37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 10 10 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 76116 270.4 1.0 99999 99999 99999 99999 116.7 1.4 99999 99999 99999 99999 546.3 6.1 99999 99999 99999 99999 99999 99999 76296 257.7 0.9 85.0 2.8 99999 99999 109.9 1.2 99999 99999 99999 99999 529.6 5.7 99999 99999 99999 99999 99999 99999 76476 253.9 0.8 82.9 2.6 99999 99999 107.9 1.2 99999 99999 99999 99999 529.7 5.7 99999 99999 99999 99999 99999 99999 76836 207.1 0.5 70.8 1.6 99999 99999 80.9 0.9 99999 99999 99999 99999 459.3 4.6 99999 99999 490 24 1508 16 77016 166.5 0.3 63.2 1.1 99999 99999 60.8 0.8 99999 99999 99999 99999 408.1 3.9 99999 99999 510 25 1415 14 77196 139.2 0.2 59.5 0.9 99999 99999 48.6 0.8 99999 99999 99999 99999 371.5 3.4 99999 99999 490 24 1362 14 77556 178.2 0.3 69.3 1.5 99999 99999 66.5 0.8 99999 99999 99999 99999 425.8 4.1 99999 99999 461 23 1471 15 77736 148.4 0.3 99999 99999 99999 99999 53.6 0.8 99999 99999 99999 99999 385.2 3.6 99999 99999 476 23 1402 14 77916 132.4 0.2 99999 99999 99999 99999 47.6 0.8 99999 99999 99999 99999 370.9 3.4 99999 99999 495 24 1393 14 78276 118.9 0.3 99999 99999 99999 99999 41.9 0.7 99999 99999 99999 99999 346.7 3.1 99999 99999 503 24 1355 13 78456 114.5 0.3 99999 99999 99999 99999 40.8 0.7 99999 99999 99999 99999 339.1 3.1 99999 99999 483 24 1351 13 78636 112.0 0.3 99999 99999 99999 99999 40.2 0.7 99999 99999 99999 99999 336.0 3.0 99999 99999 497 24 1330 13 78996 96.8 0.3 99999 99999 99999 99999 32.9 0.7 99999 99999 99999 99999 319.5 2.8 99999 99999 486 24 1312 13 79176 95.7 0.3 99999 99999 99999 99999 33.2 0.7 99999 99999 99999 99999 313.6 2.8 99999 99999 522 25 1306 13 79356 117.6 0.3 99999 99999 99999 99999 42.3 0.7 99999 99999 99999 99999 346.2 3.1 99999 99999 485 24 1351 13 79716 114.5 0.3 99999 99999 99999 99999 40.3 0.7 99999 99999 99999 99999 345.5 3.1 99999 99999 522 25 1352 13 79896 99.0 0.3 99999 99999 99999 99999 34.9 0.7 99999 99999 99999 99999 323.6 2.9 99999 99999 498 24 1308 13 80076 83.2 0.3 48.9 0.6 99999 99999 30.8 0.7 99999 99999 99999 99999 295.6 2.6 99999 99999 514 25 1258 12 80436 34.8 0.5 99999 99999 99999 99999 14.4 0.7 99999 99999 99999 99999 208.8 1.9 99999 99999 527 25 1123 11 80616 54.9 0.4 99999 99999 99999 99999 21.7 0.7 99999 99999 99999 99999 244.5 2.1 99999 99999 519 25 1208 11 80796 86.7 0.3 50.1 0.6 99999 99999 31.9 0.7 99999 99999 99999 99999 298.6 2.6 99999 99999 524 25 1289 12 81336 142.8 0.2 60.1 1.0 99999 99999 51.0 0.7 99999 99999 99999 99999 381.8 3.5 99999 99999 501 24 1436 14 81516 135.9 0.2 58.4 0.9 99999 99999 47.9 0.7 99999 99999 99999 99999 374.9 3.4 99999 99999 516 25 1405 14 81696 137.5 0.2 59.1 0.9 99999 99999 49.3 0.7 99999 99999 99999 99999 373.9 3.4 99999 99999 515 25 1415 14 82056 147.8 0.3 59.4 0.9 99999 99999 53.6 0.7 99999 99999 99999 99999 390.8 3.6 99999 99999 463 23 1452 15 82416 147.2 0.3 59.9 1.0 99999 99999 51.0 0.7 99999 99999 99999 99999 384.9 3.5 99999 99999 488 24 1427 14 82776 148.1 0.3 59.3 0.9 99999 99999 53.0 0.7 99999 99999 99999 99999 386.2 3.5 99999 99999 519 26 1417 14 82956 143.5 0.3 58.4 0.9 99999 99999 50.8 0.7 99999 99999 99999 99999 385.2 3.5 99999 99999 521 26 1412 14 83136 94.5 0.3 48.4 0.6 99999 99999 31.8 0.7 99999 99999 99999 99999 316.9 2.8 99999 99999 551 28 1306 13 83496 106.8 0.3 50.2 0.6 99999 99999 36.7 0.7 99999 99999 99999 99999 333.6 3.0 99999 99999 566 30 1346 13 83856 125.0 0.2 54.1 0.7 99999 99999 43.0 0.7 99999 99999 99999 99999 356.8 3.2 99999 99999 559 29 1371 13 84216 94.5 0.3 47.9 0.6 99999 99999 31.9 0.7 99999 99999 99999 99999 315.4 2.8 99999 99999 536 28 1306 13 84396 107.3 0.3 49.9 0.6 99999 99999 37.9 0.7 99999 99999 99999 99999 333.2 3.0 99999 99999 543 29 1333 13 84576 88.0 0.3 46.6 0.6 99999 99999 30.8 0.7 99999 99999 99999 99999 313.3 2.8 99999 99999 553 29 1288 12 84936 98.1 0.3 48.5 0.6 99999 99999 33.0 0.7 99999 99999 99999 99999 324.3 2.9 99999 99999 520 27 1327 13 85116 100.3 0.3 48.3 0.6 99999 99999 34.8 0.7 99999 99999 99999 99999 325.8 2.9 99999 99999 529 28 1322 13 85296 100.3 0.3 48.1 0.6 99999 99999 35.4 0.7 99999 99999 99999 99999 328.2 2.9 99999 99999 544 29 1315 13 85656 80.7 0.3 44.6 0.6 99999 99999 27.7 0.7 99999 99999 99999 99999 294.4 2.6 99999 99999 528 28 1278 12 85836 78.9 0.3 43.9 0.6 99999 99999 27.6 0.7 99999 99999 99999 99999 288.6 2.5 99999 99999 537 28 1283 12 86016 82.9 0.3 44.7 0.6 99999 99999 29.1 0.7 99999 99999 99999 99999 292.7 2.6 99999 99999 532 28 1273 12 86556 75.5 0.3 43.2 0.6 99999 99999 25.8 0.7 99999 99999 99999 99999 284.3 2.5 99999 99999 532 28 1243 12 86736 106.7 0.3 49.6 0.6 99999 99999 37.1 0.7 99999 99999 99999 99999 340.3 3.0 99999 99999 534 28 1327 13 86916 87.5 0.3 46.1 0.6 99999 99999 30.1 0.7 99999 99999 99999 99999 306.7 2.7 99999 99999 526 27 1296 13 87276 67.3 0.4 40.2 0.6 99999 99999 24.0 0.7 99999 99999 99999 99999 268.6 2.3 99999 99999 553 29 1215 12 87456 35.9 0.5 31.8 0.6 99999 99999 15.0 0.7 99999 99999 99999 99999 216.9 1.9 99999 99999 520 27 1116 11 87636 34.7 0.5 31.1 0.6 99999 99999 15.0 0.7 99999 99999 99999 99999 209.9 1.9 99999 99999 531 27 1113 11 87996 37.9 0.5 32.0 0.6 99999 99999 15.7 0.7 99999 99999 99999 99999 218.7 1.9 99999 99999 541 28 1117 11 88176 37.1 0.5 31.4 0.6 99999 99999 15.3 0.7 99999 99999 99999 99999 217.3 1.9 99999 99999 542 28 1137 11 88356 39.9 0.5 32.3 0.6 99999 99999 15.4 0.7 99999 99999 99999 99999 220.0 1.9 99999 99999 519 27 1139 11 88716 26.8 0.5 28.3 0.6 99999 99999 12.5 0.7 99999 99999 99999 99999 194.3 1.7 99999 99999 540 28 1087 10 88896 27.0 0.5 28.4 0.6 99999 99999 12.5 0.7 99999 99999 99999 99999 201.0 1.8 99999 99999 552 29 1098 11 89076 27.6 0.5 27.8 0.6 99999 99999 11.9 0.7 99999 99999 99999 99999 194.9 1.7 99999 99999 529 27 1100 11 89436 57.2 0.4 35.5 0.6 99999 99999 21.7 0.7 99999 99999 99999 99999 245.8 2.1 99999 99999 586 31 1167 11 89616 87.5 0.3 40.5 0.6 99999 99999 31.1 0.7 99999 99999 99999 99999 292.8 2.5 99999 99999 537 28 1240 12 89796 90.0 0.3 38.6 0.6 99999 99999 30.2 0.7 99999 99999 99999 99999 286.0 2.4 99999 99999 538 28 1210 12 90156 87.8 0.3 40.9 0.6 99999 99999 29.2 0.7 99999 99999 99999 99999 289.5 2.5 99999 99999 555 29 1230 12 90336 57.9 0.4 35.3 0.6 99999 99999 18.4 0.7 99999 99999 99999 99999 243.8 2.1 99999 99999 532 27 1145 11 90516 28.3 0.5 26.4 0.6 99999 99999 9.1 0.8 99999 99999 99999 99999 189.1 1.7 99999 99999 561 29 1092 11 90876 28.6 0.5 28.6 0.6 99999 99999 9.1 0.8 99999 99999 99999 99999 195.7 1.7 99999 99999 545 28 1097 11 91056 21.0 0.6 26.7 0.6 99999 99999 6.3 0.8 99999 99999 99999 99999 179.2 1.6 99999 99999 547 28 1078 11 91236 20.4 0.6 25.3 0.6 99999 99999 6.8 0.8 99999 99999 99999 99999 178.4 1.6 99999 99999 518 26 1073 11 91776 25.4 0.5 28.0 0.6 99999 99999 8.2 0.8 99999 99999 99999 99999 191.1 1.7 99999 99999 510 25 1111 11 91956 27.8 0.5 28.8 0.6 99999 99999 9.8 0.8 99999 99999 99999 99999 195.3 1.7 99999 99999 518 25 1125 11 92136 27.7 0.5 28.1 0.6 99999 99999 10.4 0.8 99999 99999 99999 99999 197.9 1.8 99999 99999 500 24 1119 11 92496 90.6 0.3 46.1 0.6 99999 99999 29.6 0.7 99999 99999 99999 99999 313.8 2.7 99999 99999 475 23 1316 13 92676 94.8 0.3 46.9 0.6 99999 99999 31.1 0.7 99999 99999 99999 99999 324.0 2.8 99999 99999 469 23 1329 13 92856 90.2 0.3 45.9 0.6 99999 99999 29.9 0.7 99999 99999 99999 99999 315.9 2.7 99999 99999 478 23 1320 13 93216 88.6 0.3 46.3 0.6 99999 99999 28.6 0.7 99999 99999 99999 99999 314.6 2.7 99999 99999 495 24 1309 13 93396 75.3 0.3 43.0 0.6 99999 99999 24.8 0.7 99999 99999 99999 99999 296.0 2.5 99999 99999 462 23 1276 13 93576 65.1 0.4 40.2 0.6 99999 99999 20.6 0.7 99999 99999 99999 99999 278.5 2.4 99999 99999 489 24 1245 12 93936 68.4 0.4 42.0 0.6 99999 99999 22.6 0.7 99999 99999 99999 99999 285.9 2.4 99999 99999 525 26 1269 12 94116 63.8 0.4 40.4 0.6 99999 99999 21.4 0.7 99999 99999 99999 99999 277.5 2.4 99999 99999 511 25 1270 12 94296 61.6 0.4 39.6 0.6 99999 99999 20.9 0.7 99999 99999 99999 99999 274.9 2.4 99999 99999 517 25 1244 12 94656 58.5 0.4 39.2 0.6 99999 99999 20.1 0.7 99999 99999 99999 99999 270.2 2.3 99999 99999 497 25 1253 12 94836 57.4 0.4 39.1 0.6 99999 99999 20.0 0.7 99999 99999 99999 99999 269.0 2.3 99999 99999 538 27 1241 12 95016 56.3 0.4 38.5 0.6 99999 99999 20.3 0.7 99999 99999 99999 99999 271.3 2.3 99999 99999 522 26 1238 12 95376 82.2 0.3 43.3 0.6 99999 99999 29.3 0.7 99999 99999 99999 99999 303.9 2.6 99999 99999 526 26 1281 13 95556 105.7 0.3 48.1 0.6 99999 99999 37.3 0.7 99999 99999 99999 99999 342.0 2.9 99999 99999 483 24 1341 13 95736 115.8 0.3 50.9 0.7 99999 99999 39.9 0.7 99999 99999 99999 99999 357.0 3.1 99999 99999 503 25 1386 14 96096 82.5 0.3 42.8 0.6 99999 99999 29.5 0.7 99999 99999 99999 99999 299.4 2.5 99999 99999 508 25 1298 13 96276 95.1 0.3 46.1 0.6 99999 99999 34.2 0.7 99999 99999 99999 99999 319.1 2.7 99999 99999 486 24 1335 13 96456 103.0 0.3 47.7 0.6 99999 99999 37.3 0.7 99999 99999 99999 99999 328.5 2.8 99999 99999 497 25 1357 14 96996 116.5 0.3 50.6 0.7 99999 99999 41.0 0.7 99999 99999 99999 99999 358.1 3.0 99999 99999 503 25 1386 14 97176 116.5 0.3 51.3 0.7 99999 99999 42.1 0.7 99999 99999 99999 99999 356.6 3.0 99999 99999 525 26 1386 14 97356 114.8 0.3 50.4 0.7 99999 99999 41.4 0.7 99999 99999 99999 99999 355.2 3.0 99999 99999 503 25 1393 14 97716 113.8 0.3 50.7 0.7 99999 99999 40.3 0.7 99999 99999 99999 99999 352.8 3.0 99999 99999 526 27 1381 14 97896 111.5 0.3 49.4 0.6 99999 99999 39.6 0.7 99999 99999 99999 99999 350.8 3.0 99999 99999 500 26 1361 14 98076 94.4 0.3 45.9 0.6 99999 99999 33.2 0.7 99999 99999 99999 99999 322.8 2.7 99999 99999 536 28 1322 13 98436 112.0 0.3 50.0 0.7 99999 99999 40.1 0.7 99999 99999 99999 99999 353.2 3.0 99999 99999 525 27 1350 14 98616 112.9 0.3 49.8 0.7 99999 99999 41.1 0.7 99999 99999 99999 99999 360.2 3.0 99999 99999 508 26 1380 14 98796 96.7 0.3 46.5 0.6 99999 99999 34.8 0.7 99999 99999 99999 99999 324.1 2.7 99999 99999 512 26 1305 13 99156 84.4 0.3 43.7 0.6 99999 99999 31.1 0.7 99999 99999 99999 99999 316.9 2.6 99999 99999 506 26 1284 13 99336 32.7 0.5 29.1 0.6 99999 99999 16.6 0.7 99999 99999 99999 99999 209.8 1.8 99999 99999 507 26 1138 11 99516 30.0 0.5 27.8 0.6 99999 99999 16.8 0.7 99999 99999 99999 99999 210.0 1.8 99999 99999 507 26 1135 11 99876 55.2 0.4 37.6 0.6 99999 99999 21.4 0.7 99999 99999 99999 99999 266.4 2.2 99999 99999 525 26 1238 12 100056 57.0 0.4 37.8 0.6 99999 99999 22.3 0.7 99999 99999 99999 99999 270.3 2.2 99999 99999 524 26 1243 12 100236 55.6 0.4 37.5 0.6 99999 99999 21.4 0.7 99999 99999 99999 99999 265.3 2.2 99999 99999 491 25 1244 12 100596 56.5 0.4 37.7 0.6 99999 99999 22.1 0.7 99999 99999 99999 99999 264.3 2.2 99999 99999 543 27 1245 12 100776 51.9 0.4 36.3 0.6 99999 99999 20.8 0.7 99999 99999 99999 99999 258.3 2.2 99999 99999 518 26 1232 12 100956 65.6 0.4 40.0 0.6 99999 99999 24.7 0.7 99999 99999 99999 99999 282.8 2.3 99999 99999 509 25 1283 13 101316 75.6 0.3 41.9 0.6 99999 99999 26.7 0.7 99999 99999 99999 99999 298.3 2.5 99999 99999 528 27 1286 13 101496 76.6 0.3 41.7 0.6 99999 99999 27.3 0.7 99999 99999 99999 99999 298.3 2.5 99999 99999 514 26 1270 13 101676 80.1 0.3 42.6 0.6 99999 99999 29.6 0.7 99999 99999 99999 99999 303.7 2.5 99999 99999 496 26 1283 13 102036 81.2 0.3 43.0 0.6 99999 99999 28.7 0.7 99999 99999 99999 99999 300.5 2.5 99999 99999 549 29 1300 13 102216 80.2 0.3 42.4 0.6 99999 99999 28.6 0.7 99999 99999 99999 99999 305.3 2.5 99999 99999 538 28 1296 13 102396 74.9 0.3 41.8 0.6 99999 99999 27.6 0.7 99999 99999 99999 99999 292.3 2.4 99999 99999 529 28 1292 13 102756 79.7 0.3 43.4 0.6 99999 99999 28.6 0.7 99999 99999 99999 99999 303.6 2.5 99999 99999 514 28 1329 14 102936 111.5 0.3 46.7 0.6 99999 99999 42.0 0.7 99999 99999 99999 99999 341.2 2.9 99999 99999 537 29 1410 15 103116 213.9 0.5 67.3 1.3 99999 99999 86.4 0.9 99999 99999 99999 99999 471.1 4.3 99999 99999 502 27 1604 19 103476 258.3 0.8 78.6 2.1 99999 99999 106.9 1.1 99999 99999 99999 99999 541.3 5.4 99999 99999 471 27 1748 23 103656 267.2 0.9 80.6 2.3 99999 99999 111.9 1.2 99999 99999 99999 99999 549.2 5.5 99999 99999 475 27 1775 24