37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 07 28 1995 05 21 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 72807 260.2 1.1 96.4 3.3 110.7 1.0 107.0 0.7 296.2 3.4 99999 99999 536.3 3.5 99999 99999 99999 99999 99999 99999 72987 252.8 1.0 93.7 3.1 111.2 1.0 103.8 0.7 289.3 3.3 99999 99999 528.6 3.4 99999 99999 99999 99999 99999 99999 73167 224.5 0.9 83.3 2.1 98.6 0.9 89.3 0.6 270.8 3.0 99999 99999 473.7 2.6 99999 99999 99999 99999 1691 51 73527 171.9 0.7 64.1 1.1 75.0 0.7 64.8 0.5 246.5 2.7 99999 99999 413.1 2.0 99999 99999 482 14 1499 41 73707 164.2 0.7 61.8 1.0 71.4 0.6 60.5 0.5 240.4 2.6 99999 99999 398.9 1.9 99999 99999 480 15 1465 40 73887 148.9 0.6 58.0 0.9 64.1 0.6 53.3 0.5 235.0 2.6 99999 99999 379.2 1.7 99999 99999 485 15 1412 38 74247 89.5 0.4 40.3 0.8 37.0 0.4 29.0 0.5 196.7 2.1 99999 99999 293.9 1.2 99999 99999 504 15 1236 31 74427 92.2 0.4 42.0 0.8 37.3 0.4 29.6 0.5 198.2 2.1 99999 99999 299.4 1.2 99999 99999 515 15 1262 32 74607 83.5 0.4 39.9 0.8 33.2 0.3 26.6 0.5 190.8 2.1 99999 99999 286.5 1.2 99999 99999 524 16 1221 31 74967 86.4 0.4 41.1 0.8 34.2 0.3 26.8 0.5 192.3 2.1 99999 99999 290.3 1.2 99999 99999 518 16 1257 33 75147 88.2 0.4 41.4 0.8 34.9 0.3 27.6 0.5 195.7 2.1 99999 99999 297.5 1.2 99999 99999 529 16 1270 33 75327 89.4 0.4 42.2 0.8 35.3 0.3 28.0 0.5 196.6 2.1 99999 99999 295.9 1.2 99999 99999 523 16 1242 32 75687 119.7 0.5 50.2 0.8 48.5 0.4 40.0 0.5 218.2 2.4 99999 99999 336.9 1.4 99999 99999 528 16 1364 37 75867 125.4 0.5 51.0 0.9 53.3 0.5 43.9 0.5 221.4 2.4 99999 99999 353.6 1.5 99999 99999 522 16 1350 37 76047 119.6 0.5 49.0 0.8 49.5 0.4 41.8 0.5 215.4 2.3 99999 99999 338.8 1.5 99999 99999 511 15 1316 36 76407 128.3 0.5 53.2 0.9 54.7 0.5 44.6 0.5 222.6 2.4 99999 99999 350.9 1.5 99999 99999 515 15 1336 37 76587 135.2 0.5 55.2 0.9 57.2 0.5 47.4 0.5 227.4 2.5 99999 99999 361.5 1.6 99999 99999 511 15 1390 39 76767 133.6 0.5 53.5 0.9 56.6 0.5 47.5 0.5 226.8 2.5 99999 99999 361.0 1.6 99999 99999 505 15 1391 39 77127 134.6 0.5 55.1 0.9 56.4 0.5 46.2 0.5 226.7 2.5 99999 99999 359.8 1.6 99999 99999 508 15 1390 40 77307 144.8 0.6 56.6 1.0 62.2 0.5 51.4 0.5 232.5 2.6 99999 99999 374.1 1.7 99999 99999 499 15 1460 43 77487 134.3 0.5 55.2 0.9 57.4 0.5 47.1 0.5 225.6 2.5 99999 99999 359.2 1.6 99999 99999 507 15 1396 40 78027 136.6 0.5 55.8 1.0 58.3 0.5 48.2 0.5 225.3 2.5 99999 99999 359.8 1.6 99999 99999 517 15 1411 41 78207 142.1 0.6 57.0 1.0 59.8 0.5 49.3 0.5 229.0 2.5 99999 99999 370.6 1.7 99999 99999 515 15 1474 44 78387 141.2 0.6 57.3 1.0 60.5 0.5 50.6 0.5 228.6 2.5 99999 99999 371.4 1.7 99999 99999 501 15 1446 43 78747 152.2 0.6 58.7 1.0 65.4 0.6 54.9 0.5 236.0 2.6 99999 99999 385.2 1.8 99999 99999 500 15 1461 43 79107 147.9 0.6 59.4 1.1 63.0 0.6 53.4 0.5 233.8 2.6 99999 99999 379.0 1.7 99999 99999 514 15 1461 44 79467 149.2 0.6 57.4 1.0 63.1 0.6 54.0 0.5 233.9 2.6 99999 99999 378.3 1.7 99999 99999 489 15 1461 44 79647 150.0 0.6 58.3 1.0 64.2 0.6 55.0 0.5 235.5 2.6 99999 99999 379.5 1.7 99999 99999 494 15 1433 43 79827 149.1 0.6 59.9 1.1 63.6 0.6 54.1 0.5 232.7 2.6 99999 99999 379.3 1.7 99999 99999 510 15 1458 44 80187 144.1 0.6 57.2 1.0 61.3 0.5 52.0 0.5 233.1 2.6 99999 99999 370.7 1.7 99999 99999 487 15 1434 43 80547 147.5 0.6 57.3 1.0 62.3 0.5 53.4 0.5 235.0 2.6 99999 99999 378.7 1.7 99999 99999 513 15 1476 45 80907 148.0 0.6 59.7 1.0 64.2 0.6 54.0 0.5 235.2 2.6 99999 99999 375.4 1.7 99999 99999 511 15 99999 99999 81087 147.8 0.6 57.5 1.0 61.9 0.5 54.3 0.5 234.4 2.6 99999 99999 377.7 1.7 99999 99999 488 15 1483 46 81267 133.3 0.5 54.8 0.9 53.6 0.5 47.0 0.5 225.2 2.5 99999 99999 346.4 1.5 99999 99999 507 15 1388 41 81627 89.2 0.4 41.4 0.8 34.9 0.3 27.9 0.5 197.1 2.2 99999 99999 295.2 1.2 99999 99999 491 15 1253 36 81807 87.5 0.4 41.9 0.8 35.0 0.3 28.6 0.5 200.9 2.2 99999 99999 294.2 1.2 99999 99999 489 15 1272 36 81987 88.7 0.4 44.1 0.8 34.0 0.3 27.5 0.5 196.7 2.2 99999 99999 290.4 1.2 99999 99999 493 15 1288 37 82347 95.3 0.4 45.0 0.8 36.8 0.4 30.9 0.5 204.3 2.2 99999 99999 300.2 1.3 99999 99999 497 15 1304 38 82527 96.1 0.4 45.9 0.8 38.6 0.4 31.5 0.5 204.6 2.2 99999 99999 303.3 1.3 99999 99999 504 15 1278 36 82707 100.5 0.4 46.1 0.8 40.4 0.4 33.6 0.5 204.7 2.3 99999 99999 308.8 1.3 99999 99999 473 14 1314 38 83247 104.0 0.4 48.5 0.8 42.0 0.4 35.8 0.5 206.6 2.3 99999 99999 313.6 1.3 99999 99999 473 15 1257 35 83427 102.5 0.4 46.6 0.8 42.6 0.4 34.9 0.5 205.7 2.3 99999 99999 314.1 1.3 99999 99999 490 15 1284 36 83607 98.1 0.4 45.9 0.8 39.7 0.4 33.2 0.5 202.7 2.2 99999 99999 305.0 1.3 99999 99999 510 15 99999 99999 83967 86.5 0.4 42.4 0.8 34.9 0.3 29.0 0.5 196.7 2.2 99999 99999 290.5 1.2 99999 99999 513 15 1275 36 84147 80.6 0.4 41.2 0.8 32.0 0.3 25.2 0.5 192.7 2.1 99999 99999 283.0 1.2 99999 99999 496 15 1206 33 84327 86.8 0.4 43.5 0.8 35.3 0.3 27.6 0.5 195.1 2.2 99999 99999 289.6 1.2 99999 99999 513 15 1253 35 84687 76.2 0.4 39.4 0.8 30.0 0.3 23.2 0.5 190.8 2.1 99999 99999 274.5 1.2 99999 99999 516 15 1197 33 84867 81.0 0.4 40.8 0.8 31.0 0.3 25.0 0.5 194.1 2.1 99999 99999 278.8 1.2 99999 99999 545 16 99999 99999 85047 83.7 0.4 41.4 0.8 32.1 0.3 25.5 0.5 195.0 2.1 99999 99999 283.5 1.2 99999 99999 527 16 1209 34 85407 67.6 0.4 38.4 0.8 25.7 0.3 20.2 0.5 185.4 2.0 99999 99999 263.0 1.1 99999 99999 510 16 1152 32 85587 73.3 0.4 38.7 0.8 29.5 0.3 22.5 0.5 186.9 2.0 99999 99999 270.5 1.1 99999 99999 520 16 1192 34 85767 75.8 0.4 38.1 0.8 28.9 0.3 22.8 0.5 191.6 2.1 99999 99999 270.9 1.1 99999 99999 529 16 1168 33 86127 96.4 0.4 45.1 0.8 39.0 0.4 30.2 0.5 201.0 2.2 99999 99999 302.9 1.3 99999 99999 509 16 1280 37 86307 101.4 0.4 46.3 0.8 40.5 0.4 32.4 0.5 205.2 2.3 99999 99999 307.7 1.3 99999 99999 549 16 1302 38 86487 100.5 0.4 44.1 0.8 40.8 0.4 32.5 0.5 203.0 2.3 99999 99999 309.5 1.3 99999 99999 530 16 1259 36 86847 101.2 0.4 44.4 0.8 39.5 0.4 32.4 0.5 203.9 2.3 99999 99999 306.1 1.3 99999 99999 521 16 1268 37 87027 156.9 0.6 59.5 1.0 66.2 0.6 56.8 0.5 238.4 2.7 99999 99999 385.2 1.8 99999 99999 515 16 1433 43 87207 173.7 0.7 64.7 1.2 75.6 0.6 65.7 0.5 244.5 2.8 99999 99999 405.9 2.0 99999 99999 496 16 1505 47 87567 232.6 0.9 83.1 2.4 104.5 0.9 95.4 0.6 275.3 3.3 99999 99999 494.5 2.9 99999 99999 477 15 1614 52 87747 220.2 0.9 78.9 2.0 98.7 0.8 89.6 0.6 270.1 3.2 99999 99999 477.7 2.7 99999 99999 482 15 1570 50 87927 173.2 0.7 63.6 1.1 76.3 0.7 66.0 0.5 241.7 2.8 99999 99999 407.2 2.0 99999 99999 489 15 1464 45 88467 135.1 0.6 54.6 0.9 56.9 0.5 48.1 0.5 220.6 2.5 99999 99999 356.0 1.6 99999 99999 526 16 1356 40 88647 123.5 0.5 52.4 0.9 50.8 0.4 42.3 0.5 218.6 2.5 99999 99999 341.0 1.5 99999 99999 506 16 1289 38 88827 100.7 0.4 45.6 0.8 40.8 0.4 32.5 0.5 203.3 2.3 99999 99999 308.0 1.3 99999 99999 502 15 1257 37 89187 99.8 0.4 46.6 0.8 40.0 0.4 32.1 0.5 200.8 2.3 99999 99999 310.3 1.3 99999 99999 514 16 1286 38 89367 104.4 0.5 46.3 0.8 41.3 0.4 34.2 0.5 208.9 2.3 99999 99999 314.3 1.4 99999 99999 539 16 1295 38 89547 102.3 0.4 45.9 0.8 41.4 0.4 33.4 0.5 205.5 2.3 99999 99999 314.5 1.4 99999 99999 516 16 1278 38 89907 110.2 0.5 47.7 0.8 44.7 0.4 36.8 0.5 212.5 2.4 99999 99999 322.8 1.4 99999 99999 509 15 1332 40 90087 102.3 0.4 45.3 0.8 41.6 0.4 34.0 0.5 206.2 2.3 99999 99999 312.2 1.4 99999 99999 493 15 1284 38 90267 102.7 0.4 46.2 0.8 42.0 0.4 34.0 0.5 203.2 2.3 99999 99999 312.4 1.4 99999 99999 500 15 1298 39 90627 114.8 0.5 49.2 0.8 47.2 0.4 39.0 0.5 211.2 2.4 99999 99999 328.8 1.4 99999 99999 507 15 1315 40 90807 112.0 0.5 48.8 0.8 47.0 0.4 38.3 0.5 207.1 2.4 99999 99999 331.9 1.5 99999 99999 515 15 1335 41 90987 135.2 0.6 55.1 0.9 56.2 0.5 47.4 0.5 223.7 2.6 99999 99999 359.1 1.6 99999 99999 492 15 1429 45 91347 148.1 0.6 59.3 1.0 64.1 0.5 54.5 0.5 231.4 2.7 99999 99999 378.6 1.8 99999 99999 491 15 1412 45 91527 146.2 0.6 58.1 0.9 63.4 0.5 53.1 0.5 232.6 2.7 99999 99999 377.4 1.8 99999 99999 503 15 1424 45 91707 171.3 0.7 66.7 1.2 72.4 0.6 62.9 0.5 247.3 2.9 99999 99999 405.2 2.0 99999 99999 511 15 1527 50 92067 179.9 0.7 68.3 1.3 78.4 0.7 67.8 0.5 250.6 2.9 99999 99999 423.5 2.1 99999 99999 491 15 1563 52 92247 174.4 0.7 65.8 1.2 75.3 0.6 64.8 0.5 252.0 2.9 99999 99999 416.7 2.1 99999 99999 509 15 1539 50 92427 170.6 0.7 64.5 1.1 73.2 0.6 63.8 0.5 248.3 2.9 99999 99999 408.2 2.0 99999 99999 517 16 1523 49 92787 172.6 0.7 64.9 1.2 74.5 0.6 64.5 0.5 247.5 2.8 99999 99999 409.2 2.0 99999 99999 503 15 1552 51 92967 176.2 0.7 64.9 1.2 75.2 0.6 65.8 0.5 250.0 2.9 99999 99999 414.5 2.1 99999 99999 491 15 1500 48 93147 173.4 0.7 63.1 1.1 74.4 0.6 66.7 0.5 242.6 2.8 99999 99999 412.9 2.0 99999 99999 496 15 1524 49 93687 173.5 0.7 63.8 1.2 75.0 0.6 65.0 0.5 249.3 2.9 99999 99999 412.0 2.0 99999 99999 483 15 1463 46 93867 170.1 0.7 62.5 1.1 73.6 0.6 64.1 0.5 244.3 2.8 99999 99999 410.9 2.0 99999 99999 501 15 1504 48 94047 171.7 0.7 64.7 1.2 73.6 0.6 64.7 0.5 246.8 2.9 99999 99999 410.4 2.0 99999 99999 467 15 1541 51 94407 165.9 0.7 62.8 1.1 70.7 0.6 61.6 0.5 243.2 2.8 99999 99999 399.5 1.9 99999 99999 505 15 1451 46 94587 163.2 0.7 60.9 1.0 68.9 0.6 60.3 0.5 238.7 2.8 99999 99999 397.8 1.9 99999 99999 469 15 1442 46 94767 159.6 0.6 61.2 1.0 68.9 0.6 58.8 0.5 235.0 2.7 99999 99999 394.2 1.9 99999 99999 475 15 1548 52 95127 161.3 0.6 62.1 1.1 68.8 0.6 59.1 0.5 240.3 2.8 99999 99999 395.1 1.9 99999 99999 503 15 1477 48 95307 158.8 0.6 61.9 1.0 67.9 0.6 57.8 0.5 238.7 2.8 99999 99999 393.5 1.9 99999 99999 499 15 1528 51 95487 156.6 0.6 60.7 1.0 66.3 0.6 56.7 0.5 237.9 2.8 99999 99999 389.3 1.9 99999 99999 453 14 1518 50 95847 148.1 0.6 58.0 0.9 63.2 0.5 54.0 0.5 233.5 2.7 99999 99999 379.1 1.8 99999 99999 462 14 1469 48 96027 139.7 0.6 55.8 0.9 58.2 0.5 49.3 0.5 227.4 2.6 99999 99999 368.8 1.7 99999 99999 477 15 1515 50 96207 137.2 0.6 54.8 0.9 56.9 0.5 47.8 0.5 227.8 2.6 99999 99999 363.8 1.7 99999 99999 489 15 1452 47 96567 151.1 0.6 58.3 1.0 64.7 0.6 54.2 0.5 236.0 2.7 99999 99999 384.8 1.8 99999 99999 507 15 1481 49 96747 147.6 0.6 58.2 1.0 62.2 0.5 52.2 0.5 233.0 2.7 99999 99999 378.4 1.8 99999 99999 515 15 1437 47 96927 140.9 0.6 55.3 0.9 59.4 0.5 48.8 0.5 229.3 2.6 99999 99999 370.4 1.7 99999 99999 516 15 1467 48 97287 127.2 0.5 52.2 0.9 52.7 0.5 43.5 0.5 221.6 2.5 99999 99999 352.2 1.6 99999 99999 462 14 1425 46 97467 135.1 0.6 54.5 0.9 56.6 0.5 46.5 0.5 228.0 2.6 99999 99999 362.6 1.7 99999 99999 498 15 1447 47 97647 118.6 0.5 49.5 0.8 48.5 0.4 40.2 0.5 213.0 2.4 99999 99999 332.6 1.5 99999 99999 504 15 1321 41 98007 83.1 0.4 39.7 0.8 31.8 0.3 25.1 0.5 194.2 2.2 99999 99999 284.2 1.3 99999 99999 487 14 1315 41 98187 85.7 0.4 40.5 0.8 33.5 0.3 25.9 0.5 197.7 2.2 99999 99999 288.1 1.3 99999 99999 498 15 1306 41 98367 84.9 0.4 40.2 0.8 32.5 0.3 25.8 0.5 195.5 2.2 99999 99999 286.2 1.3 99999 99999 496 14 1229 38 98727 66.1 0.4 36.3 0.8 24.1 0.3 18.7 0.5 180.1 2.0 99999 99999 258.9 1.2 99999 99999 521 15 1244 39 98907 76.3 0.4 36.7 0.8 28.5 0.3 22.3 0.5 189.1 2.1 99999 99999 266.3 1.2 99999 99999 525 15 1208 37 99087 184.6 0.7 68.2 1.3 80.3 0.7 69.4 0.5 253.7 2.9 99999 99999 425.3 2.2 99999 99999 463 14 1617 57 99447 215.2 0.9 77.2 1.9 95.6 0.8 85.6 0.6 272.7 3.2 99999 99999 468.3 2.6 99999 99999 99999 99999 99999 99999 99627 202.7 0.8 72.6 1.6 90.3 0.8 78.7 0.5 265.8 3.1 99999 99999 452.7 2.5 99999 99999 99999 99999 99999 99999 99807 249.4 1.0 84.9 2.5 110.7 0.9 104.4 0.6 294.2 3.6 99999 99999 523.8 3.4 99999 99999 99999 99999 99999 99999 100167 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999