37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 10 26 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 68995 274.9 0.4 99999 99999 99999 99999 114.6 0.9 99999 99999 99999 99999 539.7 1.8 3.62 0.07 99999 99999 99999 99999 69175 273.4 0.4 99999 99999 99999 99999 114.2 0.9 99999 99999 99999 99999 533.1 1.8 3.74 0.07 99999 99999 99999 99999 69355 273.4 0.4 99999 99999 99999 99999 113.9 0.9 99999 99999 99999 99999 539.2 1.9 3.61 0.07 99999 99999 99999 99999 69535 272.2 0.4 99999 99999 99999 99999 114.0 0.9 99999 99999 99999 99999 531.8 1.8 3.61 0.07 99999 99999 99999 99999 69895 272.6 0.4 86.2 0.9 118.1 0.5 112.1 0.9 99999 99999 99999 99999 530.5 1.8 3.57 0.07 538 16 1779 24 70075 268.3 0.4 85.0 0.9 116.9 0.5 110.3 0.9 99999 99999 99999 99999 524.2 1.7 3.41 0.07 529 16 1721 24 70255 265.8 0.4 85.7 0.9 116.0 0.5 108.9 0.9 99999 99999 99999 99999 516.9 1.7 3.25 0.06 544 16 1733 24 70435 256.1 0.4 83.6 0.9 111.3 0.5 105.2 0.9 99999 99999 99999 99999 505.5 1.6 3.09 0.06 533 16 1666 23 70795 237.2 0.4 99999 99999 103.9 0.5 97.6 0.9 99999 99999 99999 99999 481.6 1.7 2.70 0.06 567 16 1610 22 70975 247.7 0.4 82.1 0.9 107.9 0.5 101.7 0.9 283.4 4.3 2.98 0.07 502.0 1.6 2.88 0.06 503 16 1662 23 71155 244.8 0.4 81.6 0.9 107.0 0.5 99.8 0.9 99999 99999 99999 99999 498.2 1.6 2.75 0.06 543 16 1642 22 71335 245.9 0.4 82.1 0.9 107.0 0.5 99.3 0.9 282.2 4.0 2.97 0.06 496.0 1.7 2.79 0.06 528 16 1655 23 71695 238.5 0.4 79.8 0.9 103.8 0.5 96.0 0.9 281.5 3.8 2.87 0.05 486.7 1.7 2.63 0.06 528 16 1635 22 71875 237.4 0.4 79.7 0.9 103.9 0.5 95.5 0.9 99999 99999 99999 99999 487.5 1.7 2.60 0.06 546 16 1612 22 72055 244.3 0.4 81.0 0.9 105.3 0.5 98.2 0.9 289.5 3.7 2.89 0.05 493.2 1.7 2.78 0.06 546 16 1668 23 72235 253.3 0.4 81.6 0.9 108.6 0.5 102.5 0.9 99999 99999 99999 99999 505.4 1.6 2.92 0.06 526 16 1654 22 72595 254.2 0.4 82.4 0.9 109.3 0.5 103.9 0.9 99999 99999 99999 99999 506.9 1.6 3.06 0.06 526 16 1677 23 72775 260.3 0.4 83.5 0.9 110.3 0.5 106.3 0.9 305.4 3.7 2.97 0.05 513.5 1.6 3.15 0.06 481 16 1707 23 72955 261.7 0.4 84.7 0.9 111.0 0.5 107.3 0.9 99999 99999 99999 99999 516.9 1.6 3.28 0.06 523 16 1690 23 73495 258.0 0.4 83.7 0.9 109.1 0.5 105.6 0.9 302.7 3.6 2.90 0.04 510.1 1.6 3.15 0.06 540 16 1703 23 73675 259.3 0.4 84.2 0.9 110.1 0.5 106.4 0.9 99999 99999 99999 99999 514.3 1.6 3.16 0.06 527 16 1689 23 73855 260.8 0.4 83.9 0.9 109.8 0.5 106.8 0.9 306.1 3.6 3.01 0.05 513.5 1.6 3.23 0.06 550 16 1716 23 74035 258.8 0.4 83.5 0.9 109.6 0.5 106.5 0.9 99999 99999 99999 99999 512.4 1.6 3.12 0.06 528 16 1685 22 74395 260.9 0.4 83.9 0.9 109.5 0.5 108.1 0.9 99999 99999 99999 99999 516.0 1.6 3.27 0.06 540 16 1685 22 74575 263.1 0.5 84.7 0.9 110.7 0.5 108.3 0.9 307.2 3.5 2.91 0.04 519.9 1.6 3.33 0.06 540 16 1742 23 74755 259.9 0.4 83.4 0.9 109.9 0.5 106.7 0.9 99999 99999 99999 99999 516.3 1.6 3.32 0.06 535 16 1695 22 75295 256.5 0.4 82.6 0.9 107.7 0.5 105.4 0.9 302.7 3.4 2.86 0.03 508.7 1.7 3.17 0.06 532 16 1724 23 75475 261.7 0.5 84.0 0.9 109.4 0.5 107.8 0.9 99999 99999 99999 99999 516.6 1.6 3.26 0.06 536 16 1700 22 75655 266.1 0.5 84.6 0.9 111.5 0.5 109.5 0.9 308.8 3.5 2.90 0.03 522.1 1.6 3.30 0.06 551 16 1726 23 75835 266.7 0.5 84.7 0.9 113.9 0.5 109.9 0.9 99999 99999 99999 99999 525.1 1.6 3.38 0.06 564 16 1719 23 76195 266.7 0.5 84.4 0.9 111.5 0.5 109.4 0.9 99999 99999 99999 99999 525.6 1.6 3.42 0.06 542 16 1706 22 76555 265.0 0.5 84.8 0.9 110.5 0.5 108.9 0.9 99999 99999 99999 99999 524.3 1.6 3.41 0.06 533 16 1713 22 76735 267.0 0.5 85.1 0.9 111.1 0.5 109.6 0.9 309.6 3.5 2.97 0.03 521.8 1.6 3.45 0.06 511 16 1731 23 77095 267.4 0.5 84.6 0.9 111.5 0.5 108.5 0.9 310.1 3.5 3.00 0.03 522.3 1.6 3.44 0.06 491 17 1717 22 77275 266.7 0.5 84.9 0.9 110.6 0.5 109.1 0.9 99999 99999 99999 99999 526.6 1.6 3.44 0.07 573 16 1696 22 77455 267.1 0.5 84.6 0.9 110.4 0.5 109.7 0.9 310.2 3.5 2.99 0.03 522.3 1.6 3.32 0.06 542 16 1724 23 77635 267.9 0.5 84.3 0.9 111.2 0.5 110.7 0.9 99999 99999 99999 99999 530.0 1.6 3.43 0.07 532 16 1703 22 77995 267.7 0.5 85.1 0.9 111.4 0.5 109.6 0.9 99999 99999 99999 99999 528.7 1.6 3.36 0.06 552 16 1702 22 78175 267.5 0.5 84.7 0.9 111.2 0.5 109.6 0.9 312.1 3.5 2.97 0.03 524.7 1.6 3.22 0.06 532 16 1723 22 78355 267.0 0.5 85.1 0.9 110.8 0.5 109.8 0.9 99999 99999 99999 99999 527.7 1.6 3.45 0.07 538 16 1697 22 78535 267.2 0.5 85.1 0.9 110.6 0.5 109.8 0.9 311.9 3.5 2.97 0.03 523.2 1.6 3.17 0.06 523 16 1704 22 78895 267.0 0.5 84.7 0.9 110.6 0.5 110.0 0.9 310.8 3.5 2.96 0.03 526.6 1.6 3.24 0.06 540 16 1729 22 79075 266.7 0.5 84.6 0.9 110.3 0.5 108.9 0.9 99999 99999 99999 99999 525.6 1.6 3.38 0.07 551 16 1702 22 79255 267.1 0.5 85.2 0.9 110.2 0.5 108.4 0.9 312.4 3.5 2.97 0.03 526.5 1.6 3.38 0.07 539 16 1722 22 79795 267.1 0.5 86.6 0.9 109.9 0.5 110.4 0.9 99999 99999 99999 99999 525.3 1.6 3.19 0.06 531 16 1695 22 79975 267.4 0.5 86.0 0.9 110.1 0.5 110.2 0.9 311.1 3.5 2.90 0.03 528.1 1.6 3.44 0.07 542 16 1717 22 80155 267.0 0.5 86.1 0.9 109.8 0.5 108.5 0.9 99999 99999 99999 99999 524.8 1.6 3.17 0.06 525 16 1696 22 80335 267.3 0.5 86.0 0.9 109.9 0.5 108.5 0.9 310.1 3.5 2.90 0.03 526.7 1.6 3.46 0.07 526 16 1712 22 80695 266.6 0.5 85.7 0.9 109.7 0.5 110.3 0.9 310.8 3.5 2.89 0.03 524.4 1.6 3.38 0.06 529 16 1718 22 80875 266.9 0.5 85.7 0.9 109.0 0.5 109.6 0.9 99999 99999 99999 99999 521.2 1.6 3.50 0.07 530 16 1683 22 81055 266.3 0.5 86.0 0.9 109.5 0.5 110.1 0.9 310.5 3.5 3.00 0.03 524.2 1.6 3.24 0.06 519 16 1726 22 81235 271.9 0.5 86.1 0.9 111.3 0.5 112.1 0.9 99999 99999 99999 99999 531.8 1.6 3.59 0.07 548 16 1694 22 81595 273.2 0.5 85.8 0.9 111.1 0.5 112.4 0.9 99999 99999 99999 99999 534.9 1.6 3.71 0.07 512 16 1691 22 81775 273.5 0.5 85.8 0.9 115.5 0.5 114.9 0.9 312.2 3.5 3.01 0.03 532.5 1.6 3.45 0.07 505 16 1711 22 81955 270.7 0.5 86.1 0.9 111.1 0.5 112.6 0.9 99999 99999 99999 99999 531.6 1.6 3.57 0.07 510 16 1684 22 82135 262.6 0.4 84.2 0.9 108.6 0.5 107.6 0.9 307.5 3.5 2.95 0.03 514.2 1.7 3.34 0.06 528 16 1688 22 82495 255.3 0.4 82.6 0.9 105.7 0.5 103.6 0.9 305.3 3.5 2.85 0.04 512.6 1.7 3.02 0.06 535 16 1705 22 82675 253.6 0.4 82.6 0.9 104.9 0.5 102.7 0.9 99999 99999 99999 99999 512.3 1.7 2.74 0.06 544 16 1655 22 82855 245.8 0.4 81.7 0.9 100.3 0.5 97.1 0.9 301.0 3.4 2.81 0.04 504.2 1.7 2.82 0.06 533 16 1680 22 83035 245.1 0.4 82.1 0.9 101.1 0.5 96.2 0.9 99999 99999 99999 99999 503.6 1.7 2.53 0.06 527 16 1648 22 83395 241.6 0.4 80.9 0.9 98.7 0.5 95.6 0.9 99999 99999 99999 99999 500.9 1.7 2.41 0.06 513 16 1662 22 83575 242.6 0.4 81.2 0.9 99.1 0.5 95.9 0.9 301.3 3.4 2.85 0.04 503.5 1.7 2.63 0.06 532 16 1688 22 83755 242.1 0.4 81.2 0.9 99.1 0.5 94.5 0.9 99999 99999 99999 99999 502.2 1.7 2.51 0.06 559 16 1652 22 83935 242.4 0.4 80.8 0.9 99.3 0.5 95.0 0.9 300.8 3.4 2.84 0.04 499.7 1.7 2.56 0.06 571 16 1669 22 84295 241.2 0.4 81.4 0.9 98.9 0.5 95.6 0.9 300.2 3.4 2.84 0.04 499.6 1.7 2.51 0.06 551 16 1668 22 84475 240.0 0.4 80.8 0.9 98.7 0.5 94.6 0.9 99999 99999 99999 99999 501.7 1.7 2.63 0.06 544 16 1635 22 84655 240.5 0.4 80.8 0.9 98.5 0.5 93.8 0.9 300.5 3.5 2.88 0.04 499.4 1.7 2.37 0.06 544 16 1677 22 85195 239.8 0.4 80.8 0.9 98.4 0.5 94.8 0.9 99999 99999 99999 99999 499.3 1.7 2.63 0.06 534 16 1642 22 85375 239.8 0.4 80.3 0.9 97.6 0.5 94.5 0.9 298.2 3.5 2.80 0.04 498.1 1.7 2.45 0.06 572 16 1668 22 85555 239.8 0.4 81.2 0.9 98.3 0.5 94.0 0.9 99999 99999 99999 99999 501.5 1.7 2.57 0.06 543 16 1634 22 85735 238.4 0.4 80.8 0.9 98.2 0.5 92.7 0.9 299.5 3.5 2.82 0.04 497.2 1.7 2.42 0.06 541 16 1675 22 86095 235.6 0.4 80.4 0.9 96.5 0.5 92.4 0.9 298.2 3.5 2.76 0.04 495.7 1.7 2.42 0.06 543 16 1687 22 86275 235.0 0.4 80.9 0.9 96.1 0.5 91.8 0.9 99999 99999 99999 99999 496.3 1.7 2.35 0.06 568 16 1633 22 86455 235.1 0.4 80.3 0.9 96.1 0.5 91.2 0.9 297.3 3.5 2.82 0.04 496.3 1.7 2.36 0.06 514 16 1674 22 86635 234.7 0.4 80.1 0.9 95.9 0.5 90.5 0.9 99999 99999 99999 99999 495.2 1.7 2.37 0.06 528 16 1650 22 86995 234.3 0.4 80.9 0.9 96.5 0.5 91.7 0.9 99999 99999 99999 99999 495.9 1.7 2.36 0.06 542 16 1639 22 87175 234.0 0.4 80.2 0.9 96.0 0.5 90.9 0.9 296.9 3.5 2.77 0.05 494.9 1.7 2.29 0.06 538 16 1666 22 87355 231.2 0.4 79.6 0.9 94.6 0.5 89.8 0.9 99999 99999 99999 99999 494.1 1.7 2.20 0.06 542 16 1645 22 87535 226.0 0.4 78.6 0.9 92.2 0.5 86.6 0.9 291.6 3.4 2.76 0.05 484.3 1.8 2.22 0.06 533 16 1662 22 87895 228.9 0.4 79.6 0.9 93.8 0.5 88.1 0.9 295.1 3.5 2.74 0.05 490.2 1.8 2.17 0.06 527 16 1649 22 88075 225.8 0.4 79.0 0.9 92.1 0.5 86.9 0.9 99999 99999 99999 99999 485.8 1.8 2.14 0.06 542 16 1618 21 88255 221.2 0.4 78.0 0.9 90.4 0.5 85.2 0.9 289.8 3.4 2.73 0.05 479.3 1.8 2.16 0.06 534 16 1658 22 88435 221.8 0.4 78.1 0.9 90.5 0.5 85.3 0.9 99999 99999 99999 99999 481.0 1.8 2.15 0.06 530 16 1614 21 88795 219.4 0.4 76.7 0.9 90.0 0.5 84.3 0.9 99999 99999 99999 99999 476.5 1.8 2.16 0.06 528 16 1600 21 88975 217.0 0.4 76.7 0.9 88.6 0.5 82.8 0.9 285.1 3.4 2.73 0.05 471.7 1.8 2.06 0.05 571 16 1642 22 89155 213.3 0.4 75.0 0.9 86.5 0.5 82.2 0.9 99999 99999 99999 99999 466.3 1.9 2.08 0.05 586 16 1580 21 89335 212.8 0.4 75.6 0.9 87.8 0.5 81.7 0.9 281.4 3.3 2.64 0.05 462.3 1.9 2.07 0.05 554 16 1611 21 89695 211.3 0.4 74.9 0.9 86.2 0.5 81.4 0.9 280.1 3.3 2.71 0.05 460.5 1.9 2.09 0.05 510 16 1604 21 89875 210.4 0.4 74.8 0.9 85.7 0.5 80.6 0.9 99999 99999 99999 99999 461.6 1.9 2.09 0.05 553 16 1579 21 90055 210.7 0.4 74.3 0.9 86.2 0.5 81.3 0.9 279.1 3.3 2.64 0.05 459.9 1.9 2.08 0.05 545 16 1635 22 90595 208.3 0.4 72.7 0.9 85.3 0.5 81.8 0.9 99999 99999 99999 99999 451.8 1.9 2.08 0.05 552 16 1583 21 90775 205.2 0.4 72.2 0.9 83.7 0.5 79.9 0.9 272.0 3.2 2.61 0.06 442.2 1.9 2.19 0.06 578 16 1603 21 90955 215.6 0.4 73.6 0.9 88.4 0.5 85.0 0.9 99999 99999 99999 99999 457.1 1.9 2.31 0.06 566 16 1559 20 91135 236.3 0.4 77.6 0.9 96.9 0.5 94.1 0.9 291.6 3.4 2.74 0.05 483.2 1.8 2.65 0.06 552 16 1651 21 91495 259.3 0.4 82.1 0.9 106.1 0.5 106.3 0.9 304.6 3.6 2.94 0.04 506.1 1.7 3.14 0.06 546 16 1716 22 91675 263.8 0.4 83.6 0.9 108.8 0.5 107.7 0.9 99999 99999 99999 99999 516.6 1.6 3.43 0.07 544 16 1705 22 91855 272.8 0.5 84.8 0.9 111.4 0.5 111.1 0.9 313.6 3.7 2.95 0.04 528.8 1.6 3.64 0.07 559 16 1765 22 92035 273.3 0.5 85.6 0.9 112.5 0.5 115.0 0.9 99999 99999 99999 99999 530.6 1.7 3.71 0.07 539 16 1714 21 92395 273.6 0.5 85.4 0.9 114.0 0.5 114.0 0.9 99999 99999 99999 99999 536.2 1.7 3.74 0.07 504 16 99999 99999