37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 11 02 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 64258 271.1 5.0 86.2 2.6 117.4 2.1 114.5 2.2 99999 99999 99999 99999 553.0 8.7 3.65 0.06 99999 99999 99999 99999 64438 275.2 5.0 87.3 2.6 115.8 2.1 114.9 2.2 99999 99999 99999 99999 554.9 8.7 3.73 0.06 99999 99999 99999 99999 64618 268.9 4.9 84.3 2.5 116.6 2.1 112.4 2.2 99999 99999 99999 99999 537.5 8.3 3.60 0.06 99999 99999 99999 99999 64798 270.5 4.9 84.7 2.4 116.2 2.1 112.3 2.2 99999 99999 99999 99999 536.2 8.3 3.71 0.06 99999 99999 99999 99999 65158 275.3 4.9 85.6 2.4 115.6 2.1 112.5 2.2 99999 99999 99999 99999 532.4 8.2 3.76 0.06 516 13 1763 23 65338 274.4 4.9 85.9 2.4 115.3 2.1 110.9 2.2 99999 99999 99999 99999 529.5 8.1 3.52 0.06 524 13 1707 22 65518 262.5 4.7 84.0 2.4 112.6 2.1 105.8 2.2 99999 99999 99999 99999 514.5 7.8 3.37 0.05 502 13 1711 22 65698 247.8 4.4 80.7 2.3 107.2 2.1 100.4 2.1 99999 99999 99999 99999 498.8 7.6 3.06 0.05 555 12 1640 21 66058 212.8 3.7 73.1 2.2 92.5 2.0 84.5 2.0 99999 99999 99999 99999 448.5 6.7 2.46 0.05 534 13 1530 20 66238 203.9 3.6 69.7 2.2 86.0 2.0 79.0 2.0 99999 99999 99999 99999 425.3 6.3 2.11 0.05 538 13 1537 20 66418 195.2 3.4 67.6 2.2 84.1 1.9 75.8 1.9 99999 99999 99999 99999 425.8 6.3 1.96 0.05 550 13 1490 19 66598 189.8 3.3 68.1 2.2 83.0 1.9 74.3 1.9 99999 99999 99999 99999 413.7 6.1 1.89 0.04 546 13 1493 19 66958 191.0 3.3 67.3 2.1 81.2 1.9 73.9 1.9 99999 99999 99999 99999 421.1 6.2 1.96 0.05 576 13 1509 19 67138 183.7 3.2 67.5 2.2 80.2 1.9 71.9 1.9 99999 99999 99999 99999 416.5 6.2 1.89 0.04 579 13 1463 19 67318 190.5 3.3 69.9 2.2 82.4 1.9 74.2 1.9 99999 99999 99999 99999 424.9 6.3 1.97 0.05 568 13 1480 19 67498 193.1 3.4 68.9 2.2 82.8 2.0 75.2 1.9 99999 99999 99999 99999 423.8 6.4 2.03 0.05 539 13 1476 19 67858 202.7 3.5 71.1 2.2 86.8 2.0 79.6 2.0 99999 99999 99999 99999 438.4 6.7 2.08 0.05 542 13 1517 20 68038 193.7 3.4 69.1 2.2 83.2 2.0 75.7 2.0 99999 99999 99999 99999 424.6 6.4 1.97 0.05 540 13 1518 20 68218 224.7 3.9 75.4 2.2 96.0 2.0 90.3 2.0 99999 99999 99999 99999 467.7 7.2 2.55 0.05 535 13 1584 20 68758 207.0 3.6 71.9 2.2 87.7 2.0 81.4 2.0 99999 99999 99999 99999 441.4 6.7 2.19 0.05 524 13 1550 20 68938 214.4 3.7 73.7 2.2 91.1 2.0 84.5 2.0 99999 99999 99999 99999 452.7 6.9 2.31 0.05 558 13 1540 20 69118 192.7 3.3 68.8 2.2 82.3 1.9 75.6 1.9 99999 99999 99999 99999 429.5 6.5 1.90 0.05 557 13 1495 19 69298 164.8 2.8 61.5 2.1 68.1 1.9 61.7 1.9 99999 99999 99999 99999 388.3 5.7 1.53 0.04 558 13 1398 18 69658 133.3 2.3 54.5 2.1 55.5 1.9 51.0 1.8 99999 99999 99999 99999 355.0 5.2 1.32 0.04 505 13 1323 17 69838 127.8 2.2 53.5 2.1 52.1 1.9 47.3 1.8 99999 99999 99999 99999 338.6 4.9 1.24 0.04 540 13 1344 18 70018 157.7 2.7 61.3 2.1 65.1 1.9 59.4 1.9 99999 99999 99999 99999 379.1 5.6 1.55 0.04 533 13 1422 18 70558 144.7 2.6 57.8 2.2 59.0 1.9 54.0 1.9 99999 99999 99999 99999 360.1 5.3 1.34 0.04 525 13 1384 18 70738 160.7 2.8 61.9 2.2 66.3 1.9 60.7 1.9 99999 99999 99999 99999 377.0 5.7 1.50 0.04 544 13 1394 18 70918 171.2 3.0 63.8 2.2 71.0 1.9 65.4 1.9 99999 99999 99999 99999 398.2 6.0 1.66 0.04 570 13 1460 19 71098 154.3 2.7 60.0 2.2 63.0 1.9 58.1 1.9 99999 99999 99999 99999 373.7 5.6 1.43 0.04 571 13 1381 18 71458 167.1 0.4 63.3 0.6 69.1 0.5 64.1 0.8 99999 99999 99999 99999 391.3 2.7 1.66 0.04 587 13 1453 19 71818 208.3 0.4 72.5 0.5 86.6 0.5 80.4 0.8 99999 99999 99999 99999 444.1 2.9 2.08 0.05 577 13 1536 20 71998 207.4 0.4 72.2 0.5 86.7 0.5 80.8 0.8 99999 99999 99999 99999 444.1 2.9 2.13 0.05 576 13 1565 20 72358 166.0 0.4 62.5 0.6 67.7 0.5 63.2 0.8 99999 99999 99999 99999 392.9 2.7 1.71 0.04 559 13 1462 19 72538 157.8 0.4 60.4 0.6 64.5 0.5 60.1 0.8 99999 99999 99999 99999 376.8 2.6 1.50 0.04 556 13 1391 19 72718 163.0 0.4 61.5 0.6 66.9 0.5 62.4 0.8 99999 99999 99999 99999 382.9 2.7 1.55 0.04 545 13 1446 19 72898 187.7 0.4 67.5 0.5 78.0 0.5 72.6 0.8 99999 99999 99999 99999 414.1 2.8 1.77 0.05 575 13 1473 20 73258 189.6 0.4 68.1 0.5 78.5 0.5 74.0 0.8 99999 99999 99999 99999 423.6 2.9 1.93 0.05 519 13 1491 20 73438 190.1 0.4 68.1 0.5 79.1 0.5 73.3 0.8 99999 99999 99999 99999 423.6 2.9 1.84 0.05 602 13 1513 20 73618 190.4 0.4 69.1 0.5 79.4 0.5 74.1 0.8 99999 99999 99999 99999 423.5 2.9 1.90 0.05 555 13 1486 20 73798 185.4 0.4 67.1 0.6 76.7 0.5 70.9 0.8 99999 99999 99999 99999 418.5 2.9 1.83 0.05 617 14 1505 20 74158 186.4 0.4 68.0 0.5 76.7 0.5 72.2 0.8 99999 99999 99999 99999 419.3 2.9 1.83 0.05 572 13 1537 20 74338 184.8 0.4 66.8 0.6 76.4 0.5 71.9 0.8 99999 99999 99999 99999 417.6 2.9 1.83 0.05 571 13 1498 20 74518 184.6 0.4 66.6 0.6 76.3 0.5 71.8 0.8 99999 99999 99999 99999 417.2 2.8 1.80 0.05 562 13 1508 20 75058 187.4 0.4 67.7 0.5 78.0 0.5 72.9 0.8 99999 99999 99999 99999 420.5 2.9 1.84 0.05 569 13 1473 20 75238 188.3 0.4 67.7 0.5 78.3 0.5 72.8 0.8 99999 99999 99999 99999 421.3 2.9 1.86 0.05 553 13 1524 20 75418 183.3 0.4 66.2 0.6 75.1 0.5 70.9 0.8 99999 99999 99999 99999 404.9 2.8 1.76 0.04 550 13 1467 20 75598 183.8 0.4 65.7 0.6 75.7 0.5 71.5 0.8 99999 99999 99999 99999 414.2 2.8 1.89 0.05 579 13 1488 20 75958 233.4 0.5 76.2 0.4 96.8 0.5 94.0 0.8 99999 99999 99999 99999 473.8 3.0 2.62 0.05 543 13 1607 21 76138 243.9 0.5 77.8 0.4 101.4 0.5 99.1 0.8 99999 99999 99999 99999 492.0 3.1 2.87 0.05 546 13 1622 21 76318 246.4 0.5 78.6 0.4 102.8 0.5 99.5 0.8 99999 99999 99999 99999 493.9 3.1 2.97 0.05 540 13 1618 21 76498 233.8 0.5 76.3 0.4 97.2 0.5 93.7 0.8 99999 99999 99999 99999 479.4 3.0 2.70 0.05 557 13 1573 21 76858 186.2 0.4 66.7 0.6 77.0 0.5 72.9 0.8 99999 99999 99999 99999 416.6 2.8 1.91 0.05 543 13 1454 20 77038 140.5 0.3 55.4 0.6 55.5 0.5 53.0 0.8 99999 99999 99999 99999 352.9 2.5 1.34 0.04 534 13 1365 19 77218 125.6 0.3 52.4 0.6 48.6 0.5 46.8 0.8 99999 99999 99999 99999 334.3 2.3 1.23 0.04 561 13 1286 18 77398 121.5 0.3 51.0 0.6 47.3 0.5 44.7 0.8 99999 99999 99999 99999 327.8 2.2 1.14 0.04 553 13 1321 18 77758 100.8 0.3 46.7 0.5 38.0 0.5 37.6 0.8 99999 99999 99999 99999 300.0 2.0 0.92 0.04 537 13 1262 17 77938 86.8 0.3 43.5 0.5 31.4 0.5 32.4 0.8 99999 99999 99999 99999 279.7 1.8 0.85 0.04 530 13 1198 17 78118 88.3 0.3 43.6 0.5 32.7 0.5 32.3 0.8 99999 99999 99999 99999 284.3 1.8 0.72 0.04 552 13 1210 17 78298 82.4 0.3 41.8 0.5 29.7 0.5 29.5 0.8 99999 99999 99999 99999 275.7 1.8 0.80 0.04 587 13 1161 16 78658 79.9 0.3 40.9 0.4 27.7 0.5 30.2 0.8 99999 99999 99999 99999 272.9 1.7 0.74 0.04 543 13 1170 16 78838 76.6 0.3 39.9 0.4 27.1 0.5 28.0 0.8 182.7 2.3 2.18 0.02 267.7 1.7 0.71 0.04 534 13 1198 17 79018 76.1 0.3 40.3 0.4 26.4 0.5 27.3 0.8 99999 99999 99999 99999 265.4 1.7 0.73 0.04 517 13 1150 16 79198 78.4 0.3 40.7 0.4 27.3 0.5 27.9 0.8 183.8 2.3 2.20 0.02 269.8 1.7 0.72 0.04 559 13 1201 17 79558 76.0 0.3 40.1 0.4 26.8 0.5 29.2 0.8 182.6 2.2 2.24 0.02 266.5 1.7 0.71 0.04 535 13 1188 16 79738 75.3 0.3 40.0 0.4 26.0 0.5 28.3 0.8 99999 99999 99999 99999 265.6 1.7 0.70 0.04 562 13 1173 16 79918 75.3 0.3 40.0 0.4 26.8 0.5 27.4 0.8 182.2 2.2 2.18 0.02 265.9 1.7 0.77 0.04 575 13 1222 17 80458 70.0 0.3 38.6 0.4 24.4 0.5 26.7 0.8 99999 99999 99999 99999 258.2 1.6 0.69 0.04 565 13 1164 16 80638 69.0 0.3 38.0 0.4 23.6 0.5 26.4 0.8 176.7 2.1 2.13 0.02 254.0 1.6 0.64 0.04 563 13 1199 17 80818 69.7 0.3 38.7 0.4 24.0 0.5 26.6 0.8 99999 99999 99999 99999 257.8 1.6 0.69 0.04 544 13 1151 16 80998 72.4 0.3 39.8 0.4 24.9 0.5 26.0 0.8 180.1 2.1 2.23 0.02 259.4 1.6 0.71 0.04 530 13 1194 17 81358 70.3 0.3 39.1 0.4 24.0 0.5 27.1 0.7 177.9 2.1 2.19 0.02 257.5 1.6 0.65 0.04 549 13 1190 17 81538 69.7 0.3 39.0 0.4 23.7 0.5 26.0 0.7 99999 99999 99999 99999 257.4 1.6 0.67 0.04 559 13 1160 16 81718 63.2 0.3 37.3 0.4 20.7 0.5 23.5 0.8 172.6 2.0 2.18 0.02 250.0 1.6 0.65 0.04 548 13 1157 16 81898 67.8 0.3 38.1 0.4 23.1 0.5 25.1 0.7 99999 99999 99999 99999 255.0 1.6 0.63 0.04 572 13 1163 16 82258 57.6 0.3 36.0 0.4 18.4 0.5 22.6 0.8 99999 99999 99999 99999 241.2 1.6 0.65 0.04 567 13 1117 16 82438 58.9 0.3 36.3 0.4 19.2 0.5 22.5 0.8 168.4 1.9 2.19 0.02 241.9 1.6 0.64 0.04 511 13 1131 16 82618 66.7 0.3 38.5 0.4 22.0 0.5 25.1 0.7 99999 99999 99999 99999 253.2 1.6 0.66 0.04 565 13 1141 16 82798 69.5 0.3 39.2 0.4 23.8 0.5 26.0 0.7 176.3 2.0 2.15 0.02 254.0 1.6 0.71 0.04 546 13 1204 17 83158 77.2 0.3 41.1 0.5 27.0 0.5 29.5 0.7 183.3 2.0 2.24 0.02 271.0 1.7 0.80 0.04 569 13 1183 16 83338 77.5 0.3 41.0 0.5 27.0 0.5 29.3 0.7 99999 99999 99999 99999 268.2 1.7 0.79 0.04 558 13 1154 16 83518 90.2 0.3 43.7 0.5 32.6 0.5 33.7 0.7 191.7 2.1 2.27 0.02 283.4 1.8 0.84 0.04 558 13 1220 17 83698 94.5 0.3 44.4 0.5 33.4 0.5 35.8 0.8 99999 99999 99999 99999 286.4 1.8 0.85 0.04 575 13 1189 17 84058 190.9 0.4 66.4 0.6 77.3 0.5 76.1 0.8 99999 99999 99999 99999 409.2 2.8 2.06 0.05 527 13 99999 99999 84238 223.7 0.4 74.5 0.5 91.6 0.5 89.9 0.8 278.0 2.8 2.73 0.02 459.4 3.0 2.60 0.05 588 13 99999 99999 84418 265.6 0.5 83.9 0.4 112.0 0.5 109.2 0.9 99999 99999 99999 99999 519.3 3.2 3.46 0.06 546 13 99999 99999 84598 273.5 0.5 85.5 0.4 116.6 0.5 112.2 0.9 307.8 3.1 3.08 0.02 531.6 3.2 3.71 0.06 528 13 99999 99999