37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 06 03 1995 05 20 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 72333 257.7 3.4 94.2 2.2 99999 99999 99999 99999 300.7 4.6 99999 99999 511.2 6.5 99999 99999 99999 99999 99999 99999 72513 247.8 3.2 91.7 2.2 99999 99999 99999 99999 293.3 4.5 99999 99999 499.4 6.4 99999 99999 99999 99999 99999 99999 72693 229.9 2.9 86.6 2.3 99999 99999 99999 99999 281.2 4.3 99999 99999 472.1 6.0 99999 99999 99999 99999 99999 99999 73053 122.0 1.6 52.7 2.6 99999 99999 99999 99999 217.2 3.3 99999 99999 325.7 3.9 99999 99999 99999 99999 99999 99999 73233 167.7 2.0 67.5 2.4 99999 99999 99999 99999 244.0 3.7 99999 99999 384.8 4.7 99999 99999 99999 99999 99999 99999 73413 153.6 1.9 62.7 2.5 99999 99999 99999 99999 234.8 3.6 99999 99999 360.4 4.4 99999 99999 99999 99999 99999 99999 73773 123.8 1.6 51.1 2.6 99999 99999 99999 99999 218.3 3.3 99999 99999 324.8 3.9 99999 99999 99999 99999 99999 99999 73953 121.4 1.6 48.8 2.7 99999 99999 99999 99999 218.9 3.3 99999 99999 330.6 4.0 99999 99999 99999 99999 99999 99999 74133 149.7 1.8 56.9 2.5 99999 99999 99999 99999 234.4 3.6 99999 99999 371.6 4.5 99999 99999 99999 99999 99999 99999 74493 153.1 1.8 54.4 2.5 99999 99999 99999 99999 234.7 3.6 99999 99999 384.2 4.7 99999 99999 99999 99999 99999 99999 74673 158.4 1.9 60.6 2.4 99999 99999 99999 99999 239.0 3.7 99999 99999 380.7 4.6 99999 99999 99999 99999 99999 99999 74853 134.7 1.7 55.0 2.4 99999 99999 99999 99999 224.0 3.4 99999 99999 348.9 4.2 99999 99999 99999 99999 99999 99999 75213 130.4 1.6 57.4 2.3 99999 99999 99999 99999 222.2 3.4 99999 99999 351.3 4.2 99999 99999 99999 99999 99999 99999 75393 133.1 1.7 56.9 2.3 99999 99999 99999 99999 223.5 3.4 99999 99999 354.3 4.2 99999 99999 99999 99999 99999 99999 75573 137.6 1.7 57.7 2.3 99999 99999 99999 99999 225.5 3.5 99999 99999 358.6 4.3 99999 99999 99999 99999 99999 99999 75933 151.1 1.8 61.6 2.2 99999 99999 99999 99999 233.1 3.6 99999 99999 375.9 4.5 99999 99999 99999 99999 99999 99999 76113 172.9 2.0 70.5 2.3 99999 99999 99999 99999 247.2 3.8 99999 99999 403.7 4.9 99999 99999 99999 99999 99999 99999 76293 169.7 2.0 63.9 2.2 99999 99999 99999 99999 244.8 3.8 99999 99999 399.8 4.9 99999 99999 99999 99999 99999 99999 76653 152.4 1.8 62.1 2.2 99999 99999 99999 99999 238.1 3.7 99999 99999 384.2 4.7 99999 99999 99999 99999 99999 99999 76833 144.3 1.7 58.3 2.2 99999 99999 99999 99999 231.4 3.6 99999 99999 365.5 4.5 99999 99999 99999 99999 99999 99999 77013 153.2 1.8 59.1 2.2 99999 99999 99999 99999 235.0 3.6 99999 99999 372.4 4.6 99999 99999 99999 99999 99999 99999 77553 144.4 1.7 59.8 2.2 99999 99999 99999 99999 231.8 3.6 99999 99999 361.9 4.4 99999 99999 99999 99999 99999 99999 77733 135.8 1.7 57.2 2.2 99999 99999 99999 99999 222.3 3.4 99999 99999 350.6 4.3 99999 99999 99999 99999 99999 99999 77913 121.9 1.6 54.5 2.2 99999 99999 99999 99999 215.5 3.3 99999 99999 325.8 3.9 99999 99999 99999 99999 99999 99999 78273 100.7 1.5 47.5 2.2 99999 99999 99999 99999 203.3 3.1 99999 99999 300.4 3.6 99999 99999 99999 99999 99999 99999 78633 95.9 1.5 45.2 2.2 99999 99999 99999 99999 202.4 3.1 99999 99999 300.7 3.6 99999 99999 99999 99999 99999 99999 78993 98.4 1.5 44.5 2.2 99999 99999 99999 99999 203.7 3.1 99999 99999 309.0 3.7 99999 99999 99999 99999 99999 99999 79173 99.3 1.5 44.0 2.2 99999 99999 99999 99999 201.9 3.1 99999 99999 310.8 3.7 99999 99999 99999 99999 99999 99999 79353 98.2 1.5 45.4 2.2 99999 99999 99999 99999 203.2 3.1 99999 99999 305.8 3.7 99999 99999 99999 99999 99999 99999 79713 46.7 2.0 27.6 2.4 99999 99999 99999 99999 168.9 2.6 99999 99999 241.4 2.9 99999 99999 99999 99999 99999 99999 80073 51.5 1.9 28.3 2.3 99999 99999 99999 99999 171.9 2.7 99999 99999 240.1 2.9 99999 99999 99999 99999 99999 99999 80433 53.7 1.9 25.4 2.4 99999 99999 99999 99999 173.7 2.7 99999 99999 243.5 2.9 99999 99999 99999 99999 99999 99999 80613 56.5 1.8 29.3 2.3 99999 99999 99999 99999 175.2 2.7 99999 99999 244.2 2.9 99999 99999 99999 99999 99999 99999 80793 56.2 1.8 30.3 2.3 99999 99999 99999 99999 176.6 2.8 99999 99999 247.1 3.0 99999 99999 99999 99999 99999 99999 81153 57.6 1.8 27.7 2.3 99999 99999 99999 99999 178.4 2.8 99999 99999 249.8 3.0 99999 99999 99999 99999 99999 99999 81333 56.4 1.8 26.7 2.3 99999 99999 99999 99999 175.8 2.7 99999 99999 249.1 3.0 99999 99999 99999 99999 99999 99999 81513 50.1 1.9 22.6 2.4 99999 99999 99999 99999 173.8 2.7 99999 99999 240.3 2.9 99999 99999 99999 99999 99999 99999 81873 54.8 1.8 33.4 2.2 99999 99999 99999 99999 178.0 2.8 99999 99999 247.8 3.0 99999 99999 99999 99999 99999 99999 82053 53.6 1.9 27.4 2.3 99999 99999 99999 99999 177.3 2.7 99999 99999 250.7 3.1 99999 99999 99999 99999 99999 99999 82233 61.5 1.7 31.0 2.2 99999 99999 99999 99999 180.4 2.8 99999 99999 256.0 3.1 99999 99999 99999 99999 99999 99999 82773 55.9 1.8 25.8 2.3 99999 99999 99999 99999 180.1 2.8 99999 99999 250.5 3.1 99999 99999 99999 99999 99999 99999 82953 70.0 1.6 30.5 2.2 99999 99999 99999 99999 185.9 2.9 99999 99999 263.1 3.2 99999 99999 99999 99999 99999 99999 83133 88.5 1.5 40.8 2.3 99999 99999 99999 99999 204.4 3.1 99999 99999 298.2 3.7 99999 99999 99999 99999 99999 99999 83493 59.3 1.7 30.2 2.2 99999 99999 99999 99999 178.2 2.7 99999 99999 243.1 3.0 99999 99999 99999 99999 99999 99999 83673 50.5 1.9 21.8 2.3 99999 99999 99999 99999 173.3 2.7 99999 99999 236.8 2.9 99999 99999 99999 99999 99999 99999 83853 52.9 1.9 19.2 2.3 99999 99999 99999 99999 174.5 2.7 99999 99999 240.0 2.9 99999 99999 99999 99999 99999 99999 84213 54.7 1.8 99999 99999 99999 99999 99999 99999 171.5 2.6 99999 99999 246.8 3.0 99999 99999 99999 99999 99999 99999 84393 54.5 1.8 99999 99999 99999 99999 99999 99999 172.5 2.7 99999 99999 240.9 3.0 99999 99999 99999 99999 99999 99999 84573 62.6 1.7 99999 99999 99999 99999 99999 99999 180.5 2.8 99999 99999 256.7 3.2 99999 99999 99999 99999 99999 99999 84933 92.4 1.5 99999 99999 99999 99999 99999 99999 196.2 3.0 99999 99999 294.5 3.6 99999 99999 99999 99999 99999 99999 85113 95.8 1.5 99999 99999 99999 99999 99999 99999 202.4 3.1 99999 99999 289.8 3.6 99999 99999 99999 99999 99999 99999 85293 97.6 1.5 99999 99999 99999 99999 99999 99999 206.6 3.1 99999 99999 297.3 3.7 99999 99999 99999 99999 99999 99999 85653 70.3 1.6 99999 99999 99999 99999 99999 99999 176.3 2.6 99999 99999 250.1 3.1 99999 99999 99999 99999 99999 99999 85833 30.9 2.4 99999 99999 99999 99999 99999 99999 157.7 2.4 99999 99999 203.8 2.5 99999 99999 99999 99999 99999 99999 86013 35.8 2.3 99999 99999 99999 99999 99999 99999 154.5 2.3 99999 99999 210.3 2.6 99999 99999 99999 99999 99999 99999 86373 81.4 1.5 99999 99999 99999 99999 99999 99999 181.9 2.7 99999 99999 280.8 3.4 99999 99999 99999 99999 99999 99999 86553 150.7 1.8 99999 99999 99999 99999 99999 99999 232.4 3.5 99999 99999 374.6 4.7 99999 99999 99999 99999 99999 99999 86733 177.6 2.2 99999 99999 99999 99999 99999 99999 251.2 3.8 99999 99999 396.9 5.0 99999 99999 99999 99999 99999 99999 87093 169.7 2.0 99999 99999 99999 99999 99999 99999 238.2 3.6 99999 99999 392.0 5.0 99999 99999 99999 99999 99999 99999 87273 157.9 1.9 99999 99999 99999 99999 99999 99999 233.2 3.5 99999 99999 363.7 4.6 99999 99999 99999 99999 99999 99999 87453 111.0 1.5 99999 99999 99999 99999 99999 99999 204.9 3.1 99999 99999 307.0 3.8 99999 99999 99999 99999 99999 99999 87993 56.1 1.8 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 235.8 2.9 99999 99999 99999 99999 99999 99999 88173 55.2 1.9 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 242.8 3.0 99999 99999 99999 99999 99999 99999 88353 56.1 1.8 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 235.6 2.9 99999 99999 99999 99999 99999 99999 88713 49.6 2.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 234.9 2.9 99999 99999 99999 99999 99999 99999 88893 47.6 2.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 234.4 2.9 99999 99999 99999 99999 99999 99999 89073 48.0 2.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 226.9 2.8 99999 99999 99999 99999 99999 99999 89433 45.0 2.1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 224.6 2.8 99999 99999 99999 99999 99999 99999 89613 42.5 2.2 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 226.4 2.8 99999 99999 99999 99999 99999 99999 89793 40.9 2.2 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 220.7 2.7 99999 99999 99999 99999 99999 99999 90153 40.6 2.2 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 217.9 2.7 99999 99999 99999 99999 99999 99999 90333 43.7 2.2 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 228.4 2.8 99999 99999 99999 99999 99999 99999 90513 55.0 1.9 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 232.4 2.9 99999 99999 99999 99999 99999 99999 90873 60.1 1.8 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 242.8 3.0 99999 99999 99999 99999 99999 99999 91053 63.2 1.8 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 252.3 3.1 99999 99999 99999 99999 99999 99999 91233 58.7 1.9 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 245.2 3.1 99999 99999 99999 99999 99999 99999 91593 53.1 2.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 240.7 3.0 99999 99999 99999 99999 99999 99999 91773 50.0 2.1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 233.1 2.9 99999 99999 99999 99999 99999 99999 91953 46.5 2.1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 231.0 2.9 99999 99999 99999 99999 99999 99999 92313 43.2 2.2 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 226.9 2.8 99999 99999 99999 99999 99999 99999 92493 40.6 2.3 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 223.2 2.8 99999 99999 99999 99999 99999 99999 92673 38.8 2.4 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 207.4 2.6 99999 99999 99999 99999 99999 99999 93213 36.8 2.4 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 212.6 2.6 99999 99999 99999 99999 99999 99999 93393 36.9 2.4 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 214.0 2.7 99999 99999 99999 99999 99999 99999 93573 38.0 2.4 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 211.6 2.6 99999 99999 99999 99999 99999 99999 93933 34.2 2.5 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 213.8 2.7 99999 99999 99999 99999 99999 99999 94113 34.2 2.5 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 212.5 2.7 99999 99999 99999 99999 99999 99999 94293 38.6 2.4 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 216.8 2.8 99999 99999 99999 99999 99999 99999 94653 49.9 2.1 99999 99999 99999 99999 99999 99999 154.1 2.6 99999 99999 238.3 3.1 99999 99999 99999 99999 99999 99999 94833 52.7 2.1 99999 99999 99999 99999 99999 99999 158.9 2.6 99999 99999 236.0 3.1 99999 99999 99999 99999 99999 99999 95013 47.8 2.2 99999 99999 99999 99999 99999 99999 157.5 2.6 99999 99999 230.9 3.0 99999 99999 99999 99999 99999 99999 95373 35.2 2.5 99999 99999 99999 99999 99999 99999 152.7 2.6 99999 99999 210.1 2.8 99999 99999 99999 99999 99999 99999 95553 49.3 2.2 99999 99999 99999 99999 99999 99999 164.3 2.8 99999 99999 231.8 3.1 99999 99999 99999 99999 99999 99999 95733 51.2 2.1 99999 99999 99999 99999 99999 99999 166.1 2.8 99999 99999 239.0 3.2 99999 99999 99999 99999 99999 99999 96093 65.3 1.9 99999 99999 99999 99999 99999 99999 177.7 3.1 99999 99999 261.0 3.6 99999 99999 99999 99999 99999 99999 96273 55.6 2.1 99999 99999 99999 99999 99999 99999 173.9 3.0 99999 99999 248.7 3.4 99999 99999 99999 99999 99999 99999 96453 51.2 2.2 99999 99999 99999 99999 99999 99999 168.0 3.0 99999 99999 234.9 3.2 99999 99999 99999 99999 99999 99999 96813 41.2 2.4 99999 99999 99999 99999 99999 99999 160.8 2.9 99999 99999 222.8 3.1 99999 99999 99999 99999 99999 99999 96993 41.7 2.4 99999 99999 99999 99999 99999 99999 163.5 3.0 99999 99999 224.2 3.2 99999 99999 99999 99999 99999 99999 97173 42.0 2.4 99999 99999 99999 99999 99999 99999 164.4 3.0 99999 99999 221.6 3.1 99999 99999 99999 99999 99999 99999 97533 53.6 2.2 99999 99999 99999 99999 99999 99999 172.7 3.2 99999 99999 244.9 3.6 99999 99999 99999 99999 99999 99999 97713 61.4 2.0 99999 99999 99999 99999 99999 99999 179.6 3.4 99999 99999 257.2 3.8 99999 99999 99999 99999 99999 99999 97893 62.5 2.0 99999 99999 99999 99999 99999 99999 180.3 3.4 99999 99999 251.4 3.7 99999 99999 99999 99999 99999 99999 98253 59.6 2.1 99999 99999 99999 99999 99999 99999 179.9 3.5 99999 99999 253.4 3.8 99999 99999 99999 99999 99999 99999 98433 70.7 1.9 99999 99999 99999 99999 99999 99999 186.2 3.6 99999 99999 269.2 4.1 99999 99999 99999 99999 99999 99999 98613 130.1 1.5 99999 99999 99999 99999 99999 99999 226.3 4.5 99999 99999 347.0 5.5 99999 99999 99999 99999 99999 99999 98973 99999 99999 99999 99999 99999 99999 99999 99999 250.2 5.2 99999 99999 404.1 6.8 99999 99999 99999 99999 99999 99999 99153 99999 99999 99999 99999 99999 99999 99999 99999 275.7 5.9 99999 99999 452.1 7.9 99999 99999 99999 99999 99999 99999 99333 99999 99999 99999 99999 99999 99999 99999 99999 289.3 6.4 99999 99999 498.4 9.1 99999 99999 99999 99999 99999 99999