37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 10 13 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 77051 255.4 1.0 83.1 1.4 108.5 0.9 105.3 0.7 99999 99999 99999 99999 503.4 2.7 2.93 0.10 99999 99999 99999 99999 77230 238.7 0.9 81.4 1.4 102.3 0.8 96.9 0.6 99999 99999 99999 99999 482.1 2.5 2.65 0.10 99999 99999 99999 99999 77411 230.3 0.9 78.6 1.3 99.1 0.8 93.4 0.6 99999 99999 99999 99999 469.4 2.4 2.48 0.10 99999 99999 99999 99999 77771 204.1 0.7 72.4 1.0 86.6 0.8 80.0 0.5 99999 99999 99999 99999 448.3 2.2 2.24 0.09 509 18 1500 17 77951 152.6 0.5 60.4 0.7 63.6 0.7 56.6 0.5 99999 99999 99999 99999 373.2 1.5 1.56 0.08 483 17 1366 15 78131 171.9 0.6 64.5 0.8 71.9 0.7 65.2 0.5 99999 99999 99999 99999 398.8 1.7 1.64 0.08 491 17 1424 16 78491 138.5 0.5 58.1 0.6 57.3 0.7 49.8 0.5 99999 99999 99999 99999 362.3 1.4 1.31 0.08 486 17 1347 15 78671 136.0 0.5 56.8 0.6 56.7 0.7 47.8 0.5 99999 99999 99999 99999 357.2 1.4 1.21 0.08 533 20 1357 15 78851 153.6 0.5 61.9 0.7 64.7 0.7 56.0 0.5 99999 99999 99999 99999 377.7 1.5 1.54 0.08 487 17 1394 16 79210 112.3 0.4 51.7 0.6 46.2 0.7 37.6 0.5 99999 99999 99999 99999 334.0 1.2 1.02 0.08 481 17 1311 15 79391 105.4 0.4 51.8 0.6 43.1 0.7 34.3 0.5 99999 99999 99999 99999 327.8 1.2 0.90 0.08 493 17 1302 15 79571 66.3 0.4 40.5 0.6 26.6 0.7 20.0 0.5 99999 99999 99999 99999 271.4 1.0 0.61 0.08 499 18 1225 14 79931 152.9 0.5 61.9 0.8 64.3 0.7 53.0 0.5 99999 99999 99999 99999 390.5 1.6 1.29 0.08 492 17 1400 16 80111 126.6 0.5 55.4 0.6 52.1 0.7 41.9 0.5 99999 99999 99999 99999 357.1 1.4 0.99 0.08 496 18 1346 16 80291 117.7 0.5 53.8 0.6 49.3 0.7 38.8 0.5 99999 99999 99999 99999 353.2 1.3 1.05 0.08 506 18 1324 15 80651 110.9 0.4 51.8 0.6 45.1 0.7 35.6 0.5 99999 99999 99999 99999 336.1 1.2 0.85 0.08 528 20 1308 15 80831 112.8 0.4 52.3 0.6 46.4 0.7 36.3 0.5 99999 99999 99999 99999 339.9 1.3 0.70 0.08 486 17 1310 15 81011 117.5 0.4 52.1 0.6 48.1 0.7 38.1 0.5 99999 99999 99999 99999 344.4 1.3 0.96 0.08 504 18 1294 15 81371 121.5 0.5 52.9 0.6 51.0 0.7 40.1 0.5 99999 99999 99999 99999 349.1 1.3 1.10 0.08 505 18 1292 15 81550 122.0 0.5 52.9 0.6 50.6 0.7 40.7 0.5 99999 99999 99999 99999 346.7 1.3 1.05 0.08 488 17 1300 15 81730 112.8 0.4 50.9 0.6 46.9 0.7 36.7 0.5 99999 99999 99999 99999 341.8 1.3 0.99 0.08 529 20 1284 15 82271 110.1 0.4 50.6 0.6 45.0 0.7 35.9 0.5 99999 99999 99999 99999 336.2 1.2 0.73 0.08 509 18 1273 15 82451 115.1 0.4 52.1 0.6 46.8 0.7 37.8 0.5 99999 99999 99999 99999 341.5 1.3 0.83 0.09 503 18 1281 15 82630 112.2 0.4 51.2 0.6 44.9 0.7 36.7 0.5 99999 99999 99999 99999 337.5 1.2 0.85 0.09 523 19 1275 15 82991 119.5 0.5 52.6 0.6 48.7 0.7 39.4 0.5 99999 99999 99999 99999 346.9 1.3 0.95 0.09 526 20 1298 15 83351 109.6 0.4 49.9 0.6 42.7 0.7 35.8 0.5 99999 99999 99999 99999 335.5 1.2 0.86 0.10 487 17 1278 15 83711 100.1 0.4 48.7 0.6 38.3 0.7 31.3 0.5 99999 99999 99999 99999 322.5 1.2 0.88 0.10 526 20 1266 15 83891 94.7 0.4 47.4 0.6 36.4 0.7 29.6 0.5 99999 99999 99999 99999 315.4 1.1 0.74 0.09 524 20 1251 15 84071 87.9 0.4 45.2 0.6 33.9 0.7 28.0 0.5 99999 99999 99999 99999 306.5 1.1 0.71 0.09 550 22 1231 14 84431 105.2 0.4 48.7 0.6 40.3 0.7 33.8 0.5 99999 99999 99999 99999 328.8 1.2 0.87 0.09 512 19 1290 15 84790 102.0 0.4 48.3 0.6 38.3 0.7 32.6 0.5 99999 99999 99999 99999 320.2 1.2 0.83 0.10 536 21 1289 15 85151 107.4 0.4 49.1 0.6 41.9 0.7 35.0 0.5 99999 99999 99999 99999 332.5 1.2 0.87 0.10 563 23 1290 15 85331 110.9 0.4 49.7 0.6 43.5 0.7 36.6 0.5 99999 99999 99999 99999 332.7 1.2 0.89 0.10 553 22 1293 15 85511 108.2 0.4 50.1 0.6 41.7 0.7 35.4 0.5 99999 99999 99999 99999 332.1 1.2 0.82 0.10 550 22 1293 15 85870 110.4 0.4 50.4 0.6 42.3 0.7 35.8 0.5 99999 99999 99999 99999 338.8 1.3 0.88 0.10 532 20 1315 15 86051 93.2 0.4 47.3 0.6 35.5 0.7 30.1 0.5 99999 99999 99999 99999 314.1 1.1 0.79 0.10 568 23 1268 15 86231 119.8 0.5 52.4 0.6 46.8 0.7 40.4 0.5 99999 99999 99999 99999 343.2 1.3 0.86 0.10 554 22 1315 15 86591 141.9 0.5 57.5 0.7 55.9 0.7 49.5 0.5 99999 99999 99999 99999 364.3 1.4 1.49 0.11 552 22 1359 16 86771 165.4 0.6 63.1 1.0 66.7 0.7 57.1 0.5 99999 99999 99999 99999 398.0 1.7 1.74 0.11 527 20 1438 17 86951 153.1 0.5 60.6 0.9 61.7 0.7 54.6 0.5 99999 99999 99999 99999 393.6 1.6 1.70 0.11 528 20 1411 17 87491 164.8 0.6 64.0 1.0 66.9 0.7 58.7 0.5 99999 99999 99999 99999 408.0 1.7 1.47 0.11 497 18 1428 17 87671 156.9 0.6 60.8 0.9 63.3 0.7 56.3 0.5 99999 99999 99999 99999 395.9 1.6 1.34 0.10 498 18 1402 16 87850 146.4 0.5 58.0 0.8 58.2 0.7 51.7 0.5 99999 99999 99999 99999 390.2 1.6 1.29 0.10 519 19 1384 16 88210 90.2 0.4 45.9 0.6 34.5 0.7 28.7 0.5 99999 99999 99999 99999 313.5 1.1 0.88 0.10 539 20 1240 14 88391 95.7 0.4 47.1 0.6 36.5 0.7 31.3 0.5 99999 99999 99999 99999 318.5 1.1 0.85 0.09 516 19 1264 15 88571 109.6 0.4 49.8 0.6 42.4 0.7 36.0 0.5 99999 99999 99999 99999 333.5 1.2 0.95 0.09 545 21 1277 15 88931 93.4 0.4 45.2 0.6 35.5 0.7 29.6 0.5 99999 99999 99999 99999 314.8 1.1 0.81 0.09 520 19 1254 14 89110 93.7 0.4 46.1 0.6 36.5 0.7 30.7 0.5 99999 99999 99999 99999 313.8 1.1 0.88 0.09 534 20 1245 14 89291 54.2 0.4 35.9 0.6 19.0 0.7 17.6 0.5 99999 99999 99999 99999 238.9 0.9 0.59 0.09 501 18 1137 13 89651 66.0 0.4 39.3 0.6 24.3 0.7 21.1 0.5 99999 99999 99999 99999 282.4 1.0 0.71 0.09 540 21 1183 14 89831 19.9 0.6 25.7 0.6 5.3 0.7 6.3 0.6 99999 99999 99999 99999 184.4 0.9 0.42 0.09 546 21 1040 12 90010 24.3 0.6 26.7 0.6 6.9 0.7 8.1 0.6 99999 99999 99999 99999 195.3 0.9 0.45 0.09 536 20 1050 12 90371 32.5 0.5 30.0 0.6 7.2 0.7 9.8 0.6 99999 99999 99999 99999 208.1 0.9 0.41 0.09 535 20 1030 12 90551 48.5 0.4 33.4 0.6 13.2 0.7 15.3 0.5 99999 99999 99999 99999 236.5 0.9 0.49 0.09 523 19 1090 12 90731 68.5 0.4 37.0 0.6 21.5 0.7 22.0 0.5 99999 99999 99999 99999 266.0 1.0 0.61 0.09 521 19 1129 13 91090 49.7 0.4 30.1 0.6 13.1 0.7 14.6 0.5 99999 99999 99999 99999 231.1 0.9 0.52 0.09 534 20 1066 12 91270 74.0 0.4 36.6 0.6 22.4 0.7 22.6 0.5 99999 99999 99999 99999 271.2 1.0 0.60 0.09 539 21 1148 13 91451 49.4 0.4 31.6 0.6 11.6 0.7 14.1 0.5 99999 99999 99999 99999 235.4 0.9 0.46 0.09 536 20 1078 12 91811 35.7 0.5 28.3 0.6 7.5 0.7 10.2 0.6 99999 99999 99999 99999 217.6 0.9 0.46 0.08 561 22 1084 12 91991 29.5 0.5 26.2 0.6 4.1 0.7 8.6 0.6 99999 99999 99999 99999 206.9 0.9 0.41 0.08 547 21 1063 12 92171 23.3 0.6 25.1 0.6 3.1 0.7 6.6 0.6 99999 99999 99999 99999 193.1 0.9 0.43 0.08 562 22 1053 12 92711 85.7 0.4 44.1 0.6 29.0 0.7 26.6 0.5 99999 99999 99999 99999 305.2 1.1 0.67 0.09 541 21 1240 14 92891 88.2 0.4 45.0 0.6 30.7 0.7 27.7 0.5 99999 99999 99999 99999 312.2 1.1 0.73 0.09 540 21 1243 14 93071 81.6 0.4 43.9 0.6 27.6 0.7 24.6 0.5 99999 99999 99999 99999 304.0 1.1 0.68 0.09 515 19 1239 14 93431 79.6 0.4 43.6 0.6 27.6 0.7 23.9 0.5 99999 99999 99999 99999 302.1 1.1 0.65 0.09 550 22 1230 14 93611 77.9 0.4 43.8 0.6 26.5 0.7 23.2 0.5 99999 99999 99999 99999 299.8 1.1 0.66 0.09 543 21 1229 14 93791 90.2 0.4 45.9 0.6 32.2 0.7 28.0 0.5 99999 99999 99999 99999 313.9 1.1 0.74 0.09 529 20 1261 15 94151 93.2 0.4 46.3 0.6 33.5 0.7 28.7 0.5 99999 99999 99999 99999 321.5 1.2 0.78 0.09 568 23 1281 15 94331 95.9 0.4 47.1 0.6 34.0 0.7 29.7 0.5 99999 99999 99999 99999 325.5 1.2 0.78 0.09 548 22 1283 15 94511 87.6 0.4 46.1 0.6 31.5 0.7 26.8 0.5 99999 99999 99999 99999 315.1 1.1 0.68 0.09 535 20 1254 15 94871 84.0 0.4 45.2 0.6 30.4 0.7 25.2 0.5 99999 99999 99999 99999 310.9 1.1 0.63 0.09 540 21 1237 14 95051 95.7 0.4 48.1 0.6 35.2 0.7 29.8 0.5 99999 99999 99999 99999 325.4 1.2 0.69 0.09 536 20 1278 15 95231 93.1 0.4 46.1 0.6 33.5 0.7 28.1 0.5 99999 99999 99999 99999 321.8 1.2 0.73 0.09 541 21 1249 15 95591 105.9 0.4 50.1 0.6 39.4 0.7 33.4 0.5 99999 99999 99999 99999 337.3 1.2 0.84 0.09 529 20 1280 15 95771 103.6 0.4 50.1 0.6 37.7 0.7 32.8 0.5 99999 99999 99999 99999 336.9 1.2 0.76 0.09 540 21 1265 15 95951 86.4 0.4 44.9 0.6 30.3 0.7 26.0 0.5 99999 99999 99999 99999 312.3 1.1 0.73 0.09 515 19 1242 15 96311 101.7 0.4 49.2 0.6 37.8 0.7 32.2 0.5 99999 99999 99999 99999 334.3 1.2 0.78 0.09 535 20 1264 15 96490 102.0 0.4 49.4 0.6 38.4 0.7 31.7 0.5 99999 99999 99999 99999 335.6 1.2 0.73 0.09 504 18 1252 15 96671 116.7 0.4 53.3 0.7 44.7 0.7 37.3 0.5 99999 99999 99999 99999 354.8 1.3 0.83 0.09 519 19 1316 16 97031 119.5 0.5 53.3 0.7 45.8 0.7 37.9 0.5 99999 99999 99999 99999 358.3 1.3 1.04 0.09 501 18 1323 16 97211 115.0 0.4 51.4 0.7 43.7 0.7 36.9 0.5 99999 99999 99999 99999 346.7 1.3 1.02 0.09 503 18 1299 15 97391 114.0 0.4 51.6 0.7 43.8 0.7 36.9 0.5 99999 99999 99999 99999 347.5 1.3 1.00 0.09 504 18 1305 15 97931 112.5 0.4 50.5 0.7 42.9 0.7 36.4 0.5 99999 99999 99999 99999 347.0 1.3 0.87 0.09 516 19 1294 15 98111 83.4 0.4 43.5 0.6 31.4 0.7 25.7 0.5 99999 99999 99999 99999 314.9 1.1 0.72 0.09 523 19 1240 14 98291 107.2 0.4 48.9 0.6 41.7 0.7 33.2 0.5 99999 99999 99999 99999 340.2 1.2 0.82 0.09 513 18 1280 15 98651 63.6 0.4 40.4 0.6 22.9 0.7 18.2 0.5 99999 99999 99999 99999 282.8 1.0 0.48 0.09 506 18 1199 14 98831 59.7 0.4 40.0 0.6 20.8 0.7 17.2 0.5 99999 99999 99999 99999 277.0 1.0 0.49 0.09 520 19 1187 14 99010 59.6 0.4 40.3 0.6 20.6 0.7 17.6 0.5 99999 99999 99999 99999 277.3 1.0 0.56 0.09 523 19 1189 14 99371 56.2 0.4 38.4 0.6 18.2 0.7 16.3 0.5 99999 99999 99999 99999 272.2 1.0 0.46 0.09 532 20 1179 14 99551 50.8 0.4 99999 99999 19.5 0.7 16.5 0.5 99999 99999 99999 99999 271.7 1.0 0.51 0.09 515 19 1190 14 99731 54.6 0.4 38.9 0.6 17.3 0.7 15.5 0.5 99999 99999 99999 99999 271.1 1.0 0.52 0.09 491 17 1179 14 100090 55.9 0.4 40.2 0.6 17.3 0.7 16.2 0.5 99999 99999 99999 99999 273.9 1.0 0.47 0.09 506 18 1189 14 100271 56.7 0.4 39.5 0.6 18.7 0.7 16.5 0.5 99999 99999 99999 99999 274.0 1.0 0.57 0.09 509 18 1183 14 100451 54.1 0.4 37.3 0.6 18.4 0.7 15.7 0.5 99999 99999 99999 99999 273.0 1.0 0.48 0.09 513 18 1183 14 100811 57.8 0.4 39.0 0.6 19.4 0.7 16.9 0.5 99999 99999 99999 99999 276.9 1.0 0.51 0.08 514 19 1183 14 100991 93.3 0.4 47.6 0.6 34.7 0.7 28.9 0.5 99999 99999 99999 99999 310.2 1.1 0.66 0.08 504 18 1245 14 101171 108.2 0.4 50.2 0.6 41.5 0.7 34.1 0.5 99999 99999 99999 99999 357.0 1.3 1.10 0.09 500 18 1307 15 101531 121.4 0.5 51.7 0.7 45.7 0.7 38.8 0.5 99999 99999 99999 99999 364.4 1.4 0.87 0.09 514 19 1326 15 101711 141.3 0.5 58.4 0.9 54.4 0.7 45.4 0.5 99999 99999 99999 99999 392.0 1.6 0.95 0.09 503 18 1375 16 101890 136.8 0.5 57.4 0.9 52.0 0.7 44.3 0.5 99999 99999 99999 99999 386.3 1.5 0.86 0.09 508 18 1332 16 102251 127.3 0.5 53.9 0.8 48.5 0.7 40.7 0.5 99999 99999 99999 99999 371.3 1.4 0.84 0.09 509 18 1335 16 102431 112.5 0.4 49.1 0.7 41.3 0.7 35.9 0.5 99999 99999 99999 99999 357.4 1.3 1.22 0.09 506 18 1304 15 102611 89.1 0.4 45.5 0.6 32.4 0.7 27.5 0.5 99999 99999 99999 99999 320.7 1.1 0.89 0.09 500 18 1268 15 102971 88.3 0.4 47.9 0.8 32.4 0.7 27.7 0.5 99999 99999 99999 99999 320.9 1.1 0.66 0.09 513 19 1250 14 103151 74.1 0.4 42.4 0.6 27.7 0.7 23.5 0.5 99999 99999 99999 99999 295.2 1.0 0.58 0.08 506 18 1212 14 103331 100.2 0.4 48.4 0.9 38.3 0.7 32.1 0.5 99999 99999 99999 99999 331.6 1.2 0.74 0.08 501 18 1270 14 103691 99.4 0.4 47.5 0.9 37.2 0.7 31.9 0.5 99999 99999 99999 99999 335.7 1.2 0.74 0.08 517 19 1292 14 103871 109.6 0.4 52.5 1.1 41.0 0.7 34.8 0.5 99999 99999 99999 99999 350.3 1.3 0.78 0.08 491 17 99999 99999 104051 111.6 0.4 52.9 1.1 42.3 0.7 35.3 0.5 99999 99999 99999 99999 351.7 1.3 0.75 0.08 514 19 1357 15 104410 121.8 0.5 49.5 0.8 41.9 0.7 42.8 0.5 99999 99999 99999 99999 316.9 1.1 0.80 0.09 516 19 1235 13 104591 237.1 1.0 69.7 2.0 95.1 0.9 94.7 0.7 99999 99999 99999 99999 476.2 2.4 2.76 0.13 531 20 1581 18 104771 239.7 1.0 72.2 2.0 97.9 0.8 96.4 0.7 99999 99999 99999 99999 474.9 2.4 2.77 0.13 524 20 1529 17 105131 270.4 1.2 79.9 2.4 110.6 0.9 111.6 0.9 99999 99999 99999 99999 518.4 3.1 3.42 0.17 501 18 99999 99999