37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 10 22 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final Calibrations. Time delay computed from Proffit et al. O3 data. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 79808 269.9 0.4 83.0 0.4 111.2 0.4 111.6 0.6 99999 99999 99999 99999 525.9 2.8 3.52 0.07 99999 99999 1858 33 79988 272.3 0.4 83.6 0.4 111.0 0.4 111.3 0.6 99999 99999 99999 99999 526.1 2.8 3.44 0.07 99999 99999 1795 31 80168 266.5 0.4 82.7 0.4 112.2 0.4 109.6 0.6 99999 99999 99999 99999 523.9 2.8 3.47 0.07 99999 99999 1721 30 80348 260.1 0.4 81.4 0.4 109.3 0.4 106.2 0.6 99999 99999 99999 99999 514.3 2.7 3.34 0.07 99999 99999 1731 30 80708 225.5 0.3 74.1 0.5 94.9 0.4 90.1 0.6 99999 99999 99999 99999 467.1 2.7 2.61 0.06 501 21 1585 28 80888 192.9 0.3 68.2 0.5 80.4 0.4 75.5 0.6 99999 99999 99999 99999 424.9 2.6 1.94 0.06 530 21 1488 26 81068 174.7 0.3 64.3 0.6 72.1 0.4 66.6 0.6 99999 99999 99999 99999 401.0 2.5 1.57 0.05 533 21 1429 25 81248 191.9 0.3 69.1 0.5 80.3 0.4 75.3 0.6 99999 99999 99999 99999 426.5 2.6 1.95 0.06 504 21 1477 26 81608 149.3 0.3 59.6 0.6 61.2 0.4 56.1 0.6 99999 99999 99999 99999 374.4 2.4 1.37 0.05 483 21 1373 24 81788 161.1 0.3 62.6 0.6 65.8 0.4 59.6 0.6 244.3 2.7 2.60 0.06 387.8 2.5 1.58 0.05 538 21 1443 25 81968 172.4 0.3 64.8 0.6 72.1 0.4 66.2 0.6 99999 99999 99999 99999 404.2 2.6 1.71 0.05 603 21 1440 25 82148 171.0 0.3 64.9 0.6 70.5 0.4 63.6 0.6 250.6 2.7 2.41 0.06 401.0 2.6 1.55 0.05 573 21 1472 26 82508 154.4 0.3 61.8 0.6 62.7 0.4 55.9 0.6 240.8 2.7 2.36 0.06 380.1 2.5 1.43 0.05 587 21 1416 25 82688 154.9 0.3 61.2 0.6 63.3 0.4 58.4 0.6 99999 99999 99999 99999 383.3 2.5 1.37 0.05 457 21 1387 24 82868 162.7 0.3 62.6 0.6 65.5 0.4 59.9 0.6 249.7 2.8 2.45 0.06 391.5 2.5 1.53 0.05 552 21 1435 25 83048 166.8 0.3 64.4 0.6 68.0 0.4 62.5 0.6 99999 99999 99999 99999 398.0 2.6 1.43 0.05 562 21 1427 25 83408 171.4 0.3 65.8 0.6 70.6 0.4 65.4 0.6 99999 99999 99999 99999 405.3 2.6 1.60 0.05 530 21 1448 25 83588 162.0 0.3 63.1 0.6 65.7 0.4 59.9 0.6 247.5 2.8 2.43 0.06 389.1 2.5 1.54 0.05 579 21 1439 25 83768 165.6 0.3 63.2 0.6 67.1 0.4 63.1 0.6 99999 99999 99999 99999 397.9 2.6 1.54 0.05 496 21 1450 25 84308 157.5 0.3 62.2 0.6 63.3 0.4 57.8 0.6 246.7 2.8 2.37 0.06 389.7 2.5 1.48 0.05 497 20 1426 25 84488 170.9 0.3 65.0 0.6 71.1 0.4 64.6 0.6 99999 99999 99999 99999 405.4 2.6 1.59 0.05 537 20 1446 25 84668 172.1 0.3 64.9 0.6 70.0 0.4 63.7 0.6 256.4 2.9 2.45 0.06 403.3 2.6 1.60 0.05 514 20 1447 25 84848 169.3 0.3 64.4 0.6 68.9 0.4 63.3 0.6 99999 99999 99999 99999 403.8 2.6 1.50 0.05 517 20 1414 24 85208 168.7 0.3 64.6 0.6 69.1 0.4 64.5 0.6 99999 99999 99999 99999 402.5 2.6 1.57 0.05 552 20 1432 25 85388 170.1 0.3 63.7 0.6 69.0 0.4 63.2 0.6 243.2 2.8 2.38 0.06 400.7 2.6 1.46 0.05 495 20 99999 99999 85568 169.2 0.3 64.0 0.6 69.2 0.4 64.2 0.6 99999 99999 99999 99999 401.4 2.6 1.61 0.05 515 20 1413 24 86108 165.7 0.3 62.6 0.6 67.4 0.4 61.6 0.6 245.6 2.9 2.50 0.06 396.6 2.6 1.58 0.05 530 20 1421 24 86288 152.5 0.3 60.1 0.6 61.2 0.4 57.3 0.6 99999 99999 99999 99999 382.0 2.5 1.35 0.05 491 20 1395 24 86468 153.0 0.3 60.3 0.6 60.3 0.4 55.1 0.6 240.7 2.9 2.35 0.06 380.6 2.5 1.50 0.05 535 20 1398 24 86648 129.1 0.3 55.4 0.6 50.8 0.4 47.3 0.6 99999 99999 99999 99999 352.5 2.3 1.14 0.05 567 20 1323 23 87008 124.7 0.3 53.9 0.6 48.0 0.4 46.2 0.6 99999 99999 99999 99999 347.4 2.3 1.00 0.05 559 20 1331 23 87368 143.9 0.3 58.8 0.6 56.5 0.4 52.9 0.6 99999 99999 99999 99999 372.0 2.5 1.26 0.05 519 20 1375 24 87548 138.4 0.3 57.4 0.6 53.8 0.4 48.7 0.6 234.9 2.8 2.27 0.07 364.8 2.4 1.22 0.05 523 20 1374 24 87908 129.6 0.3 55.4 0.6 49.6 0.4 46.2 0.6 230.1 2.8 2.23 0.07 353.2 2.3 1.15 0.05 551 20 1359 24 88088 131.5 0.3 55.9 0.6 50.4 0.4 47.9 0.6 99999 99999 99999 99999 358.3 2.4 1.13 0.05 551 20 1349 24 88268 137.7 0.3 57.5 0.6 53.6 0.4 48.5 0.6 234.5 2.8 2.28 0.07 361.5 2.4 1.17 0.05 551 19 1375 24 88448 143.8 0.3 58.5 0.6 56.5 0.4 53.4 0.6 99999 99999 99999 99999 371.8 2.5 1.20 0.05 520 19 1379 24 88808 137.7 0.3 57.1 0.6 53.0 0.4 51.0 0.6 99999 99999 99999 99999 364.4 2.4 1.19 0.05 509 19 1379 24 88988 142.9 0.3 57.8 0.6 56.0 0.4 51.2 0.6 236.9 2.9 2.44 0.06 368.1 2.4 1.20 0.05 507 19 1425 25 89168 136.6 0.3 56.8 0.6 52.3 0.4 49.5 0.6 99999 99999 99999 99999 362.1 2.4 1.20 0.05 487 19 1363 24 89348 142.1 0.3 57.9 0.6 55.2 0.4 50.3 0.6 236.9 2.9 2.32 0.07 367.9 2.4 1.26 0.05 540 19 1383 24 89708 135.8 0.3 56.5 0.6 52.3 0.4 48.9 0.6 233.6 2.8 2.25 0.07 359.1 2.4 1.21 0.05 487 19 1364 24 89888 136.8 0.3 56.7 0.6 52.4 0.4 50.6 0.6 99999 99999 99999 99999 363.8 2.4 1.19 0.05 500 19 1370 24 90068 130.9 0.3 55.3 0.6 50.8 0.4 45.8 0.5 230.1 2.8 2.29 0.07 351.1 2.3 1.09 0.05 490 19 1353 24 90608 136.9 0.3 57.0 0.6 52.0 0.4 51.1 0.6 99999 99999 99999 99999 363.0 2.4 1.16 0.05 517 19 1351 24 90788 138.9 0.3 56.2 0.6 53.2 0.4 49.4 0.6 235.1 2.8 2.34 0.07 364.4 2.4 1.24 0.05 587 19 1390 24 90968 135.4 0.3 56.2 0.6 52.5 0.4 49.9 0.6 99999 99999 99999 99999 359.2 2.4 1.15 0.05 539 19 1356 24 91148 134.8 0.3 56.0 0.6 51.5 0.4 47.6 0.6 231.2 2.8 2.35 0.07 357.7 2.4 1.10 0.05 539 19 1366 24 91508 144.5 0.3 58.4 0.6 56.1 0.4 52.5 0.6 238.4 2.9 2.40 0.06 370.6 2.4 1.29 0.05 524 20 1403 25 91688 154.4 0.3 60.3 0.6 60.8 0.4 57.5 0.6 99999 99999 99999 99999 383.7 2.5 1.41 0.05 556 20 1401 25 91868 158.0 0.3 60.7 0.6 61.8 0.4 57.5 0.6 245.9 3.0 2.50 0.06 385.5 2.5 1.46 0.05 535 20 1419 25 92048 156.6 0.3 61.0 0.6 61.6 0.4 58.6 0.6 99999 99999 99999 99999 385.8 2.5 1.41 0.05 540 20 1401 25 92408 170.7 0.3 63.9 0.6 68.0 0.4 65.1 0.6 99999 99999 99999 99999 402.1 2.6 1.62 0.05 553 20 1432 25 92588 164.4 0.3 62.4 0.6 65.8 0.4 60.2 0.6 250.7 3.0 2.49 0.06 393.5 2.6 1.53 0.05 534 20 1441 25 92768 178.9 0.3 65.7 0.6 71.6 0.4 67.3 0.6 99999 99999 99999 99999 418.1 2.7 1.69 0.05 549 20 1479 26 92948 195.9 0.3 69.3 0.5 78.5 0.4 73.6 0.6 270.8 3.2 2.56 0.06 438.9 2.7 1.96 0.06 517 20 1518 27 93308 209.0 0.3 72.6 0.5 84.6 0.4 79.3 0.6 277.8 3.3 2.67 0.06 453.3 2.8 2.13 0.06 510 20 1567 27 93488 210.0 0.3 72.8 0.5 84.9 0.4 80.1 0.6 99999 99999 99999 99999 457.0 2.8 2.17 0.06 562 20 1574 27 93668 207.6 0.3 71.9 0.5 83.2 0.4 77.8 0.6 277.1 3.3 2.64 0.06 451.3 2.7 2.08 0.06 507 20 1561 27 93848 209.7 0.3 72.8 0.5 84.9 0.4 80.2 0.6 99999 99999 99999 99999 456.5 2.8 2.17 0.06 538 20 1535 27 94208 208.8 0.3 72.6 0.5 85.0 0.4 80.4 0.6 99999 99999 99999 99999 454.5 2.8 2.18 0.06 555 20 1534 27 94388 210.0 0.3 72.4 0.5 84.7 0.4 79.2 0.6 278.9 3.3 2.63 0.06 454.6 2.8 2.23 0.06 554 20 1552 27 94568 210.7 0.3 73.2 0.5 85.3 0.4 80.7 0.6 99999 99999 99999 99999 456.1 2.8 2.16 0.06 574 20 1548 27 94748 206.6 0.3 72.0 0.5 83.3 0.4 78.4 0.6 278.0 3.3 2.67 0.06 449.3 2.7 2.20 0.06 543 20 1543 27 95108 192.1 0.3 68.9 0.5 77.7 0.4 72.3 0.6 270.0 3.2 2.56 0.06 432.0 2.7 1.98 0.06 569 20 1525 27 95288 194.6 0.3 70.3 0.5 77.7 0.4 74.0 0.6 99999 99999 99999 99999 437.3 2.7 1.99 0.06 502 20 1506 26 95468 204.7 0.3 72.3 0.5 82.4 0.4 76.9 0.6 277.0 3.3 2.61 0.06 446.2 2.7 2.06 0.06 558 20 1551 27 96008 217.4 0.3 75.5 0.4 87.9 0.4 83.8 0.6 99999 99999 99999 99999 469.7 2.8 2.09 0.06 502 19 1570 27 96188 218.2 0.3 75.7 0.4 88.2 0.4 82.6 0.6 287.4 3.4 2.69 0.06 469.1 2.8 2.25 0.06 530 19 1581 28 96368 211.4 0.3 74.2 0.5 85.2 0.4 80.7 0.6 99999 99999 99999 99999 461.3 2.8 2.05 0.06 534 19 1544 27 96548 219.8 0.3 75.6 0.4 88.7 0.4 83.0 0.6 288.6 3.5 2.72 0.06 473.8 2.8 2.22 0.06 518 19 1620 28 96908 223.7 0.3 76.5 0.4 90.6 0.4 85.2 0.6 291.0 3.5 2.74 0.06 476.6 2.8 2.24 0.06 557 19 1604 28 97088 221.9 0.3 76.7 0.4 90.3 0.4 85.6 0.6 99999 99999 99999 99999 476.6 2.8 2.17 0.06 556 19 1581 28 97268 219.4 0.3 76.4 0.4 88.8 0.4 83.1 0.6 290.7 3.5 2.67 0.06 484.2 2.8 2.18 0.06 518 19 1615 28 97448 219.3 0.3 76.7 0.4 88.7 0.4 83.2 0.6 99999 99999 99999 99999 468.5 2.8 2.19 0.06 519 19 1564 27 97808 218.3 0.3 76.2 0.4 87.6 0.4 83.8 0.6 99999 99999 99999 99999 473.9 2.8 2.19 0.06 536 19 1609 28 97988 223.3 0.3 76.9 0.4 89.9 0.4 84.9 0.6 289.6 3.5 2.83 0.05 476.8 2.8 2.21 0.06 549 19 1607 28 98168 211.9 0.3 74.0 0.5 85.6 0.4 81.8 0.6 99999 99999 99999 99999 466.8 2.8 2.19 0.06 506 19 1582 28 98348 227.0 0.3 77.7 0.4 92.3 0.4 86.6 0.6 293.6 3.5 2.79 0.06 485.4 2.8 2.41 0.06 507 19 1672 29 98708 218.9 0.3 75.8 0.4 88.6 0.4 83.1 0.6 288.0 3.4 2.71 0.06 469.6 2.8 2.29 0.06 512 19 1591 28 98888 224.9 0.3 77.1 0.4 92.1 0.4 88.1 0.6 99999 99999 99999 99999 482.1 2.8 2.32 0.06 532 19 1608 29 99068 250.0 0.3 80.7 0.4 102.3 0.4 99.1 0.6 301.9 3.6 2.83 0.05 502.4 2.8 2.81 0.07 505 19 1678 30 99248 268.4 0.4 84.5 0.4 109.6 0.4 108.7 0.6 99999 99999 99999 99999 526.0 2.9 3.61 0.07 525 19 1682 30 99608 272.6 0.4 84.2 0.4 109.2 0.4 111.8 0.6 99999 99999 99999 99999 531.1 3.0 3.55 0.07 530 19 1648 30 99788 271.0 0.4 83.8 0.4 109.0 0.4 109.6 0.6 310.6 3.8 2.99 0.05 523.9 2.9 3.57 0.07 505 20 1697 30 99968 267.6 0.4 84.1 0.4 108.7 0.4 108.9 0.6 99999 99999 99999 99999 526.8 2.9 3.36 0.07 490 20 1659 30 100148 248.6 0.3 80.0 0.4 101.5 0.4 98.4 0.6 299.7 3.6 2.84 0.05 500.8 2.8 3.01 0.07 527 20 1656 30 100508 218.4 0.3 74.2 0.5 87.7 0.4 84.8 0.6 282.1 3.4 2.67 0.06 461.3 2.8 2.32 0.06 554 20 1595 29 100688 202.6 0.3 71.4 0.5 81.1 0.4 78.4 0.6 99999 99999 99999 99999 447.5 2.7 2.08 0.06 534 20 1553 28 100868 202.7 0.3 70.7 0.5 81.2 0.4 77.0 0.6 274.0 3.3 2.60 0.06 440.3 2.7 1.97 0.06 550 20 1577 29 101408 266.4 0.4 82.6 0.4 108.2 0.4 110.1 0.6 99999 99999 99999 99999 523.5 2.9 3.45 0.07 538 20 1718 31 101588 272.0 0.4 83.5 0.4 110.3 0.4 111.8 0.6 313.6 3.8 99999 99999 526.5 2.9 3.55 0.07 486 20 1728 32 101768 272.6 0.4 83.4 0.3 110.5 0.4 112.0 0.6 99999 99999 99999 99999 533.5 3.0 3.55 0.07 532 20 1707 32 101948 273.1 0.4 83.5 0.3 109.8 0.4 111.3 0.6 315.6 3.8 99999 99999 531.2 3.0 3.56 0.07 508 20 1712 32 102308 273.2 0.4 83.5 0.3 110.3 0.4 112.1 0.6 316.3 3.9 99999 99999 536.6 3.0 3.57 0.07 99999 99999 99999 99999 102488 272.4 0.4 83.4 0.3 111.1 0.4 112.0 0.6 99999 99999 99999 99999 541.4 3.1 3.58 0.07 99999 99999 99999 99999 102668 272.3 0.4 82.5 0.4 109.7 0.4 111.1 0.6 321.1 4.0 99999 99999 544.5 3.1 3.48 0.07 99999 99999 99999 99999 102848 271.6 0.4 83.6 0.4 99999 99999 115.5 0.6 99999 99999 99999 99999 553.3 3.2 3.55 0.07 99999 99999 99999 99999