37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 10 29 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 69844 273.8 0.3 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 545.6 2.6 3.69 0.06 99999 99999 99999 99999 70024 276.3 0.4 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 537.0 2.5 3.94 0.06 99999 99999 99999 99999 70204 275.4 0.4 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 539.7 2.5 3.80 0.06 99999 99999 99999 99999 70384 274.6 0.4 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 531.5 2.4 3.91 0.06 99999 99999 99999 99999 70744 272.7 0.4 86.6 0.4 117.2 0.7 111.5 0.6 99999 99999 99999 99999 529.2 2.4 3.59 0.06 538 20 1769 23 70924 270.1 0.4 85.7 0.4 117.7 0.7 109.8 0.6 99999 99999 99999 99999 525.8 2.4 3.58 0.06 554 20 1720 23 71104 253.2 0.4 83.1 0.4 110.8 0.7 101.7 0.6 99999 99999 99999 99999 503.2 2.3 3.33 0.06 541 20 1686 22 71284 258.9 0.4 84.1 0.4 113.6 0.7 106.2 0.6 99999 99999 99999 99999 512.2 2.3 3.23 0.06 570 19 1689 22 71644 235.1 0.3 78.5 0.4 103.0 0.7 95.5 0.6 99999 99999 99999 99999 480.0 2.3 2.68 0.05 543 19 1619 21 71825 230.6 0.3 77.9 0.4 100.2 0.7 92.8 0.6 99999 99999 99999 99999 473.1 2.3 2.63 0.05 525 19 1603 21 72004 230.7 0.3 78.8 0.4 101.2 0.7 92.4 0.6 99999 99999 99999 99999 475.8 2.3 2.59 0.05 559 19 1585 21 72184 235.7 0.3 80.2 0.4 103.2 0.7 94.4 0.6 99999 99999 99999 99999 484.2 2.3 2.59 0.05 540 19 1643 22 72544 238.4 0.3 80.0 0.4 104.0 0.7 95.8 0.6 99999 99999 99999 99999 490.0 2.3 2.71 0.05 541 19 1651 22 72725 229.9 0.3 77.6 0.4 100.5 0.7 92.2 0.6 99999 99999 99999 99999 474.4 2.3 2.55 0.05 547 19 1605 21 72904 231.8 0.3 78.8 0.4 100.7 0.7 92.4 0.6 99999 99999 99999 99999 479.4 2.3 2.63 0.05 539 19 99999 99999 73084 234.0 0.3 78.5 0.4 101.5 0.7 93.6 0.6 99999 99999 99999 99999 479.6 2.3 2.57 0.05 577 19 1592 21 73444 231.4 0.3 78.2 0.4 99.2 0.7 91.3 0.6 99999 99999 99999 99999 482.0 2.3 2.48 0.05 559 19 1601 21 73624 238.2 0.3 81.3 0.4 101.5 0.7 94.5 0.6 296.1 1.5 2.73 0.05 488.4 2.3 2.55 0.05 535 19 1647 22 73805 240.0 0.3 81.6 0.4 102.2 0.7 95.4 0.6 99999 99999 99999 99999 493.9 2.3 2.66 0.05 552 19 1639 22 74345 245.6 0.3 81.6 0.4 104.0 0.7 98.0 0.6 299.8 1.6 2.82 0.05 500.2 2.3 2.77 0.05 557 19 1655 22 74525 241.5 0.3 81.7 0.4 102.2 0.7 96.3 0.6 99999 99999 99999 99999 496.7 2.3 2.76 0.05 555 19 1625 22 74704 243.7 0.3 81.7 0.4 102.9 0.7 97.1 0.6 298.9 1.6 2.81 0.04 498.4 2.3 2.81 0.05 572 19 1658 22 74885 243.4 0.3 81.7 0.4 102.9 0.7 97.0 0.6 99999 99999 99999 99999 500.2 2.3 2.71 0.05 558 19 1625 22 75244 246.8 0.3 82.8 0.4 103.5 0.7 98.3 0.6 99999 99999 99999 99999 504.3 2.3 2.86 0.05 570 19 1621 21 75424 247.9 0.3 82.6 0.4 104.9 0.7 99.1 0.6 302.1 1.7 2.83 0.04 505.3 2.3 2.75 0.05 549 19 1667 22 75604 247.4 0.3 83.0 0.4 104.3 0.7 98.5 0.6 99999 99999 99999 99999 503.9 2.3 2.79 0.05 580 19 1650 22 76145 245.9 0.3 82.3 0.4 102.8 0.7 98.2 0.6 304.2 1.7 2.90 0.04 503.8 2.3 2.72 0.05 560 19 1678 22 76324 245.8 0.3 82.2 0.4 102.8 0.7 98.1 0.6 99999 99999 99999 99999 505.2 2.3 2.78 0.05 546 19 1636 22 76504 247.1 0.3 81.9 0.4 103.6 0.7 98.0 0.6 303.1 1.7 2.79 0.04 504.8 2.3 2.83 0.05 539 20 1669 22 76684 247.2 0.3 82.7 0.4 103.5 0.7 97.9 0.6 99999 99999 99999 99999 506.4 2.3 2.84 0.05 550 20 1649 22 77045 248.1 0.3 83.1 0.4 103.7 0.7 99.1 0.6 99999 99999 99999 99999 506.9 2.3 2.76 0.05 559 20 1657 22 77404 248.3 0.3 82.6 0.4 103.0 0.7 98.4 0.6 99999 99999 99999 99999 507.7 2.3 2.83 0.05 518 20 1648 22 77585 248.1 0.3 82.4 0.4 103.4 0.7 98.5 0.6 304.3 1.8 2.79 0.04 505.1 2.3 2.76 0.05 570 20 1678 22 77944 247.2 0.3 82.3 0.4 103.0 0.7 98.3 0.6 304.3 1.8 2.82 0.04 503.5 2.3 2.67 0.05 530 20 1669 22 78125 246.8 0.3 82.7 0.4 103.1 0.7 98.1 0.6 99999 99999 99999 99999 504.7 2.3 2.77 0.05 529 20 1644 21 78304 246.1 0.3 81.7 0.4 102.8 0.7 97.1 0.6 302.0 1.8 2.85 0.04 504.2 2.3 2.70 0.05 556 20 1678 22 78484 246.9 0.3 82.2 0.4 102.7 0.7 97.3 0.6 99999 99999 99999 99999 505.8 2.3 2.63 0.05 543 20 1662 22 78844 247.9 0.3 82.0 0.4 103.3 0.7 98.8 0.6 99999 99999 99999 99999 505.2 2.3 2.84 0.05 543 20 1669 22 79024 246.4 0.3 81.9 0.4 102.5 0.7 97.1 0.6 302.8 1.8 2.77 0.04 507.9 2.3 2.64 0.05 565 20 1689 22 79205 246.8 0.3 82.5 0.4 103.3 0.7 97.4 0.6 99999 99999 99999 99999 504.4 2.3 2.78 0.05 542 20 1646 21 79385 246.2 0.3 82.0 0.4 102.1 0.7 96.4 0.6 304.2 1.9 2.82 0.04 507.1 2.3 2.69 0.05 534 20 1689 22 79744 245.6 0.3 81.8 0.4 101.9 0.7 97.9 0.6 304.5 1.9 2.88 0.03 507.3 2.3 2.70 0.05 575 19 1694 22 79924 243.9 0.3 82.1 0.4 101.0 0.7 95.8 0.6 99999 99999 99999 99999 505.6 2.3 2.55 0.05 550 20 1684 22 80105 244.6 0.3 82.5 0.4 100.7 0.7 95.3 0.6 304.5 1.9 2.87 0.03 504.6 2.3 2.61 0.05 547 20 1697 22 80644 243.9 0.3 82.5 0.4 100.7 0.7 96.2 0.6 99999 99999 99999 99999 505.7 2.3 2.63 0.05 517 20 1669 22 80824 244.2 0.3 82.1 0.4 100.3 0.7 96.5 0.6 303.7 1.9 2.79 0.04 504.1 2.3 2.61 0.05 541 20 1690 22 81005 244.6 0.3 82.1 0.4 101.2 0.7 95.5 0.6 99999 99999 99999 99999 505.3 2.3 2.64 0.05 563 19 1674 22 81184 244.9 0.3 82.6 0.4 100.5 0.7 95.6 0.6 303.6 2.0 2.86 0.03 502.2 2.3 2.59 0.05 555 19 1678 22 81545 246.2 0.3 81.1 0.4 101.6 0.7 98.0 0.6 304.9 2.0 2.91 0.03 504.5 2.3 2.62 0.05 558 19 1676 22 81724 245.9 0.3 82.4 0.4 100.4 0.7 96.7 0.6 99999 99999 99999 99999 506.3 2.3 2.63 0.05 532 20 1658 21 81904 245.9 0.3 81.9 0.4 100.4 0.7 96.3 0.6 304.3 2.0 2.83 0.03 503.9 2.3 2.65 0.05 530 20 1684 22 82085 243.7 0.3 82.0 0.4 99.5 0.7 94.8 0.6 99999 99999 99999 99999 505.9 2.3 2.63 0.05 548 19 1671 22 82445 241.3 0.3 81.4 0.4 98.2 0.7 94.6 0.6 99999 99999 99999 99999 504.0 2.3 2.62 0.05 547 19 1657 21 82625 242.9 0.3 82.1 0.4 99.1 0.7 94.3 0.6 303.2 2.0 2.88 0.03 499.2 2.3 2.48 0.05 561 19 1671 22 82804 242.4 0.3 82.1 0.4 99.3 0.7 94.0 0.6 99999 99999 99999 99999 503.9 2.3 2.66 0.05 583 19 1651 21 82984 242.9 0.3 82.8 0.4 98.8 0.7 95.2 0.6 302.1 2.1 2.86 0.03 502.3 2.3 2.55 0.05 579 19 1678 22 83344 256.4 0.4 83.8 0.4 104.2 0.7 102.8 0.6 307.3 2.1 2.98 0.03 515.3 2.3 2.97 0.06 572 19 1729 22 83525 269.1 0.4 84.5 0.4 109.3 0.7 109.6 0.6 99999 99999 99999 99999 527.7 2.3 3.41 0.06 587 19 1700 22 83705 272.1 0.4 84.8 0.4 109.3 0.7 110.9 0.6 310.7 2.2 3.03 0.03 531.7 2.3 3.44 0.06 527 20 1730 22 83884 272.5 0.4 85.0 0.4 109.0 0.7 111.4 0.6 99999 99999 99999 99999 531.6 2.3 3.49 0.06 536 20 1676 21 84244 271.2 0.4 85.1 0.4 111.3 0.7 111.2 0.6 99999 99999 99999 99999 530.5 2.3 3.47 0.06 545 19 1669 21 84424 268.9 0.4 84.8 0.4 109.5 0.7 109.4 0.6 310.8 2.3 3.06 0.03 530.8 2.3 3.40 0.06 529 20 1680 21 84605 257.8 0.4 83.9 0.4 105.4 0.7 104.1 0.6 99999 99999 99999 99999 513.7 2.3 3.18 0.06 530 20 1634 21 84785 257.6 0.4 83.8 0.4 104.9 0.7 103.7 0.6 307.0 2.3 2.96 0.03 517.5 2.3 3.05 0.06 542 20 1685 21 85144 246.7 0.3 81.9 0.4 99.6 0.7 98.1 0.6 302.5 2.2 2.97 0.03 506.7 2.3 2.71 0.05 546 20 1666 21 85325 245.6 0.3 81.1 0.4 100.2 0.7 97.8 0.6 99999 99999 99999 99999 504.8 2.3 2.68 0.05 523 20 1646 21 85505 244.8 0.3 82.0 0.4 99.5 0.7 97.2 0.6 303.7 2.3 2.86 0.03 504.7 2.3 2.61 0.05 543 20 1648 21 86044 242.2 0.3 81.2 0.4 98.1 0.7 96.4 0.6 99999 99999 99999 99999 503.9 2.3 2.63 0.05 581 20 1656 21 86225 246.0 0.3 81.8 0.4 99.3 0.7 97.8 0.6 300.8 2.3 2.85 0.03 503.8 2.3 2.70 0.05 583 20 1676 21 86404 245.6 0.3 82.3 0.4 100.2 0.7 97.0 0.6 99999 99999 99999 99999 506.4 2.3 2.70 0.05 559 20 1625 21 86584 245.9 0.3 82.2 0.4 99.7 0.7 97.3 0.6 300.8 2.4 2.85 0.03 503.6 2.3 2.70 0.05 527 20 1670 21 86945 244.5 0.3 81.3 0.4 99.4 0.7 96.4 0.6 300.8 2.4 2.88 0.03 502.2 2.3 2.73 0.05 547 20 1678 22 87124 243.7 0.3 82.5 0.4 98.9 0.7 96.0 0.6 99999 99999 99999 99999 505.0 2.3 2.67 0.05 537 20 1647 21 87304 244.1 0.3 82.0 0.4 98.8 0.7 95.5 0.6 300.4 2.4 2.92 0.03 501.6 2.3 2.64 0.05 549 20 1656 21 87484 243.1 0.3 81.7 0.4 98.9 0.7 94.8 0.6 99999 99999 99999 99999 503.7 2.3 2.70 0.05 518 20 1637 21 87845 243.4 0.3 81.2 0.4 97.6 0.7 96.0 0.6 99999 99999 99999 99999 505.5 2.3 2.62 0.05 552 20 1631 21 88025 242.5 0.3 83.5 0.4 98.2 0.7 94.0 0.6 299.3 2.5 2.87 0.03 500.4 2.3 2.53 0.05 564 20 1656 21 88204 241.8 0.3 82.0 0.4 98.0 0.7 94.5 0.6 99999 99999 99999 99999 503.9 2.3 2.54 0.05 527 20 1638 21 88384 241.2 0.3 81.6 0.4 97.5 0.7 94.5 0.6 299.0 2.5 2.83 0.03 499.4 2.3 2.53 0.05 579 20 1651 21 88744 236.3 0.3 81.1 0.4 95.0 0.7 92.0 0.6 297.9 2.5 2.84 0.03 498.4 2.3 2.52 0.05 563 20 1658 21 88924 236.4 0.3 81.2 0.4 95.7 0.7 91.5 0.6 99999 99999 99999 99999 500.2 2.3 2.44 0.05 561 20 1634 21 89105 232.8 0.3 79.9 0.4 92.9 0.7 90.2 0.6 296.9 2.5 2.71 0.03 492.2 2.3 2.40 0.05 587 20 1665 21 89284 235.2 0.3 80.5 0.4 94.5 0.7 91.5 0.6 99999 99999 99999 99999 497.3 2.3 2.40 0.05 579 20 1609 21 89645 235.5 0.3 80.5 0.4 94.4 0.7 91.5 0.6 99999 99999 99999 99999 495.7 2.3 2.41 0.05 548 20 1630 21 89824 232.6 0.3 80.3 0.4 94.6 0.7 89.5 0.6 297.2 2.6 2.88 0.03 493.0 2.3 2.39 0.05 558 20 1649 21 90005 236.3 0.3 80.1 0.4 95.9 0.7 91.6 0.6 99999 99999 99999 99999 495.9 2.3 2.46 0.05 536 20 1630 21 90185 230.5 0.3 79.6 0.4 92.3 0.7 88.3 0.6 295.7 2.6 2.78 0.03 489.2 2.3 2.31 0.05 537 20 1645 21 90544 236.1 0.3 80.6 0.4 95.3 0.7 92.5 0.6 298.9 2.7 2.86 0.03 497.8 2.3 2.48 0.05 571 20 1672 21 90724 235.7 0.3 79.6 0.4 95.4 0.7 91.7 0.6 99999 99999 99999 99999 496.8 2.3 2.41 0.05 583 20 1645 21 90904 238.9 0.3 80.3 0.4 96.6 0.7 92.8 0.6 299.7 2.8 2.89 0.03 501.8 2.3 2.55 0.05 560 20 1683 22 91444 235.1 0.3 80.6 0.4 94.4 0.7 92.0 0.6 99999 99999 99999 99999 497.3 2.3 2.29 0.05 569 20 1624 21 91624 233.8 0.3 80.0 0.4 93.7 0.7 90.3 0.6 297.3 2.8 2.81 0.03 494.9 2.3 2.33 0.05 543 20 1658 21 91805 235.6 0.3 81.0 0.4 94.5 0.7 90.4 0.6 99999 99999 99999 99999 498.0 2.3 2.37 0.05 515 20 1633 21 91984 235.1 0.3 80.6 0.4 95.3 0.7 90.3 0.6 297.8 2.9 2.77 0.03 495.8 2.3 2.43 0.05 568 19 1642 21 92345 233.8 0.3 81.0 0.4 94.4 0.7 90.7 0.6 296.6 2.9 2.81 0.03 493.8 2.3 2.37 0.05 549 19 1637 21 92524 235.5 0.3 80.8 0.4 94.9 0.7 91.3 0.6 99999 99999 99999 99999 497.1 2.3 2.50 0.05 560 19 1618 21 92704 233.5 0.3 79.9 0.4 94.3 0.7 90.4 0.6 295.2 2.9 2.82 0.03 491.4 2.3 2.40 0.05 517 19 1648 21 92884 233.8 0.3 79.3 0.4 94.9 0.7 91.3 0.6 99999 99999 99999 99999 491.4 2.3 2.48 0.05 563 19 1616 21 93245 227.3 0.3 77.7 0.4 92.8 0.7 88.7 0.6 99999 99999 99999 99999 479.0 2.3 2.40 0.05 582 19 1585 20 93425 225.9 0.3 77.6 0.4 91.7 0.7 88.0 0.6 289.6 2.8 2.80 0.03 478.2 2.3 2.33 0.05 544 19 1625 21 93604 220.4 0.3 76.5 0.4 89.5 0.7 85.6 0.6 99999 99999 99999 99999 471.1 2.3 2.32 0.05 584 19 1593 20 93784 219.3 0.3 76.4 0.4 88.9 0.7 84.5 0.6 286.2 2.7 2.77 0.03 471.4 2.3 2.31 0.05 552 19 1599 20 94145 205.9 0.3 73.8 0.5 82.5 0.7 79.1 0.6 276.0 2.5 2.55 0.04 451.7 2.3 2.00 0.05 548 19 1573 20 94325 196.5 0.3 71.1 0.5 78.0 0.7 75.0 0.6 99999 99999 99999 99999 437.2 2.3 1.98 0.05 553 19 1523 19 94505 192.5 0.3 69.4 0.5 76.5 0.7 74.3 0.6 265.1 2.3 2.59 0.04 430.9 2.3 1.93 0.05 566 19 1544 20 94684 189.3 0.3 68.1 0.5 76.0 0.7 73.0 0.6 99999 99999 99999 99999 424.8 2.3 1.91 0.05 536 19 1496 19 95044 198.0 0.3 70.4 0.5 79.5 0.7 77.0 0.6 99999 99999 99999 99999 435.5 2.3 2.09 0.05 565 19 1534 19 95224 219.8 0.3 73.8 0.5 88.9 0.7 86.5 0.6 279.6 2.7 2.70 0.03 448.9 2.3 2.27 0.05 494 19 1584 20 95405 218.5 0.3 73.3 0.5 89.5 0.7 87.3 0.6 99999 99999 99999 99999 454.3 2.3 2.42 0.05 549 19 1584 20 95585 263.9 0.4 83.6 0.4 108.2 0.7 106.6 0.6 305.2 3.7 2.92 0.03 511.4 2.3 3.31 0.06 535 19 1745 21 95944 272.9 0.4 83.8 0.4 112.3 0.7 112.3 0.6 308.2 3.9 2.94 0.03 533.2 2.4 3.57 0.06 565 19 99999 99999 96124 273.9 0.4 85.2 0.4 113.6 0.7 112.5 0.6 99999 99999 99999 99999 534.8 2.4 3.62 0.06 592 19 99999 99999 96304 274.1 0.4 83.8 0.4 115.0 0.7 113.5 0.6 309.6 4.1 3.05 0.04 538.8 2.5 3.78 0.06 509 19 99999 99999