37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 10 16 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 76368 267.0 0.9 89.8 2.3 112.6 0.8 112.3 1.1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 1798 44 76548 266.0 0.9 88.9 2.5 112.6 0.8 111.1 1.1 99999 99999 99999 99999 567.4 7.0 99999 99999 99999 99999 1696 41 76728 259.7 0.9 87.6 2.5 111.7 0.8 109.1 1.1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 1668 40 76908 262.6 0.9 86.7 2.6 110.9 0.9 110.5 1.1 99999 99999 99999 99999 557.7 6.8 99999 99999 99999 99999 1659 40 77268 220.1 0.6 76.4 1.8 90.7 0.7 99999 99999 99999 99999 99999 99999 502.4 5.9 99999 99999 501 17 1563 38 77448 205.7 0.5 73.3 1.6 84.1 0.6 81.0 0.8 99999 99999 99999 99999 99999 99999 99999 99999 523 18 1532 37 77628 157.8 0.3 61.9 0.9 61.6 0.6 58.1 0.7 99999 99999 99999 99999 413.1 4.5 99999 99999 495 17 1406 34 77808 134.8 0.3 57.1 0.7 51.3 0.5 47.5 0.6 99999 99999 99999 99999 99999 99999 99999 99999 544 20 1340 33 78168 131.0 0.3 56.4 0.7 49.0 0.5 45.3 0.6 99999 99999 99999 99999 99999 99999 99999 99999 489 16 1372 33 78348 122.3 0.3 53.8 0.7 45.3 0.5 41.2 0.6 99999 99999 99999 99999 357.7 3.8 99999 99999 545 20 1348 33 78528 132.6 0.3 56.6 0.7 49.7 0.5 45.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 542 20 1369 33 78708 138.5 0.3 57.9 0.8 52.3 0.5 47.7 0.6 99999 99999 99999 99999 383.7 4.2 99999 99999 547 20 1397 34 79068 132.9 0.3 56.7 0.7 48.8 0.5 45.1 0.6 99999 99999 99999 99999 375.0 4.1 99999 99999 520 18 1396 34 79248 125.4 0.3 54.6 0.7 44.3 0.5 41.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 510 18 1347 33 79428 132.1 0.3 56.5 0.7 48.0 0.5 44.5 0.6 99999 99999 99999 99999 369.3 4.0 99999 99999 553 21 1375 34 79608 130.6 0.3 56.3 0.7 47.8 0.5 44.4 0.6 99999 99999 99999 99999 99999 99999 99999 99999 546 20 1366 34 79968 110.0 0.3 51.1 0.6 39.1 0.5 35.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 491 16 1310 32 80148 103.0 0.3 49.9 0.6 35.4 0.5 32.6 0.6 99999 99999 99999 99999 325.1 3.5 99999 99999 554 21 1321 33 80328 99.4 0.3 48.5 0.6 34.6 0.5 31.3 0.6 99999 99999 99999 99999 99999 99999 99999 99999 517 18 1297 32 80868 91.3 0.3 47.4 0.6 30.6 0.6 27.7 0.6 99999 99999 99999 99999 308.1 3.3 99999 99999 543 20 1331 33 81048 89.7 0.3 46.4 0.6 29.7 0.6 27.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 522 19 1294 32 81228 89.0 0.3 46.9 0.5 29.5 0.6 27.1 0.6 99999 99999 99999 99999 308.8 3.3 99999 99999 559 21 1375 34 81408 87.2 0.3 46.4 0.5 29.3 0.6 26.6 0.6 99999 99999 99999 99999 99999 99999 99999 99999 560 22 1276 32 81768 89.4 0.3 46.9 0.6 29.8 0.6 28.1 0.6 99999 99999 99999 99999 99999 99999 99999 99999 568 22 1271 32 81948 87.4 0.3 45.3 0.6 29.0 0.6 27.0 0.6 99999 99999 99999 99999 311.9 3.4 99999 99999 550 21 1382 34 82128 84.8 0.3 45.5 0.5 28.6 0.6 26.1 0.6 99999 99999 99999 99999 99999 99999 99999 99999 556 21 1255 31 82668 77.6 0.3 44.0 0.5 24.2 0.6 23.1 0.6 99999 99999 99999 99999 297.0 3.2 99999 99999 522 18 1278 32 82848 80.8 0.3 44.3 0.5 26.5 0.6 24.9 0.6 99999 99999 99999 99999 99999 99999 99999 99999 499 17 1271 32 83028 80.1 0.3 45.3 0.5 26.3 0.6 24.0 0.6 99999 99999 99999 99999 298.7 3.2 99999 99999 563 22 1271 32 83208 80.1 0.3 45.6 0.5 26.4 0.6 23.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 525 19 1263 31 83568 77.5 0.3 44.8 0.5 24.8 0.6 23.9 0.6 99999 99999 99999 99999 99999 99999 99999 99999 490 16 1272 31 83928 80.8 0.3 44.5 0.5 26.0 0.6 24.1 0.6 99999 99999 99999 99999 99999 99999 99999 99999 544 20 1274 31 84108 75.2 0.3 43.8 0.5 24.6 0.6 21.3 0.6 99999 99999 99999 99999 293.0 3.2 99999 99999 553 21 1293 32 84468 85.1 0.3 46.2 0.5 28.6 0.6 26.3 0.6 99999 99999 99999 99999 304.8 3.3 99999 99999 569 22 1440 35 84648 94.8 0.3 48.7 0.6 33.8 0.6 30.0 0.6 99999 99999 99999 99999 99999 99999 99999 99999 526 19 1338 33 84828 105.1 0.3 50.5 0.6 37.6 0.5 33.4 0.6 99999 99999 99999 99999 338.9 3.7 99999 99999 566 22 1369 33 85008 110.8 0.3 51.9 0.6 40.5 0.5 35.7 0.6 99999 99999 99999 99999 99999 99999 99999 99999 516 18 1370 34 85368 106.6 0.3 51.4 0.6 39.6 0.5 34.4 0.6 99999 99999 99999 99999 99999 99999 99999 99999 526 19 1349 33 85548 104.3 0.3 50.5 0.6 38.1 0.5 33.4 0.6 99999 99999 99999 99999 334.0 3.7 99999 99999 521 18 1349 33 85728 91.2 0.3 47.4 0.6 31.7 0.6 28.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 538 19 1305 32 85908 91.9 0.3 47.9 0.5 31.6 0.6 28.4 0.6 99999 99999 99999 99999 316.8 3.5 99999 99999 538 19 1315 33 86268 95.1 0.3 48.3 0.6 33.6 0.6 30.3 0.6 99999 99999 99999 99999 321.0 3.5 99999 99999 508 17 1311 32 86448 95.4 0.3 49.3 0.6 34.1 0.6 30.0 0.6 99999 99999 99999 99999 99999 99999 99999 99999 534 19 1329 33 86628 97.9 0.3 50.4 0.6 34.7 0.5 30.1 0.6 99999 99999 99999 99999 321.2 3.5 99999 99999 517 18 1329 33 87168 102.5 0.3 50.9 0.6 37.8 0.5 33.2 0.6 99999 99999 99999 99999 99999 99999 99999 99999 501 17 1338 33 87348 101.9 0.3 51.0 0.6 37.5 0.5 32.1 0.6 99999 99999 99999 99999 326.7 3.6 99999 99999 520 18 1341 33 87528 98.2 0.3 49.9 0.6 36.5 0.5 30.9 0.6 99999 99999 99999 99999 99999 99999 99999 99999 515 18 1326 33 87708 86.0 0.3 46.4 0.5 30.6 0.6 26.3 0.6 99999 99999 99999 99999 298.3 3.3 99999 99999 501 17 1311 32 88068 85.2 0.3 46.3 0.5 30.7 0.6 26.5 0.6 99999 99999 99999 99999 296.7 3.3 99999 99999 529 19 1302 32 88248 102.8 0.3 51.1 0.6 40.1 0.5 33.1 0.6 99999 99999 99999 99999 99999 99999 99999 99999 524 18 1345 33 88428 95.2 0.3 48.6 0.6 36.0 0.5 29.5 0.6 99999 99999 99999 99999 312.0 3.4 99999 99999 529 19 1339 33 88608 93.8 0.3 48.5 0.6 36.3 0.5 29.6 0.6 99999 99999 99999 99999 99999 99999 99999 99999 519 18 1327 33 88968 65.2 0.4 40.4 0.5 23.9 0.6 20.6 0.6 99999 99999 99999 99999 99999 99999 99999 99999 525 19 1248 31 89148 56.6 0.4 37.8 0.6 21.3 0.6 17.9 0.6 99999 99999 99999 99999 253.1 2.8 99999 99999 555 21 1258 31 89328 46.0 0.4 34.5 0.6 16.0 0.6 14.7 0.6 99999 99999 99999 99999 99999 99999 99999 99999 528 19 1236 30 89508 54.1 0.4 37.4 0.6 19.2 0.6 17.3 0.6 99999 99999 99999 99999 233.5 2.6 99999 99999 563 22 1225 30 89868 27.6 0.5 28.7 0.6 8.4 0.6 8.5 0.7 99999 99999 99999 99999 184.6 2.1 99999 99999 590 24 1131 28 90048 31.4 0.5 28.7 0.6 8.4 0.6 10.2 0.7 99999 99999 99999 99999 99999 99999 99999 99999 562 22 1132 28 90228 31.8 0.5 29.2 0.6 6.2 0.6 10.0 0.7 99999 99999 99999 99999 198.6 2.2 99999 99999 557 21 1123 28 90408 88.9 0.3 41.7 0.5 29.8 0.6 30.5 0.6 99999 99999 99999 99999 99999 99999 99999 99999 562 22 1252 31 90768 47.1 0.4 31.3 0.6 12.9 0.6 16.1 0.6 99999 99999 99999 99999 99999 99999 99999 99999 534 19 1130 28 90948 55.2 0.4 34.3 0.6 14.6 0.6 17.6 0.6 99999 99999 99999 99999 248.5 2.8 99999 99999 553 21 1159 28 91128 45.2 0.4 32.6 0.6 10.2 0.6 13.8 0.7 99999 99999 99999 99999 99999 99999 99999 99999 551 21 1148 28 91308 67.8 0.4 39.0 0.5 20.4 0.6 21.4 0.6 99999 99999 99999 99999 301.2 3.4 99999 99999 572 23 1264 31 91668 93.7 0.3 46.2 0.5 31.3 0.6 29.7 0.6 99999 99999 99999 99999 318.6 3.6 99999 99999 545 20 1318 32 91848 90.3 0.3 45.7 0.5 30.2 0.6 29.3 0.6 99999 99999 99999 99999 99999 99999 99999 99999 565 22 1293 32 92028 97.2 0.3 47.3 0.5 33.5 0.6 31.1 0.6 99999 99999 99999 99999 325.0 3.7 99999 99999 541 20 1309 32 92568 92.1 0.3 47.3 0.5 32.6 0.6 29.6 0.6 99999 99999 99999 99999 99999 99999 99999 99999 569 22 1291 32 92748 91.4 0.3 47.7 0.5 32.5 0.6 28.0 0.6 99999 99999 99999 99999 315.2 3.6 99999 99999 563 22 1325 32 92928 84.1 0.3 44.8 0.5 28.0 0.6 25.4 0.6 99999 99999 99999 99999 99999 99999 99999 99999 566 22 1276 31 93108 83.8 0.3 45.7 0.5 28.9 0.6 25.0 0.6 99999 99999 99999 99999 309.8 3.6 99999 99999 565 22 1303 32 93468 92.1 0.3 48.0 0.5 32.9 0.6 29.1 0.6 99999 99999 99999 99999 325.1 3.8 99999 99999 566 22 1316 32 93648 88.6 0.3 47.2 0.5 32.5 0.6 27.4 0.6 99999 99999 99999 99999 99999 99999 99999 99999 561 22 1297 32 93828 74.8 0.3 44.0 0.5 26.1 0.6 22.2 0.6 99999 99999 99999 99999 302.5 3.5 99999 99999 552 21 1278 31 94008 90.4 0.3 47.2 0.5 31.9 0.6 28.0 0.6 99999 99999 99999 99999 99999 99999 99999 99999 581 24 1303 32 94368 69.5 0.4 42.7 0.5 24.3 0.6 21.2 0.6 99999 99999 99999 99999 99999 99999 99999 99999 570 23 1255 31 94548 57.3 0.4 39.0 0.5 19.4 0.6 17.5 0.6 99999 99999 99999 99999 270.7 3.2 99999 99999 606 26 1236 30 94728 59.3 0.4 39.4 0.5 19.0 0.6 18.0 0.6 99999 99999 99999 99999 99999 99999 99999 99999 554 21 1239 30 94908 61.8 0.4 41.1 0.5 21.0 0.6 18.0 0.6 99999 99999 99999 99999 276.5 3.2 99999 99999 517 18 1263 31 95268 59.3 0.4 40.4 0.5 19.8 0.6 17.5 0.6 99999 99999 99999 99999 270.1 3.2 99999 99999 569 22 1254 30 95448 66.3 0.4 42.5 0.5 22.0 0.6 19.4 0.6 99999 99999 99999 99999 99999 99999 99999 99999 516 18 1252 30 95628 65.4 0.4 42.1 0.5 21.4 0.6 19.3 0.6 99999 99999 99999 99999 287.1 3.4 99999 99999 552 21 1277 31 95808 59.3 0.4 40.5 0.5 19.7 0.6 17.5 0.6 99999 99999 99999 99999 99999 99999 99999 99999 544 20 1237 30 96168 63.8 0.4 41.0 0.5 21.4 0.6 18.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 548 20 1257 30 96348 57.1 0.4 40.0 0.5 19.1 0.6 16.2 0.6 99999 99999 99999 99999 272.7 3.2 99999 99999 561 21 1243 30 96528 56.2 0.4 39.8 0.5 18.7 0.6 16.0 0.6 99999 99999 99999 99999 99999 99999 99999 99999 560 21 1246 30 96708 56.1 0.4 39.4 0.5 18.6 0.6 16.1 0.6 99999 99999 99999 99999 267.1 3.2 99999 99999 571 22 1352 33 97068 56.2 0.4 38.6 0.5 18.9 0.6 16.3 0.6 99999 99999 99999 99999 268.7 3.2 99999 99999 549 20 1243 30 97248 56.6 0.4 39.5 0.5 18.5 0.6 16.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 522 18 1226 30 97428 57.2 0.4 39.4 0.5 19.1 0.6 16.1 0.6 99999 99999 99999 99999 267.3 3.2 99999 99999 550 20 1277 31 97968 57.7 0.4 39.6 0.5 18.7 0.6 16.6 0.6 99999 99999 99999 99999 99999 99999 99999 99999 551 20 1242 30 98148 56.3 0.4 38.9 0.5 18.5 0.6 16.5 0.6 99999 99999 99999 99999 265.8 3.1 99999 99999 537 19 1290 31 98328 57.2 0.4 39.7 0.5 18.4 0.6 16.9 0.6 99999 99999 99999 99999 99999 99999 99999 99999 519 18 1238 30 98508 56.8 0.4 39.4 0.5 19.0 0.6 16.8 0.6 99999 99999 99999 99999 267.4 3.2 99999 99999 536 19 1304 32 98868 57.7 0.4 40.0 0.5 18.7 0.6 16.0 0.6 99999 99999 99999 99999 270.5 3.2 99999 99999 530 19 1274 31 99048 56.8 0.4 40.1 0.5 16.9 0.6 15.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 526 18 1240 30 99228 56.1 0.4 40.4 0.5 17.3 0.6 15.6 0.6 99999 99999 99999 99999 265.4 3.1 99999 99999 535 19 1286 31 99408 58.1 0.4 39.7 0.5 17.9 0.6 16.9 0.6 99999 99999 99999 99999 99999 99999 99999 99999 534 19 1252 31 99768 55.7 0.4 40.2 0.5 16.6 0.6 15.7 0.6 99999 99999 99999 99999 99999 99999 99999 99999 542 20 1230 30 99948 58.2 0.4 40.7 0.5 17.8 0.6 16.2 0.6 99999 99999 99999 99999 273.0 3.2 99999 99999 538 20 1314 32 100128 58.6 0.4 40.8 0.5 16.9 0.6 16.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 536 19 1274 31 100308 59.3 0.4 40.3 0.5 17.8 0.6 17.4 0.6 99999 99999 99999 99999 278.6 3.3 99999 99999 520 18 1334 32 100668 56.4 0.4 40.0 0.5 16.5 0.6 15.6 0.6 99999 99999 99999 99999 272.5 3.2 99999 99999 526 19 1311 32 100848 57.2 0.4 40.6 0.5 14.6 0.6 15.4 0.6 99999 99999 99999 99999 99999 99999 99999 99999 561 22 1257 30 101028 56.5 0.4 39.8 0.5 14.8 0.6 14.9 0.6 99999 99999 99999 99999 275.6 3.2 99999 99999 575 23 1357 33 101208 58.7 0.4 40.9 0.5 16.0 0.6 17.1 0.6 99999 99999 99999 99999 99999 99999 99999 99999 569 22 1280 31 101568 56.9 0.4 38.4 0.5 16.2 0.6 17.2 0.6 99999 99999 99999 99999 99999 99999 99999 99999 534 19 1212 29 101748 55.2 0.4 38.3 0.5 15.5 0.6 16.5 0.6 99999 99999 99999 99999 253.0 3.0 99999 99999 546 20 1372 32 101928 57.8 0.4 38.9 0.5 15.0 0.6 16.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 542 20 1298 30 102108 58.7 0.4 39.7 0.5 16.4 0.6 17.0 0.6 99999 99999 99999 99999 262.0 3.1 99999 99999 522 18 1444 33 102468 191.4 0.4 65.6 1.1 71.1 0.6 71.9 0.7 99999 99999 99999 99999 422.6 5.2 99999 99999 99999 99999 1511 34 102648 225.6 0.6 72.5 1.5 88.3 0.7 90.7 0.8 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 1608 36 102828 246.3 0.8 77.1 1.8 99.0 0.7 98.5 0.9 99999 99999 99999 99999 521.4 6.8 99999 99999 434 13 1672 37 103008 266.4 0.9 84.1 2.3 107.4 0.8 109.4 1.0 99999 99999 99999 99999 99999 99999 99999 99999 491 16 1649 36