37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 10 24 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 66238 271.3 0.3 82.7 0.7 99999 99999 113.3 0.5 99999 99999 99999 99999 528.3 3.8 3.54 0.06 99999 99999 1646 20 66418 271.7 0.3 83.2 0.7 99999 99999 112.8 0.5 99999 99999 99999 99999 524.6 3.7 3.49 0.06 99999 99999 1610 20 66598 272.5 0.3 83.9 0.7 99999 99999 112.7 0.5 99999 99999 99999 99999 526.0 3.7 3.34 0.06 99999 99999 1593 19 66778 272.1 0.3 82.6 0.7 99999 99999 112.3 0.5 99999 99999 99999 99999 525.5 3.7 3.51 0.06 99999 99999 1668 19 67138 272.7 0.3 84.1 0.7 114.4 0.6 112.9 0.5 99999 99999 99999 99999 530.0 3.8 3.70 0.06 526 16 1694 19 67318 271.0 0.3 86.3 0.7 114.8 0.6 111.4 0.5 99999 99999 99999 99999 527.7 3.8 3.53 0.06 575 16 1705 19 67498 260.5 0.3 81.6 0.7 112.0 0.7 107.0 0.5 99999 99999 99999 99999 520.9 3.7 3.47 0.06 547 16 1666 19 67678 255.2 0.3 80.8 0.7 110.5 0.7 105.2 0.5 99999 99999 99999 99999 506.2 3.6 3.18 0.06 543 16 1635 19 68038 223.5 0.3 74.5 0.7 96.0 0.7 89.9 0.5 99999 99999 99999 99999 466.5 3.4 2.50 0.06 591 16 1543 18 68218 216.0 0.3 73.1 0.7 92.2 0.7 85.2 0.5 99999 99999 99999 99999 457.6 3.4 2.42 0.06 562 16 1557 18 68398 230.1 0.3 77.5 0.7 99999 99999 91.8 0.5 99999 99999 99999 99999 477.7 3.5 2.37 0.06 562 16 1576 18 68578 240.3 0.3 79.5 0.7 101.6 0.7 95.8 0.5 99999 99999 99999 99999 490.1 3.6 2.65 0.06 562 16 1598 19 68938 241.2 0.3 79.5 0.7 102.7 0.7 95.5 0.5 99999 99999 99999 99999 495.9 3.6 2.67 0.06 548 16 1619 19 69118 237.3 0.3 79.4 0.7 101.0 0.7 94.0 0.5 99999 99999 99999 99999 490.2 3.6 2.63 0.06 569 16 1592 19 69298 237.9 0.3 78.6 0.7 100.8 0.7 94.5 0.5 99999 99999 99999 99999 490.2 3.6 2.50 0.06 547 16 1623 19 69478 237.5 0.3 78.7 0.7 101.4 0.7 94.2 0.5 99999 99999 99999 99999 489.2 3.5 2.62 0.06 554 16 1606 19 69838 238.1 0.3 78.8 0.7 100.9 0.7 94.5 0.5 99999 99999 99999 99999 492.4 3.6 2.61 0.06 542 16 1614 19 70018 239.2 0.3 79.1 0.7 100.4 0.7 94.9 0.5 295.5 2.0 2.75 0.05 486.9 3.5 2.64 0.06 589 16 1631 19 70198 240.1 0.3 79.2 0.7 101.5 0.7 96.1 0.5 99999 99999 99999 99999 495.4 3.6 2.67 0.06 557 16 1601 19 70738 241.4 0.3 79.8 0.7 101.2 0.7 96.0 0.5 297.9 2.1 2.78 0.05 493.8 3.6 2.63 0.06 545 16 1639 19 70918 242.7 0.3 80.6 0.7 101.8 0.7 96.5 0.5 99999 99999 99999 99999 499.2 3.6 2.71 0.06 541 16 1635 19 71098 243.1 0.3 80.8 0.7 101.6 0.7 96.5 0.5 296.7 2.1 2.70 0.05 493.4 3.6 2.64 0.06 560 16 1640 19 71278 241.4 0.3 81.0 0.7 101.3 0.7 95.8 0.5 99999 99999 99999 99999 494.4 3.6 2.53 0.06 551 16 1620 19 71638 252.5 0.3 82.8 0.7 106.4 0.7 101.2 0.5 99999 99999 99999 99999 508.1 3.6 2.78 0.06 544 16 1653 19 71818 245.4 0.3 80.9 0.7 103.1 0.7 97.7 0.5 299.0 2.2 2.73 0.05 496.0 3.6 2.73 0.06 523 16 1661 19 71998 245.4 0.3 81.7 0.7 103.8 0.7 97.9 0.5 99999 99999 99999 99999 503.1 3.6 2.68 0.06 531 16 1634 19 72538 248.6 0.3 82.2 0.7 104.7 0.7 99.8 0.5 302.0 2.3 2.82 0.05 505.2 3.6 2.79 0.06 590 16 1668 19 72718 249.4 0.3 82.6 0.7 105.1 0.7 100.4 0.5 99999 99999 99999 99999 508.6 3.7 2.83 0.06 571 16 1646 19 72898 249.6 0.3 82.8 0.7 104.9 0.7 99.0 0.5 302.8 2.4 2.82 0.05 507.1 3.6 2.82 0.06 583 16 1668 19 73078 248.3 0.3 83.4 0.7 103.8 0.7 98.2 0.5 99999 99999 99999 99999 507.7 3.7 2.79 0.06 531 16 1643 19 73438 247.9 0.3 82.6 0.7 103.6 0.7 99.7 0.5 99999 99999 99999 99999 506.0 3.6 2.68 0.06 585 16 1644 19 73798 247.5 0.3 82.3 0.7 103.4 0.7 97.8 0.5 99999 99999 99999 99999 505.5 3.7 2.78 0.06 547 16 1639 19 73978 245.1 0.3 81.8 0.7 101.3 0.7 96.5 0.5 302.4 2.5 2.85 0.05 499.9 3.6 2.67 0.06 574 16 1654 19 74338 243.5 0.3 81.2 0.7 100.9 0.7 97.5 0.5 302.0 2.5 2.83 0.05 496.8 3.6 2.63 0.06 545 16 1647 19 74518 243.7 0.3 81.8 0.7 101.5 0.7 96.9 0.5 99999 99999 99999 99999 499.7 3.6 2.63 0.06 541 16 1648 19 74698 242.2 0.3 81.0 0.7 100.3 0.7 95.4 0.5 301.2 2.5 2.85 0.05 495.3 3.6 2.65 0.06 572 15 1656 19 74878 246.9 0.3 82.2 0.7 103.0 0.7 97.7 0.5 99999 99999 99999 99999 502.1 3.7 2.79 0.06 580 15 1661 19 75238 268.6 0.3 84.7 0.7 110.3 0.7 110.9 0.5 99999 99999 99999 99999 525.5 3.8 3.42 0.06 533 15 1702 20 75418 271.6 0.3 84.7 0.7 110.4 0.7 111.4 0.5 312.0 2.6 3.00 0.04 528.2 3.8 3.44 0.06 549 15 1716 20 75598 272.6 0.3 85.0 0.7 110.7 0.7 111.4 0.5 99999 99999 99999 99999 530.9 3.9 3.50 0.06 559 15 1697 19 75778 272.4 0.3 85.0 0.7 109.6 0.7 110.4 0.5 312.0 2.7 2.95 0.04 526.4 3.8 3.53 0.06 539 15 1688 19 76138 271.3 0.3 85.0 0.7 99999 99999 109.8 0.5 310.9 2.7 3.01 0.04 526.2 3.8 3.60 0.07 547 15 1715 19 76318 262.8 0.3 84.7 0.7 109.7 0.7 105.9 0.5 99999 99999 99999 99999 519.9 3.8 3.21 0.06 554 15 1688 19 76498 260.1 0.3 83.8 0.7 106.8 0.7 103.7 0.5 307.8 2.7 2.97 0.04 513.4 3.7 3.11 0.06 539 15 99999 99999 77038 248.6 0.3 82.6 0.7 102.8 0.7 99.1 0.5 99999 99999 99999 99999 506.7 3.7 2.79 0.06 523 15 1656 19 77218 244.5 0.3 81.8 0.7 100.8 0.7 96.1 0.5 300.1 2.7 2.85 0.05 500.6 3.7 2.81 0.06 514 15 1657 19 77398 247.8 0.3 83.2 0.7 102.0 0.7 97.5 0.5 99999 99999 99999 99999 506.3 3.7 2.83 0.06 545 15 1666 19 77578 249.7 0.3 82.2 0.7 102.2 0.7 98.3 0.5 302.4 2.8 2.86 0.05 505.1 3.7 2.82 0.06 530 15 1679 19 77938 240.5 0.3 80.6 0.7 98.6 0.7 94.2 0.5 299.2 2.8 2.86 0.05 495.6 3.6 2.66 0.06 513 15 1658 19 78118 240.1 0.3 81.5 0.7 98.4 0.7 93.9 0.5 99999 99999 99999 99999 499.5 3.6 2.67 0.06 533 15 1646 19 78298 241.6 0.3 80.9 0.7 98.4 0.7 94.0 0.5 300.7 2.8 2.89 0.05 495.4 3.6 2.72 0.06 549 15 1664 19 78478 244.2 0.3 81.2 0.7 100.6 0.7 96.3 0.5 99999 99999 99999 99999 503.0 3.7 2.61 0.06 542 15 1638 19 78838 239.5 0.3 81.1 0.7 98.5 0.7 94.1 0.5 99999 99999 99999 99999 498.6 3.6 2.57 0.06 516 15 1623 19 79018 239.5 0.3 80.7 0.7 98.1 0.7 93.3 0.5 298.9 2.9 2.83 0.05 494.8 3.6 2.54 0.06 537 15 1646 19 79198 239.5 0.3 80.7 0.7 97.3 0.7 93.4 0.5 99999 99999 99999 99999 499.3 3.6 2.56 0.06 527 15 1609 19 79378 240.1 0.3 80.4 0.7 97.5 0.7 94.0 0.5 300.6 3.0 2.88 0.05 496.2 3.6 2.47 0.06 535 15 1658 19 79738 239.6 0.3 80.4 0.7 97.5 0.7 93.2 0.5 298.3 3.0 2.79 0.05 493.2 3.6 2.55 0.06 554 15 1640 19 79918 239.3 0.3 81.6 0.7 97.9 0.7 94.0 0.5 99999 99999 99999 99999 499.0 3.6 2.49 0.06 543 15 1642 19 80098 239.2 0.3 80.6 0.7 98.4 0.7 93.8 0.5 300.1 3.0 2.87 0.05 497.5 3.6 2.53 0.06 545 15 1668 19 80278 239.5 0.3 80.9 0.7 98.5 0.7 93.9 0.5 99999 99999 99999 99999 499.2 3.6 2.53 0.06 591 15 1632 19 80638 238.9 0.3 81.5 0.7 98.4 0.7 94.3 0.5 99999 99999 99999 99999 497.8 3.6 2.52 0.06 575 15 1632 19 80818 239.0 0.3 81.2 0.7 98.0 0.7 93.6 0.5 298.7 3.1 2.79 0.05 498.6 3.6 2.54 0.06 552 15 1651 19 80998 239.0 0.3 81.5 0.7 98.9 0.7 94.2 0.5 99999 99999 99999 99999 500.2 3.6 2.53 0.06 549 15 1649 19 81178 239.1 0.3 81.3 0.7 97.7 0.7 93.8 0.5 298.9 3.1 2.86 0.04 499.7 3.6 2.53 0.06 544 15 1678 19 81538 238.0 0.3 81.2 0.7 97.8 0.7 93.0 0.5 298.8 3.2 2.83 0.05 499.0 3.6 2.54 0.06 557 15 1657 19 81718 235.0 0.3 81.4 0.7 96.1 0.7 91.5 0.5 99999 99999 99999 99999 499.6 3.6 2.42 0.06 542 15 1646 19 81898 237.6 0.3 81.2 0.7 97.0 0.7 92.7 0.5 299.1 3.2 2.84 0.04 498.1 3.6 2.37 0.06 547 15 1671 19 82438 233.5 0.3 80.8 0.7 96.2 0.7 91.4 0.5 99999 99999 99999 99999 497.8 3.6 2.38 0.06 574 15 1626 19 82618 233.1 0.3 80.1 0.7 95.5 0.7 90.3 0.5 298.3 3.3 2.87 0.04 497.1 3.6 2.32 0.06 559 15 1647 19 82798 234.6 0.3 81.4 0.7 96.6 0.7 90.7 0.5 99999 99999 99999 99999 498.9 3.6 2.39 0.06 557 15 1631 19 82978 233.0 0.3 81.1 0.7 95.6 0.7 89.0 0.5 299.7 3.4 2.79 0.05 497.6 3.6 2.38 0.06 549 15 1664 19 83338 233.2 0.3 80.6 0.7 95.2 0.7 90.8 0.5 299.4 3.4 2.80 0.05 496.9 3.6 2.34 0.06 558 14 1668 19 83518 232.7 0.3 80.8 0.7 95.2 0.7 89.6 0.5 99999 99999 99999 99999 498.0 3.6 2.31 0.06 572 14 1626 19 83698 232.0 0.3 80.7 0.7 94.2 0.7 88.1 0.5 298.2 3.5 2.82 0.04 493.1 3.6 2.31 0.06 550 14 1652 19 83878 232.8 0.3 81.1 0.7 95.2 0.7 88.6 0.5 99999 99999 99999 99999 498.0 3.6 2.29 0.06 544 14 1629 19 84238 231.5 0.3 80.5 0.7 94.5 0.7 90.0 0.5 99999 99999 99999 99999 497.6 3.6 2.25 0.06 584 14 1647 19 84418 229.3 0.3 80.6 0.7 93.8 0.7 87.8 0.5 297.9 3.6 2.82 0.04 494.0 3.6 2.27 0.06 557 14 1674 19 84598 228.8 0.3 79.7 0.7 93.4 0.7 86.9 0.5 99999 99999 99999 99999 496.9 3.6 2.17 0.05 544 14 1637 19 84778 229.4 0.3 80.6 0.7 93.8 0.7 86.9 0.5 297.1 3.6 2.81 0.04 491.4 3.6 2.27 0.06 546 14 1678 19 85138 229.0 0.3 80.5 0.7 93.1 0.7 88.7 0.5 298.1 3.7 2.75 0.05 493.3 3.6 2.25 0.06 560 14 1664 19 85318 229.4 0.3 80.3 0.7 93.7 0.7 88.6 0.5 99999 99999 99999 99999 496.9 3.6 2.29 0.06 561 14 1644 19 85498 228.2 0.3 80.1 0.7 93.7 0.7 86.9 0.5 298.6 3.8 2.84 0.04 492.6 3.6 2.27 0.06 562 14 1671 19 85678 227.8 0.3 80.4 0.7 93.5 0.7 87.0 0.5 99999 99999 99999 99999 495.8 3.6 2.22 0.06 511 15 1647 19 86038 227.0 0.3 80.2 0.7 92.5 0.7 88.2 0.5 99999 99999 99999 99999 492.8 3.6 2.17 0.05 562 14 1634 19 86218 230.2 0.3 80.8 0.7 93.9 0.7 88.3 0.5 296.5 3.9 2.77 0.04 494.1 3.6 2.31 0.06 547 14 1674 19 86398 222.9 0.3 79.7 0.7 91.4 0.7 84.8 0.5 99999 99999 99999 99999 488.2 3.6 2.13 0.05 565 14 1637 19 86578 225.3 0.3 80.0 0.7 93.2 0.7 85.6 0.5 294.8 3.9 2.76 0.04 491.4 3.6 2.19 0.06 583 14 1673 19 86938 221.9 0.3 79.3 0.7 90.2 0.7 85.3 0.5 290.9 3.9 2.80 0.04 486.3 3.6 2.08 0.05 563 14 1664 19 87118 223.8 0.3 79.7 0.7 91.7 0.7 86.5 0.5 99999 99999 99999 99999 491.8 3.6 2.16 0.05 569 14 1649 19 87298 222.0 0.3 79.5 0.7 91.0 0.7 85.0 0.5 290.6 4.0 2.76 0.04 488.5 3.6 2.10 0.05 570 14 1678 19 87838 213.5 0.3 78.3 0.7 87.7 0.7 82.3 0.5 99999 99999 99999 99999 478.4 3.5 1.90 0.05 541 14 1595 19 88018 211.9 0.3 77.8 0.7 86.3 0.7 80.5 0.5 289.1 4.1 2.80 0.04 473.8 3.5 1.88 0.05 550 14 1642 19 88198 213.4 0.3 77.6 0.7 87.5 0.7 81.0 0.5 99999 99999 99999 99999 477.6 3.5 1.89 0.05 559 14 1614 19 88378 216.6 0.3 78.0 0.7 88.3 0.7 81.0 0.5 290.9 4.2 2.75 0.04 478.4 3.6 2.01 0.05 561 14 1650 19 88738 216.3 0.3 78.2 0.7 88.6 0.7 82.6 0.5 291.7 4.3 2.79 0.04 478.3 3.6 2.01 0.05 545 14 1635 19 88918 214.5 0.3 78.1 0.7 87.5 0.7 81.2 0.5 99999 99999 99999 99999 477.5 3.5 1.92 0.05 562 14 1610 19 89098 215.1 0.3 77.8 0.7 88.4 0.7 81.0 0.5 290.4 4.4 2.80 0.04 478.2 3.6 1.99 0.05 541 14 1663 19 89278 213.6 0.3 78.1 0.7 87.8 0.7 80.5 0.5 99999 99999 99999 99999 476.8 3.5 2.05 0.05 558 14 1602 19 89638 217.2 0.3 78.7 0.7 89.1 0.7 83.3 0.5 99999 99999 99999 99999 479.2 3.6 1.89 0.05 542 14 1602 19 89818 216.3 0.3 78.3 0.7 88.7 0.7 81.8 0.5 291.8 4.5 2.79 0.04 475.5 3.5 2.07 0.05 552 14 1646 19 89998 214.2 0.3 77.5 0.7 87.2 0.7 81.1 0.5 99999 99999 99999 99999 474.5 3.5 2.07 0.05 548 14 1583 19 90178 215.1 0.3 78.1 0.7 87.7 0.7 80.9 0.5 289.8 4.5 2.72 0.04 473.9 3.5 2.04 0.05 571 14 1639 19 90538 216.2 0.3 77.8 0.7 88.5 0.7 82.1 0.5 288.9 4.5 2.74 0.04 475.0 3.5 2.05 0.05 548 14 1627 19 90718 215.7 0.3 77.7 0.7 88.1 0.7 82.1 0.5 99999 99999 99999 99999 474.7 3.5 2.02 0.05 548 14 1614 19 90898 215.3 0.3 77.4 0.7 88.0 0.7 81.3 0.5 289.2 4.6 2.78 0.04 473.6 3.5 2.05 0.05 575 14 1645 19 91078 213.1 0.3 77.2 0.7 87.1 0.7 80.8 0.5 99999 99999 99999 99999 471.8 3.5 1.90 0.05 567 14 1622 19 91438 211.3 0.3 77.2 0.7 86.3 0.7 80.2 0.5 99999 99999 99999 99999 469.4 3.5 1.99 0.05 562 14 1589 18 91618 209.8 0.3 76.9 0.7 85.7 0.7 78.9 0.5 289.6 4.6 2.75 0.04 465.7 3.5 2.02 0.05 584 15 1661 19 91798 219.3 0.3 76.8 0.7 90.8 0.7 85.4 0.5 99999 99999 99999 99999 467.8 3.5 2.08 0.05 558 15 1613 18 91978 211.7 0.3 72.0 0.7 86.7 0.7 83.3 0.5 277.2 4.1 2.69 0.05 434.9 3.4 2.22 0.06 583 15 1586 18 92338 263.2 0.3 82.6 0.7 108.6 0.7 108.4 0.5 306.8 5.4 2.97 0.04 511.0 3.8 3.38 0.06 560 15 99999 99999 92518 271.1 0.3 84.9 0.7 113.9 0.7 111.7 0.5 99999 99999 99999 99999 531.9 4.1 3.51 0.07 573 15 99999 99999 92698 273.3 0.3 85.1 0.7 112.8 0.7 112.0 0.5 312.2 5.6 3.03 0.04 531.2 4.1 3.58 0.07 518 15 99999 99999 92878 273.6 0.3 85.3 0.7 114.9 0.7 115.7 0.6 99999 99999 99999 99999 539.7 4.2 3.80 0.07 514 15 99999 99999