 28 81748 226.9 0.3 73.8 0.6 94.3 0.7 90.8 1.0 99999 99999 99999 99999 472.1 2.1 2.67 0.06 571 19 1552 27 81928 236.9 0.3 76.0 0.5 98.4 0.7 94.9 1.0 290.5 1.0 2.78 0.02 483.6 2.0 2.74 0.06 537 20 1604 28 82288 195.4 0.3 67.7 0.6 80.5 0.7 77.1 1.0 264.2 1.1 2.57 0.02 430.0 2.2 1.93 0.05 554 20 1506 27 82468 188.5 0.3 67.0 0.6 77.1 0.7 72.5 1.0 99999 99999 99999 99999 420.8 2.2 1.89 0.05 519 20 1479 26 82648 153.2 0.3 58.4 0.7 61.5 0.6 58.4 1.0 238.4 1.2 2.44 0.02 374.1 2.1 1.47 0.05 584 19 1415 25 83188 163.7 0.3 62.8 0.7 66.9 0.6 63.1 1.0 99999 99999 99999 99999 391.9 2.1 1.46 0.05 569 19 1424 25 83368 176.2 0.3 66.1 0.6 72.0 0.7 66.5 1.0 258.6 1.1 2.54 0.02 411.2 2.2 1.61 0.05 563 19 1496 26 83548 179.7 0.3 66.8 0.6 73.7 0.7 68.2 1.0 99999 99999 99999 99999 421.1 2.2 1.60 0.05 556 19 1490 26 83728 166.9 0.3 64.6 0.7 67.8 0.6 62.3 1.0 253.1 1.1 2.51 0.02 397.8 2.1 1.52 0.05 553 19 1470 26 84088 164.3 0.3 63.7 0.7 66.3 0.6 62.2 1.0 250.2 1.2 2.45 0.02 385.5 2.1 1.41 0.05 557 19 1464 26 84268 152.1 0.3 59.8 0.7 61.0 0.6 57.2 1.0 99999 99999 99999 99999 376.1 2.1 1.37 0.05 554 19 1392 25 84448 166.2 0.3 63.7 0.7 67.2 0.6 62.4 1.0 250.8 1.1 2.46 0.02 394.9 2.1 1.57 0.05 551 19 1457 26 84628 172.9 0.3 65.0 0.7 70.3 0.6 65.3 1.0 99999 99999 99999 99999 406.3 2.1 1.54 0.05 532 19 1468 26 85528 171.5 0.3 65.8 0.6 71.6 0.6 59.6 1.0 250.0 1.2 2.51 0.02 99999 99999 99999 99999 99999 99999 99999 99999 85888 152.4 0.3 61.2 0.7 62.9 0.6 58.6 1.0 240.8 1.2 2.46 0.02 376.7 2.1 1.40 0.05 586 19 99999 99999 86068 157.8 0.3 62.0 0.7 64.3 0.6 60.5 1.0 99999 99999 99999 99999 385.8 2.1 1.49 0.05 545 19 99999 99999 86248 163.4 0.3 63.6 0.7 66.4 0.6 61.4 1.0 249.5 1.2 2.50 0.02 394.8 2.1 1.53 0.05 554 19 99999 99999 86428 158.8 0.3 62.6 0.7 64.1 0.6 59.3 1.0 99999 99999 99999 99999 387.4 2.1 1.52 0.05 566 19 99999 99999 86788 139.7 0.3 57.5 0.7 55.8 0.6 53.1 1.0 99999 99999 99999 99999 359.3 2.0 1.26 0.05 575 19 99999 99999 86968 130.2 0.2 54.8 0.7 51.3 0.6 48.9 1.0 224.7 1.2 2.33 0.02 345.6 1.9 1.30 0.05 581 19 99999 99999 87148 123.0 0.2 53.1 0.7 48.3 0.6 46.2 1.0 99999 99999 99999 99999 335.9 1.8 1.11 0.05 580 19 1375 25 87328 126.4 0.2 53.4 0.7 49.1 0.6 47.2 1.0 221.3 1.2 2.40 0.02 339.1 1.9 1.14 0.05 577 19 1432 26 87688 230.6 0.3 76.5 0.5 94.7 0.6 92.8 1.1 287.7 1.0 2.71 0.02 474.8 2.1 2.58 0.06 528 20 1593 29 87868 252.1 0.3 80.9 0.5 105.3 0.6 102.1 1.1 99999 99999 99999 99999 500.7 2.0 3.11 0.06 519 20 1665 30 88048 244.9 0.3 78.4 0.5 101.8 0.6 98.1 1.1 294.7 1.0 2.76 0.02 490.5 2.0 3.06 0.06 538 20 1656 30 88228 272.7 0.3 84.5 0.5 113.5 0.6 109.5 1.1 99999 99999 99999 99999 528.8 2.0 3.46 0.07 505 20 1718 31 88588 273.8 0.3 85.4 0.5 114.1 0.6 109.4 1.1 99999 99999 99999 99999 530.0 2.0 3.69 0.07 504 20 99999 99999 88768 273.2 0.3 84.5 0.5 99999 99999 109.6 1.1 99999 99999 99999 99999 99999 99999 3.72 0.07 490 20 99999 99999