37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 07 30 1995 05 21 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 72282 263.2 0.9 99.2 3.6 114.4 0.6 109.9 0.5 293.5 2.2 99999 99999 99999 99999 99999 99999 99999 99999 1746 184 72462 257.7 0.9 97.2 3.4 113.3 0.6 108.3 0.4 295.5 2.2 99999 99999 99999 99999 99999 99999 99999 99999 1797 196 72642 243.8 0.8 92.8 3.0 109.5 0.6 100.9 0.4 287.1 2.1 99999 99999 99999 99999 99999 99999 99999 99999 1726 165 73002 244.1 0.8 92.7 3.1 108.9 0.6 100.4 0.4 282.9 2.0 99999 99999 488.0 6.7 99999 99999 521 32 1713 149 73182 226.6 0.7 84.7 2.3 100.3 0.5 92.1 0.3 276.3 1.9 99999 99999 465.3 6.4 99999 99999 431 27 1626 125 73362 210.2 0.7 77.8 1.7 93.5 0.5 84.1 0.3 267.5 1.8 99999 99999 444.5 6.0 99999 99999 458 29 1633 122 73722 168.8 0.5 65.3 1.0 72.7 0.5 63.2 0.3 245.6 1.5 99999 99999 400.7 5.3 99999 99999 475 29 1492 97 73902 160.9 0.5 64.1 1.0 69.4 0.5 59.4 0.3 241.0 1.5 99999 99999 391.2 5.2 99999 99999 509 31 1412 86 74082 157.9 0.5 62.9 0.9 67.0 0.5 58.1 0.3 238.4 1.4 99999 99999 381.4 5.0 99999 99999 497 30 1501 94 74442 162.1 0.5 64.4 1.0 69.3 0.5 59.3 0.3 241.6 1.5 99999 99999 392.5 5.1 99999 99999 477 29 1489 91 74622 154.9 0.5 61.5 0.9 65.7 0.5 56.9 0.3 239.1 1.5 99999 99999 375.0 4.9 99999 99999 452 28 1460 87 74802 152.4 0.5 61.1 0.9 64.9 0.5 56.1 0.3 236.5 1.4 99999 99999 367.6 4.8 99999 99999 536 33 1463 86 75162 154.8 0.5 62.0 0.9 65.9 0.5 57.1 0.3 237.9 1.4 99999 99999 381.0 5.0 99999 99999 520 32 1445 84 75342 159.8 0.5 62.1 0.9 68.6 0.5 59.1 0.3 240.8 1.5 99999 99999 388.5 5.1 99999 99999 438 29 1503 90 75522 116.1 0.4 51.0 0.7 47.6 0.4 39.8 0.3 215.2 1.2 99999 99999 335.2 4.3 99999 99999 481 31 1285 70 75881 106.7 0.4 48.4 0.6 42.9 0.4 35.5 0.3 211.6 1.2 99999 99999 312.0 4.0 99999 99999 507 33 1316 73 76062 98.6 0.4 46.9 0.6 39.2 0.4 32.4 0.3 204.9 1.1 99999 99999 306.3 3.9 99999 99999 574 36 1309 72 76242 93.4 0.4 44.4 0.6 37.0 0.4 29.8 0.3 203.4 1.1 99999 99999 305.5 3.9 99999 99999 548 35 1149 60 76602 91.9 0.4 44.2 0.6 36.1 0.5 30.7 0.3 200.5 1.1 99999 99999 306.9 3.9 99999 99999 563 36 1176 60 76782 94.5 0.4 43.5 0.6 37.5 0.4 30.3 0.3 201.6 1.1 99999 99999 310.7 4.0 99999 99999 515 34 1224 63 76962 98.1 0.4 45.5 0.6 39.4 0.4 32.0 0.3 204.6 1.1 99999 99999 310.2 4.0 99999 99999 484 32 1202 60 77502 91.6 0.4 43.8 0.6 36.9 0.4 30.1 0.3 200.3 1.1 99999 99999 313.9 4.0 99999 99999 505 33 1289 63 77682 91.3 0.4 43.6 0.6 35.3 0.5 29.3 0.3 205.1 1.1 99999 99999 317.4 4.1 99999 99999 562 36 1287 63 77862 90.6 0.4 43.0 0.6 36.0 0.5 29.6 0.3 200.8 1.1 99999 99999 293.7 3.7 99999 99999 566 35 1280 61 78222 79.6 0.4 40.9 0.6 30.6 0.5 24.9 0.3 190.1 1.0 99999 99999 280.9 3.6 99999 99999 474 31 1218 57 78582 85.8 0.4 42.3 0.6 33.5 0.5 27.5 0.3 195.3 1.1 99999 99999 280.7 3.6 99999 99999 477 30 1193 57 78942 85.3 0.4 41.9 0.6 34.7 0.5 27.9 0.3 196.9 1.1 99999 99999 290.8 3.8 99999 99999 520 32 1286 63 79122 64.2 0.4 36.0 0.6 24.2 0.5 18.9 0.3 182.0 1.0 99999 99999 253.1 3.3 99999 99999 497 31 1107 52 79302 62.9 0.4 35.8 0.6 22.4 0.5 18.1 0.3 179.5 1.0 99999 99999 251.6 3.3 99999 99999 472 30 1119 52 79662 63.1 0.4 36.6 0.6 22.5 0.5 18.5 0.3 180.4 1.0 99999 99999 250.0 3.2 99999 99999 489 30 1157 54 80022 67.2 0.4 37.9 0.6 24.7 0.5 19.6 0.3 181.3 1.0 99999 99999 265.8 3.4 99999 99999 503 31 1155 52 80382 66.9 0.4 36.7 0.6 24.5 0.5 19.2 0.3 183.5 1.0 99999 99999 267.5 3.5 99999 99999 500 30 1201 54 80562 71.6 0.4 38.3 0.6 27.0 0.5 20.7 0.3 183.4 1.0 99999 99999 265.0 3.4 99999 99999 456 28 1227 55 80742 71.3 0.4 38.3 0.6 25.7 0.5 21.6 0.3 185.7 1.0 99999 99999 268.4 3.5 99999 99999 482 30 1182 52 81102 75.2 0.4 39.9 0.6 27.9 0.5 22.6 0.3 187.5 1.0 99999 99999 275.9 3.5 99999 99999 508 31 1261 57 81282 71.8 0.4 38.5 0.6 26.7 0.5 20.9 0.3 184.5 1.0 99999 99999 266.7 3.4 99999 99999 499 31 1230 55 81462 70.2 0.4 37.7 0.6 26.7 0.5 20.9 0.3 182.8 1.0 99999 99999 265.1 3.4 99999 99999 499 31 1138 51 81822 55.6 0.4 34.1 0.6 20.0 0.5 15.5 0.3 171.8 0.9 99999 99999 243.5 3.1 99999 99999 501 31 1140 52 82002 64.7 0.4 35.2 0.6 23.2 0.5 19.2 0.3 178.4 1.0 99999 99999 258.8 3.3 99999 99999 510 32 1216 57 82182 61.2 0.4 35.2 0.6 21.4 0.5 17.5 0.3 176.5 0.9 99999 99999 252.5 3.2 99999 99999 498 31 1135 52 82722 55.2 0.4 34.4 0.6 19.3 0.5 15.5 0.3 172.8 0.9 99999 99999 243.2 3.1 99999 99999 504 31 1163 54 82902 51.5 0.4 33.8 0.6 18.0 0.5 14.5 0.3 171.0 0.9 99999 99999 234.8 3.0 99999 99999 483 30 1075 48 83082 54.0 0.4 33.1 0.6 18.9 0.5 14.9 0.3 173.1 0.9 99999 99999 252.7 3.2 99999 99999 485 30 1144 52 83442 69.4 0.4 37.2 0.6 26.0 0.5 21.4 0.3 180.0 1.0 99999 99999 262.4 3.3 99999 99999 516 31 1152 51 83622 62.2 0.4 36.3 0.6 22.6 0.5 18.0 0.3 177.2 0.9 99999 99999 253.2 3.2 99999 99999 504 30 1214 54 83802 52.6 0.4 33.6 0.6 18.8 0.5 14.4 0.3 171.3 0.9 99999 99999 244.8 3.1 99999 99999 448 28 1088 47 84162 64.0 0.4 37.4 0.6 24.3 0.5 18.8 0.3 180.8 1.0 99999 99999 258.7 3.3 99999 99999 475 29 1241 55 84342 61.2 0.4 36.3 0.6 22.9 0.5 17.8 0.3 179.3 1.0 99999 99999 243.9 3.1 99999 99999 472 29 1180 52 84522 58.9 0.4 35.9 0.6 21.6 0.5 16.4 0.3 177.2 0.9 99999 99999 251.4 3.2 99999 99999 468 28 1220 54 84882 59.7 0.4 35.9 0.6 21.5 0.5 16.7 0.3 176.0 0.9 99999 99999 252.7 3.2 99999 99999 495 30 1099 48 85062 63.6 0.4 36.3 0.6 23.0 0.5 17.9 0.3 180.6 1.0 99999 99999 255.6 3.3 99999 99999 492 30 1144 51 85242 65.8 0.4 37.2 0.6 24.6 0.5 19.4 0.3 181.8 1.0 99999 99999 261.3 3.4 99999 99999 456 29 1174 54 85602 70.0 0.4 38.7 0.6 25.5 0.5 20.5 0.3 184.6 1.0 99999 99999 262.5 3.4 99999 99999 498 31 1218 57 85782 68.0 0.4 38.0 0.6 24.8 0.5 19.7 0.3 182.7 1.0 99999 99999 260.4 3.4 99999 99999 502 32 1139 52 85962 73.0 0.4 39.0 0.6 26.5 0.5 21.5 0.3 187.0 1.0 99999 99999 267.4 3.5 99999 99999 506 33 1117 51 86322 65.5 0.4 36.9 0.6 24.0 0.5 18.8 0.3 180.0 1.0 99999 99999 255.4 3.3 99999 99999 475 32 1088 48 86502 99.5 0.4 45.0 0.6 37.9 0.4 31.8 0.3 202.6 1.1 99999 99999 292.0 3.8 99999 99999 535 35 1251 57 86682 156.8 0.5 60.2 0.8 66.8 0.5 57.1 0.3 235.8 1.4 99999 99999 375.5 5.0 99999 99999 526 35 1523 74 87042 213.6 0.7 78.1 1.7 94.5 0.5 84.3 0.3 270.6 1.8 99999 99999 447.6 6.2 99999 99999 521 34 1769 90 87222 200.4 0.7 73.2 1.4 88.3 0.5 78.5 0.3 262.6 1.7 99999 99999 428.6 5.8 99999 99999 505 34 1724 86 87402 173.5 0.6 63.8 0.9 75.4 0.5 65.8 0.3 247.0 1.5 99999 99999 406.5 5.5 99999 99999 520 34 1616 77 87942 93.5 0.4 42.9 0.6 37.0 0.5 30.0 0.3 199.2 1.1 99999 99999 299.1 3.9 99999 99999 485 32 1323 58 88122 58.5 0.4 34.6 0.6 22.2 0.5 17.4 0.3 175.6 0.9 99999 99999 248.0 3.2 99999 99999 519 33 1187 51 88302 48.5 0.4 31.5 0.6 16.4 0.5 12.9 0.3 169.9 0.9 99999 99999 233.6 3.0 99999 99999 487 31 1168 50 88662 47.1 0.4 31.9 0.6 16.2 0.5 12.9 0.3 169.5 0.9 99999 99999 227.5 2.9 99999 99999 487 31 1117 48 88842 46.8 0.4 31.4 0.6 17.2 0.5 13.6 0.3 170.5 0.9 99999 99999 226.8 2.9 99999 99999 475 30 1166 51 89022 47.8 0.4 32.4 0.6 16.9 0.5 13.3 0.3 167.6 0.9 99999 99999 229.7 3.0 99999 99999 505 31 1107 48 89382 50.3 0.4 32.5 0.6 17.3 0.5 13.4 0.3 172.2 0.9 99999 99999 226.0 2.9 99999 99999 462 29 1125 48 89562 48.2 0.4 31.8 0.6 17.0 0.5 13.3 0.3 170.3 0.9 99999 99999 232.0 3.0 99999 99999 474 30 1143 49 89742 52.2 0.4 34.3 0.6 19.5 0.5 14.6 0.3 173.7 0.9 99999 99999 238.2 3.1 99999 99999 473 30 1167 50 90102 60.1 0.4 35.6 0.6 21.7 0.5 17.0 0.3 178.5 1.0 99999 99999 244.7 3.2 99999 99999 465 29 1163 50 90282 58.5 0.4 35.4 0.6 22.3 0.5 16.8 0.3 176.1 0.9 99999 99999 246.6 3.2 99999 99999 496 31 1166 51 90462 58.7 0.4 35.7 0.6 21.7 0.5 16.9 0.3 180.5 1.0 99999 99999 248.2 3.2 99999 99999 481 31 1129 49 90822 61.9 0.4 37.5 0.6 22.8 0.5 17.8 0.3 178.7 1.0 99999 99999 256.2 3.3 99999 99999 506 32 1148 50 91002 64.0 0.4 38.2 0.6 23.1 0.5 17.9 0.3 183.7 1.0 99999 99999 259.4 3.3 99999 99999 495 32 1224 55 91182 66.2 0.4 38.3 0.6 24.4 0.5 18.8 0.3 185.5 1.0 99999 99999 266.8 3.4 99999 99999 489 32 1204 54 91542 68.6 0.4 38.8 0.6 25.0 0.5 20.0 0.3 187.5 1.0 99999 99999 276.5 3.6 99999 99999 510 33 1217 55 91722 69.0 0.4 38.9 0.6 25.4 0.5 19.9 0.3 189.0 1.0 99999 99999 272.5 3.5 99999 99999 487 32 1192 53 91902 64.7 0.4 38.0 0.6 23.8 0.5 18.7 0.3 187.9 1.0 99999 99999 266.9 3.4 99999 99999 473 32 1185 53 92262 65.5 0.4 38.6 0.6 23.5 0.5 17.6 0.3 184.5 1.0 99999 99999 266.5 3.4 99999 99999 559 36 1206 53 92442 64.0 0.4 37.7 0.6 22.7 0.5 17.8 0.3 186.0 1.0 99999 99999 268.7 3.5 99999 99999 495 33 1234 55 92622 66.3 0.4 38.6 0.6 23.6 0.5 18.0 0.3 190.8 1.0 99999 99999 278.2 3.6 99999 99999 507 34 1225 54 93162 62.8 0.4 36.6 0.6 22.7 0.5 17.0 0.3 186.7 1.0 99999 99999 261.3 3.4 99999 99999 513 34 1220 52 93342 59.7 0.4 37.0 0.6 21.3 0.5 16.5 0.3 182.2 1.0 99999 99999 261.7 3.4 99999 99999 526 34 1178 50 93522 60.2 0.4 36.7 0.6 20.9 0.5 16.2 0.3 182.4 1.0 99999 99999 258.6 3.3 99999 99999 475 32 1250 53 93882 58.6 0.4 36.5 0.6 20.6 0.5 16.0 0.3 182.9 1.0 99999 99999 255.0 3.3 99999 99999 485 32 1280 54 94062 47.4 0.4 33.4 0.6 16.2 0.5 12.8 0.3 172.3 0.9 99999 99999 237.9 3.1 99999 99999 504 33 1111 46 94242 49.9 0.4 33.9 0.6 16.7 0.5 12.5 0.3 173.9 0.9 99999 99999 242.8 3.2 99999 99999 520 33 1155 47 94602 46.1 0.4 33.7 0.6 15.7 0.5 11.9 0.4 172.1 0.9 99999 99999 235.6 3.1 99999 99999 495 32 1202 49 94782 48.3 0.4 33.8 0.6 16.2 0.5 12.6 0.3 172.9 0.9 99999 99999 240.7 3.1 99999 99999 480 31 1197 48 94962 44.9 0.4 32.8 0.6 14.7 0.5 11.6 0.4 171.4 0.9 99999 99999 234.6 3.0 99999 99999 473 31 1112 44 95322 41.0 0.4 30.8 0.6 13.5 0.5 10.2 0.4 166.9 0.9 99999 99999 223.0 2.9 99999 99999 513 33 1113 43 95502 40.3 0.5 31.8 0.6 13.0 0.5 10.0 0.4 165.7 0.9 99999 99999 226.6 2.9 99999 99999 506 33 1140 45 95682 39.7 0.5 31.0 0.6 12.5 0.5 9.6 0.4 164.6 0.9 99999 99999 223.4 2.9 99999 99999 501 33 1085 42 96042 40.2 0.5 31.4 0.6 13.2 0.5 10.2 0.4 165.6 0.9 99999 99999 222.2 2.9 99999 99999 508 35 1102 42 96222 40.2 0.5 30.7 0.6 13.2 0.5 10.0 0.4 165.9 0.9 99999 99999 229.9 3.0 99999 99999 541 37 1188 46 96402 41.0 0.4 30.7 0.6 13.1 0.5 10.4 0.4 165.0 0.9 99999 99999 230.0 3.0 99999 99999 549 38 1154 44 96762 40.7 0.4 30.9 0.6 12.7 0.5 9.8 0.4 166.0 0.9 99999 99999 226.3 2.9 99999 99999 520 37 1116 42 96942 40.6 0.4 30.9 0.6 13.7 0.5 10.3 0.4 169.4 0.9 99999 99999 227.9 2.9 99999 99999 547 39 1193 45 97122 38.3 0.5 30.0 0.6 12.5 0.5 9.5 0.4 165.4 0.9 99999 99999 222.2 2.9 99999 99999 588 41 1237 46 97482 34.3 0.5 29.5 0.6 11.0 0.5 8.6 0.4 162.4 0.9 99999 99999 213.4 2.8 99999 99999 564 41 1260 47 97662 35.7 0.5 30.2 0.6 11.2 0.5 8.6 0.4 162.5 0.9 99999 99999 217.5 2.8 99999 99999 552 41 1275 47 97842 42.2 0.4 31.7 0.6 13.9 0.5 11.2 0.4 167.6 0.9 99999 99999 230.4 3.0 99999 99999 581 43 1195 44 98202 71.6 0.4 40.8 0.6 26.3 0.5 20.8 0.3 191.1 1.0 99999 99999 280.0 3.6 99999 99999 584 42 1279 48 98382 75.9 0.4 41.8 0.6 28.5 0.5 21.8 0.3 193.5 1.0 99999 99999 285.4 3.7 99999 99999 536 38 1344 52 98562 86.5 0.4 46.0 0.6 32.5 0.5 25.6 0.3 203.1 1.1 99999 99999 308.9 4.0 99999 99999 524 35 1312 51 98922 79.4 0.4 43.6 0.6 29.7 0.5 22.9 0.3 194.9 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99102 81.4 0.4 44.4 0.6 30.0 0.5 23.0 0.3 193.6 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99282 157.6 0.5 58.7 0.8 66.9 0.5 57.5 0.3 230.3 1.3 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99642 99999 99999 99999 99999 113.9 0.6 110.1 0.4 284.0 1.9 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99822 99999 99999 99999 99999 99999 99999 99999 99999 286.2 2.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999