37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 10 20 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 77801 263.7 1.4 86.3 2.8 111.1 0.8 111.7 0.9 99999 99999 99999 99999 514.2 2.7 3.38 0.08 99999 99999 1746 35 77981 245.5 1.3 81.8 2.4 105.8 0.8 102.0 0.7 99999 99999 2.79 0.03 488.8 2.3 3.01 0.06 99999 99999 1634 32 78161 243.0 1.3 83.5 2.5 104.8 0.8 100.6 0.7 99999 99999 99999 99999 484.3 2.3 2.91 0.05 99999 99999 1591 31 78341 242.4 1.3 82.0 2.4 102.7 0.8 99.5 0.7 99999 99999 2.69 0.03 477.7 2.2 2.83 0.05 99999 99999 1598 31 78701 202.1 1.1 73.0 1.6 86.2 0.7 79.4 0.5 99999 99999 2.52 0.03 432.8 1.7 2.10 0.03 505 20 1504 29 78881 180.5 0.9 68.0 1.3 76.0 0.6 68.9 0.5 99999 99999 99999 99999 409.6 1.5 1.80 0.03 491 19 1457 28 79061 177.8 0.9 67.2 1.2 72.5 0.6 66.9 0.5 99999 99999 2.42 0.03 404.4 1.4 1.73 0.03 514 21 1474 28 79241 171.6 0.9 66.2 1.1 70.5 0.6 64.3 0.5 99999 99999 99999 99999 400.6 1.4 1.63 0.03 529 21 1438 27 79601 170.5 0.9 65.7 1.1 71.5 0.6 64.2 0.5 99999 99999 99999 99999 399.9 1.4 1.65 0.03 498 20 1444 28 79781 167.9 0.9 64.2 1.0 69.9 0.6 61.1 0.5 251.0 2.3 2.39 0.03 394.4 1.3 1.53 0.03 549 23 1453 28 79961 166.4 0.9 65.1 1.1 69.1 0.6 60.7 0.5 99999 99999 99999 99999 395.4 1.4 1.48 0.03 515 20 1453 28 80141 157.8 0.8 62.6 0.9 64.9 0.6 57.1 0.4 246.6 2.2 2.35 0.03 385.6 1.3 1.47 0.03 515 20 1440 28 80501 124.9 0.7 56.1 0.6 49.6 0.6 42.1 0.4 227.5 1.7 2.32 0.03 349.4 1.1 1.07 0.03 525 21 1374 26 80681 127.0 0.7 55.8 0.6 50.9 0.6 43.9 0.4 99999 99999 99999 99999 353.5 1.1 1.09 0.03 506 20 1376 27 80861 124.7 0.7 55.5 0.6 49.7 0.6 42.6 0.4 230.2 1.8 2.31 0.03 347.9 1.0 1.10 0.03 509 20 1366 26 81041 123.4 0.7 55.0 0.6 49.0 0.6 42.1 0.4 99999 99999 99999 99999 348.8 1.1 1.05 0.03 517 20 1357 26 81401 120.8 0.7 54.5 0.6 48.1 0.6 40.7 0.4 99999 99999 99999 99999 345.5 1.0 1.01 0.03 533 21 1351 26 81581 119.3 0.7 54.0 0.6 47.5 0.6 39.7 0.4 225.9 1.7 2.26 0.03 341.1 1.0 0.98 0.03 507 20 1364 26 81761 108.8 0.6 51.5 0.5 41.4 0.6 35.6 0.4 99999 99999 99999 99999 331.0 1.0 0.89 0.03 524 21 1338 26 82301 116.2 0.7 53.7 0.5 45.5 0.6 38.4 0.4 226.1 1.7 2.24 0.03 338.4 1.0 0.97 0.03 506 19 1370 27 82481 121.7 0.7 54.2 0.6 48.9 0.6 41.3 0.4 99999 99999 99999 99999 348.5 1.1 1.03 0.03 504 19 1345 26 82661 111.6 0.6 51.4 0.5 43.9 0.6 37.4 0.4 221.2 1.6 2.22 0.03 333.2 1.0 0.98 0.03 507 19 1347 26 82841 115.0 0.7 53.8 0.5 45.1 0.6 38.5 0.4 99999 99999 99999 99999 343.9 1.0 0.96 0.03 500 19 1351 26 83201 132.3 0.7 57.2 0.7 52.1 0.6 44.7 0.4 99999 99999 99999 99999 363.8 1.2 1.12 0.03 494 19 1392 27 83381 128.9 0.7 56.4 0.6 51.2 0.6 43.8 0.4 233.0 1.8 2.29 0.03 355.1 1.1 1.09 0.03 526 21 1381 27 83561 120.0 0.7 54.1 0.6 46.9 0.6 40.1 0.4 99999 99999 99999 99999 347.1 1.1 0.99 0.03 499 19 1361 27 84101 103.2 0.6 51.0 0.5 38.6 0.6 33.2 0.4 219.4 1.5 2.24 0.03 324.9 1.0 0.86 0.03 506 19 1344 26 84281 106.9 0.6 50.8 0.5 40.7 0.6 35.2 0.4 99999 99999 99999 99999 331.2 1.0 0.84 0.03 523 20 1314 26 84461 108.4 0.6 51.9 0.5 42.0 0.6 35.5 0.4 223.4 1.6 2.35 0.03 326.9 1.0 0.84 0.03 535 21 1334 26 84641 111.1 0.6 50.8 0.5 42.4 0.6 37.1 0.4 99999 99999 99999 99999 335.1 1.0 0.94 0.03 496 19 1329 26 85001 104.8 0.6 50.0 0.5 41.4 0.6 34.8 0.4 99999 99999 99999 99999 328.7 1.0 0.84 0.03 501 19 1305 26 85361 115.0 0.6 50.4 0.5 45.1 0.6 38.4 0.4 99999 99999 99999 99999 340.1 1.0 0.92 0.03 515 20 1357 27 85541 116.0 0.6 52.2 0.5 44.9 0.6 38.1 0.4 226.3 1.6 2.30 0.03 340.7 1.0 0.94 0.03 526 21 1359 27 85901 110.6 0.6 51.1 0.5 43.5 0.6 36.8 0.4 222.7 1.6 2.14 0.03 334.8 1.0 0.97 0.03 522 21 1344 26 86081 112.8 0.6 52.3 0.5 43.6 0.6 37.9 0.4 99999 99999 99999 99999 338.3 1.0 0.94 0.03 522 21 1339 26 86261 114.4 0.6 51.2 0.5 44.8 0.6 38.1 0.4 224.2 1.6 2.25 0.03 339.9 1.0 0.98 0.03 509 20 1336 26 86441 114.6 0.6 52.4 0.5 44.5 0.6 38.2 0.4 99999 99999 99999 99999 341.0 1.0 0.98 0.03 510 20 1325 26 86801 115.6 0.6 52.3 0.5 44.2 0.6 38.3 0.4 99999 99999 99999 99999 343.1 1.0 0.98 0.03 525 21 1363 26 86981 110.8 0.6 51.5 0.5 42.8 0.6 36.5 0.4 223.8 1.6 2.29 0.03 337.1 1.0 0.96 0.03 535 22 1467 29 87161 109.4 0.6 51.0 0.5 42.2 0.6 35.8 0.4 99999 99999 99999 99999 335.8 1.0 0.97 0.03 521 21 1327 26 87341 106.7 0.6 50.2 0.5 40.7 0.6 34.6 0.4 221.2 1.6 2.25 0.03 328.4 1.0 0.88 0.03 547 23 1360 26 87701 115.9 0.6 52.6 0.5 45.0 0.6 38.7 0.4 226.5 1.6 2.27 0.03 338.8 1.0 0.94 0.03 543 23 1345 26 87881 136.7 0.7 57.6 0.7 54.7 0.6 47.2 0.4 99999 99999 99999 99999 367.5 1.2 1.14 0.03 548 23 1405 27 88061 147.5 0.8 59.8 0.8 58.3 0.6 51.1 0.4 247.7 2.1 2.41 0.03 376.7 1.2 1.17 0.03 525 22 1452 28 88601 97.2 0.6 47.6 0.4 36.7 0.6 32.0 0.4 99999 99999 99999 99999 313.9 0.9 0.81 0.03 566 25 1307 25 88781 116.2 0.6 52.5 0.5 45.6 0.6 39.0 0.4 227.3 1.7 2.32 0.03 339.8 1.0 0.94 0.03 557 24 1396 27 88961 117.6 0.7 52.3 0.5 45.6 0.6 39.4 0.4 99999 99999 99999 99999 345.2 1.1 0.98 0.03 546 23 1345 26 89141 114.9 0.6 52.5 0.5 44.1 0.6 37.9 0.4 226.5 1.7 2.32 0.03 340.7 1.0 0.95 0.03 548 23 1384 27 89501 111.0 0.6 51.7 0.5 42.2 0.6 36.6 0.4 223.5 1.6 2.31 0.03 336.7 1.0 0.85 0.03 548 23 1370 26 89681 109.3 0.6 51.4 0.5 40.8 0.6 36.2 0.4 99999 99999 99999 99999 335.8 1.0 0.89 0.03 538 22 1345 26 89861 95.9 0.6 47.2 0.4 36.0 0.6 30.4 0.4 212.8 1.4 2.18 0.03 313.8 0.9 0.83 0.03 571 25 1328 25 90041 109.0 0.6 51.2 0.5 41.2 0.6 35.8 0.4 99999 99999 99999 99999 336.7 1.0 0.94 0.03 555 24 1350 26 90401 28.2 0.5 28.1 0.5 8.0 0.7 9.5 0.6 99999 99999 99999 99999 205.1 0.8 0.43 0.04 566 24 1100 21 90581 21.3 0.6 25.1 0.6 4.2 0.7 6.8 0.6 145.5 0.9 2.04 0.03 183.7 0.8 0.41 0.04 544 23 1076 21 90761 16.9 0.6 22.2 0.6 3.4 0.7 5.7 0.6 99999 99999 99999 99999 168.9 0.9 0.38 0.04 589 26 1034 20 90941 17.3 0.6 22.3 0.6 3.3 0.7 5.5 0.6 138.4 0.9 1.93 0.03 170.3 0.9 0.37 0.04 566 24 1054 21 91301 14.9 0.6 19.9 0.6 1.7 0.7 5.2 0.6 131.2 0.9 1.99 0.03 157.0 0.9 0.36 0.04 556 23 1028 20 91481 17.1 0.6 21.6 0.6 2.9 0.7 5.7 0.6 99999 99999 99999 99999 163.9 0.9 0.35 0.04 554 23 1009 20 91661 14.6 0.6 18.4 0.6 0.9 0.7 4.6 0.6 131.5 0.9 2.06 0.03 153.4 0.9 0.33 0.04 548 23 1013 20 91841 16.3 0.6 21.1 0.6 2.3 0.7 5.5 0.6 99999 99999 99999 99999 161.8 0.9 0.37 0.04 557 23 1005 20 92201 79.4 0.5 39.5 0.4 25.9 0.6 26.9 0.5 99999 99999 99999 99999 273.0 0.8 0.67 0.03 523 21 1185 23 92381 102.6 0.6 44.7 0.4 36.1 0.6 35.6 0.4 207.3 1.3 2.10 0.03 304.5 0.9 0.93 0.03 531 21 1238 24 92561 215.9 1.2 71.7 1.5 87.3 0.7 85.3 0.5 99999 99999 99999 99999 452.8 1.9 2.38 0.03 486 19 1519 29 92741 118.4 0.7 47.9 0.4 43.0 0.6 41.0 0.4 215.0 1.4 2.20 0.03 315.7 0.9 1.02 0.03 527 21 1281 24 93101 74.0 0.5 38.5 0.5 21.7 0.6 24.1 0.5 187.9 1.1 2.14 0.03 269.5 0.8 0.68 0.03 525 21 1194 23 93281 127.2 0.7 53.3 0.5 44.9 0.6 44.0 0.4 99999 99999 99999 99999 355.8 1.1 1.15 0.03 517 20 1346 25 93461 127.9 0.7 53.2 0.5 45.1 0.6 43.7 0.4 231.0 1.7 2.40 0.03 354.3 1.1 1.08 0.03 511 20 1375 26 94001 105.7 0.6 49.2 0.4 36.1 0.6 35.0 0.4 99999 99999 99999 99999 331.2 1.0 0.87 0.03 525 21 1358 26 94181 90.4 0.6 45.9 0.4 30.0 0.6 29.0 0.5 207.9 1.3 2.26 0.03 305.9 0.9 0.81 0.03 526 21 1304 25 94361 110.2 0.6 50.6 0.5 38.7 0.6 36.3 0.4 99999 99999 99999 99999 338.1 1.0 0.91 0.03 518 20 1340 26 94541 105.8 0.6 48.9 0.4 37.7 0.6 33.9 0.4 220.0 1.5 2.22 0.03 332.7 1.0 0.87 0.03 502 19 1330 25 94901 107.4 0.6 50.0 0.5 38.7 0.6 35.3 0.4 222.2 1.6 2.36 0.03 330.8 1.0 0.81 0.03 515 20 1345 26 95081 111.9 0.6 51.0 0.5 39.5 0.6 36.9 0.4 99999 99999 99999 99999 338.6 1.0 0.91 0.03 489 18 1330 25 95261 108.5 0.6 50.2 0.5 38.4 0.6 35.3 0.4 223.1 1.6 2.32 0.03 333.2 1.0 0.86 0.03 532 21 1342 26 95441 84.2 0.5 44.5 0.4 28.0 0.6 26.3 0.5 99999 99999 99999 99999 302.9 0.9 0.70 0.03 504 19 1269 24 95801 80.0 0.5 43.1 0.4 26.0 0.6 25.1 0.5 99999 99999 99999 99999 295.6 0.9 0.69 0.03 500 19 1259 24 95981 73.5 0.5 42.2 0.4 24.0 0.6 22.5 0.5 199.0 1.2 2.09 0.03 290.8 0.8 0.62 0.04 533 21 1285 25 96161 77.9 0.5 43.2 0.4 24.9 0.6 23.7 0.5 99999 99999 99999 99999 296.2 0.9 0.65 0.03 516 20 1258 24 96341 93.8 0.6 47.4 0.4 32.8 0.6 29.8 0.5 214.1 1.5 2.27 0.03 314.5 0.9 0.74 0.03 507 19 1352 26 96701 110.2 0.6 51.3 0.5 39.9 0.6 35.4 0.4 225.7 1.6 2.32 0.03 337.7 1.0 0.89 0.03 496 19 1365 26 96881 106.0 0.6 51.0 0.5 37.4 0.6 33.8 0.4 99999 99999 99999 99999 334.6 1.0 0.84 0.03 510 20 1350 26 97061 106.7 0.6 50.5 0.5 37.4 0.6 33.6 0.4 224.9 1.6 2.34 0.03 334.9 1.0 0.88 0.03 516 20 1384 26 97241 94.4 0.6 47.6 0.4 33.1 0.6 29.8 0.5 99999 99999 99999 99999 319.7 0.9 0.79 0.03 514 20 1315 25 97601 88.6 0.6 45.7 0.4 30.0 0.6 27.4 0.5 99999 99999 99999 99999 312.5 0.9 0.75 0.03 518 20 1287 24 97781 88.4 0.6 46.7 0.4 29.8 0.6 27.1 0.5 210.2 1.4 2.19 0.03 309.8 0.9 0.72 0.03 516 20 1347 26 97961 90.5 0.6 46.4 0.4 30.3 0.6 28.3 0.5 99999 99999 99999 99999 314.3 0.9 0.77 0.03 508 20 1320 25 98141 89.7 0.6 46.5 0.4 31.1 0.6 27.1 0.5 211.4 1.4 2.29 0.03 310.6 0.9 0.77 0.03 542 22 1347 26 98501 90.6 0.6 46.4 0.4 31.8 0.6 27.9 0.5 213.4 1.4 2.24 0.03 314.0 0.9 0.75 0.03 553 23 1347 26 98681 83.9 0.5 45.8 0.4 27.5 0.6 25.3 0.5 99999 99999 99999 99999 306.4 0.9 0.66 0.03 534 22 1284 24 98861 81.7 0.5 44.8 0.4 27.3 0.6 25.0 0.5 209.1 1.4 2.16 0.03 300.9 0.9 0.67 0.03 525 21 1328 25 99401 62.1 0.5 40.3 0.4 18.6 0.6 17.7 0.5 99999 99999 99999 99999 276.9 0.8 0.53 0.04 561 24 1234 23 99581 60.8 0.5 40.4 0.4 17.8 0.6 17.1 0.5 193.2 1.2 2.18 0.03 273.9 0.8 0.53 0.04 550 23 1296 25 99761 57.8 0.5 38.7 0.4 16.1 0.6 16.6 0.5 99999 99999 99999 99999 271.3 0.8 0.52 0.04 553 23 1237 23 99941 56.4 0.5 37.1 0.5 15.5 0.6 15.8 0.5 188.4 1.1 2.24 0.03 265.1 0.8 0.53 0.04 548 23 1311 25 100301 45.5 0.5 33.7 0.5 11.3 0.6 13.1 0.5 175.3 1.0 2.14 0.03 238.7 0.8 0.49 0.04 579 26 1227 23 100481 43.5 0.5 32.6 0.5 10.9 0.6 12.6 0.5 99999 99999 99999 99999 239.0 0.8 0.46 0.04 560 24 1178 22 100661 39.0 0.5 30.5 0.5 9.8 0.6 10.9 0.5 167.2 1.0 2.12 0.03 223.5 0.8 0.47 0.04 545 23 1233 23 100841 35.1 0.5 28.3 0.5 8.0 0.6 10.4 0.5 99999 99999 99999 99999 214.1 0.8 0.50 0.04 557 24 1168 22 101201 27.5 0.5 26.5 0.5 3.7 0.7 8.8 0.6 99999 99999 99999 99999 198.4 0.8 0.40 0.04 573 25 1096 21 101381 25.0 0.6 26.1 0.5 2.1 0.7 7.4 0.6 151.6 0.9 2.05 0.03 191.4 0.8 0.38 0.04 581 26 1169 22 101561 24.8 0.6 25.0 0.5 2.0 0.7 7.8 0.6 99999 99999 99999 99999 193.3 0.8 0.40 0.04 549 23 1117 21 101741 24.9 0.6 25.2 0.5 2.4 0.7 7.4 0.6 151.4 0.9 2.06 0.03 191.6 0.8 0.38 0.04 556 24 1209 23 102101 25.4 0.6 25.3 0.5 3.3 0.7 8.1 0.6 152.8 0.9 2.04 0.03 193.3 0.8 0.41 0.04 582 25 1163 22 102281 29.8 0.5 27.5 0.5 3.2 0.7 9.0 0.6 99999 99999 99999 99999 204.9 0.8 0.43 0.04 577 25 1128 21 102461 69.7 0.5 41.9 0.4 20.3 0.6 20.4 0.5 200.0 1.3 2.23 0.03 286.9 0.8 0.58 0.04 536 22 1353 26 102641 65.0 0.5 40.5 0.4 17.3 0.6 18.7 0.5 99999 99999 99999 99999 281.2 0.8 0.57 0.04 515 20 1264 24 103001 61.3 0.5 39.6 0.4 16.0 0.6 18.6 0.5 99999 99999 99999 99999 272.4 0.8 0.62 0.04 535 22 1212 23 103181 62.9 0.5 39.5 0.4 16.6 0.6 18.3 0.5 193.3 1.2 2.19 0.03 271.3 0.8 0.55 0.04 533 22 1304 25 103361 61.8 0.5 39.1 0.4 15.6 0.6 18.9 0.5 99999 99999 99999 99999 269.2 0.8 0.55 0.04 557 23 1238 23 103541 64.9 0.5 40.1 0.4 16.7 0.6 18.9 0.5 195.2 1.2 2.18 0.03 275.8 0.8 0.58 0.04 515 20 1333 25 103901 177.3 1.0 63.3 1.0 67.0 0.6 67.6 0.5 260.8 2.5 2.58 0.03 402.9 1.4 1.78 0.03 507 20 99999 99999 104081 229.4 1.4 76.8 1.9 93.4 0.7 92.9 0.6 99999 99999 99999 99999 474.7 2.2 2.78 0.04 515 21 99999 99999 104261 245.8 1.5 79.7 2.1 101.0 0.7 100.0 0.7 305.2 4.0 3.03 0.04 484.7 2.3 2.96 0.05 483 19 99999 99999 104441 264.0 1.7 86.5 2.8 107.2 0.8 110.6 0.9 99999 99999 99999 99999 517.1 2.7 3.24 0.06 498 20 99999 99999